Chemical Properties of Trichloromethane (CAS 67-66-3)

Trichloromethane

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InChI
InChI=1S/CHCl3/c2-1(3)4/h1H
InChI Key
HEDRZPFGACZZDS-UHFFFAOYSA-N
Formula
CHCl3
SMILES
ClC(Cl)Cl
Molecular Weight1
119.38
CAS
67-66-3
Other Names
  • CHCl3
  • Chloroform
  • Chloroforme
  • Cloroformio
  • F 20
  • Formyl trichloride
  • Freon 20
  • Methane trichloride
  • Methane, trichloro-
  • Methenyl trichloride
  • Methyl trichloride
  • NCI-C02686
  • NSC 77361
  • R 20
  • R 20 (refrigerant)
  • R-20
  • Rcra waste number U044
  • Trichloormethaan
  • Trichlormethan
  • Trichloroform
  • Triclorometano
  • UN 1888
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Contents

  1. Physical Properties
  2. Temperature Dependent Properties
  3. Pressure Dependent Properties
  4. Datasets
  5. Correlations
  6. Similar Compounds
  7. Mixtures
  8. Sources

Physical Properties

Property Value Unit Source
ω 0.2180 KDB
Δcliquid [-474.00; -473.21] kJ/mol Show Hide
Δcliquid -473.21 kJ/mol NIST
Δcliquid -474.00 ± 8.40 kJ/mol NIST
μ 1.10 debye KDB
EA [0.62; 1.76] eV Show Hide
EA 0.62 ± 0.16 eV NIST
EA 1.76 ± 0.05 eV NIST
Δf -68.58 kJ/mol KDB
Rg 3.1780 KDB
Δfgas [-102.90; -101.30] kJ/mol Show Hide
Δfgas -101.30 kJ/mol KDB
Δfgas -102.90 ± 2.50 kJ/mol NIST
Δfliquid [-134.30; -134.10] kJ/mol Show Hide
Δfliquid -134.10 ± 2.50 kJ/mol NIST
Δfliquid -134.30 kJ/mol NIST
Δfus 7.41 kJ/mol Joback Calculated Property
Δvap [30.50; 31.40] kJ/mol Show Hide
Δvap 31.40 kJ/mol NIST
Δvap 31.32 ± 0.08 kJ/mol NIST
Δvap 31.10 kJ/mol NIST
Δvap 30.50 ± 0.42 kJ/mol NIST
IE [11.30; 11.50] eV Show Hide
IE 11.37 ± 0.02 eV NIST
IE 11.41 ± 0.02 eV NIST
IE 11.30 eV NIST
IE 11.48 eV NIST
IE 11.37 ± 0.02 eV NIST
IE 11.40 eV NIST
IE 11.50 eV NIST
IE 11.42 ± 0.03 eV NIST
IE 11.50 eV NIST
IE 11.48 eV NIST
log10WS [-1.17; -1.17]   Show Hide
log10WS -1.17 Estimat...
log10WS -1.17 Aq. Sol...
logPoct/wat 1.986 Crippen Calculated Property
McVol 61.670 ml/mol McGowan Calculated Property
NFPA Health 2 KDB
Pc [5328.68; 5470.00] kPa Show Hide
Pc 5470.00 kPa KDB
Pc 5328.68 ± 10.13 kPa NIST
Pc 5328.68 ± 6.07 kPa NIST
ρc [458.41; 495.42] kg/m3 Show Hide
ρc 490.64 ± 3.58 kg/m3 NIST
ρc 458.41 ± 2.39 kg/m3 NIST
ρc 495.42 ± 2.39 kg/m3 NIST
Inp [561.00; 630.00]   Show Hide
Inp 617.20 NIST
Inp 619.00 NIST
Inp 628.40 NIST
Inp 625.80 NIST
Inp 621.10 NIST
Inp 618.20 NIST
Inp 614.80 NIST
Inp 607.90 NIST
Inp 604.00 NIST
Inp 606.00 NIST
Inp 604.00 NIST
Inp 606.80 NIST
Inp 610.00 NIST
Inp 604.00 NIST
Inp 608.00 NIST
Inp 602.00 NIST
Inp 582.00 NIST
Inp 609.00 NIST
Inp Outlier 568.00 NIST
Inp 595.20 NIST
Inp 616.00 NIST
Inp 610.00 NIST
Inp 587.00 NIST
Inp 622.00 NIST
Inp 622.00 NIST
Inp 613.00 NIST
Inp 598.00 NIST
Inp 601.00 NIST
Inp 616.00 NIST
Inp 615.00 NIST
Inp 601.00 NIST
Inp 621.70 NIST
Inp 601.00 NIST
Inp 590.00 NIST
Inp 618.00 NIST
Inp 600.00 NIST
Inp Outlier 561.00 NIST
Inp Outlier 569.00 NIST
Inp 630.00 NIST
Inp 605.00 NIST
Inp 615.00 NIST
Inp 601.00 NIST
Inp 615.00 NIST
Inp 618.00 NIST
Inp 618.00 NIST
Inp 600.00 NIST
Inp 588.00 NIST
Inp 601.00 NIST
Inp 616.00 NIST
Inp 609.00 NIST
Inp 617.00 NIST
Inp 609.00 NIST
Inp 609.00 NIST
Inp 611.00 NIST
Inp 629.00 NIST
Inp 609.00 NIST
Inp 603.00 NIST
Inp 620.00 NIST
Inp 618.00 NIST
Inp 609.00 NIST
Inp 601.00 NIST
Inp 601.00 NIST
Inp 603.00 NIST
Inp 605.00 NIST
Inp 620.00 NIST
Inp 609.00 NIST
Inp 611.00 NIST
Inp 601.00 NIST
Inp 606.00 NIST
Inp 603.00 NIST
Inp 609.00 NIST
Inp 616.00 NIST
Inp 595.00 NIST
Inp 605.00 NIST
Inp 605.00 NIST
Inp 598.00 NIST
I [992.00; 1045.00]   Show Hide
I 1037.00 NIST
I 1037.00 NIST
I 1034.00 NIST
I 1030.11 NIST
I 1028.95 NIST
I 1027.69 NIST
I 1026.00 NIST
I 1026.00 NIST
I 1024.00 NIST
I 1021.00 NIST
I 1020.00 NIST
I 1022.00 NIST
I 1026.00 NIST
I 1026.00 NIST
I 1013.00 NIST
I 1028.00 NIST
I 1010.00 NIST
I 1020.00 NIST
I 1021.00 NIST
I 1022.00 NIST
I 1022.00 NIST
I 1018.00 NIST
I 1020.00 NIST
I 1023.00 NIST
I 1022.00 NIST
I Outlier 999.00 NIST
I 1038.00 NIST
I 1010.00 NIST
I Outlier 1045.00 NIST
I 1007.00 NIST
I 1037.00 NIST
I 1037.00 NIST
I 1017.00 NIST
I 1025.00 NIST
I 1015.00 NIST
I 1016.00 NIST
I 1037.00 NIST
I 1037.00 NIST
I 1018.00 NIST
I 1020.00 NIST
I Outlier 992.00 NIST
I 1014.00 NIST
I 1014.00 NIST
I 1000.00 NIST
I 1000.00 NIST
I 1024.00 NIST
I 1037.00 NIST
I 1027.69 NIST
I 1010.00 NIST
I 1024.00 NIST
Tboil [333.95; 335.00] K Show Hide
Tboil 334.32 K KDB
Tboil Outlier 335.00 K The rol...
Tboil 334.10 K Phase d...
Tboil 334.35 K Separat...
Tboil 334.12 K Isobari...
Tboil 334.30 K NIST
Tboil 334.37 ± 0.15 K NIST
Tboil 334.45 ± 0.50 K NIST
Tboil 334.10 ± 0.30 K NIST
Tboil 334.35 ± 0.06 K NIST
Tboil 334.34 ± 0.25 K NIST
Tboil 334.39 ± 0.30 K NIST
Tboil 334.30 ± 0.20 K NIST
Tboil 334.35 ± 0.10 K NIST
Tboil 334.24 ± 0.15 K NIST
Tboil Outlier 333.95 ± 0.40 K NIST
Tboil 334.42 ± 0.35 K NIST
Tboil 334.42 ± 0.30 K NIST
Tboil 334.35 ± 0.30 K NIST
Tboil 334.35 ± 0.30 K NIST
Tboil 334.35 ± 0.30 K NIST
Tboil 334.30 ± 0.20 K NIST
Tboil 334.30 ± 0.50 K NIST
Tboil 334.45 ± 0.50 K NIST
Tboil 334.20 ± 1.00 K NIST
Tboil 334.50 ± 0.20 K NIST
Tboil 334.22 ± 0.50 K NIST
Tboil 334.27 ± 0.30 K NIST
Tboil 334.30 ± 0.25 K NIST
Tboil 334.30 ± 0.50 K NIST
Tboil 334.23 ± 0.06 K NIST
Tboil 334.30 ± 0.30 K NIST
Tboil 334.40 ± 0.50 K NIST
Tboil 334.37 ± 0.20 K NIST
Tboil 334.20 ± 0.30 K NIST
Tboil 334.22 ± 0.20 K NIST
Tboil 334.35 ± 0.30 K NIST
Tboil 334.30 ± 0.50 K NIST
Tboil 334.15 ± 0.50 K NIST
Tboil 334.40 ± 0.30 K NIST
Tboil 334.35 ± 0.20 K NIST
Tboil 334.45 ± 0.60 K NIST
Tc 536.40 K KDB
Tfus [209.50; 212.15] K Show Hide
Tfus 209.50 K KDB
Tfus 209.95 K Aq. Sol...
Tfus 209.73 ± 0.01 K NIST
Tfus 209.64 ± 0.10 K NIST
Tfus 210.15 ± 1.00 K NIST
Tfus 209.61 ± 0.08 K NIST
Tfus 209.65 ± 0.20 K NIST
Tfus 211.05 ± 0.30 K NIST
Tfus 209.50 ± 0.70 K NIST
Tfus 210.00 ± 2.00 K NIST
Tfus 209.65 ± 0.20 K NIST
Tfus 211.59 ± 0.50 K NIST
Tfus 209.90 ± 0.30 K NIST
Tfus Outlier 212.15 ± 1.00 K NIST
Tfus 210.46 ± 0.20 K NIST
Tfus 210.00 ± 2.00 K NIST
Ttriple 209.61 ± 0.20 K NIST
Vc 0.239 m3/kmol KDB
Vm 8.07e-05 m3/mol Excess ...
Zc 0.2931300 KDB
Zra 0.28 KDB

Temperature Dependent Properties

Property Value Unit Temperature (K) Source
Cp,gas [71.18; 82.74] J/mol×K [334.13; 532.11] Show Hide
Cp,gas 71.18 J/mol×K 334.13 Joback Calculated Property
Cp,gas 73.44 J/mol×K 367.13 Joback Calculated Property
Cp,gas 75.56 J/mol×K 400.12 Joback Calculated Property
Cp,gas 77.54 J/mol×K 433.12 Joback Calculated Property
Cp,gas 79.40 J/mol×K 466.12 Joback Calculated Property
Cp,gas 81.13 J/mol×K 499.12 Joback Calculated Property
Cp,gas 82.74 J/mol×K 532.11 Joback Calculated Property
Cp,liquid [113.00; 139.70] J/mol×K [293.00; 303.60] Show Hide
Cp,liquid 116.20 J/mol×K 293.00 NIST
Cp,liquid 115.50 J/mol×K 293.20 NIST
Cp,liquid 117.10 J/mol×K 298.00 NIST
Cp,liquid 114.18 J/mol×K 298.00 NIST
Cp,liquid 113.00 J/mol×K 298.10 NIST
Cp,liquid 114.25 J/mol×K 298.15 NIST
Cp,liquid 115.50 J/mol×K 298.15 NIST
Cp,liquid 113.73 J/mol×K 298.15 NIST
Cp,liquid 114.26 J/mol×K 298.15 NIST
Cp,liquid 113.85 J/mol×K 298.15 NIST
Cp,liquid 115.50 J/mol×K 298.15 NIST
Cp,liquid 114.35 J/mol×K 298.15 NIST
Cp,liquid 114.32 J/mol×K 298.15 NIST
Cp,liquid 113.20 J/mol×K 298.15 NIST
Cp,liquid 113.40 J/mol×K 300.00 NIST
Cp,liquid 116.70 J/mol×K 303.00 NIST
Cp,liquid 114.00 J/mol×K 303.20 NIST
Cp,liquid 139.70 J/mol×K 303.60 NIST
η [0.0004710; 0.0007130] Pa×s [273.15; 318.15] Show Hide
η 0.0007130 Pa×s 273.15 Density...
η 0.0006510 Pa×s 283.15 Density...
η 0.0006000 Pa×s 293.15 Density...
η 0.0005560 Pa×s 298.15 Densiti...
η 0.0005760 Pa×s 298.15 Density...
η 0.0005340 Pa×s 303.15 Densiti...
η 0.0005340 Pa×s 303.15 Densiti...
η 0.0005200 Pa×s 303.15 Studies...
η 0.0005520 Pa×s 303.15 Density...
η 0.0005130 Pa×s 308.15 Densiti...
η 0.0004910 Pa×s 313.15 Densiti...
η 0.0004910 Pa×s 313.15 Densiti...
η 0.0004710 Pa×s 313.15 Studies...
η 0.0005090 Pa×s 313.15 Density...
η 0.0004910 Pa×s 318.15 Density...
ΔfusH [8.80; 8.80] kJ/mol [209.60; 209.60] Show Hide
ΔfusH 8.80 kJ/mol 209.60 NIST
ΔfusH 8.80 kJ/mol 209.60 NIST
ΔvapH [28.90; 35.00] kJ/mol [248.00; 501.00] Show Hide
ΔvapH 31.80 kJ/mol 248.00 NIST
ΔvapH 35.00 kJ/mol 274.50 NIST
ΔvapH 32.50 kJ/mol 296.50 NIST
ΔvapH 30.90 kJ/mol 320.50 NIST
ΔvapH 29.71 kJ/mol 334.30 KDB
ΔvapH 29.24 kJ/mol 334.30 NIST
ΔvapH 30.80 kJ/mol 366.50 NIST
ΔvapH 30.40 kJ/mol 374.50 NIST
ΔvapH 28.90 kJ/mol 445.50 NIST
ΔvapH 30.10 kJ/mol 501.00 NIST
ν [0.0000003; 0.0000004] m2/s [303.15; 313.15] Show Hide
ν 0.0000004 m2/s 303.15 Densiti...
ν 0.0000003 m2/s 313.15 Densiti...
Pvap [32.19; 129.28] kPa [303.15; 342.00] Show Hide
Pvap 32.19 kPa 303.15 Density...
Pvap 32.41 kPa 303.15 Total V...
Pvap 32.19 kPa 303.15 Density...
Pvap 34.81 kPa 305.00 Isobari...
Pvap 42.47 kPa 310.00 Isobari...
Pvap 51.43 kPa 315.00 Isobari...
Pvap 61.85 kPa 320.00 Isobari...
Pvap 73.88 kPa 325.00 Isobari...
Pvap 87.71 kPa 330.00 Isobari...
Pvap 101.30 kPa 334.12 Isobari...
Pvap 101.30 kPa 334.35 Separat...
Pvap 103.50 kPa 335.00 Isobari...
Pvap 121.45 kPa 340.00 Isobari...
Pvap 129.28 kPa 342.00 Isobari...
n0 [1.44100; 1.45000]   [283.15; 303.15] Show Hide
n0 1.45000 283.15 Partial...
n0 1.44710 288.15 Partial...
n0 1.44760 293.15 Solubil...
n0 1.44390 293.15 Partial...
n0 1.44280 298.15 Vapour ...
n0 1.44300 298.15 Liquid-...
n0 1.44200 298.15 Partial...
n0 1.44290 298.15 Study o...
n0 1.44100 303.15 Densiti...
ρl [1429.89; 1498.14] kg/m3 [288.15; 323.15] Show Hide
ρl 1498.08 kg/m3 288.15 Volumet...
ρl 1498.08 kg/m3 288.15 Tempera...
ρl 1491.86 kg/m3 288.15 Densiti...
ρl 1498.08 kg/m3 288.15 Densiti...
ρl 1498.08 kg/m3 288.15 Volumet...
ρl 1498.14 kg/m3 288.15 Volumet...
ρl 1492.31 kg/m3 288.15 Densiti...
ρl 1489.00 kg/m3 293.00 KDB
ρl 1488.70 kg/m3 293.15 Excess ...
ρl 1488.64 kg/m3 293.15 Volumet...
ρl 1488.64 kg/m3 293.15 Densiti...
ρl 1488.64 kg/m3 293.15 Volumet...
ρl 1488.70 kg/m3 293.15 Volumet...
ρl 1488.64 kg/m3 293.15 Tempera...
ρl 1487.63 kg/m3 293.15 Speed o...
ρl 1483.02 kg/m3 293.20 Isobari...
ρl 1478.16 kg/m3 298.15 Speed o...
ρl 1478.75 kg/m3 298.15 Densiti...
ρl 1473.42 kg/m3 298.15 Volumet...
ρl 1479.15 kg/m3 298.15 Volumet...
ρl 1473.43 kg/m3 298.15 Densiti...
ρl 1479.15 kg/m3 298.15 Tempera...
ρl 1479.21 kg/m3 298.15 Volumet...
ρl 1473.16 kg/m3 298.15 Densiti...
ρl 1479.15 kg/m3 298.15 Densiti...
ρl 1479.15 kg/m3 298.15 Volumet...
ρl 1480.34 kg/m3 298.20 The cho...
ρl 1475.30 kg/m3 303.00 Thermo-...
ρl 1475.30 kg/m3 303.00 Thermo-...
ρl 1468.61 kg/m3 303.15 Speed o...
ρl 1469.63 kg/m3 303.15 Volumet...
ρl 1469.61 kg/m3 303.15 Densiti...
ρl 1469.61 kg/m3 303.15 Volumet...
ρl 1469.61 kg/m3 303.15 Volumet...
ρl 1470.50 kg/m3 303.15 Viscosi...
ρl 1469.61 kg/m3 303.15 Tempera...
ρl 1469.16 kg/m3 303.15 Densiti...
ρl 1469.69 kg/m3 303.15 Excess ...
ρl 1470.80 kg/m3 308.00 Thermo-...
ρl 1470.80 kg/m3 308.00 Thermo-...
ρl 1459.00 kg/m3 308.15 Speed o...
ρl 1460.01 kg/m3 308.15 Densiti...
ρl 1454.33 kg/m3 308.15 Volumet...
ρl 1454.33 kg/m3 308.15 Densiti...
ρl 1460.03 kg/m3 308.15 Tempera...
ρl 1460.03 kg/m3 308.15 Volumet...
ρl 1460.03 kg/m3 308.15 Densiti...
ρl 1454.07 kg/m3 308.15 Densiti...
ρl 1460.03 kg/m3 308.15 Volumet...
ρl 1465.80 kg/m3 313.00 Thermo-...
ρl 1465.80 kg/m3 313.00 Thermo-...
ρl 1450.39 kg/m3 313.15 Excess ...
ρl 1450.41 kg/m3 313.15 Volumet...
ρl 1450.41 kg/m3 313.15 Densiti...
ρl 1450.41 kg/m3 313.15 Volumet...
ρl 1450.41 kg/m3 313.15 Tempera...
ρl 1450.39 kg/m3 313.15 Densiti...
ρl 1434.72 kg/m3 318.15 Densiti...
ρl 1440.03 kg/m3 318.15 Densiti...
ρl 1434.97 kg/m3 318.15 Densiti...
ρl 1434.98 kg/m3 318.15 Volumet...
ρl 1429.89 kg/m3 323.15 Excess ...
csound,fluid [916.63; 984.42] m/s [298.15; 318.15] Show Hide
csound,fluid 984.42 m/s 298.15 Speeds ...
csound,fluid 950.45 m/s 308.15 Speeds ...
csound,fluid 916.63 m/s 318.15 Speeds ...
γ [0.03; 0.03] N/m [293.15; 298.20] Show Hide
γ 0.03 N/m 293.15 Investi...
γ 0.03 N/m 298.20 KDB

Pressure Dependent Properties

Property Value Unit Pressure (kPa) Source
Tboil 334.25 K 96.60 Low cos...

Datasets

Viscosity, Pa*s

Fixed Measured
Temperature, K - Liquid Pressure, kPa - Liquid Viscosity, Pa*s - Liquid
303.15 101.30 0.0005
Reference
Fixed Measured
Temperature, K - Liquid Pressure, kPa - Liquid Viscosity, Pa*s - Liquid
303.15 101.30 0.0005
Reference

Correlations

Property Value Unit Temperature (K) Source
Pvap [1.33; 5482.48] kPa [244.65; 536.40] The Yaw... Show Hide
Equationln(Pvp) = A + B/(T + C)
Coefficient A1.43630e+01
Coefficient B-2.83926e+03
Coefficient C-4.29370e+01
Temperature range, min.244.65
Temperature range, max.536.40
Pvap 1.33 kPa 244.65 Calculated Property
Pvap 9.36 kPa 277.07 Calculated Property
Pvap 40.90 kPa 309.48 Calculated Property
Pvap 129.81 kPa 341.90 Calculated Property
Pvap 328.67 kPa 374.32 Calculated Property
Pvap 705.23 kPa 406.73 Calculated Property
Pvap 1335.51 kPa 439.15 Calculated Property
Pvap 2296.22 kPa 471.57 Calculated Property
Pvap 3658.33 kPa 503.98 Calculated Property
Pvap 5482.48 kPa 536.40 Calculated Property
Pvap [0.08; 5628.11] kPa [209.63; 536.40] KDB Vap... Show Hide
Equationln(Pvp) = A + B/T + C*ln(T) + D*T^2
Coefficient A8.11439e+01
Coefficient B-6.35114e+03
Coefficient C-1.00709e+01
Coefficient D9.12761e-06
Temperature range, min.209.63
Temperature range, max.536.40
Pvap 0.08 kPa 209.63 Calculated Property
Pvap 1.54 kPa 245.94 Calculated Property
Pvap 12.69 kPa 282.25 Calculated Property
Pvap 59.51 kPa 318.55 Calculated Property
Pvap 192.92 kPa 354.86 Calculated Property
Pvap 487.71 kPa 391.17 Calculated Property
Pvap 1039.15 kPa 427.48 Calculated Property
Pvap 1965.80 kPa 463.78 Calculated Property
Pvap 3422.90 kPa 500.09 Calculated Property
Pvap 5628.11 kPa 536.40 Calculated Property

Similar Compounds

Methane-d, trichloro-. Dichloromethyl radical. Methane-D2-, dichloro-. Methylene chloride. Trichloromethyl radical. Chloromethylene. Methane, bromodichloro-. Fluorodichloromethane. Carbon Tetrachloride. Chloromethyl radical. Dichloromethylene. Trichloromonofluoromethane. Methane, trichloroiodo-. Chlorofluoromethyl radical. Methane, bromotrichloro-.

Find more compounds similar to Trichloromethane.

Mixtures

Find more mixtures with Trichloromethane.

Sources

Note: Cheméo is only indexing the data, follow the source links to retrieve the latest data. The source is also providing more information like the publication year, authors and more. Take the time to validate and double check the source of the data.
Outlier This icon means that the value is more than 2 standard deviations away from the property mean.