Chemical Properties of Trichloromonofluoromethane (CAS 75-69-4)

InChI

InChI=1S/CCl3F/c2-1(3,4)5

InChI Key

CYRMSUTZVYGINF-UHFFFAOYSA-N

Formula

CCl3F

SMILES

FC(Cl)(Cl)Cl

Molecular Weight¹

137.37

CAS

75-69-4

Other Names

• ARCTON 9
• Algofrene Type 1
• Arcton 11
• CCl3F
• CFCl3
• Chladone 11
• Chlorofluoromethane (CCl3F)
• Daiflon 11
• Daiflon S 1
• Distillex DS6
• Dymel 11
• Electro-CF 11
• F 11
• F 11 (halocarbon)
• F 11B
• FC 11
• FC 11, Halocarbon
• FKW 11
• Fluon 11
• Fluorocarbon 11
• Fluorochloroform
• Fluorotrichloromethane
• Freon 11
• Freon 11A
• Freon MF
• Frigen 11
• Frigen 11A
• Frigen S 11
• Genetron 11
• Genetron 11SBA
• Halon 11
• Isceon 131
• Isotron 11
• Kaltron 11
• Khladon 11
• Ledon 11
• Methane, fluorotrichloro-
• Methane, trichlorofluoro-
• Monofluorotrichloromethane
• Propellant 11
• R 11
• R 11, Halocarbon
• R-11
• REFRIGERANT-11
• Refrigerant 11
• Refrigerant R11
• Trichlorofluorocarbon
• Trichlorofluoromethane
• Trichloromethyl fluoride
• Triclorofluormethane

• ω : Acentric Factor.
• C_p,gas : Ideal gas heat capacity (J/mol×K).
• C_p,liquid : Liquid phase heat capacity (J/mol×K).
• μ : Dipole Moment (debye).
• EA : Electron affinity (eV).
• Δ_fG° : Standard Gibbs free energy of formation (kJ/mol).
• Δ_fH°_gas : Enthalpy of formation at standard conditions (kJ/mol).
• Δ_fusH° : Enthalpy of fusion at standard conditions (kJ/mol).
• Δ_fusH : Enthalpy of fusion at a given temperature (kJ/mol).
• Δ_vapH° : Enthalpy of vaporization at standard conditions (kJ/mol).
• Δ_vapH : Enthalpy of vaporization at a given temperature (kJ/mol).
• IE : Ionization energy (eV).
• log₁₀WS : Log10 of Water solubility in mol/l.
• logP_oct/wat : Octanol/Water partition coefficient.
• McVol : McGowan's characteristic volume (ml/mol).
• P_c : Critical Pressure (kPa).
• P_vap : Vapor pressure (kPa).
• ρ_c : Critical density (kg/m³).
• ρ_l : Liquid Density (kg/m³).
• I_np : Non-polar retention indices.
• I : Polar retention indices.
• Δ_fusS : Entropy of fusion at a given temperature (J/mol×K).
• S°_liquid : Liquid phase molar entropy at standard conditions (J/mol×K).
• γ : Surface Tension (N/m).
• Δ_vapS : Entropy of vaporization at a given temperature (J/mol×K).
• T_boil : Normal Boiling Point Temperature (K).
• T_c : Critical Temperature (K).
• T_fus : Normal melting (fusion) point (K).
• T_triple : Triple Point Temperature (K).
• V_c : Critical Volume (m³/kmol).
• Z_c : Critical Compressibility.
• Z_ra : Rackett Parameter.
• ¹: Molecular weight from the IUPAC atomic weights tables.

Physical Properties

Property	Value	Unit	Source
ω	0.1890		KDB
μ	0.50	debye	KDB
EA	[1.02; 1.10]	eV
EA	1.02	eV	NIST
EA	1.10 ± 0.30	eV	NIST
ΔfG°	-245.50	kJ/mol	KDB
ΔfH°gas	[-290.00; -268.30]	kJ/mol
ΔfH°gas	-284.70	kJ/mol	KDB
ΔfH°gas	-278.00 ± 8.80	kJ/mol	NIST
ΔfH°gas	-268.30 ± 8.40	kJ/mol	NIST
ΔfH°gas	-290.00 ± 20.00	kJ/mol	NIST
ΔfusH°	6.60	kJ/mol	Joback Calculated Property
ΔvapH°	28.86	kJ/mol	Joback Calculated Property
IE	[11.46; 11.90]	eV
IE	11.68 ± 0.13	eV	NIST
IE	11.73 ± 0.02	eV	NIST
IE	Outlier 11.46 ± 0.02	eV	NIST
IE	11.77 ± 0.01	eV	NIST
IE	11.77 ± 0.02	eV	NIST
IE	11.76 ± 0.01	eV	NIST
IE	11.85	eV	NIST
IE	11.90	eV	NIST
log10WS	-2.15		Crippen Calculated Property
logPoct/wat	2.284		Crippen Calculated Property
McVol	63.440	ml/mol	McGowan Calculated Property
Pc	[4370.00; 4466.00]	kPa
Pc	4410.00	kPa	KDB
Pc	4466.00 ± 12.00	kPa	NIST
Pc	4370.00 ± 50.00	kPa	NIST
Pc	4405.73	kPa	NIST
ρc	[553.59; 570.21]	kg/m3
ρc	570.21 ± 0.55	kg/m3	NIST
ρc	553.59 ± 5.54	kg/m3	NIST
ρc	553.59 ± 1.37	kg/m3	NIST
Inp	[460.00; 486.00]
Inp	470.00		NIST
Inp	485.00		NIST
Inp	486.00		NIST
Inp	482.00		NIST
Inp	Outlier 460.00		NIST
Inp	478.00		NIST
Inp	478.00		NIST
Inp	484.00		NIST
Inp	482.00		NIST
Inp	484.00		NIST
Inp	Outlier 460.00		NIST
Inp	484.00		NIST
Inp	470.00		NIST
Inp	486.00		NIST
I	[605.00; 605.00]
I	605.00		NIST
I	605.00		NIST
S°liquid	225.60	J/mol×K	NIST
Tboil	[296.80; 296.92]	K
Tboil	296.90	K	KDB
Tboil	296.90	K	NIST
Tboil	296.80 ± 0.05	K	NIST
Tboil	296.92	K	NIST
Tc	[471.10; 471.20]	K
Tc	471.20	K	KDB
Tc	471.10 ± 0.50	K	NIST
Tc	471.15 ± 0.10	K	NIST
Tc	471.15 ± 0.04	K	NIST
Tc	471.15	K	NIST
Tc	471.15 ± 0.40	K	NIST
Tfus	[162.00; 165.40]	K
Tfus	162.04	K	KDB
Tfus	162.00 ± 2.00	K	NIST
Tfus	162.72 ± 0.01	K	NIST
Tfus	162.70 ± 0.10	K	NIST
Tfus	Outlier 165.40 ± 0.20	K	NIST
Tfus	162.67 ± 0.05	K	NIST
Ttriple	[162.10; 162.70]	K
Ttriple	162.19 ± 0.05	K	NIST
Ttriple	162.69 ± 0.06	K	NIST
Ttriple	162.67 ± 0.06	K	NIST
Ttriple	162.68 ± 0.03	K	NIST
Ttriple	162.65 ± 0.02	K	NIST
Ttriple	162.69 ± 0.03	K	NIST
Ttriple	162.70 ± 0.01	K	NIST
Ttriple	Outlier 162.10 ± 0.20	K	NIST
Ttriple	162.68 ± 0.07	K	NIST
Vc	[0.247; 0.248]	m3/kmol
Vc	0.248	m3/kmol	KDB
Vc	0.247 ± 0.006	m3/kmol	NIST
Zc	0.2791570		KDB
Zra	0.27		KDB

Temperature Dependent Properties

Property	Value	Unit	Temperature (K)	Source
Cp,gas	[80.37; 95.16]	J/mol×K	[330.61; 525.49]
T(K) Ideal gas heat capacity (J/mol×K) 80 85 90 95 350 400 450 500
Cp,gas	80.37	J/mol×K	330.61	Joback Calculated Property
Cp,gas	83.63	J/mol×K	363.09	Joback Calculated Property
Cp,gas	86.55	J/mol×K	395.57	Joback Calculated Property
Cp,gas	89.14	J/mol×K	428.05	Joback Calculated Property
Cp,gas	91.42	J/mol×K	460.53	Joback Calculated Property
Cp,gas	93.42	J/mol×K	493.01	Joback Calculated Property
Cp,gas	95.16	J/mol×K	525.49	Joback Calculated Property
Cp,liquid	[121.55; 126.70]	J/mol×K	[298.15; 303.15]
Cp,liquid	121.55	J/mol×K	298.15	NIST
Cp,liquid	126.70	J/mol×K	298.15	NIST
Cp,liquid	122.50	J/mol×K	303.15	NIST
ΔfusH	[6.89; 7.90]	kJ/mol	[162.68; 165.40]
ΔfusH	6.89	kJ/mol	162.68	NIST
ΔfusH	6.90	kJ/mol	162.70	NIST
ΔfusH	7.90	kJ/mol	165.40	NIST
ΔvapH	[24.70; 28.50]	kJ/mol	[231.00; 446.00]
T(K) Enthalpy of vaporization at a given temperature (kJ/mol) 25 26 27 28 300 400
ΔvapH	28.20	kJ/mol	231.00	NIST
ΔvapH	28.50	kJ/mol	257.00	NIST
ΔvapH	27.30	kJ/mol	265.00	NIST
ΔvapH	27.10	kJ/mol	265.00	NIST
ΔvapH	26.40	kJ/mol	289.00	NIST
ΔvapH	25.20	kJ/mol	290.00	NIST
ΔvapH	25.21	kJ/mol	290.40	NIST
ΔvapH	24.77	kJ/mol	297.10	KDB
ΔvapH	25.60	kJ/mol	329.00	NIST
ΔvapH	24.70	kJ/mol	393.00	NIST
ΔvapH	25.10	kJ/mol	446.00	NIST
ρl	1494.00	kg/m3	290.00	KDB
ΔfusS	[42.38; 47.80]	J/mol×K	[162.68; 165.40]
ΔfusS	42.38	J/mol×K	162.68	NIST
ΔfusS	47.80	J/mol×K	165.40	NIST
γ	0.02	N/m	277.60	KDB
ΔvapS	86.81	J/mol×K	290.40	NIST

Correlations

Property	Value	Unit	Temperature (K)	Source
Pvap	[1.33; 4420.29]	kPa	[214.36; 471.11]	The Yaw...
Equation			ln(Pvp) = A + B/(T + C)
Coefficient A			1.40921e+01
Coefficient B			-2.49136e+03
Coefficient C			-3.38850e+01
Temperature range, min.			214.36
Temperature range, max.			471.11
T(K) Vapor pressure (kPa) 0 1000 2000 3000 4000 300 400
Pvap	1.33	kPa	214.36	Calculated Property
Pvap	8.77	kPa	242.89	Calculated Property
Pvap	36.73	kPa	271.42	Calculated Property
Pvap	113.08	kPa	299.94	Calculated Property
Pvap	280.04	kPa	328.47	Calculated Property
Pvap	590.88	kPa	357.00	Calculated Property
Pvap	1104.49	kPa	385.53	Calculated Property
Pvap	1879.56	kPa	414.05	Calculated Property
Pvap	2969.72	kPa	442.58	Calculated Property
Pvap	4420.29	kPa	471.11	Calculated Property
Pvap	[4.88e-03; 4467.78]	kPa	[162.04; 471.20]	KDB Vap...
Equation			ln(Pvp) = A + B/T + C*ln(T) + D*T^2
Coefficient A			7.72409e+01
Coefficient B			-5.39795e+03
Coefficient C			-9.73971e+00
Coefficient D			1.15758e-05
Temperature range, min.			162.04
Temperature range, max.			471.20
T(K) Vapor pressure (kPa) 0 1000 2000 3000 4000 200 300 400
Pvap	4.88e-03	kPa	162.04	Calculated Property
Pvap	0.29	kPa	196.39	Calculated Property
Pvap	4.33	kPa	230.74	Calculated Property
Pvap	28.32	kPa	265.09	Calculated Property
Pvap	111.85	kPa	299.44	Calculated Property
Pvap	319.38	kPa	333.80	Calculated Property
Pvap	735.39	kPa	368.15	Calculated Property
Pvap	1464.61	kPa	402.50	Calculated Property
Pvap	2643.90	kPa	436.85	Calculated Property
Pvap	4467.78	kPa	471.20	Calculated Property

Similar Compounds

Find more compounds similar to Trichloromonofluoromethane.

Mixtures

• Trichloromonofluoromethane + Water

Sources

• KDB Vapor Pressure Data
• Crippen Method
• Crippen Method
• Hydrogen substitution effect on the solubility of perhalogenated compounds in ionic liquid [bmim][PF6]
• Determination of Henry's Law Constants Using Internal Standards with Benchmark Values
• Joback Method
• KDB
• McGowan Method
• NIST Webbook
• The Yaws Handbook of Vapor Pressure

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