Chemical Properties of Cyclooctane (CAS 292-64-8)

InChI

InChI=1S/C8H16/c1-2-4-6-8-7-5-3-1/h1-8H2

InChI Key

WJTCGQSWYFHTAC-UHFFFAOYSA-N

Formula

C8H16

SMILES

C1CCCCCCC1

Molecular Weight¹

112.21

CAS

292-64-8

Other Names

• 292-64-8
• OCTAMETHYLENE

• ω : Acentric Factor.
• Δ_cH°_liquid : Standard liquid enthalpy of combustion (kJ/mol).
• Δ_cH°_solid : Standard solid enthalpy of combustion (kJ/mol).
• C_p,gas : Ideal gas heat capacity (J/mol×K).
• C_p,liquid : Liquid phase heat capacity (J/mol×K).
• η : Dynamic viscosity (Pa×s).
• Δ_fG° : Standard Gibbs free energy of formation (kJ/mol).
• Δ_c,grossH : Heat of Combustion, Gross form (kJ/mol).
• Δ_c,netH : Heat of Combustion, Net Form (kJ/mol).
• Δ_fH°_gas : Enthalpy of formation at standard conditions (kJ/mol).
• Δ_fH°_liquid : Liquid phase enthalpy of formation at standard conditions (kJ/mol).
• Δ_fusH° : Enthalpy of fusion at standard conditions (kJ/mol).
• Δ_fusH : Enthalpy of fusion at a given temperature (kJ/mol).
• Δ_subH : Enthalpy of sublimation at a given temperature (kJ/mol).
• Δ_vapH° : Enthalpy of vaporization at standard conditions (kJ/mol).
• Δ_vapH : Enthalpy of vaporization at a given temperature (kJ/mol).
• IE : Ionization energy (eV).
• log₁₀WS : Log10 of Water solubility in mol/l.
• logP_oct/wat : Octanol/Water partition coefficient.
• McVol : McGowan's characteristic volume (ml/mol).
• P_c : Critical Pressure (kPa).
• P_vap : Vapor pressure (kPa).
• n₀ : Refractive Index.
• ρ_c : Critical density (kg/m³).
• ρ_l : Liquid Density (kg/m³).
• I_np : Non-polar retention indices.
• I : Polar retention indices.
• Δ_fusS : Entropy of fusion at a given temperature (J/mol×K).
• S°_gas : Molar entropy at standard conditions (J/mol×K).
• S°_liquid : Liquid phase molar entropy at standard conditions (J/mol×K).
• γ : Surface Tension (N/m).
• T_boil : Normal Boiling Point Temperature (K).
• T_boilr : Boiling point at reduced pressure (K).
• T_c : Critical Temperature (K).
• λ : Liquid thermal conductivity (W/m×K).
• T_fus : Normal melting (fusion) point (K).
• T_triple : Triple Point Temperature (K).
• V_c : Critical Volume (m³/kmol).
• Z_c : Critical Compressibility.
• ¹: Molecular weight from the IUPAC atomic weights tables.

Physical Properties

Property	Value	Unit	Source
ω	0.2360		KDB
ΔcH°liquid	[-5265.70; -5265.30]	kJ/mol
ΔcH°liquid	-5265.70 ± 0.90	kJ/mol	NIST
ΔcH°liquid	-5265.30 ± 1.60	kJ/mol	NIST
ΔcH°solid	-5252.60	kJ/mol	NIST
ΔfG°	24.44	kJ/mol	Joback Calculated Property
Δc,grossH	5265.56	kJ/mol	KDB
Δc,netH	4913.690	kJ/mol	KDB
ΔfH°gas	-126.10 ± 1.60	kJ/mol	NIST
ΔfH°liquid	-169.40 ± 1.60	kJ/mol	NIST
ΔfusH°	3.04	kJ/mol	Joback Calculated Property
ΔvapH°	[43.30; 44.70]	kJ/mol
ΔvapH°	43.35 ± 0.21	kJ/mol	NIST
ΔvapH°	43.30 ± 0.20	kJ/mol	NIST
ΔvapH°	44.70	kJ/mol	NIST
ΔvapH°	43.50	kJ/mol	NIST
IE	[9.70; 10.08]	eV
IE	9.75 ± 0.04	eV	NIST
IE	9.82 ± 0.05	eV	NIST
IE	9.75	eV	NIST
IE	9.74 ± 0.05	eV	NIST
IE	Outlier 10.08 ± 0.05	eV	NIST
IE	9.80	eV	NIST
IE	9.70	eV	NIST
log10WS	[-4.15; -4.15]
log10WS	-4.15		Aq. Sol...
log10WS	-4.15		Estimat...
logPoct/wat	3.121		Crippen Calculated Property
McVol	112.720	ml/mol	McGowan Calculated Property
Pc	[3550.00; 3560.00]	kPa
Pc	3560.00	kPa	KDB
Pc	3560.00 ± 40.00	kPa	NIST
Pc	3550.00 ± 40.00	kPa	NIST
Pc	3560.00 ± 40.53	kPa	NIST
ρc	273.80 ± 4.49	kg/m3	NIST
Inp	[908.00; 965.80]
Inp	Outlier 965.80		NIST
Inp	Outlier 963.90		NIST
Inp	911.00		NIST
Inp	912.00		NIST
Inp	928.00		NIST
Inp	929.00		NIST
Inp	Outlier 965.00		NIST
Inp	927.20		NIST
Inp	941.00		NIST
Inp	920.00		NIST
Inp	928.50		NIST
Inp	908.00		NIST
Inp	925.00		NIST
Inp	933.00		NIST
Inp	957.00		NIST
Inp	927.00		NIST
Inp	925.00		NIST
Inp	916.00		NIST
Inp	920.00		NIST
Inp	923.00		NIST
Inp	926.00		NIST
Inp	930.00		NIST
Inp	912.00		NIST
Inp	920.00		NIST
Inp	928.00		NIST
Inp	934.00		NIST
Inp	946.00		NIST
Inp	920.00		NIST
Inp	925.00		NIST
Inp	946.00		NIST
Inp	948.00		NIST
Inp	911.00		NIST
Inp	932.00		NIST
Inp	910.00		NIST
Inp	932.00		NIST
Inp	932.00		NIST
Inp	918.00		NIST
Inp	920.00		NIST
Inp	947.00		NIST
Inp	927.00		NIST
Inp	947.00		NIST
Inp	920.00		NIST
Inp	910.00		NIST
Inp	911.00		NIST
I	[1014.00; 1043.00]
I	1036.00		NIST
I	1023.00		NIST
I	1043.00		NIST
I	1014.00		NIST
I	1036.00		NIST
S°gas	366.80 ± 1.30	J/mol×K	NIST
S°liquid	262.00	J/mol×K	NIST
Tboil	[416.00; 425.15]	K
Tboil	422.00	K	KDB
Tboil	420.80 ± 1.00	K	NIST
Tboil	422.70 ± 1.00	K	NIST
Tboil	424.12 ± 0.30	K	NIST
Tboil	423.30 ± 0.50	K	NIST
Tboil	423.85 ± 0.30	K	NIST
Tboil	425.15 ± 2.00	K	NIST
Tboil	416.00 ± 4.00	K	NIST
Tboil	416.15 ± 5.00	K	NIST
Tboil	423.15 ± 1.00	K	NIST
Tc	[647.20; 674.20]	K
Tc	647.20	K	KDB
Tc	647.50	K	Gas-Liq...
Tc	647.20 ± 0.50	K	NIST
Tc	674.20 ± 0.60	K	NIST
Tc	647.20 ± 0.50	K	NIST
Tfus	[281.75; 287.98]	K
Tfus	287.98	K	KDB
Tfus	287.08	K	Aq. Sol...
Tfus	287.74 ± 0.10	K	NIST
Tfus	287.82 ± 0.10	K	NIST
Tfus	287.50 ± 0.60	K	NIST
Tfus	284.20 ± 5.00	K	NIST
Tfus	281.90 ± 3.00	K	NIST
Tfus	284.90 ± 2.00	K	NIST
Tfus	286.90 ± 1.50	K	NIST
Tfus	281.75 ± 4.00	K	NIST
Tfus	282.90 ± 3.00	K	NIST
Tfus	287.65 ± 0.30	K	NIST
Ttriple	[287.94; 288.00]	K
Ttriple	287.94 ± 0.07	K	NIST
Ttriple	287.98 ± 0.05	K	NIST
Ttriple	287.94 ± 0.05	K	NIST
Ttriple	287.97 ± 0.02	K	NIST
Ttriple	288.00 ± 3.00	K	NIST
Vc	[0.410; 0.411]	m3/kmol
Vc	0.410	m3/kmol	KDB
Vc	0.410	m3/kmol	NIST
Vc	0.411 ± 0.007	m3/kmol	NIST
Zc	0.2712430		KDB

Temperature Dependent Properties

Property	Value	Unit	Temperature (K)	Source
Cp,gas	[210.69; 313.06]	J/mol×K	[415.20; 634.09]
T(K) Ideal gas heat capacity (J/mol×K) 220 240 260 280 300 320 450 500 550 600
Cp,gas	210.69	J/mol×K	415.20	Joback Calculated Property
Cp,gas	230.16	J/mol×K	451.68	Joback Calculated Property
Cp,gas	248.64	J/mol×K	488.16	Joback Calculated Property
Cp,gas	266.16	J/mol×K	524.64	Joback Calculated Property
Cp,gas	282.72	J/mol×K	561.12	Joback Calculated Property
Cp,gas	298.35	J/mol×K	597.61	Joback Calculated Property
Cp,gas	313.06	J/mol×K	634.09	Joback Calculated Property
Cp,liquid	[214.24; 215.78]	J/mol×K	[298.15; 298.15]
T(K) Liquid phase heat capacity (J/mol×K) 214.5 215 215.5
Cp,liquid	215.78	J/mol×K	298.15	NIST
Cp,liquid	215.53	J/mol×K	298.15	NIST
Cp,liquid	215.46	J/mol×K	298.15	NIST
Cp,liquid	214.53	J/mol×K	298.15	NIST
Cp,liquid	214.24	J/mol×K	298.15	NIST
Cp,liquid	215.48	J/mol×K	298.15	NIST
η	[0.0016360; 0.0018026]	Pa×s	[308.15; 313.15]
η	0.0018026	Pa×s	308.15	Viscome...
η	0.0016360	Pa×s	313.15	Viscome...
ΔfusH	[0.48; 6.32]	kJ/mol	[166.50; 288.00]
ΔfusH	6.32	kJ/mol	166.50	NIST
ΔfusH	0.48	kJ/mol	183.80	NIST
ΔfusH	2.41	kJ/mol	288.00	NIST
ΔfusH	2.41	kJ/mol	288.00	NIST
ΔsubH	58.70	kJ/mol	166.00	NIST
ΔvapH	[39.30; 43.30]	kJ/mol	[307.00; 418.00]
T(K) Enthalpy of vaporization at a given temperature (kJ/mol) 39 40 41 42 43 350 400
ΔvapH	43.10	kJ/mol	307.00	NIST
ΔvapH	43.30	kJ/mol	329.00	NIST
ΔvapH	40.30	kJ/mol	385.50	NIST
ΔvapH	39.30	kJ/mol	403.50	NIST
ΔvapH	39.40	kJ/mol	418.00	NIST
n0	[1.44877; 1.45630]		[298.15; 313.15]
T(K) Refractive Index 1.45 1.45 1.45 1.46 300 305 310
n0	1.45630		298.15	KDB
n0	1.45624		298.15	Liquid ...
n0	1.45598		298.15	Experim...
n0	1.45598		298.15	Separat...
n0	1.45598		298.15	(Liquid...
n0	1.45598		298.15	Liquid ...
n0	1.45598		298.15	Extract...
n0	1.45598		298.15	Liquid ...
n0	1.45598		298.15	Density...
n0	1.45598		298.15	Density...
n0	1.44877		313.15	Density...
ρl	[831.47; 834.00]	kg/m3	[293.00; 298.15]
ρl	834.00	kg/m3	293.00	KDB
ρl	831.47	kg/m3	298.15	Evaluat...
ρl	831.87	kg/m3	298.15	Thermod...
ΔfusS	[2.60; 37.94]	J/mol×K	[166.50; 288.00]
ΔfusS	37.94	J/mol×K	166.50	NIST
ΔfusS	2.60	J/mol×K	183.80	NIST
ΔfusS	8.35	J/mol×K	288.00	NIST
γ	0.03	N/m	293.20	KDB
λ	[0.11; 0.12]	W/m×K	[288.70; 329.43]
T(K) Liquid thermal conductivity (W/m×K) 0.11 0.11 0.12 0.12 0.12 300 320
λ	0.12	W/m×K	288.70	Thermal...
λ	0.12	W/m×K	288.96	Thermal...
λ	0.12	W/m×K	289.17	Thermal...
λ	0.12	W/m×K	295.85	Thermal...
λ	0.12	W/m×K	295.88	Thermal...
λ	0.12	W/m×K	296.09	Thermal...
λ	0.12	W/m×K	296.21	Thermal...
λ	0.12	W/m×K	311.67	Thermal...
λ	0.12	W/m×K	311.88	Thermal...
λ	0.12	W/m×K	312.10	Thermal...
λ	0.11	W/m×K	328.99	Thermal...
λ	0.11	W/m×K	329.22	Thermal...
λ	0.11	W/m×K	329.43	Thermal...

Pressure Dependent Properties

Property	Value	Unit	Pressure (kPa)	Source
Tboilr	[421.70; 424.20]	K	[98.70; 99.90]
Tboilr	424.20	K	98.70	NIST
Tboilr	421.70	K	99.90	NIST

Datasets

Mass density, kg/m3

Fixed		Measured
Pressure, kPa - Liquid	Temperature, K - Liquid	Mass density, kg/m3 - Liquid
100.00	298.15	831.61
Reference

Correlations

Property	Value	Unit	Temperature (K)	Source
Pvap	[0.99; 202.65]	kPa	[303.15; 445.51]	The Yaw...
Equation			ln(Pvp) = A + B/(T + C)
Coefficient A			1.45798e+01
Coefficient B			-3.61720e+03
Coefficient C			-5.52360e+01
Temperature range, min.			303.15
Temperature range, max.			445.51
T(K) Vapor pressure (kPa) 0 50 100 150 200 300 350 400
Pvap	0.99	kPa	303.15	Calculated Property
Pvap	2.37	kPa	318.97	Calculated Property
Pvap	5.16	kPa	334.79	Calculated Property
Pvap	10.31	kPa	350.60	Calculated Property
Pvap	19.22	kPa	366.42	Calculated Property
Pvap	33.72	kPa	382.24	Calculated Property
Pvap	56.18	kPa	398.06	Calculated Property
Pvap	89.47	kPa	413.87	Calculated Property
Pvap	137.00	kPa	429.69	Calculated Property
Pvap	202.65	kPa	445.51	Calculated Property
Pvap	[17.98; 3564.09]	kPa	[367.00; 647.20]	KDB Vap...
Equation			ln(Pvp) = A + B/T + C*ln(T) + D*T^2
Coefficient A			7.82856e+01
Coefficient B			-7.74858e+03
Coefficient C			-9.30682e+00
Coefficient D			5.02648e-06
Temperature range, min.			367.00
Temperature range, max.			647.20
T(K) Vapor pressure (kPa) 0 500 1000 1500 2000 2500 3000 3500 400 500 600
Pvap	17.98	kPa	367.00	Calculated Property
Pvap	49.50	kPa	398.13	Calculated Property
Pvap	114.70	kPa	429.27	Calculated Property
Pvap	232.89	kPa	460.40	Calculated Property
Pvap	426.91	kPa	491.53	Calculated Property
Pvap	722.50	kPa	522.67	Calculated Property
Pvap	1148.39	kPa	553.80	Calculated Property
Pvap	1737.15	kPa	584.93	Calculated Property
Pvap	2526.94	kPa	616.07	Calculated Property
Pvap	3564.09	kPa	647.20	Calculated Property

Similar Compounds

Find more compounds similar to Cyclooctane.

Mixtures

• Benzene + Cyclooctane
• Toluene + Cyclooctane
• Cyclooctane + Ethylbenzene
• Cyclooctane + Heptane
• 2-Pyrrolidinone, 1-methyl- + Cyclooctane
• Cyclooctane + Ethanol, 2,2'-oxybis-
• Cyclooctane + Triethylene glycol
• Cyclooctane + Benzyl nitrile
• Cyclooctane + Benzene, fluoro-
• Cyclooctane + Benzene, chloro-
• Benzene, 1,2-dichloro- + Cyclooctane
• Cyclooctane + Benzene, 1,3-dichloro-
• Cyclooctane + N,N-Dimethylacetamide
• Cyclooctane + o-Xylene
• Cyclooctane + Benzene, 1,3-dimethyl-
• p-Xylene + Cyclooctane
• Cyclooctane + Mesitylene
• Cyclooctane + Tetramethylammonium chloride + Glycerin
• Cyclooctane + Dimethyl Sulfoxide
• Hexadecane + Cyclooctane

Find more mixtures with Cyclooctane.

Sources

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• Activity coefficients at infinite dilution and physicochemical properties for organic solutes and water in the ionic liquid 1-(2-methoxyethyl)-1-methylpiperidinium bis(trifluoromethylsulfonyl)-amide
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• Activity coefficients at infinite dilution and physicochemical properties for organic solutes and water in the ionic liquid 1-(2-methoxyethyl)-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)-amide
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• Activity coefficients at infinite dilution of organic solutes in N-formylmorpholine and N-methylpyrrolidone from gas-liquid chromatography
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• Thermodynamics and activity coefficients at infinite dilution for organic solutes and water in the ionic liquid 1-butyl-1-methylmorpholinium tricyanomethanide
• The study of activity coefficients at infinite dilution for organic solutes and water in 1-butyl-4-methylpyridinium dicyanamide, [B4MPy][DCA] using GLC
• Measurement of activity coefficients at infinite dilution of organic solutes in the ionic liquid 1-ethyl-3-methylimidazolium 2-(2-methoxyethoxy) ethylsulfate at T = (308.15, 313.15, 323.15 and 333.15) K using gas + liquid chromatography
• Measurement of activity coefficients at infinite dilution of organic solutes in the ionic liquid 1-hexyl-1,4-diaza[2.2.2]bicyclooctanium bis(trifluoromethylsulfonyl)imide using gas-liquid chromatography
• Thermodynamics and activity coefficients at infinite dilution for organic solutes, water and diols in the ionic liquid choline bis(trifluoromethylsulfonyl)imide
• Thermodynamics of solvation in propylene glycol and methyl cellosolve
• Activity coefficients at infinite dilution and physicochemical properties for organic solutes and water in the ionic liquid 4-(3-hydroxypropyl)-4-methylmorpholinium bis(trifluoromethylsulfonyl)-amide
• Activity coefficients at infinite dilution for organic solutes and water in 1-ethyl-1-methylpyrrolidinium lactate
• Activity coefficients at infinite dilution, physicochemical and thermodynamic properties for organic solutes and water in the ionic liquid ethyl-dimethyl-(2-methoxyethyl)ammonium trifluorotris-(perfluoroethyl)phosphate
• Screening of environmental friendly ionic liquid as a solvent for the different types of separations problem: Insight from activity coefficients at infinite dilution measurement using (gas + liquid) chromatography technique
• A 1-alkylcyanopyridinium-based ionic liquid in the separation processes
• Thermodynamics and selectivity of separation based on activity coefficients at infinite dilution of various solutes in 1-allyl-3-methylimidazolium bis{(trifluoromethyl)sulfonyl}imide ionic liquid
• Separation of aliphatic from aromatic hydrocarbons and sulphur compounds from fuel based on measurements of activity coefficients at infinite dilution for organic solutes and water in the ionic liquid N,N-diethyl-N-methyl-N-(2-methoxy-ethyl)ammonium bis(trifluoromethylsulfonyl)imide
• Thermodynamics and limiting activity coefficients measurements for organic solutes and water in the ionic liquid 1-dodecyl-3-methylimidzolium bis(trifluoromethylsulfonyl) imide
• Separation of binary mixtures hexane/hex-1-ene, cyclohexane/cyclohexene and ethylbenzene/styrene based on limiting activity coefficients
• Thermodynamics of mixtures containing aromatic nitriles
• Separation of water/butan-1-ol based on activity coefficients at infinite dilution in 1,3-didecyl-2-methylimidazolium dicyanamide ionic liquid
• Separation of binary mixtures hexane/hex-1-ene, cyclohexane/cyclohexene and ethylbenzene/styrene based on gamma infinity data measurements
• Activity coefficients at infinite dilution and physicochemical properties for organic solutes and water in the ionic liquid trihexyl-tetradecyl-phosphonium tricyanomethanide
• Thermodynamic study of molecular interaction-selectivity in separation processes based on limiting activity coefficients
• The use of ionic liquids for separation of binary hydrocarbons mixtures based on gamma infinity data measurements
• Separation of (water/butan-1-ol) binary systems based on activity coefficients at infinite dilution with phosphonium ionic liquid
• Activity Coefficients at Infinite Dilution of Organic Solutes and Water in Tributylethylphosphonium Diethylphosphate Using Gas Liquid Chromatography: Thermodynamic Properties of Mixtures Containing Ionic Liquids
• The Critical Temperatures of a Number of (i) (Chloroalkane (C3 C4) + Hydrocarbon (C6 C7)) Binary Mixtures and (ii) (Aromatic Halocarbon (Chlorobenzene, Fluorobenzene, 1,2-Dichlorobenzene, or 1,3-Dichlorobenzene) + Alkane (C8)) Binary Mixtures
• Activity Coefficients at Infinite Dilution of Various Solutes in Tetrapropylammonium Bromide + 1,6-Hexanediol Deep Eutectic Solvent
• Assessment of Pyrrolidinium-Based Ionic Liquid for the Separation of Binary Mixtures Based on Activity Coefficients at Infinite Dilution
• Liquid-Liquid Equilibria for the Binary Systems of N-Formylmorpholine with Cycloalkanes
• Activity Coefficients at Infinite Dilution of Organic Solutes in 1-Hexyl-3-methylimidazolium Hexafluorophosphate from Gas-Liquid Chromatography
• Gas-Liquid Critical Temperatures of Some Alkenes, Amines, and Cyclic Hydrocarbons
• Thermal Conductivity and Thermal Diffusivity of Twenty-Nine Liquids: Alkenes, Cyclic (Alkanes, Alkenes, Alkadienes, Aromatics), and Deuterated Hydrocarbons
• Determination of Activity Coefficients at Infinite Dilution of Polar and Nonpolar Solutes in the Ionic Liquid 1-Ethyl-3-methyl- imidazolium Bis(trifluoromethylsulfonyl) Imidate Using Gas-Liquid Chromatography at the Temperature 303.15 K or 318.15 K
• Liquid-Liquid Equilibria for the Binary Systems of Sulfolane with Cycloalkanes
• Activity Coefficients at Infinite Dilution Measurements for Organic Solutes and Water in the Ionic Liquid 1-Butyl-3-methyl-pyridinium Trifluoromethanesulfonate
• Determination of Activity Coefficients at Infinite Dilution of 35 Solutes in the Ionic Liquid, 1-Butyl-3-methylimidazolium Tosylate, Using Gas-Liquid Chromatography
• Liquid Extraction of Benzene from Its Mixtures Using 1-Ethyl-3-methylimidazolium Ethylsulfate as a Solvent
• Measurements of Activity Coefficients at Infinite Dilution for Organic Solutes and Water in the Ionic Liquid 1-Butyl-1-methylpiperydinium Thiocyanate
• Extraction of Benzene from Aliphatic Compounds Using Commercial Ionic Liquids as Solvents: Study of the Liquid Liquid Equilibrium at T = 298.15 K
• Liquid Liquid Extraction of Aromatic Compounds from Cycloalkanes Using 1-Butyl-3-methylimidazolium Methylsulfate Ionic Liquid
• Thermodynamics of Mixtures Containing a Very Strongly Polar Compound. 10. Liquid Liquid Equilibria for N,N-Dimethylacetamide + Selected Alkanes
• Density, Speed of Sound, and Refractive Index of the Binary Systems Cyclohexane (1) or Methylcyclohexane (1) or Cyclo-octane (1) with Benzene (2), Toluene (2), and Ethylbenzene (2) at Two Temperatures
• Activity Coefficients at Infinite Dilution Measurements for Organic Solutes and Water in the Ionic Liquid 1-Hexyl-3-methylimidazolium Thiocyanate
• Density, Speed of Sound, and Refractive Index for Binary Mixtures Containing Cycloalkanes with o-Xylene, m-Xylene, p-Xylene, and Mesitylene at T = (298.15 and 313.15) K
• Joback Method
• KDB
• Aqueous Solubility Prediction Method
• Estimated Solubility Method
• McGowan Method
• NIST Webbook
• The Yaws Handbook of Vapor Pressure

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