Chemical Properties of D-Mannitol (CAS 69-65-8)

InChI

InChI=1S/C6H14O6/c7-1-3(9)5(11)6(12)4(10)2-8/h3-12H,1-2H2/t3-,4-,5-,6-/m1/s1

InChI Key

FBPFZTCFMRRESA-KVTDHHQDSA-N

Formula

C6H14O6

SMILES

OCC(O)C(O)C(O)C(O)CO

Molecular Weight¹

182.17

CAS

69-65-8

Other Names

• 1,2,3,4,5,6-Hexanehexol
• CORDYCEPIC ACID
• D-(-)-Mannitol
• DIOSMOL
• Isotol
• MANNITOL
• Manicol
• Maniton-S
• Manna sugar
• Mannazucker
• Mannazucker (German)
• Mannidex
• Mannigen
• Mannistol
• Mannit
• Mannite
• Mannitol, D-
• Mannogem 2080
• Marine Crystal
• NCI-C50362
• Osmitrol
• Osmosal
• Partek M
• Pearlitol 25C
• Resectisol

• Δ_cH°_solid : Standard solid enthalpy of combustion (kJ/mol).
• C_p,gas : Ideal gas heat capacity (J/mol×K).
• C_p,solid : Solid phase heat capacity (J/mol×K).
• η : Dynamic viscosity (Pa×s).
• Δ_fG° : Standard Gibbs free energy of formation (kJ/mol).
• Δ_fH°_gas : Enthalpy of formation at standard conditions (kJ/mol).
• Δ_fH°_solid : Solid phase enthalpy of formation at standard conditions (kJ/mol).
• Δ_fusH° : Enthalpy of fusion at standard conditions (kJ/mol).
• Δ_fusH : Enthalpy of fusion at a given temperature (kJ/mol).
• Δ_subH° : Enthalpy of sublimation at standard conditions (kJ/mol).
• Δ_vapH° : Enthalpy of vaporization at standard conditions (kJ/mol).
• Δ_vapH : Enthalpy of vaporization at a given temperature (kJ/mol).
• log₁₀WS : Log10 of Water solubility in mol/l.
• logP_oct/wat : Octanol/Water partition coefficient.
• McVol : McGowan's characteristic volume (ml/mol).
• P_c : Critical Pressure (kPa).
• Δ_fusS : Entropy of fusion at a given temperature (J/mol×K).
• S°_{solid,1 bar} : Solid phase molar entropy at standard conditions (J/mol×K).
• T_boil : Normal Boiling Point Temperature (K).
• T_boilr : Boiling point at reduced pressure (K).
• T_c : Critical Temperature (K).
• T_fus : Normal melting (fusion) point (K).
• V_c : Critical Volume (m³/kmol).
• ¹: Molecular weight from the IUPAC atomic weights tables.

Physical Properties

Property	Value	Unit	Source
ΔcH°solid	[-3053.00; -3024.70]	kJ/mol
ΔcH°solid	-3053.00	kJ/mol	NIST
ΔcH°solid	-3045.70	kJ/mol	NIST
ΔcH°solid	-3025.00 ± 2.00	kJ/mol	NIST
ΔcH°solid	-3024.70 ± 1.80	kJ/mol	NIST
ΔfG°	-831.04	kJ/mol	Joback Calculated Property
ΔfH°gas	-1101.67	kJ/mol	Joback Calculated Property
ΔfH°solid	[-1337.50; -1337.20]	kJ/mol
ΔfH°solid	-1337.50	kJ/mol	NIST
ΔfH°solid	-1337.20 ± 0.79	kJ/mol	NIST
ΔfusH°	54.69	kJ/mol	Heat Ca...
ΔsubH°	202.00	kJ/mol	NIST
ΔvapH°	127.47	kJ/mol	Joback Calculated Property
log10WS	0.06		Estimat...
logPoct/wat	-3.585		Crippen Calculated Property
McVol	130.620	ml/mol	McGowan Calculated Property
Pc	6830.13	kPa	Joback Calculated Property
S°solid,1 bar	[238.50; 253.10]	J/mol×K
S°solid,1 bar	238.50	J/mol×K	NIST
S°solid,1 bar	253.10	J/mol×K	NIST
Tboil	888.00	K	Joback Calculated Property
Tc	1092.90	K	Joback Calculated Property
Tfus	[435.00; 440.62]	K
Tfus	439.13	K	KDB
Tfus	440.62	K	Heat ca...
Tfus	Outlier 435.00	K	Nanocal...
Tfus	438.88	K	Cycling...
Tfus	439.10 ± 0.10	K	NIST
Tfus	439.00 ± 1.00	K	NIST
Tfus	439.20 ± 0.20	K	NIST
Tfus	439.13 ± 0.20	K	NIST
Vc	0.462	m3/kmol	Joback Calculated Property

Temperature Dependent Properties

Property	Value	Unit	Temperature (K)	Source
Cp,gas	[423.48; 456.45]	J/mol×K	[888.00; 1092.90]
T(K) Ideal gas heat capacity (J/mol×K) 425 430 435 440 445 450 455 900 950 1000 1050
Cp,gas	423.48	J/mol×K	888.00	Joback Calculated Property
Cp,gas	429.90	J/mol×K	922.15	Joback Calculated Property
Cp,gas	435.91	J/mol×K	956.30	Joback Calculated Property
Cp,gas	441.54	J/mol×K	990.45	Joback Calculated Property
Cp,gas	446.82	J/mol×K	1024.60	Joback Calculated Property
Cp,gas	451.78	J/mol×K	1058.75	Joback Calculated Property
Cp,gas	456.45	J/mol×K	1092.90	Joback Calculated Property
Cp,solid	[236.00; 244.80]	J/mol×K	[294.10; 303.00]
Cp,solid	236.00	J/mol×K	294.10	NIST
Cp,solid	239.00	J/mol×K	298.15	NIST
Cp,solid	244.80	J/mol×K	303.00	NIST
η	[4.5232902e-09; 0.0005812]	Pa×s	[462.30; 888.00]
T(K) Dynamic viscosity (Pa×s) 0 1.00e-4 2.00e-4 3.00e-4 4.00e-4 5.00e-4 6.00e-4 500 600 700 800
η	0.0005812	Pa×s	462.30	Joback Calculated Property
η	0.0000222	Pa×s	533.25	Joback Calculated Property
η	0.0000018	Pa×s	604.20	Joback Calculated Property
η	0.0000003	Pa×s	675.15	Joback Calculated Property
η	5.1362493e-08	Pa×s	746.10	Joback Calculated Property
η	1.3716255e-08	Pa×s	817.05	Joback Calculated Property
η	4.5232902e-09	Pa×s	888.00	Joback Calculated Property
ΔfusH	[53.58; 56.10]	kJ/mol	[433.20; 439.10]
ΔfusH	53.58	kJ/mol	433.20	NIST
ΔfusH	54.69	kJ/mol	437.30	NIST
ΔfusH	56.10	kJ/mol	439.10	NIST
ΔfusH	56.10	kJ/mol	439.10	NIST
ΔvapH	135.60 ± 1.10	kJ/mol	479.50	NIST
ΔfusS	[123.70; 127.80]	J/mol×K	[433.20; 439.10]
ΔfusS	123.70	J/mol×K	433.20	NIST
ΔfusS	127.80	J/mol×K	439.10	NIST

Pressure Dependent Properties

Similar Compounds

Find more compounds similar to D-Mannitol.

Mixtures

• D-Mannitol + Glycine + Water
• D-Mannitol + Water
• D-Mannitol + Vitamin C + Water
• D-Mannitol + Water + Rofecoxib
• Sorbitol + D-Mannitol + Water
• Sucrose + D-Mannitol + Water
• D-Mannitol + Water + Cetrimonium Bromide
• D-Mannitol + Water + ammonium bromide
• D-Alanine + D-Mannitol + Water
• D-Mannitol + D-Valine + Water
• Threonine + D-Mannitol + Water
• D-Mannitol + (-)-D-arginine hydrate + Water
• D-Mannitol + Ethanol + Water
• D-Mannitol + Ethanol
• 1-Propanol + D-Mannitol + Water
• Isopropyl Alcohol + D-Mannitol + Water

Sources

• Crippen Method
• Modulation in physico-chemical characteristics of some polyhydroxy solutes in presence of L-glycine: Volumetric and NMR spectroscopic approach
• Rheological and time domain 1H NMR relaxation studies of some polyhydroxy solutes in presence of L-glycine
• Heat capacities of some sugar alcohols as phase change materials for thermal energy storage applications
• Nanocalorimetry measurements of metastable states
• Cycling stability of D-mannitol when used as phase change material for thermal storage applications
• Solubility of Rofecoxib in the Presence of Mannitol, Poly(vinylpyrrolidone) K30, Urea, Polyethylene Glycol 4000, and Polyethylene Glycol 6000 at (298.15, 303.15, and 308.15) K
• Viscosity and Density of the Nonelectrolyte System Mannitol + Sorbitol + Sucrose + H2O and Its Binary and Ternary Subsystems at 298.15 K
• Apparent Molar Volumes and Viscosity B-Coefficients of Carbohydrates in Aqueous Cetrimonium Bromide Solutions at (298.15, 308.15, and 318.15) K
• Enthalpies of Dilution, Volumetric Properties, and Refractive Indices of N,N'-Hexamethylenebisacetamide in Aqueous Xylitol or d-Mannitol Solutions at T = 298.15 K
• Ionic Liquids as Promising Solvents for Biomass Derived Mannitol and Xylitol
• Densities and Viscosities of Erythritol, Xylitol, and Mannitol in l-ascorbic Acid Aqueous Solutions at T = (293.15 to 323.15) K
• Influence of NH4Br on Solvation Behavior of Polyhydroxy Solutes in Aqueous Solutions at Different Temperatures and Atmospheric Pressure
• Volumetric and Viscometric Studies of Amino Acids in Mannitol Aqueous Solutions at T = (293.15 to 323.15) K
• Properties of Sugar, Polyol, and Polysaccharide Water-Ethanol Solutions
• Heat Capacities and Nonisothermal Thermal Decomposition Reaction Kinetics of d-Mannitol
• Molar Volumes and Refractive Indexes of Hexane-1,2,3,4,5,6-hexol in Aqueous Solutions of 1-Propanol and 2-Propanol
• Densities and Viscosities of Sugar Alcohol Aqueous Solutions
• Joback Method
• KDB
• Estimated Solubility Method
• McGowan Method
• NIST Webbook

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Outlier This icon means that the value is more than 2 standard deviations away from the property mean.