Chemical Properties of Diethyl sulfide (CAS 352-93-2)

Diethyl sulfide

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InChI
InChI=1S/C4H10S/c1-3-5-4-2/h3-4H2,1-2H3
InChI Key
LJSQFQKUNVCTIA-UHFFFAOYSA-N
Formula
C4H10S
SMILES
CCSCC
Molecular Weight1
90.19
CAS
352-93-2
Other Names
  • (C2H5)2S
  • 1,1'-Thiobisethane
  • 3-Thiapentane
  • Diethyl sulphide
  • Diethyl thioether
  • Diethylsulfid
  • Ethane, 1,1'-thiobis-
  • Ethyl monosulfide
  • Ethyl sulfide
  • Ethyl thioether
  • Ethylthioethane
  • NSC 75157
  • Sulfodor
  • Thioethyl ether
  • UN 2375
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Physical Properties

Property Value Unit Source
PAff 856.70 kJ/mol NIST
BasG 827.00 kJ/mol NIST
Δcliquid [-3486.10; -3471.00] kJ/mol Show Hide
Δcliquid -3486.10 ± 0.67 kJ/mol NIST
Δcliquid -3471.00 kJ/mol NIST
Δf 15.92 kJ/mol Joback Calculated Property
Δfgas [-83.50; -82.72] kJ/mol Show Hide
Δfgas -83.50 ± 2.30 kJ/mol NIST
Δfgas -82.72 ± 0.79 kJ/mol NIST
Δfliquid [-119.40; -119.30] kJ/mol Show Hide
Δfliquid -119.30 ± 2.00 kJ/mol NIST
Δfliquid -119.40 ± 0.84 kJ/mol NIST
Δfus 10.25 kJ/mol Joback Calculated Property
Δvap 31.32 kJ/mol Joback Calculated Property
IE [8.40; 8.46] eV Show Hide
IE 8.42 ± 0.01 eV NIST
IE 8.41 eV NIST
IE 8.42 ± 0.01 eV NIST
IE 8.43 ± 0.01 eV NIST
IE 8.40 eV NIST
IE 8.46 eV NIST
IE 8.44 eV NIST
IE 8.44 eV NIST
log10WS [-1.34; -1.34]   Show Hide
log10WS -1.34 Aq. Sol...
log10WS -1.34 Estimat...
logPoct/wat 1.759 Crippen Calculated Property
McVol 83.570 ml/mol McGowan Calculated Property
Pc 3960.00 ± 40.53 kPa NIST
ρc 284.18 ± 1.80 kg/m3 NIST
Inp [683.00; 720.00]   Show Hide
Inp 708.50 NIST
Inp Outlier 717.90 NIST
Inp 700.40 NIST
Inp 703.70 NIST
Inp 698.00 NIST
Inp 698.00 NIST
Inp 698.00 NIST
Inp 699.00 NIST
Inp 696.00 NIST
Inp 695.00 NIST
Inp 692.00 NIST
Inp 695.00 NIST
Inp 692.00 NIST
Inp 696.00 NIST
Inp 693.00 NIST
Inp 693.00 NIST
Inp 692.00 NIST
Inp 692.00 NIST
Inp 694.00 NIST
Inp 698.00 NIST
Inp 704.00 NIST
Inp 708.00 NIST
Inp 700.00 NIST
Inp 704.00 NIST
Inp Outlier 720.00 NIST
Inp 704.00 NIST
Inp 699.00 NIST
Inp 699.00 NIST
Inp 690.00 NIST
Inp 690.00 NIST
Inp 698.00 NIST
Inp 693.00 NIST
Inp 704.00 NIST
Inp Outlier 683.00 NIST
Inp 685.00 NIST
Inp 704.00 NIST
Inp 708.00 NIST
I [895.00; 927.00]   Show Hide
I 903.00 NIST
I Outlier 927.00 NIST
I 904.00 NIST
I 895.00 NIST
I 899.00 NIST
I 895.00 NIST
I 899.00 NIST
I 903.00 NIST
I 904.00 NIST
liquid 269.28 J/mol×K NIST
Tboil 359.70 K Joback Calculated Property
Tc [557.00; 557.00] K Show Hide
Tc 557.00 K NIST
Tc 557.00 ± 0.50 K NIST
Tfus [169.18; 169.85] K Show Hide
Tfus 169.18 K Aq. Sol...
Tfus 169.85 ± 0.60 K NIST
Tfus 169.24 ± 0.10 K NIST
Tfus 169.85 ± 0.40 K NIST
Ttriple 169.21 ± 0.02 K NIST
Vc 0.314 m3/kmol Joback Calculated Property

Temperature Dependent Properties

Property Value Unit Temperature (K) Source
Cp,gas [135.44; 182.04] J/mol×K [359.70; 550.75] Show Hide
Cp,gas 135.44 J/mol×K 359.70 Joback Calculated Property
Cp,gas 143.93 J/mol×K 391.54 Joback Calculated Property
Cp,gas 152.12 J/mol×K 423.38 Joback Calculated Property
Cp,gas 160.03 J/mol×K 455.23 Joback Calculated Property
Cp,gas 167.65 J/mol×K 487.07 Joback Calculated Property
Cp,gas 174.99 J/mol×K 518.91 Joback Calculated Property
Cp,gas 182.04 J/mol×K 550.75 Joback Calculated Property
Cp,liquid 171.42 J/mol×K 298.15 NIST
ΔfusH [11.90; 11.92] kJ/mol [169.20; 169.21] Show Hide
ΔfusH 11.92 kJ/mol 169.20 NIST
ΔfusH 11.90 kJ/mol 169.20 NIST
ΔfusH 11.90 kJ/mol 169.21 NIST
ΔvapH [31.77; 37.50] kJ/mol [297.00; 365.30] Show Hide
ΔvapH 37.50 kJ/mol 297.00 NIST
ΔvapH 34.90 kJ/mol 327.00 NIST
ΔvapH 34.80 kJ/mol 340.00 NIST
ΔvapH 34.40 kJ/mol 357.00 NIST
ΔvapH 33.50 kJ/mol 364.00 NIST
ΔvapH 31.77 kJ/mol 365.30 NIST
Pvap [13.30; 18.80] kPa [307.94; 317.62] Show Hide
Pvap 13.30 kPa 307.94 Vapour ...
Pvap 15.00 kPa 312.58 Vapour ...
Pvap 15.20 kPa 312.58 Vapour ...
Pvap 15.10 kPa 312.59 Vapour ...
Pvap 18.50 kPa 317.46 Vapour ...
Pvap 18.80 kPa 317.62 Vapour ...
n0 [1.43998; 1.44000]   [298.15; 298.15] Show Hide
n0 1.44000 298.15 Vapor l...
n0 1.44000 298.15 Vapor-L...
n0 1.44000 298.15 Vapor-L...
n0 1.44000 298.15 Vapor-L...
n0 1.43998 298.15 Vapor L...
ΔfusS 70.35 J/mol×K 169.21 NIST
λ [0.13; 0.14] W/m×K [273.15; 333.15] Show Hide
λ 0.14 W/m×K 273.15 Liquid ...
λ 0.14 W/m×K 293.15 Liquid ...
λ 0.14 W/m×K 313.15 Liquid ...
λ 0.13 W/m×K 333.15 Liquid ...

Correlations

Property Value Unit Temperature (K) Source
Pvap [1.33; 202.64] kPa [265.45; 389.55] The Yaw... Show Hide
Equationln(Pvp) = A + B/(T + C)
Coefficient A1.45990e+01
Coefficient B-3.28325e+03
Coefficient C-3.60380e+01
Temperature range, min.265.45
Temperature range, max.389.55
Pvap 1.33 kPa 265.45 Calculated Property
Pvap 3.00 kPa 279.24 Calculated Property
Pvap 6.19 kPa 293.03 Calculated Property
Pvap 11.87 kPa 306.82 Calculated Property
Pvap 21.35 kPa 320.61 Calculated Property
Pvap 36.40 kPa 334.39 Calculated Property
Pvap 59.18 kPa 348.18 Calculated Property
Pvap 92.35 kPa 361.97 Calculated Property
Pvap 139.00 kPa 375.76 Calculated Property
Pvap 202.64 kPa 389.55 Calculated Property
Pvap [4.25e-05; 3818.68] kPa [169.20; 557.15] KDB Vap... Show Hide
Equationln(Pvp) = A + B/T + C*ln(T) + D*T^2
Coefficient A6.58385e+01
Coefficient B-6.29676e+03
Coefficient C-7.56818e+00
Coefficient D5.03613e-06
Temperature range, min.169.20
Temperature range, max.557.15
Pvap 4.25e-05 kPa 169.20 Calculated Property
Pvap 0.02 kPa 212.31 Calculated Property
Pvap 0.65 kPa 255.41 Calculated Property
Pvap 7.88 kPa 298.52 Calculated Property
Pvap 46.70 kPa 341.62 Calculated Property
Pvap 175.43 kPa 384.73 Calculated Property
Pvap 487.31 kPa 427.83 Calculated Property
Pvap 1101.72 kPa 470.94 Calculated Property
Pvap 2157.77 kPa 514.04 Calculated Property
Pvap 3818.68 kPa 557.15 Calculated Property

Similar Compounds

Ethane, (methylthio)-. 2-[Ethylthio]ethanal. diethyl sulfoxide. Propargyl ethyl sulfide. 2-Chloroethyl ethyl sulfide. 1,2-Bis(ethylthio)ethane. CF3CH2SC2H5. 2,5-dithiaheptane. Propane, 2-(ethylthio)-. 1,4-Dithiane. S-Ethyl ethanethioate. 3-Thia-1-pentanethiol. Ethyl chloromethyl sulfide. 1,4,7,10-Tetrathiacyclododecane. Mustard Gas.

Find more compounds similar to Diethyl sulfide.

Mixtures

Sources

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Outlier This icon means that the value is more than 2 standard deviations away from the property mean.