Mixture of 1-Hexyne + n-Propyl acetate

Datasets

1. Mole fraction (2)
2. Excess molar enthalpy (molar enthalpy (2)
3. P_vap - Vapor or sublimation pressure, kPa (2)

Mole fraction of n-Propyl acetate (2) [ref]

Fixed		Measured
Mole fraction of n-Propyl acetate (2) - Liquid	Temperature, K - Liquid	Mole fraction of n-Propyl acetate (2) - Gas
0.0000	273.15	0.0000
0.0000	283.15	0.0000
0.0000	293.15	0.0000
0.0000	298.15	0.0000
0.0000	303.15	0.0000
0.0000	313.15	0.0000
0.0000	323.15	0.0000
0.0000	333.15	0.0000
0.0000	343.15	0.0000
0.0000	353.15	0.0000
0.0000	363.15	0.0000
0.1510	273.15	0.0334
0.1510	283.15	0.0374
0.1510	293.15	0.0414
0.1510	298.15	0.0435
0.1510	303.15	0.0455
0.1510	313.15	0.0495
0.1510	323.15	0.0535
0.1510	333.15	0.0576
0.1510	343.15	0.0616
0.1510	353.15	0.0655
0.1510	363.15	0.0695
0.2671	273.15	0.0665
0.2671	283.15	0.0740
0.2671	293.15	0.0815
0.2671	298.15	0.0852
0.2671	303.15	0.0889
0.2671	313.15	0.0962
0.2671	323.15	0.1034
0.2671	333.15	0.1105
0.2671	343.15	0.1175
0.2671	353.15	0.1244
0.2671	363.15	0.1312
0.3758	273.15	0.1067
0.3758	283.15	0.1178
0.3758	293.15	0.1287
0.3758	298.15	0.1340
0.3758	303.15	0.1393
0.3758	313.15	0.1498
0.3758	323.15	0.1600
0.3758	333.15	0.1700
0.3758	343.15	0.1797
0.3758	353.15	0.1893
0.3758	363.15	0.1986
0.5278	273.15	0.1863
0.5278	283.15	0.2025
0.5278	293.15	0.2182
0.5278	298.15	0.2259
0.5278	303.15	0.2334
0.5278	313.15	0.2481
0.5278	323.15	0.2623
0.5278	333.15	0.2761
0.5278	343.15	0.2893
0.5278	353.15	0.3022
0.5278	363.15	0.3146
0.6405	273.15	0.2727
0.6405	283.15	0.2924
0.6405	293.15	0.3113
0.6405	298.15	0.3205
0.6405	303.15	0.3294
0.6405	313.15	0.3467
0.6405	323.15	0.3633
0.6405	333.15	0.3792
0.6405	343.15	0.3944
0.6405	353.15	0.4090
0.6405	363.15	0.4230
0.7766	273.15	0.4305
0.7766	283.15	0.4527
0.7766	293.15	0.4735
0.7766	298.15	0.4834
0.7766	303.15	0.4931
0.7766	313.15	0.5115
0.7766	323.15	0.5289
0.7766	333.15	0.5454
0.7766	343.15	0.5609
0.7766	353.15	0.5758
0.7766	363.15	0.5898
0.9044	273.15	0.6787
0.9044	283.15	0.6967
0.9044	293.15	0.7130
0.9044	298.15	0.7207
0.9044	303.15	0.7280
0.9044	313.15	0.7418
0.9044	323.15	0.7546
0.9044	333.15	0.7664
0.9044	343.15	0.7774
0.9044	353.15	0.7877
0.9044	363.15	0.7973
1.0000	273.15	1.0000
1.0000	283.15	1.0000
1.0000	293.15	1.0000
1.0000	298.15	1.0000
1.0000	303.15	1.0000
1.0000	313.15	1.0000
1.0000	323.15	1.0000
1.0000	333.15	1.0000
1.0000	343.15	1.0000
1.0000	353.15	1.0000
1.0000	363.15	1.0000

Mole fraction of n-Propyl acetate (2) [ref]

Fixed		Measured
Mole fraction of n-Propyl acetate (2) - Liquid	Temperature, K - Liquid	Mole fraction of n-Propyl acetate (2) - Gas
0.0000	273.15	0.0000
0.0000	283.15	0.0000
0.0000	293.15	0.0000
0.0000	298.15	0.0000
0.0000	303.15	0.0000
0.0000	313.15	0.0000
0.0000	323.15	0.0000
0.0000	333.15	0.0000
0.0000	343.15	0.0000
0.0000	353.15	0.0000
0.0000	363.15	0.0000
0.1510	273.15	0.0334
0.1510	283.15	0.0374
0.1510	293.15	0.0414
0.1510	298.15	0.0435
0.1510	303.15	0.0455
0.1510	313.15	0.0495
0.1510	323.15	0.0535
0.1510	333.15	0.0576
0.1510	343.15	0.0616
0.1510	353.15	0.0655
0.1510	363.15	0.0695
0.2671	273.15	0.0665
0.2671	283.15	0.0740
0.2671	293.15	0.0815
0.2671	298.15	0.0852
0.2671	303.15	0.0889
0.2671	313.15	0.0962
0.2671	323.15	0.1034
0.2671	333.15	0.1105
0.2671	343.15	0.1175
0.2671	353.15	0.1244
0.2671	363.15	0.1312
0.3758	273.15	0.1067
0.3758	283.15	0.1178
0.3758	293.15	0.1287
0.3758	298.15	0.1340
0.3758	303.15	0.1393
0.3758	313.15	0.1498
0.3758	323.15	0.1600
0.3758	333.15	0.1700
0.3758	343.15	0.1797
0.3758	353.15	0.1893
0.3758	363.15	0.1986
0.5278	273.15	0.1863
0.5278	283.15	0.2025
0.5278	293.15	0.2182
0.5278	298.15	0.2259
0.5278	303.15	0.2334
0.5278	313.15	0.2481
0.5278	323.15	0.2623
0.5278	333.15	0.2761
0.5278	343.15	0.2893
0.5278	353.15	0.3022
0.5278	363.15	0.3146
0.6405	273.15	0.2727
0.6405	283.15	0.2924
0.6405	293.15	0.3113
0.6405	298.15	0.3205
0.6405	303.15	0.3294
0.6405	313.15	0.3467
0.6405	323.15	0.3633
0.6405	333.15	0.3792
0.6405	343.15	0.3944
0.6405	353.15	0.4090
0.6405	363.15	0.4230
0.7766	273.15	0.4305
0.7766	283.15	0.4527
0.7766	293.15	0.4735
0.7766	298.15	0.4834
0.7766	303.15	0.4931
0.7766	313.15	0.5115
0.7766	323.15	0.5289
0.7766	333.15	0.5454
0.7766	343.15	0.5609
0.7766	353.15	0.5758
0.7766	363.15	0.5898
0.9044	273.15	0.6787
0.9044	283.15	0.6967
0.9044	293.15	0.7130
0.9044	298.15	0.7207
0.9044	303.15	0.7280
0.9044	313.15	0.7418
0.9044	323.15	0.7546
0.9044	333.15	0.7664
0.9044	343.15	0.7774
0.9044	353.15	0.7877
0.9044	363.15	0.7973
1.0000	273.15	1.0000
1.0000	283.15	1.0000
1.0000	293.15	1.0000
1.0000	298.15	1.0000
1.0000	303.15	1.0000
1.0000	313.15	1.0000
1.0000	323.15	1.0000
1.0000	333.15	1.0000
1.0000	343.15	1.0000
1.0000	353.15	1.0000
1.0000	363.15	1.0000

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Mole fraction of n-Propyl acetate (2) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.1079	-0.1274
0.1967	-0.1994
0.3032	-0.2542
0.3950	-0.2760
0.4373	-0.2778
0.5003	-0.2738
0.5950	-0.2532
0.6575	-0.2315
0.6989	-0.2138
0.7967	-0.1590
0.8992	-0.0857

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Mole fraction of n-Propyl acetate (2) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.1079	-0.1274
0.1967	-0.1994
0.3032	-0.2542
0.3950	-0.2760
0.4373	-0.2778
0.5003	-0.2738
0.5950	-0.2532
0.6575	-0.2315
0.6989	-0.2138
0.7967	-0.1590
0.8992	-0.0857

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Mole fraction of n-Propyl acetate (2) - Liquid	Temperature, K - Liquid	Vapor or sublimation pressure, kPa - Liquid
0.0000	273.15	4.91
0.0000	283.15	8.42
0.0000	293.15	13.81
0.0000	298.15	17.41
0.0000	303.15	21.75
0.0000	313.15	33.07
0.0000	323.15	48.74
0.0000	333.15	69.84
0.0000	343.15	97.60
0.0000	353.15	133.35
0.0000	363.15	178.53
0.1510	273.15	4.31
0.1510	283.15	7.43
0.1510	293.15	12.24
0.1510	298.15	15.47
0.1510	303.15	19.36
0.1510	313.15	29.57
0.1510	323.15	43.75
0.1510	333.15	62.93
0.1510	343.15	88.28
0.1510	353.15	121.05
0.1510	363.15	162.63
0.2671	273.15	3.85
0.2671	283.15	6.66
0.2671	293.15	11.01
0.2671	298.15	13.93
0.2671	303.15	17.47
0.2671	313.15	26.77
0.2671	323.15	39.74
0.2671	333.15	57.36
0.2671	343.15	80.73
0.2671	353.15	111.06
0.2671	363.15	149.70
0.3758	273.15	3.41
0.3758	283.15	5.92
0.3758	293.15	9.84
0.3758	298.15	12.48
0.3758	303.15	15.69
0.3758	313.15	24.15
0.3758	323.15	35.99
0.3758	333.15	52.15
0.3758	343.15	73.64
0.3758	353.15	101.64
0.3758	363.15	137.41
0.5278	273.15	2.78
0.5278	283.15	4.88
0.5278	293.15	8.19
0.5278	298.15	10.45
0.5278	303.15	13.19
0.5278	313.15	20.48
0.5278	323.15	30.78
0.5278	333.15	44.94
0.5278	343.15	63.94
0.5278	353.15	88.87
0.5278	363.15	120.94
0.6405	273.15	2.33
0.6405	283.15	4.15
0.6405	293.15	7.03
0.6405	298.15	9.00
0.6405	303.15	11.42
0.6405	313.15	17.87
0.6405	323.15	27.06
0.6405	333.15	39.77
0.6405	343.15	56.93
0.6405	353.15	79.56
0.6405	363.15	108.83
0.7766	273.15	1.81
0.7766	283.15	3.27
0.7766	293.15	5.63
0.7766	298.15	7.27
0.7766	303.15	9.28
0.7766	313.15	14.71
0.7766	323.15	22.53
0.7766	333.15	33.47
0.7766	343.15	48.38
0.7766	353.15	68.23
0.7766	363.15	94.11
0.9044	273.15	1.34
0.9044	283.15	2.48
0.9044	293.15	4.35
0.9044	298.15	5.66
0.9044	303.15	7.30
0.9044	313.15	11.76
0.9044	323.15	18.30
0.9044	333.15	27.57
0.9044	343.15	40.39
0.9044	353.15	57.66
0.9044	363.15	80.43
1.0000	273.15	1.01
1.0000	283.15	1.91
1.0000	293.15	3.43
1.0000	298.15	4.51
1.0000	303.15	5.87
1.0000	313.15	9.64
1.0000	323.15	15.25
1.0000	333.15	23.33
1.0000	343.15	34.64
1.0000	353.15	50.07
1.0000	363.15	70.64

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Mole fraction of n-Propyl acetate (2) - Liquid	Temperature, K - Liquid	Vapor or sublimation pressure, kPa - Liquid
0.0000	273.15	4.91
0.0000	283.15	8.42
0.0000	293.15	13.81
0.0000	298.15	17.41
0.0000	303.15	21.75
0.0000	313.15	33.07
0.0000	323.15	48.74
0.0000	333.15	69.84
0.0000	343.15	97.60
0.0000	353.15	133.35
0.0000	363.15	178.53
0.1510	273.15	4.31
0.1510	283.15	7.43
0.1510	293.15	12.24
0.1510	298.15	15.47
0.1510	303.15	19.36
0.1510	313.15	29.57
0.1510	323.15	43.75
0.1510	333.15	62.93
0.1510	343.15	88.28
0.1510	353.15	121.05
0.1510	363.15	162.63
0.2671	273.15	3.85
0.2671	283.15	6.66
0.2671	293.15	11.01
0.2671	298.15	13.93
0.2671	303.15	17.47
0.2671	313.15	26.77
0.2671	323.15	39.74
0.2671	333.15	57.36
0.2671	343.15	80.73
0.2671	353.15	111.06
0.2671	363.15	149.70
0.3758	273.15	3.41
0.3758	283.15	5.92
0.3758	293.15	9.84
0.3758	298.15	12.48
0.3758	303.15	15.69
0.3758	313.15	24.15
0.3758	323.15	35.99
0.3758	333.15	52.15
0.3758	343.15	73.64
0.3758	353.15	101.64
0.3758	363.15	137.41
0.5278	273.15	2.78
0.5278	283.15	4.88
0.5278	293.15	8.19
0.5278	298.15	10.45
0.5278	303.15	13.19
0.5278	313.15	20.48
0.5278	323.15	30.78
0.5278	333.15	44.94
0.5278	343.15	63.94
0.5278	353.15	88.87
0.5278	363.15	120.94
0.6405	273.15	2.33
0.6405	283.15	4.15
0.6405	293.15	7.03
0.6405	298.15	9.00
0.6405	303.15	11.42
0.6405	313.15	17.87
0.6405	323.15	27.06
0.6405	333.15	39.77
0.6405	343.15	56.93
0.6405	353.15	79.56
0.6405	363.15	108.83
0.7766	273.15	1.81
0.7766	283.15	3.27
0.7766	293.15	5.63
0.7766	298.15	7.27
0.7766	303.15	9.28
0.7766	313.15	14.71
0.7766	323.15	22.53
0.7766	333.15	33.47
0.7766	343.15	48.38
0.7766	353.15	68.23
0.7766	363.15	94.11
0.9044	273.15	1.34
0.9044	283.15	2.48
0.9044	293.15	4.35
0.9044	298.15	5.66
0.9044	303.15	7.30
0.9044	313.15	11.76
0.9044	323.15	18.30
0.9044	333.15	27.57
0.9044	343.15	40.39
0.9044	353.15	57.66
0.9044	363.15	80.43
1.0000	273.15	1.01
1.0000	283.15	1.91
1.0000	293.15	3.43
1.0000	298.15	4.51
1.0000	303.15	5.87
1.0000	313.15	9.64
1.0000	323.15	15.25
1.0000	333.15	23.33
1.0000	343.15	34.64
1.0000	353.15	50.07
1.0000	363.15	70.64

Sources

• Isothermal vapor-liquid equilibria and excess enthalpies of binary mixtures of propyl ethanoate + 1-hexyne, +2-hexyne, +3-hexyne