Mixture of Formic acid, butyl ester + Decane

Datasets

1. Mole fraction (2)
2. Excess molar enthalpy (molar enthalpy (2)
3. ρ_l - Mass density, kg/m3 (2)
4. T_boil - Boiling temperature at pressure P, K (2)

Mole fraction of Formic acid, butyl ester (1) [ref]

Operational condition: Pressure, kPa = 101.32 (Gas)

Mole fraction of Formic acid, butyl ester (1) - Liquid	Mole fraction of Formic acid, butyl ester (1) - Gas
0.0000	0.0000
0.0108	0.0847
0.0135	0.1204
0.0284	0.1965
0.0452	0.2843
0.0824	0.4290
0.1030	0.4856
0.1341	0.5526
0.1699	0.6254
0.2199	0.6962
0.2490	0.7236
0.3239	0.7922
0.3582	0.8094
0.4074	0.8354
0.4514	0.8554
0.5337	0.8816
0.5882	0.8999
0.6377	0.9076
0.6932	0.9211
0.7327	0.9300
0.7785	0.9413
0.8203	0.9527
0.8539	0.9622
0.8896	0.9719
0.9390	0.9844
0.9603	0.9899
0.9769	0.9939
1.0000	1.0000
0.0000	0.0000
0.0108	0.0847
0.0284	0.1965
0.0452	0.2843
0.0824	0.4290
0.1030	0.4856
0.1341	0.5526
0.1699	0.6254
0.2199	0.6962
0.2490	0.7236
0.3239	0.7922
0.3582	0.8094
0.4074	0.8354
0.4514	0.8554
0.5337	0.8816
0.5882	0.8999
0.6377	0.9076
0.6932	0.9211
0.7327	0.9300
0.7785	0.9413
0.8203	0.9527
0.8539	0.9622
0.8896	0.9719
0.9390	0.9844
0.9603	0.9899
0.9769	0.9939
1.0000	1.0000

Mole fraction of Formic acid, butyl ester (1) [ref]

Operational condition: Pressure, kPa = 101.32 (Gas)

Mole fraction of Formic acid, butyl ester (1) - Liquid	Mole fraction of Formic acid, butyl ester (1) - Gas
0.0000	0.0000
0.0108	0.0847
0.0135	0.1204
0.0284	0.1965
0.0452	0.2843
0.0824	0.4290
0.1030	0.4856
0.1341	0.5526
0.1699	0.6254
0.2199	0.6962
0.2490	0.7236
0.3239	0.7922
0.3582	0.8094
0.4074	0.8354
0.4514	0.8554
0.5337	0.8816
0.5882	0.8999
0.6377	0.9076
0.6932	0.9211
0.7327	0.9300
0.7785	0.9413
0.8203	0.9527
0.8539	0.9622
0.8896	0.9719
0.9390	0.9844
0.9603	0.9899
0.9769	0.9939
1.0000	1.0000
0.0000	0.0000
0.0108	0.0847
0.0284	0.1965
0.0452	0.2843
0.0824	0.4290
0.1030	0.4856
0.1341	0.5526
0.1699	0.6254
0.2199	0.6962
0.2490	0.7236
0.3239	0.7922
0.3582	0.8094
0.4074	0.8354
0.4514	0.8554
0.5337	0.8816
0.5882	0.8999
0.6377	0.9076
0.6932	0.9211
0.7327	0.9300
0.7785	0.9413
0.8203	0.9527
0.8539	0.9622
0.8896	0.9719
0.9390	0.9844
0.9603	0.9899
0.9769	0.9939
1.0000	1.0000

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational condition: Pressure, kPa = 101.32 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Formic acid, butyl ester (1) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
291.15	0.0883	0.4710
291.15	0.1638	0.7710
291.15	0.2402	1.017
291.15	0.3191	1.202
291.15	0.3928	1.319
291.15	0.4529	1.374
291.15	0.5186	1.386
291.15	0.5700	1.363
291.15	0.5814	1.347
291.15	0.6110	1.324
291.15	0.6591	1.262
291.15	0.7085	1.15
291.15	0.7591	1.02
291.15	0.8110	0.8650
291.15	0.8617	0.6780
291.15	0.9107	0.4650
291.15	0.9571	0.2400
318.15	0.1089	0.5210
318.15	0.2303	0.9890
318.15	0.3519	1.311
318.15	0.4595	1.442
318.15	0.5353	1.457
318.15	0.5931	1.412
318.15	0.6414	1.334
318.15	0.7023	1.209
318.15	0.7704	1.021
318.15	0.8416	0.7670
318.15	0.9017	0.4950
318.15	0.9610	0.2400

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational condition: Pressure, kPa = 101.32 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Formic acid, butyl ester (1) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
291.15	0.0883	0.4710
291.15	0.1638	0.7710
291.15	0.2402	1.017
291.15	0.3191	1.202
291.15	0.3928	1.319
291.15	0.4529	1.374
291.15	0.5186	1.386
291.15	0.5700	1.363
291.15	0.5814	1.347
291.15	0.6110	1.324
291.15	0.6591	1.262
291.15	0.7085	1.15
291.15	0.7591	1.02
291.15	0.8110	0.8650
291.15	0.8617	0.6780
291.15	0.9107	0.4650
291.15	0.9571	0.2400
318.15	0.1089	0.5210
318.15	0.2303	0.9890
318.15	0.3519	1.311
318.15	0.4595	1.442
318.15	0.5353	1.457
318.15	0.5931	1.412
318.15	0.6414	1.334
318.15	0.7023	1.209
318.15	0.7704	1.021
318.15	0.8416	0.7670
318.15	0.9017	0.4950
318.15	0.9610	0.2400

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 101.32 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Formic acid, butyl ester (1) - Liquid	Mass density, kg/m3 - Liquid
291.15	0.0000	731.24
291.15	0.0360	734.46
291.15	0.0912	739.3
291.15	0.1417	744.12
291.15	0.1926	748.99
291.15	0.2446	754.61
291.15	0.3002	760.95
291.15	0.3984	773.44
291.15	0.4994	787.95
291.15	0.5988	804.04
291.15	0.6976	822.2
291.15	0.7487	832.36
291.15	0.7895	841.15
291.15	0.8520	855.74
291.15	0.8994	867.64
291.15	0.9498	881.15
291.15	1.0000	896.0
298.15	0.0000	726.26
298.15	0.0497	730.42
298.15	0.0975	734.48
298.15	0.1471	739.16
298.15	0.1909	743.43
298.15	0.2423	748.85
298.15	0.2941	754.68
298.15	0.3856	765.96
298.15	0.4923	780.87
298.15	0.5884	796.04
298.15	0.6947	814.97
298.15	0.7484	825.6
298.15	0.7926	835.06
298.15	0.8669	852.05
298.15	0.8982	860.1
298.15	0.9463	872.69
298.15	1.0000	888.66
308.15	0.0000	717.9
308.15	0.0257	720.58
308.15	0.0873	725.9
308.15	0.1414	730.67
308.15	0.1894	735.3
308.15	0.2354	740.0
308.15	0.2945	746.5
308.15	0.3957	758.7
308.15	0.5030	773.4
308.15	0.5983	788.2
308.15	0.6557	798.1
308.15	0.7040	807.0
308.15	0.7997	826.5
308.15	0.8846	846.3
308.15	0.9719	869.5
308.15	1.0000	878.24
318.15	0.0000	710.99
318.15	0.0595	715.56
318.15	0.1047	719.25
318.15	0.1832	726.5
318.15	0.2736	735.55
318.15	0.3418	743.15
318.15	0.4274	753.61
318.15	0.4825	760.98
318.15	0.5424	769.71
318.15	0.6001	778.67
318.15	0.6566	788.22
318.15	0.7096	797.9
318.15	0.7562	807.07
318.15	0.8057	817.66
318.15	0.8419	825.85
318.15	0.8877	836.56
318.15	0.9277	846.79
318.15	0.9669	857.26
318.15	1.0000	867.21

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 101.32 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Formic acid, butyl ester (1) - Liquid	Mass density, kg/m3 - Liquid
291.15	0.0000	731.24
291.15	0.0360	734.46
291.15	0.0912	739.3
291.15	0.1417	744.12
291.15	0.1926	748.99
291.15	0.2446	754.61
291.15	0.3002	760.95
291.15	0.3984	773.44
291.15	0.4994	787.95
291.15	0.5988	804.04
291.15	0.6976	822.2
291.15	0.7487	832.36
291.15	0.7895	841.15
291.15	0.8520	855.74
291.15	0.8994	867.64
291.15	0.9498	881.15
291.15	1.0000	896.0
298.15	0.0000	726.26
298.15	0.0497	730.42
298.15	0.0975	734.48
298.15	0.1471	739.16
298.15	0.1909	743.43
298.15	0.2423	748.85
298.15	0.2941	754.68
298.15	0.3856	765.96
298.15	0.4923	780.87
298.15	0.5884	796.04
298.15	0.6947	814.97
298.15	0.7484	825.6
298.15	0.7926	835.06
298.15	0.8669	852.05
298.15	0.8982	860.1
298.15	0.9463	872.69
298.15	1.0000	888.66
308.15	0.0000	717.9
308.15	0.0257	720.58
308.15	0.0873	725.9
308.15	0.1414	730.67
308.15	0.1894	735.3
308.15	0.2354	740.0
308.15	0.2945	746.5
308.15	0.3957	758.7
308.15	0.5030	773.4
308.15	0.5983	788.2
308.15	0.6557	798.1
308.15	0.7040	807.0
308.15	0.7997	826.5
308.15	0.8846	846.3
308.15	0.9719	869.5
308.15	1.0000	878.24
318.15	0.0000	710.99
318.15	0.0595	715.56
318.15	0.1047	719.25
318.15	0.1832	726.5
318.15	0.2736	735.55
318.15	0.3418	743.15
318.15	0.4274	753.61
318.15	0.4825	760.98
318.15	0.5424	769.71
318.15	0.6001	778.67
318.15	0.6566	788.22
318.15	0.7096	797.9
318.15	0.7562	807.07
318.15	0.8057	817.66
318.15	0.8419	825.85
318.15	0.8877	836.56
318.15	0.9277	846.79
318.15	0.9669	857.26
318.15	1.0000	867.21

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 101.32 (Liquid)

Mole fraction of Formic acid, butyl ester (1) - Liquid	Boiling temperature at pressure P, K - Liquid
0.0000	446.93
0.0108	443.75
0.0135	442.30
0.0284	439.32
0.0452	435.55
0.0824	428.68
0.1030	425.63
0.1341	421.60
0.1699	416.85
0.2199	411.54
0.2490	409.09
0.3239	402.67
0.3582	400.78
0.4074	397.95
0.4514	395.55
0.5337	392.29
0.5882	390.07
0.6377	389.05
0.6932	387.55
0.7327	386.52
0.7785	385.60
0.8203	384.32
0.8539	383.45
0.8896	382.61
0.9390	381.37
0.9603	380.85
0.9769	380.39
1.0000	380.13
0.0000	446.93
0.0108	443.75
0.0284	439.32
0.0452	435.55
0.0824	428.68
0.1030	425.63
0.1341	421.60
0.1699	416.85
0.2199	411.54
0.2490	409.09
0.3239	402.67
0.3582	400.78
0.4074	397.95
0.4514	395.55
0.5337	392.29
0.5882	390.07
0.6377	389.05
0.6932	387.55
0.7327	386.52
0.7785	385.60
0.8203	384.32
0.8539	383.45
0.8896	382.61
0.9390	381.37
0.9603	380.85
0.9769	380.39
1.0000	380.13

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 101.32 (Liquid)

Mole fraction of Formic acid, butyl ester (1) - Liquid	Boiling temperature at pressure P, K - Liquid
0.0000	446.93
0.0108	443.75
0.0135	442.30
0.0284	439.32
0.0452	435.55
0.0824	428.68
0.1030	425.63
0.1341	421.60
0.1699	416.85
0.2199	411.54
0.2490	409.09
0.3239	402.67
0.3582	400.78
0.4074	397.95
0.4514	395.55
0.5337	392.29
0.5882	390.07
0.6377	389.05
0.6932	387.55
0.7327	386.52
0.7785	385.60
0.8203	384.32
0.8539	383.45
0.8896	382.61
0.9390	381.37
0.9603	380.85
0.9769	380.39
1.0000	380.13
0.0000	446.93
0.0108	443.75
0.0284	439.32
0.0452	435.55
0.0824	428.68
0.1030	425.63
0.1341	421.60
0.1699	416.85
0.2199	411.54
0.2490	409.09
0.3239	402.67
0.3582	400.78
0.4074	397.95
0.4514	395.55
0.5337	392.29
0.5882	390.07
0.6377	389.05
0.6932	387.55
0.7327	386.52
0.7785	385.60
0.8203	384.32
0.8539	383.45
0.8896	382.61
0.9390	381.37
0.9603	380.85
0.9769	380.39
1.0000	380.13

Sources

• Excess properties and isobaric vapor liquid equilibria for four binary systems of alkyl (methyl to butyl) methanoates with decane