Mixture of Ethyl formate + Decane

Datasets

1. Mole fraction (2)
2. Excess molar enthalpy (molar enthalpy (2)
3. ρ_l - Mass density, kg/m3 (2)
4. T_boil - Boiling temperature at pressure P, K (2)

Mole fraction of Ethyl formate (1) [ref]

Operational condition: Pressure, kPa = 101.32 (Gas)

Mole fraction of Ethyl formate (1) - Liquid	Mole fraction of Ethyl formate (1) - Gas
0.0000	0.0000
0.0303	0.4204
0.0493	0.6402
0.0725	0.7706
0.1226	0.8742
0.1585	0.9304
0.1833	0.9458
0.2135	0.9577
0.2807	0.9712
0.3427	0.9776
0.3756	0.9788
0.4549	0.9798
0.5634	0.9877
0.6353	0.9891
0.7037	0.9904
0.7589	0.9912
0.8192	0.9923
0.8590	0.9935
0.8898	0.9948
0.9147	0.9955
0.9418	0.9968
0.9575	0.9974
1.0000	1.0000
0.0000	0.0000
0.0493	0.6402
0.0725	0.7706
0.1226	0.8742
0.1585	0.9304
0.1833	0.9458
0.2135	0.9577
0.2807	0.9712
0.3427	0.9776
0.3756	0.9788
0.4549	0.9798
0.5634	0.9877
0.6353	0.9891
0.7037	0.9904
0.7589	0.9912
0.8192	0.9923
0.8590	0.9935
0.8898	0.9948
0.9147	0.9955
0.9418	0.9968
0.9575	0.9974
1.0000	1.0000

Mole fraction of Ethyl formate (1) [ref]

Operational condition: Pressure, kPa = 101.32 (Gas)

Mole fraction of Ethyl formate (1) - Liquid	Mole fraction of Ethyl formate (1) - Gas
0.0000	0.0000
0.0303	0.4204
0.0493	0.6402
0.0725	0.7706
0.1226	0.8742
0.1585	0.9304
0.1833	0.9458
0.2135	0.9577
0.2807	0.9712
0.3427	0.9776
0.3756	0.9788
0.4549	0.9798
0.5634	0.9877
0.6353	0.9891
0.7037	0.9904
0.7589	0.9912
0.8192	0.9923
0.8590	0.9935
0.8898	0.9948
0.9147	0.9955
0.9418	0.9968
0.9575	0.9974
1.0000	1.0000
0.0000	0.0000
0.0493	0.6402
0.0725	0.7706
0.1226	0.8742
0.1585	0.9304
0.1833	0.9458
0.2135	0.9577
0.2807	0.9712
0.3427	0.9776
0.3756	0.9788
0.4549	0.9798
0.5634	0.9877
0.6353	0.9891
0.7037	0.9904
0.7589	0.9912
0.8192	0.9923
0.8590	0.9935
0.8898	0.9948
0.9147	0.9955
0.9418	0.9968
0.9575	0.9974
1.0000	1.0000

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational condition: Pressure, kPa = 101.32 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Ethyl formate (1) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
291.15	0.0822	0.6170
291.15	0.1859	1.072
291.15	0.2713	1.434
291.15	0.3499	1.694
291.15	0.4126	1.83
291.15	0.4692	1.911
291.15	0.5169	1.949
291.15	0.5649	1.951
291.15	0.6207	1.9
291.15	0.6612	1.819
291.15	0.7038	1.71
291.15	0.7476	1.557
291.15	0.7913	1.375
291.15	0.8325	1.175
291.15	0.8736	0.9300
291.15	0.9116	0.6770
291.15	0.9477	0.3690
318.15	0.1112	0.7360
318.15	0.2286	1.348
318.15	0.3382	1.763
318.15	0.4345	2.014
318.15	0.5100	2.101
318.15	0.5685	2.094
318.15	0.6188	2.045
318.15	0.6693	1.941
318.15	0.7138	1.808
318.15	0.7758	1.594
318.15	0.8310	1.32
318.15	0.8841	0.9970
318.15	0.9315	0.6440
318.15	0.9711	0.3070

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational condition: Pressure, kPa = 101.32 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Ethyl formate (1) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
291.15	0.0822	0.6170
291.15	0.1859	1.072
291.15	0.2713	1.434
291.15	0.3499	1.694
291.15	0.4126	1.83
291.15	0.4692	1.911
291.15	0.5169	1.949
291.15	0.5649	1.951
291.15	0.6207	1.9
291.15	0.6612	1.819
291.15	0.7038	1.71
291.15	0.7476	1.557
291.15	0.7913	1.375
291.15	0.8325	1.175
291.15	0.8736	0.9300
291.15	0.9116	0.6770
291.15	0.9477	0.3690
318.15	0.1112	0.7360
318.15	0.2286	1.348
318.15	0.3382	1.763
318.15	0.4345	2.014
318.15	0.5100	2.101
318.15	0.5685	2.094
318.15	0.6188	2.045
318.15	0.6693	1.941
318.15	0.7138	1.808
318.15	0.7758	1.594
318.15	0.8310	1.32
318.15	0.8841	0.9970
318.15	0.9315	0.6440
318.15	0.9711	0.3070

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 101.32 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Ethyl formate (1) - Liquid	Mass density, kg/m3 - Liquid
291.15	0.0000	731.24
291.15	0.0369	733.67
291.15	0.0776	735.97
291.15	0.0978	737.54
291.15	0.1340	740.05
291.15	0.1725	742.85
291.15	0.1933	744.66
291.15	0.2570	750.31
291.15	0.3043	754.75
291.15	0.4065	766.41
291.15	0.5031	779.53
291.15	0.6097	797.49
291.15	0.6965	815.77
291.15	0.7487	828.5
291.15	0.7966	841.64
291.15	0.8479	857.71
291.15	0.8993	876.59
291.15	0.9515	898.85
291.15	1.0000	924.7
298.15	0.0000	726.26
298.15	0.0613	729.71
298.15	0.1265	734.08
298.15	0.1845	738.4
298.15	0.2400	742.88
298.15	0.3359	752.24
298.15	0.4224	762.26
298.15	0.5000	772.57
298.15	0.5684	783.54
298.15	0.6307	794.86
298.15	0.6827	805.36
298.15	0.7324	816.84
298.15	0.7802	828.91
298.15	0.8172	839.7
298.15	0.8519	851.25
298.15	0.8895	864.02
298.15	0.9193	876.39
298.15	0.9496	889.23
298.15	0.9781	902.17
298.15	1.0000	915.16
308.15	0.0000	717.9
308.15	0.0575	721.82
308.15	0.0851	723.08
308.15	0.1229	725.68
308.15	0.1878	730.48
308.15	0.2373	734.34
308.15	0.2993	739.84
308.15	0.4007	750.53
308.15	0.4266	753.53
308.15	0.5665	773.36
308.15	0.6829	795.01
308.15	0.7746	816.85
308.15	0.8537	839.92
308.15	0.9166	862.73
308.15	0.9764	889.19
308.15	1.0000	902.07
318.15	0.0000	710.99
318.15	0.0662	713.35
318.15	0.0942	715.02
318.15	0.1622	719.52
318.15	0.1774	720.46
318.15	0.2434	725.57
318.15	0.2955	729.88
318.15	0.4007	740.55
318.15	0.4952	752.12
318.15	0.5971	767.58
318.15	0.6941	785.97
318.15	0.7524	799.48
318.15	0.7979	811.07
318.15	0.8481	825.85
318.15	0.9055	845.58
318.15	0.9550	866.05
318.15	1.0000	888.42

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 101.32 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Ethyl formate (1) - Liquid	Mass density, kg/m3 - Liquid
291.15	0.0000	731.24
291.15	0.0369	733.67
291.15	0.0776	735.97
291.15	0.0978	737.54
291.15	0.1340	740.05
291.15	0.1725	742.85
291.15	0.1933	744.66
291.15	0.2570	750.31
291.15	0.3043	754.75
291.15	0.4065	766.41
291.15	0.5031	779.53
291.15	0.6097	797.49
291.15	0.6965	815.77
291.15	0.7487	828.5
291.15	0.7966	841.64
291.15	0.8479	857.71
291.15	0.8993	876.59
291.15	0.9515	898.85
291.15	1.0000	924.7
298.15	0.0000	726.26
298.15	0.0613	729.71
298.15	0.1265	734.08
298.15	0.1845	738.4
298.15	0.2400	742.88
298.15	0.3359	752.24
298.15	0.4224	762.26
298.15	0.5000	772.57
298.15	0.5684	783.54
298.15	0.6307	794.86
298.15	0.6827	805.36
298.15	0.7324	816.84
298.15	0.7802	828.91
298.15	0.8172	839.7
298.15	0.8519	851.25
298.15	0.8895	864.02
298.15	0.9193	876.39
298.15	0.9496	889.23
298.15	0.9781	902.17
298.15	1.0000	915.16
308.15	0.0000	717.9
308.15	0.0575	721.82
308.15	0.0851	723.08
308.15	0.1229	725.68
308.15	0.1878	730.48
308.15	0.2373	734.34
308.15	0.2993	739.84
308.15	0.4007	750.53
308.15	0.4266	753.53
308.15	0.5665	773.36
308.15	0.6829	795.01
308.15	0.7746	816.85
308.15	0.8537	839.92
308.15	0.9166	862.73
308.15	0.9764	889.19
308.15	1.0000	902.07
318.15	0.0000	710.99
318.15	0.0662	713.35
318.15	0.0942	715.02
318.15	0.1622	719.52
318.15	0.1774	720.46
318.15	0.2434	725.57
318.15	0.2955	729.88
318.15	0.4007	740.55
318.15	0.4952	752.12
318.15	0.5971	767.58
318.15	0.6941	785.97
318.15	0.7524	799.48
318.15	0.7979	811.07
318.15	0.8481	825.85
318.15	0.9055	845.58
318.15	0.9550	866.05
318.15	1.0000	888.42

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 101.32 (Liquid)

Mole fraction of Ethyl formate (1) - Liquid	Boiling temperature at pressure P, K - Liquid
0.0000	446.93
0.0303	426.41
0.0493	410.34
0.0725	396.55
0.1226	375.24
0.1585	365.49
0.1833	360.01
0.2135	354.88
0.2807	347.55
0.3427	343.16
0.3756	342.18
0.4549	340.94
0.5634	334.54
0.6353	333.18
0.7037	331.95
0.7589	331.18
0.8192	330.53
0.8590	329.95
0.8898	329.50
0.9147	329.12
0.9418	328.74
0.9575	328.43
1.0000	327.33
0.0000	446.93
0.0493	410.34
0.0725	396.55
0.1226	375.24
0.1585	365.49
0.1833	360.01
0.2135	354.88
0.2807	347.55
0.3427	343.16
0.3756	342.18
0.4549	340.94
0.5634	334.54
0.6353	333.18
0.7037	331.95
0.7589	331.18
0.8192	330.53
0.8590	329.95
0.8898	329.50
0.9147	329.12
0.9418	328.74
0.9575	328.43
1.0000	327.33

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 101.32 (Liquid)

Mole fraction of Ethyl formate (1) - Liquid	Boiling temperature at pressure P, K - Liquid
0.0000	446.93
0.0303	426.41
0.0493	410.34
0.0725	396.55
0.1226	375.24
0.1585	365.49
0.1833	360.01
0.2135	354.88
0.2807	347.55
0.3427	343.16
0.3756	342.18
0.4549	340.94
0.5634	334.54
0.6353	333.18
0.7037	331.95
0.7589	331.18
0.8192	330.53
0.8590	329.95
0.8898	329.50
0.9147	329.12
0.9418	328.74
0.9575	328.43
1.0000	327.33
0.0000	446.93
0.0493	410.34
0.0725	396.55
0.1226	375.24
0.1585	365.49
0.1833	360.01
0.2135	354.88
0.2807	347.55
0.3427	343.16
0.3756	342.18
0.4549	340.94
0.5634	334.54
0.6353	333.18
0.7037	331.95
0.7589	331.18
0.8192	330.53
0.8590	329.95
0.8898	329.50
0.9147	329.12
0.9418	328.74
0.9575	328.43
1.0000	327.33

Sources

• Excess properties and isobaric vapor liquid equilibria for four binary systems of alkyl (methyl to butyl) methanoates with decane