Mixture of Dodecanoic acid, methyl ester + Decanoic acid, methyl ester

Datasets

1. Mole fraction (2)
2. C_p,liquid - Molar heat capacity at constant pressure, J/K/mol (2)
3. T_boil - Boiling temperature at pressure P, K (2)

Mole fraction of Decanoic acid, methyl ester (2) [ref]

Fixed		Measured
Mole fraction of Decanoic acid, methyl ester (2) - Liquid	Pressure, kPa - Liquid	Mole fraction of Decanoic acid, methyl ester (2) - Gas
0.0000	2.00	0.0000
0.0623	2.00	0.2137
0.0935	2.00	0.2926
0.1438	2.00	0.4007
0.2009	2.00	0.4941
0.2852	2.00	0.6049
0.3889	2.00	0.7027
0.5346	2.00	0.8102
0.6691	2.00	0.8797
0.7541	2.00	0.9167
0.8227	2.00	0.9423
0.8836	2.00	0.9631
1.0000	2.00	1.0000
0.0000	4.00	0.0000
0.0659	4.00	0.2162
0.0973	4.00	0.2950
0.1524	4.00	0.4075
0.2096	4.00	0.5032
0.2908	4.00	0.6030
0.3932	4.00	0.7036
0.5354	4.00	0.7983
0.6695	4.00	0.8696
0.7580	4.00	0.9108
0.8291	4.00	0.9398
0.8834	4.00	0.9611
1.0000	4.00	1.0000
0.0000	6.00	0.0000
0.0676	6.00	0.2139
0.1000	6.00	0.2936
0.1552	6.00	0.4028
0.2136	6.00	0.4971
0.2950	6.00	0.6019
0.3951	6.00	0.6933
0.5375	6.00	0.7933
0.6730	6.00	0.8703
0.7596	6.00	0.9099
0.8365	6.00	0.9407
0.8802	6.00	0.9577
1.0000	6.00	1.0000

Mole fraction of Decanoic acid, methyl ester (2) [ref]

Fixed		Measured
Mole fraction of Decanoic acid, methyl ester (2) - Liquid	Pressure, kPa - Liquid	Mole fraction of Decanoic acid, methyl ester (2) - Gas
0.0000	2.00	0.0000
0.0623	2.00	0.2137
0.0935	2.00	0.2926
0.1438	2.00	0.4007
0.2009	2.00	0.4941
0.2852	2.00	0.6049
0.3889	2.00	0.7027
0.5346	2.00	0.8102
0.6691	2.00	0.8797
0.7541	2.00	0.9167
0.8227	2.00	0.9423
0.8836	2.00	0.9631
1.0000	2.00	1.0000
0.0000	4.00	0.0000
0.0659	4.00	0.2162
0.0973	4.00	0.2950
0.1524	4.00	0.4075
0.2096	4.00	0.5032
0.2908	4.00	0.6030
0.3932	4.00	0.7036
0.5354	4.00	0.7983
0.6695	4.00	0.8696
0.7580	4.00	0.9108
0.8291	4.00	0.9398
0.8834	4.00	0.9611
1.0000	4.00	1.0000
0.0000	6.00	0.0000
0.0676	6.00	0.2139
0.1000	6.00	0.2936
0.1552	6.00	0.4028
0.2136	6.00	0.4971
0.2950	6.00	0.6019
0.3951	6.00	0.6933
0.5375	6.00	0.7933
0.6730	6.00	0.8703
0.7596	6.00	0.9099
0.8365	6.00	0.9407
0.8802	6.00	0.9577
1.0000	6.00	1.0000

Molar heat capacity at constant pressure, J/K/mol [ref]

Fixed			Measured
Pressure, kPa - Liquid	Temperature, K - Liquid	Mole fraction of Dodecanoic acid, methyl ester (1) - Liquid	Molar heat capacity at constant pressure, J/K/mol - Liquid
100.00	313.97	1.0000	442.60
4040.00	313.99	1.0000	441.60
8070.00	314.06	1.0000	439.50
12160.00	314.09	1.0000	438.30
16180.00	314.14	1.0000	436.90
100.00	323.88	1.0000	449.50
4070.00	323.93	1.0000	447.20
8060.00	324.01	1.0000	445.80
12090.00	323.84	1.0000	444.80
16080.00	323.94	1.0000	443.30
100.00	333.88	1.0000	456.40
4050.00	333.96	1.0000	453.60
8050.00	334.00	1.0000	452.10
12060.00	334.05	1.0000	450.50
16170.00	334.11	1.0000	448.00
100.00	313.71	0.0000	383.90
4070.00	313.82	0.0000	382.10
8030.00	313.83	0.0000	380.50
12010.00	313.99	0.0000	378.50
16140.00	314.01	0.0000	376.60
100.00	324.79	0.0000	387.60
4070.00	324.79	0.0000	386.00
8030.00	325.01	0.0000	384.40
12010.00	325.06	0.0000	382.50
16140.00	325.20	0.0000	379.30
100.00	334.12	0.0000	393.20
4070.00	334.53	0.0000	390.30
8030.00	334.33	0.0000	388.30
12010.00	334.60	0.0000	386.20
16140.00	334.84	0.0000	384.20
100.00	314.37	0.3001	403.70
4090.00	314.53	0.3001	402.20
8010.00	314.71	0.3001	400.60
12020.00	314.95	0.3001	397.70
16080.00	315.06	0.3001	395.60
100.00	323.53	0.3001	412.00
4100.00	323.58	0.3001	409.50
8070.00	323.69	0.3001	406.90
12080.00	323.84	0.3001	403.90
16190.00	324.39	0.3001	400.50
100.00	333.55	0.3001	418.30
4130.00	333.76	0.3001	415.80
8110.00	333.79	0.3001	413.50
12080.00	334.03	0.3001	411.70
16110.00	334.21	0.3001	408.40
100.00	313.71	0.5001	414.90
4060.00	313.82	0.5001	413.30
8100.00	313.83	0.5001	412.30
12140.00	313.99	0.5001	410.10
16150.00	314.01	0.5001	408.90
100.00	324.79	0.5001	424.40
4150.00	324.79	0.5001	421.60
8140.00	325.01	0.5001	418.70
12110.00	325.06	0.5001	416.10
16230.00	325.20	0.5001	413.70
100.00	334.12	0.5001	431.70
4120.00	334.53	0.5001	428.80
8140.00	334.33	0.5001	425.50
12200.00	334.60	0.5001	423.10
16030.00	334.84	0.5001	420.70
100.00	314.01	0.6999	426.40
4080.00	314.08	0.6999	425.10
8140.00	314.18	0.6999	422.70
12080.00	314.17	0.6999	421.20
16150.00	314.21	0.6999	419.40
100.00	324.05	0.6999	435.50
4120.00	324.08	0.6999	433.40
8050.00	324.13	0.6999	431.30
12080.00	324.19	0.6999	428.20
16120.00	324.24	0.6999	426.40
100.00	333.71	0.6999	442.80
4150.00	333.98	0.6999	440.90
8040.00	334.04	0.6999	439.00
12160.00	333.97	0.6999	434.70
16170.00	334.04	0.6999	431.90

Molar heat capacity at constant pressure, J/K/mol [ref]

Fixed			Measured
Pressure, kPa - Liquid	Temperature, K - Liquid	Mole fraction of Dodecanoic acid, methyl ester (1) - Liquid	Molar heat capacity at constant pressure, J/K/mol - Liquid
100.00	313.97	1.0000	442.60
4040.00	313.99	1.0000	441.60
8070.00	314.06	1.0000	439.50
12160.00	314.09	1.0000	438.30
16180.00	314.14	1.0000	436.90
100.00	323.88	1.0000	449.50
4070.00	323.93	1.0000	447.20
8060.00	324.01	1.0000	445.80
12090.00	323.84	1.0000	444.80
16080.00	323.94	1.0000	443.30
100.00	333.88	1.0000	456.40
4050.00	333.96	1.0000	453.60
8050.00	334.00	1.0000	452.10
12060.00	334.05	1.0000	450.50
16170.00	334.11	1.0000	448.00
100.00	313.71	0.0000	383.90
4070.00	313.82	0.0000	382.10
8030.00	313.83	0.0000	380.50
12010.00	313.99	0.0000	378.50
16140.00	314.01	0.0000	376.60
100.00	324.79	0.0000	387.60
4070.00	324.79	0.0000	386.00
8030.00	325.01	0.0000	384.40
12010.00	325.06	0.0000	382.50
16140.00	325.20	0.0000	379.30
100.00	334.12	0.0000	393.20
4070.00	334.53	0.0000	390.30
8030.00	334.33	0.0000	388.30
12010.00	334.60	0.0000	386.20
16140.00	334.84	0.0000	384.20
100.00	314.37	0.3001	403.70
4090.00	314.53	0.3001	402.20
8010.00	314.71	0.3001	400.60
12020.00	314.95	0.3001	397.70
16080.00	315.06	0.3001	395.60
100.00	323.53	0.3001	412.00
4100.00	323.58	0.3001	409.50
8070.00	323.69	0.3001	406.90
12080.00	323.84	0.3001	403.90
16190.00	324.39	0.3001	400.50
100.00	333.55	0.3001	418.30
4130.00	333.76	0.3001	415.80
8110.00	333.79	0.3001	413.50
12080.00	334.03	0.3001	411.70
16110.00	334.21	0.3001	408.40
100.00	313.71	0.5001	414.90
4060.00	313.82	0.5001	413.30
8100.00	313.83	0.5001	412.30
12140.00	313.99	0.5001	410.10
16150.00	314.01	0.5001	408.90
100.00	324.79	0.5001	424.40
4150.00	324.79	0.5001	421.60
8140.00	325.01	0.5001	418.70
12110.00	325.06	0.5001	416.10
16230.00	325.20	0.5001	413.70
100.00	334.12	0.5001	431.70
4120.00	334.53	0.5001	428.80
8140.00	334.33	0.5001	425.50
12200.00	334.60	0.5001	423.10
16030.00	334.84	0.5001	420.70
100.00	314.01	0.6999	426.40
4080.00	314.08	0.6999	425.10
8140.00	314.18	0.6999	422.70
12080.00	314.17	0.6999	421.20
16150.00	314.21	0.6999	419.40
100.00	324.05	0.6999	435.50
4120.00	324.08	0.6999	433.40
8050.00	324.13	0.6999	431.30
12080.00	324.19	0.6999	428.20
16120.00	324.24	0.6999	426.40
100.00	333.71	0.6999	442.80
4150.00	333.98	0.6999	440.90
8040.00	334.04	0.6999	439.00
12160.00	333.97	0.6999	434.70
16170.00	334.04	0.6999	431.90

Boiling temperature at pressure P, K [ref]

Fixed		Measured
Mole fraction of Decanoic acid, methyl ester (2) - Liquid	Pressure, kPa - Liquid	Boiling temperature at pressure P, K - Liquid
0.0000	2.00	417.53
0.0623	2.00	413.52
0.0935	2.00	411.63
0.1438	2.00	409.17
0.2009	2.00	406.77
0.2852	2.00	403.66
0.3889	2.00	400.44
0.5346	2.00	396.72
0.6691	2.00	393.75
0.7541	2.00	392.09
0.8227	2.00	391.15
0.8836	2.00	390.43
1.0000	2.00	389.10
0.0000	4.00	433.71
0.0659	4.00	429.37
0.0973	4.00	427.43
0.1524	4.00	424.78
0.2096	4.00	422.19
0.2908	4.00	419.12
0.3932	4.00	415.62
0.5354	4.00	412.11
0.6695	4.00	409.70
0.7580	4.00	408.15
0.8291	4.00	406.87
0.8834	4.00	405.74
1.0000	4.00	404.15
0.0000	6.00	443.30
0.0676	6.00	439.01
0.1000	6.00	437.07
0.1552	6.00	434.63
0.2136	6.00	432.01
0.2950	6.00	428.75
0.3951	6.00	425.49
0.5375	6.00	421.95
0.6730	6.00	418.93
0.7596	6.00	417.10
0.8365	6.00	415.91
0.8802	6.00	415.12
1.0000	6.00	413.57

Boiling temperature at pressure P, K [ref]

Fixed		Measured
Mole fraction of Decanoic acid, methyl ester (2) - Liquid	Pressure, kPa - Liquid	Boiling temperature at pressure P, K - Liquid
0.0000	2.00	417.53
0.0623	2.00	413.52
0.0935	2.00	411.63
0.1438	2.00	409.17
0.2009	2.00	406.77
0.2852	2.00	403.66
0.3889	2.00	400.44
0.5346	2.00	396.72
0.6691	2.00	393.75
0.7541	2.00	392.09
0.8227	2.00	391.15
0.8836	2.00	390.43
1.0000	2.00	389.10
0.0000	4.00	433.71
0.0659	4.00	429.37
0.0973	4.00	427.43
0.1524	4.00	424.78
0.2096	4.00	422.19
0.2908	4.00	419.12
0.3932	4.00	415.62
0.5354	4.00	412.11
0.6695	4.00	409.70
0.7580	4.00	408.15
0.8291	4.00	406.87
0.8834	4.00	405.74
1.0000	4.00	404.15
0.0000	6.00	443.30
0.0676	6.00	439.01
0.1000	6.00	437.07
0.1552	6.00	434.63
0.2136	6.00	432.01
0.2950	6.00	428.75
0.3951	6.00	425.49
0.5375	6.00	421.95
0.6730	6.00	418.93
0.7596	6.00	417.10
0.8365	6.00	415.91
0.8802	6.00	415.12
1.0000	6.00	413.57

Sources

• Isobaric vapor-liquid equilibrium for binary system of methyl caprate + methyl laurate at 2, 4 and 6 kPa
• Isobaric molar heat capacities of binary mixtures containing methyl caprate and methyl laurate at pressures up to 16.2 MPa