Mixture of Methyl formate + Methyl valerate + Methyl Alcohol

Datasets

1. Molar enthalpy of mixing with solvent, kJ/mol (2)
2. ρ_l - Mass density, kg/m3 (2)

Molar enthalpy of mixing with solvent, kJ/mol of Methyl formate (1) [ref]

Operational conditions:

• Pressure, kPa = 100 (Liquid)
• Temperature, K = 298.15 (Liquid)

Fixed		Measured
Mole fraction of Methyl valerate (2) - Liquid	Mole fraction of Methyl formate (1) - Liquid	Molar enthalpy of mixing with solvent, kJ/mol of Methyl formate (1) - Liquid
0.0335	0.8498	0.6470
0.0343	0.8463	0.6950
0.0377	0.8312	0.7460
0.0416	0.8135	0.8060
0.0469	0.7900	0.8680
0.0532	0.7618	0.9280
0.0606	0.7286	0.9830
0.0693	0.6898	1.033
0.0799	0.6421	1.063
0.0925	0.5855	1.069
0.1068	0.5214	1.046
0.1232	0.4480	0.9780
0.1387	0.3785	0.8760
0.1555	0.3032	0.7410
0.1730	0.2249	0.5830
0.1900	0.1488	0.3760
0.2056	0.0788	0.1720
0.0804	0.7786	0.7360
0.0881	0.7574	0.7810
0.0977	0.7310	0.8260
0.1098	0.6977	0.8710
0.1249	0.6561	0.9050
0.1419	0.6092	0.9230
0.1602	0.5588	0.9260
0.1811	0.5012	0.9060
0.2042	0.4377	0.8580
0.2281	0.3719	0.7880
0.2507	0.3096	0.7020
0.2711	0.2533	0.5980
0.2968	0.1827	0.4480
0.3231	0.1102	0.2760
0.3461	0.0468	0.1210
0.0987	0.7864	0.6440
0.1091	0.7638	0.6870
0.1218	0.7363	0.7290
0.1363	0.7049	0.7680
0.1529	0.6690	0.8010
0.1720	0.6276	0.8250
0.1930	0.5821	0.8350
0.2163	0.5317	0.8270
0.2401	0.4802	0.8020
0.2644	0.4275	0.7620
0.2909	0.3702	0.7030
0.3214	0.3042	0.6120
0.3518	0.2383	0.4970
0.3828	0.1712	0.3610
0.4143	0.1030	0.2160
0.4412	0.0448	0.0870
0.1103	0.7725	0.6540
0.1216	0.7492	0.6910
0.1342	0.7232	0.7420
0.1538	0.6827	0.7840
0.1766	0.6357	0.8090
0.2012	0.5850	0.8230
0.2328	0.5198	0.8090
0.2691	0.4449	0.7570
0.3085	0.3637	0.6650
0.3509	0.2762	0.5360
0.3939	0.1875	0.3770
0.4331	0.1067	0.2130
0.4617	0.0477	0.0890
0.1668	0.7482	0.5530
0.1844	0.7216	0.5940
0.2077	0.6864	0.6330
0.2362	0.6434	0.6630
0.2689	0.5940	0.6810
0.3063	0.5375	0.6880
0.3523	0.4680	0.6710
0.4046	0.3891	0.6210
0.4580	0.3084	0.5380
0.5182	0.2175	0.4190
0.5693	0.1404	0.2970
0.6206	0.0629	0.1630
0.2334	0.7002	0.4650
0.2615	0.6641	0.4920
0.2953	0.6207	0.5110
0.3339	0.5711	0.5200
0.3808	0.5109	0.5140
0.4322	0.4449	0.4890
0.4889	0.3721	0.4440
0.5529	0.2898	0.3740
0.6205	0.2030	0.2770
0.6870	0.1176	0.1620
0.7469	0.0407	0.0570

Molar enthalpy of mixing with solvent, kJ/mol of Methyl formate (1) [ref]

Operational conditions:

• Pressure, kPa = 100 (Liquid)
• Temperature, K = 298.15 (Liquid)

Fixed		Measured
Mole fraction of Methyl valerate (2) - Liquid	Mole fraction of Methyl formate (1) - Liquid	Molar enthalpy of mixing with solvent, kJ/mol of Methyl formate (1) - Liquid
0.0335	0.8498	0.6470
0.0343	0.8463	0.6950
0.0377	0.8312	0.7460
0.0416	0.8135	0.8060
0.0469	0.7900	0.8680
0.0532	0.7618	0.9280
0.0606	0.7286	0.9830
0.0693	0.6898	1.033
0.0799	0.6421	1.063
0.0925	0.5855	1.069
0.1068	0.5214	1.046
0.1232	0.4480	0.9780
0.1387	0.3785	0.8760
0.1555	0.3032	0.7410
0.1730	0.2249	0.5830
0.1900	0.1488	0.3760
0.2056	0.0788	0.1720
0.0804	0.7786	0.7360
0.0881	0.7574	0.7810
0.0977	0.7310	0.8260
0.1098	0.6977	0.8710
0.1249	0.6561	0.9050
0.1419	0.6092	0.9230
0.1602	0.5588	0.9260
0.1811	0.5012	0.9060
0.2042	0.4377	0.8580
0.2281	0.3719	0.7880
0.2507	0.3096	0.7020
0.2711	0.2533	0.5980
0.2968	0.1827	0.4480
0.3231	0.1102	0.2760
0.3461	0.0468	0.1210
0.0987	0.7864	0.6440
0.1091	0.7638	0.6870
0.1218	0.7363	0.7290
0.1363	0.7049	0.7680
0.1529	0.6690	0.8010
0.1720	0.6276	0.8250
0.1930	0.5821	0.8350
0.2163	0.5317	0.8270
0.2401	0.4802	0.8020
0.2644	0.4275	0.7620
0.2909	0.3702	0.7030
0.3214	0.3042	0.6120
0.3518	0.2383	0.4970
0.3828	0.1712	0.3610
0.4143	0.1030	0.2160
0.4412	0.0448	0.0870
0.1103	0.7725	0.6540
0.1216	0.7492	0.6910
0.1342	0.7232	0.7420
0.1538	0.6827	0.7840
0.1766	0.6357	0.8090
0.2012	0.5850	0.8230
0.2328	0.5198	0.8090
0.2691	0.4449	0.7570
0.3085	0.3637	0.6650
0.3509	0.2762	0.5360
0.3939	0.1875	0.3770
0.4331	0.1067	0.2130
0.4617	0.0477	0.0890
0.1668	0.7482	0.5530
0.1844	0.7216	0.5940
0.2077	0.6864	0.6330
0.2362	0.6434	0.6630
0.2689	0.5940	0.6810
0.3063	0.5375	0.6880
0.3523	0.4680	0.6710
0.4046	0.3891	0.6210
0.4580	0.3084	0.5380
0.5182	0.2175	0.4190
0.5693	0.1404	0.2970
0.6206	0.0629	0.1630
0.2334	0.7002	0.4650
0.2615	0.6641	0.4920
0.2953	0.6207	0.5110
0.3339	0.5711	0.5200
0.3808	0.5109	0.5140
0.4322	0.4449	0.4890
0.4889	0.3721	0.4440
0.5529	0.2898	0.3740
0.6205	0.2030	0.2770
0.6870	0.1176	0.1620
0.7469	0.0407	0.0570

Mass density, kg/m3 [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 100 (Liquid)

Fixed		Measured
Mole fraction of Methyl valerate (2) - Liquid	Mole fraction of Methyl formate (1) - Liquid	Mass density, kg/m3 - Liquid
0.0000	1.0000	966.28
0.0097	0.9605	961.26
0.0190	0.9224	956.25
0.0352	0.8557	947.43
0.0480	0.8035	940.51
0.0595	0.7561	934.22
0.0716	0.7069	927.72
0.0827	0.6611	921.67
0.0949	0.6112	915.09
0.1189	0.5130	902.25
0.1417	0.4194	890.13
0.1560	0.3609	882.62
0.1679	0.3122	876.39
0.1890	0.2261	865.47
0.2055	0.1583	856.93
0.2177	0.1083	850.65
0.0000	1.0000	966.28
0.0209	0.9481	958.88
0.0418	0.8963	951.68
0.0585	0.8548	945.98
0.0769	0.8093	939.94
0.1018	0.7475	931.91
0.1121	0.7218	928.62
0.1451	0.6401	918.6
0.1802	0.5529	908.44
0.2057	0.4898	901.41
0.2182	0.4586	898.04
0.2597	0.3558	887.35
0.3020	0.2508	877.03
0.3225	0.1999	872.27
0.3436	0.1476	867.43
0.3570	0.1143	864.43
0.3788	0.0603	859.62
0.0000	1.0000	966.28
0.0320	0.9460	957.92
0.0630	0.8936	950.16
0.0980	0.8345	941.91
0.1213	0.7952	936.81
0.1456	0.7542	931.64
0.1793	0.6972	924.89
0.2438	0.5883	913.16
0.2970	0.4985	904.5
0.3199	0.4598	901.04
0.3563	0.3983	895.8
0.3806	0.3573	892.49
0.4481	0.2433	883.9
0.4179	0.2943	887.6
0.4692	0.2077	881.36
0.4909	0.1710	878.87
0.5292	0.1064	874.57
0.5521	0.0677	872.1
0.5610	0.0527	871.23
0.0000	1.0000	966.28
0.0506	0.9353	955.31
0.0785	0.8996	949.82
0.1181	0.8489	942.53
0.1753	0.7758	933.1
0.2286	0.7076	925.27
0.2836	0.6372	918.11
0.3239	0.5857	913.33
0.3973	0.4918	905.54
0.4191	0.4639	903.4
0.4848	0.3799	897.52
0.5488	0.2980	892.37
0.5893	0.2462	889.4
0.6185	0.2089	887.35
0.6698	0.1433	884.0
0.7028	0.1010	881.92
0.0000	1.0000	966.28
0.0473	0.9461	956.79
0.0928	0.8943	948.38
0.1403	0.8402	940.79
0.2139	0.7564	930.5
0.2638	0.6995	924.38
0.3317	0.6222	916.97
0.3953	0.5497	910.9
0.4309	0.5092	907.81
0.4743	0.4597	904.27
0.5584	0.3639	898.15
0.6482	0.2616	892.48
0.6933	0.2103	889.95
0.7383	0.1590	887.59
0.7692	0.1238	886.03
0.8152	0.0714	883.8

Mass density, kg/m3 [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 100 (Liquid)

Fixed		Measured
Mole fraction of Methyl valerate (2) - Liquid	Mole fraction of Methyl formate (1) - Liquid	Mass density, kg/m3 - Liquid
0.0000	1.0000	966.28
0.0097	0.9605	961.26
0.0190	0.9224	956.25
0.0352	0.8557	947.43
0.0480	0.8035	940.51
0.0595	0.7561	934.22
0.0716	0.7069	927.72
0.0827	0.6611	921.67
0.0949	0.6112	915.09
0.1189	0.5130	902.25
0.1417	0.4194	890.13
0.1560	0.3609	882.62
0.1679	0.3122	876.39
0.1890	0.2261	865.47
0.2055	0.1583	856.93
0.2177	0.1083	850.65
0.0000	1.0000	966.28
0.0209	0.9481	958.88
0.0418	0.8963	951.68
0.0585	0.8548	945.98
0.0769	0.8093	939.94
0.1018	0.7475	931.91
0.1121	0.7218	928.62
0.1451	0.6401	918.6
0.1802	0.5529	908.44
0.2057	0.4898	901.41
0.2182	0.4586	898.04
0.2597	0.3558	887.35
0.3020	0.2508	877.03
0.3225	0.1999	872.27
0.3436	0.1476	867.43
0.3570	0.1143	864.43
0.3788	0.0603	859.62
0.0000	1.0000	966.28
0.0320	0.9460	957.92
0.0630	0.8936	950.16
0.0980	0.8345	941.91
0.1213	0.7952	936.81
0.1456	0.7542	931.64
0.1793	0.6972	924.89
0.2438	0.5883	913.16
0.2970	0.4985	904.5
0.3199	0.4598	901.04
0.3563	0.3983	895.8
0.3806	0.3573	892.49
0.4481	0.2433	883.9
0.4179	0.2943	887.6
0.4692	0.2077	881.36
0.4909	0.1710	878.87
0.5292	0.1064	874.57
0.5521	0.0677	872.1
0.5610	0.0527	871.23
0.0000	1.0000	966.28
0.0506	0.9353	955.31
0.0785	0.8996	949.82
0.1181	0.8489	942.53
0.1753	0.7758	933.1
0.2286	0.7076	925.27
0.2836	0.6372	918.11
0.3239	0.5857	913.33
0.3973	0.4918	905.54
0.4191	0.4639	903.4
0.4848	0.3799	897.52
0.5488	0.2980	892.37
0.5893	0.2462	889.4
0.6185	0.2089	887.35
0.6698	0.1433	884.0
0.7028	0.1010	881.92
0.0000	1.0000	966.28
0.0473	0.9461	956.79
0.0928	0.8943	948.38
0.1403	0.8402	940.79
0.2139	0.7564	930.5
0.2638	0.6995	924.38
0.3317	0.6222	916.97
0.3953	0.5497	910.9
0.4309	0.5092	907.81
0.4743	0.4597	904.27
0.5584	0.3639	898.15
0.6482	0.2616	892.48
0.6933	0.2103	889.95
0.7383	0.1590	887.59
0.7692	0.1238	886.03
0.8152	0.0714	883.8

Sources

• Mixing thermodynamic properties of ester-containing solutions: A study on the ternary (methyl alkanoate (pentanoate and methanoate) + methanol) and the corresponding binaries. New contributions to the (ester + ester) interactions