Mixture of Acetic acid + Ethyl Acetate

Datasets

1. Mole fraction (2)
2. η - Viscosity, Pa*s (2)
3. Excess molar enthalpy (molar enthalpy (2)
4. ρ_l - Mass density, kg/m3 (2)
5. c_sound,fluid - Speed of Sound, m/s (2)
6. T_boil - Boiling temperature at pressure P, K (6)
7. Vapor Liquid Equilibrium at Constant Pressure
8. Vapor Liquid Equilibrium at Constant Temperature (2)
9. Vapor or sublimation pressure, kPa (2)

Mole fraction of Ethyl Acetate (2) [ref]

Operational condition: Pressure, kPa = 101.325 (Liquid)

Mole fraction of Ethyl Acetate (2) - Liquid	Mole fraction of Ethyl Acetate (2) - Gas
0.0238	0.0825
0.0366	0.1189
0.0476	0.1518
0.0776	0.2443
0.0907	0.2718
0.1170	0.3265
0.1410	0.3795
0.1657	0.4297
0.2203	0.5369
0.2661	0.6113
0.3085	0.6739
0.3924	0.7621
0.4617	0.8215
0.4924	0.8463
0.5332	0.8702
0.5559	0.8820
0.6068	0.9074
0.6568	0.9266
0.6986	0.9439
0.7426	0.9571
0.7974	0.9710
0.8415	0.9769
0.8644	0.9811
0.9197	0.9898
0.9482	0.9938
0.9809	0.9968

Mole fraction of Ethyl Acetate (2) [ref]

Operational condition: Pressure, kPa = 101.325 (Liquid)

Mole fraction of Ethyl Acetate (2) - Liquid	Mole fraction of Ethyl Acetate (2) - Gas
0.0238	0.0825
0.0366	0.1189
0.0476	0.1518
0.0776	0.2443
0.0907	0.2718
0.1170	0.3265
0.1410	0.3795
0.1657	0.4297
0.2203	0.5369
0.2661	0.6113
0.3085	0.6739
0.3924	0.7621
0.4617	0.8215
0.4924	0.8463
0.5332	0.8702
0.5559	0.8820
0.6068	0.9074
0.6568	0.9266
0.6986	0.9439
0.7426	0.9571
0.7974	0.9710
0.8415	0.9769
0.8644	0.9811
0.9197	0.9898
0.9482	0.9938
0.9809	0.9968

Viscosity, Pa*s [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Acetic acid (1) - Liquid	Viscosity, Pa*s - Liquid
293.15	0.0000	0.0005
293.15	0.0697	0.0005
293.15	0.0988	0.0005
293.15	0.1960	0.0005
293.15	0.2944	0.0006
293.15	0.3968	0.0006
293.15	0.5007	0.0007
293.15	0.5967	0.0007
293.15	0.7000	0.0008
293.15	0.7989	0.0009
293.15	0.8993	0.0011
293.15	0.9493	0.0011
293.15	1.0000	0.0012
298.15	0.0000	0.0004
298.15	0.0697	0.0004
298.15	0.0988	0.0005
298.15	0.1960	0.0005
298.15	0.2944	0.0005
298.15	0.3968	0.0006
298.15	0.5007	0.0006
298.15	0.5967	0.0007
298.15	0.7000	0.0008
298.15	0.7989	0.0008
298.15	0.8993	0.0010
298.15	0.9493	0.0010
298.15	1.0000	0.0011
303.15	0.0000	0.0004
303.15	0.0697	0.0004
303.15	0.0988	0.0004
303.15	0.1960	0.0005
303.15	0.2944	0.0005
303.15	0.3968	0.0005
303.15	0.5007	0.0006
303.15	0.5967	0.0006
303.15	0.7000	0.0007
303.15	0.7989	0.0008
303.15	0.8993	0.0009
303.15	0.9493	0.0010
303.15	1.0000	0.0010

Viscosity, Pa*s [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Acetic acid (1) - Liquid	Viscosity, Pa*s - Liquid
293.15	0.0000	0.0005
293.15	0.0697	0.0005
293.15	0.0988	0.0005
293.15	0.1960	0.0005
293.15	0.2944	0.0006
293.15	0.3968	0.0006
293.15	0.5007	0.0007
293.15	0.5967	0.0007
293.15	0.7000	0.0008
293.15	0.7989	0.0009
293.15	0.8993	0.0011
293.15	0.9493	0.0011
293.15	1.0000	0.0012
298.15	0.0000	0.0004
298.15	0.0697	0.0004
298.15	0.0988	0.0005
298.15	0.1960	0.0005
298.15	0.2944	0.0005
298.15	0.3968	0.0006
298.15	0.5007	0.0006
298.15	0.5967	0.0007
298.15	0.7000	0.0008
298.15	0.7989	0.0008
298.15	0.8993	0.0010
298.15	0.9493	0.0010
298.15	1.0000	0.0011
303.15	0.0000	0.0004
303.15	0.0697	0.0004
303.15	0.0988	0.0004
303.15	0.1960	0.0005
303.15	0.2944	0.0005
303.15	0.3968	0.0005
303.15	0.5007	0.0006
303.15	0.5967	0.0006
303.15	0.7000	0.0007
303.15	0.7989	0.0008
303.15	0.8993	0.0009
303.15	0.9493	0.0010
303.15	1.0000	0.0010

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational conditions:

• Temperature, K = 323.15 (Liquid)
• Pressure, kPa = 1548 (Liquid)

Mole fraction of Ethyl Acetate (2) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.0148	-0.0074
0.0300	-0.0148
0.0613	-0.0266
0.1108	-0.0387
0.1637	-0.0437
0.2403	-0.0394
0.3246	-0.0264
0.4179	-0.0055
0.5217	0.0219
0.6379	0.0539
0.7347	0.0730
0.8409	0.0786
0.9178	0.0638
0.9582	0.0440

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational conditions:

• Temperature, K = 323.15 (Liquid)
• Pressure, kPa = 1548 (Liquid)

Mole fraction of Ethyl Acetate (2) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.0148	-0.0074
0.0300	-0.0148
0.0613	-0.0266
0.1108	-0.0387
0.1637	-0.0437
0.2403	-0.0394
0.3246	-0.0264
0.4179	-0.0055
0.5217	0.0219
0.6379	0.0539
0.7347	0.0730
0.8409	0.0786
0.9178	0.0638
0.9582	0.0440

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Acetic acid (1) - Liquid	Mass density, kg/m3 - Liquid
293.15	0.0000	900.52
293.15	0.0697	907.35
293.15	0.0988	910.56
293.15	0.1960	920.61
293.15	0.2944	931.46
293.15	0.3968	943.68
293.15	0.5007	957.31
293.15	0.5967	971.28
293.15	0.7000	987.79
293.15	0.7989	1005.47
293.15	0.8993	1025.8
293.15	0.9493	1037.09
293.15	1.0000	1049.3
298.15	0.0000	894.43
298.15	0.0697	901.3
298.15	0.0988	904.53
298.15	0.1960	914.62
298.15	0.2944	925.5
298.15	0.3968	937.74
298.15	0.5007	951.4
298.15	0.5967	965.4
298.15	0.7000	981.94
298.15	0.7989	999.66
298.15	0.8993	1020.06
298.15	0.9493	1031.4
298.15	1.0000	1043.65
303.15	0.0000	888.3
303.15	0.0697	895.2
303.15	0.0988	898.44
303.15	0.1960	908.59
303.15	0.2944	919.49
303.15	0.3968	931.77
303.15	0.5007	945.46
303.15	0.5967	959.5
303.15	0.7000	976.09
303.15	0.7989	993.85
303.15	0.8993	1014.32
303.15	0.9493	1025.69
303.15	1.0000	1038.0

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Acetic acid (1) - Liquid	Mass density, kg/m3 - Liquid
293.15	0.0000	900.52
293.15	0.0697	907.35
293.15	0.0988	910.56
293.15	0.1960	920.61
293.15	0.2944	931.46
293.15	0.3968	943.68
293.15	0.5007	957.31
293.15	0.5967	971.28
293.15	0.7000	987.79
293.15	0.7989	1005.47
293.15	0.8993	1025.8
293.15	0.9493	1037.09
293.15	1.0000	1049.3
298.15	0.0000	894.43
298.15	0.0697	901.3
298.15	0.0988	904.53
298.15	0.1960	914.62
298.15	0.2944	925.5
298.15	0.3968	937.74
298.15	0.5007	951.4
298.15	0.5967	965.4
298.15	0.7000	981.94
298.15	0.7989	999.66
298.15	0.8993	1020.06
298.15	0.9493	1031.4
298.15	1.0000	1043.65
303.15	0.0000	888.3
303.15	0.0697	895.2
303.15	0.0988	898.44
303.15	0.1960	908.59
303.15	0.2944	919.49
303.15	0.3968	931.77
303.15	0.5007	945.46
303.15	0.5967	959.5
303.15	0.7000	976.09
303.15	0.7989	993.85
303.15	0.8993	1014.32
303.15	0.9493	1025.69
303.15	1.0000	1038.0

Speed of sound, m/s [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Acetic acid (1) - Liquid	Speed of sound, m/s - Liquid
293.15	0.0000	1163.0
293.15	0.0697	1165.0
293.15	0.0988	1166.0
293.15	0.1960	1166.0
293.15	0.2944	1165.0
293.15	0.3968	1165.0
293.15	0.5007	1163.0
293.15	0.5967	1162.0
293.15	0.7000	1159.0
293.15	0.7989	1157.0
293.15	0.8993	1153.0
293.15	0.9493	1152.0
293.15	1.0000	1149.0
298.15	0.0000	1140.0
298.15	0.0697	1143.0
298.15	0.0988	1144.0
298.15	0.1960	1144.0
298.15	0.2944	1144.0
298.15	0.3968	1143.0
298.15	0.5007	1142.0
298.15	0.5967	1141.0
298.15	0.7000	1140.0
298.15	0.7989	1137.0
298.15	0.8993	1135.0
298.15	0.9493	1134.0
298.15	1.0000	1132.0
303.15	0.0000	1118.0
303.15	0.0697	1121.0
303.15	0.0988	1122.0
303.15	0.1960	1123.0
303.15	0.2944	1123.0
303.15	0.3968	1123.0
303.15	0.5007	1122.0
303.15	0.5967	1121.0
303.15	0.7000	1120.0
303.15	0.7989	1119.0
303.15	0.8993	1117.0
303.15	0.9493	1116.0
303.15	1.0000	1115.0

Speed of sound, m/s [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Acetic acid (1) - Liquid	Speed of sound, m/s - Liquid
293.15	0.0000	1163.0
293.15	0.0697	1165.0
293.15	0.0988	1166.0
293.15	0.1960	1166.0
293.15	0.2944	1165.0
293.15	0.3968	1165.0
293.15	0.5007	1163.0
293.15	0.5967	1162.0
293.15	0.7000	1159.0
293.15	0.7989	1157.0
293.15	0.8993	1153.0
293.15	0.9493	1152.0
293.15	1.0000	1149.0
298.15	0.0000	1140.0
298.15	0.0697	1143.0
298.15	0.0988	1144.0
298.15	0.1960	1144.0
298.15	0.2944	1144.0
298.15	0.3968	1143.0
298.15	0.5007	1142.0
298.15	0.5967	1141.0
298.15	0.7000	1140.0
298.15	0.7989	1137.0
298.15	0.8993	1135.0
298.15	0.9493	1134.0
298.15	1.0000	1132.0
303.15	0.0000	1118.0
303.15	0.0697	1121.0
303.15	0.0988	1122.0
303.15	0.1960	1123.0
303.15	0.2944	1123.0
303.15	0.3968	1123.0
303.15	0.5007	1122.0
303.15	0.5967	1121.0
303.15	0.7000	1120.0
303.15	0.7989	1119.0
303.15	0.8993	1117.0
303.15	0.9493	1116.0
303.15	1.0000	1115.0

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 101.325 (Liquid)

Mole fraction of Ethyl Acetate (2) - Liquid	Boiling temperature at pressure P, K - Liquid
0.0238	388.86
0.0366	387.91
0.0476	386.97
0.0776	385.03
0.0907	384.03
0.1170	382.21
0.1410	380.57
0.1657	379.12
0.2203	376.35
0.2661	373.77
0.3085	371.67
0.3924	367.87
0.4617	365.00
0.4924	364.00
0.5332	362.65
0.5559	361.91
0.6068	360.21
0.6568	358.94
0.6986	357.82
0.7426	356.57
0.7974	355.20
0.8415	354.21
0.8644	353.55
0.9197	352.20
0.9482	351.45
0.9809	350.61

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 77.3 (Liquid)

Mole fraction of Ethyl Acetate (2) - Liquid	Boiling temperature at pressure P, K - Liquid
0.1030	375.25
0.2220	368.85
0.3770	360.75
0.5460	352.95
0.7090	347.75

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 77.3 (Gas)

Mole fraction of Ethyl Acetate (2) - Gas	Boiling temperature at pressure P, K - Liquid
0.2790	375.25
0.4520	368.85
0.6830	360.75
0.8290	352.95
0.9010	347.75

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 101.325 (Liquid)

Mole fraction of Ethyl Acetate (2) - Liquid	Boiling temperature at pressure P, K - Liquid
0.0238	388.86
0.0366	387.91
0.0476	386.97
0.0776	385.03
0.0907	384.03
0.1170	382.21
0.1410	380.57
0.1657	379.12
0.2203	376.35
0.2661	373.77
0.3085	371.67
0.3924	367.87
0.4617	365.00
0.4924	364.00
0.5332	362.65
0.5559	361.91
0.6068	360.21
0.6568	358.94
0.6986	357.82
0.7426	356.57
0.7974	355.20
0.8415	354.21
0.8644	353.55
0.9197	352.20
0.9482	351.45
0.9809	350.61

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 77.3 (Liquid)

Mole fraction of Ethyl Acetate (2) - Liquid	Boiling temperature at pressure P, K - Liquid
0.1030	375.25
0.2220	368.85
0.3770	360.75
0.5460	352.95
0.7090	347.75

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 77.3 (Gas)

Mole fraction of Ethyl Acetate (2) - Gas	Boiling temperature at pressure P, K - Liquid
0.2790	375.25
0.4520	368.85
0.6830	360.75
0.8290	352.95
0.9010	347.75

Vapor Liquid Equilibrium at Constant Pressure [ref]

Operational condition: Pressure, kPa = 101.33 (VLE)

Fixed	Measured
T [K] - VLE	x1[mol/mol] of Ethyl Acetate (2) - Liquid	y1[mol/mol] of Ethyl Acetate (2) - Vapour
381.25	0.1380	0.3270
378.25	0.1820	0.4220
372.85	0.2860	0.5890
366.75	0.4200	0.7320
361.45	0.5610	0.8540
352.65	0.8720	0.9780

Vapor Liquid Equilibrium at Constant Temperature [ref]

Operational condition: Temperature, K = 333.11 (VLE)

Fixed	Measured
P [kPa] - VLE	x1[mol/mol] of Ethyl Acetate (2) - Liquid	y1[mol/mol] of Ethyl Acetate (2) - Vapour
17.025	0.1098	0.3055
23.585	0.2425	0.5516
29.998	0.3725	0.7158
31.064	0.3930	0.7332
31.197	0.3986	0.7379
35.33	0.4939	0.8160
44.596	0.7311	0.9390
53.382	0.9033	0.9785
53.489	0.9410	0.9892

Vapor Liquid Equilibrium at Constant Temperature [ref]

Operational condition: Temperature, K = 315.15 (VLE)

Fixed	Measured
P [kPa] - VLE	x1[mol/mol] of Ethyl Acetate (2) - Liquid	y1[mol/mol] of Ethyl Acetate (2) - Vapour
5.133	0.0000	0.0000
9.133	0.1632	0.4725
12.772	0.3168	0.6892
18.932	0.5796	0.8934
21.865	0.7312	0.9488
25.078	0.9033	0.9787
25.878	0.9295	0.9866

Vapor or sublimation pressure, kPa [ref]

Operational condition: Temperature, K = 323.15 (Liquid)

Mole fraction of Ethyl Acetate (2) - Liquid	Vapor or sublimation pressure, kPa - Gas
0.0000	7.61
0.0012	7.65
0.0022	7.69
0.0035	7.73
0.0057	7.80
0.0082	7.88
0.0125	8.03
0.0184	8.23
0.0272	8.52
0.0384	8.90
0.0526	9.38
0.0699	9.97
0.0904	10.67
0.1163	11.56
0.1455	12.55
0.1781	13.66
0.2133	14.85
0.2505	16.10
0.2895	17.39
0.3287	18.65
0.3298	18.70
0.3677	19.89
0.3702	20.00
0.4104	21.21
0.4109	21.28
0.4572	22.64
0.5073	24.13
0.5601	25.66
0.6150	27.21
0.6710	28.76
0.7260	30.25
0.7793	31.67
0.8243	32.87
0.8647	33.96
0.8993	34.88
0.9275	35.67
0.9502	36.31
0.9654	36.76
0.9760	37.08
0.9842	37.33
0.9897	37.50
0.9952	37.68
0.9976	37.76
1.0000	37.85

Vapor or sublimation pressure, kPa [ref]

Operational condition: Temperature, K = 323.15 (Liquid)

Mole fraction of Ethyl Acetate (2) - Liquid	Vapor or sublimation pressure, kPa - Gas
0.0000	7.61
0.0012	7.65
0.0022	7.69
0.0035	7.73
0.0057	7.80
0.0082	7.88
0.0125	8.03
0.0184	8.23
0.0272	8.52
0.0384	8.90
0.0526	9.38
0.0699	9.97
0.0904	10.67
0.1163	11.56
0.1455	12.55
0.1781	13.66
0.2133	14.85
0.2505	16.10
0.2895	17.39
0.3287	18.65
0.3298	18.70
0.3677	19.89
0.3702	20.00
0.4104	21.21
0.4109	21.28
0.4572	22.64
0.5073	24.13
0.5601	25.66
0.6150	27.21
0.6710	28.76
0.7260	30.25
0.7793	31.67
0.8243	32.87
0.8647	33.96
0.8993	34.88
0.9275	35.67
0.9502	36.31
0.9654	36.76
0.9760	37.08
0.9842	37.33
0.9897	37.50
0.9952	37.68
0.9976	37.76
1.0000	37.85

Sources

• Dortmund Data Bank Vapor-Liquid Equilibrium Data
• Vapor liquid equilibria for the quaternary reactive system ethyl acetate + ethanol +water + acetic acid and some of the constituent binary systems at 101.3 kPa
• Experimental measurements of vapor liquid equilibria at low pressure: Systems containing alcohols, esters and organic acids
• Phase equilibria and excess properties for binary systems in reactive distillation processes Part II. Ethyl acetate synthesis
• Dynamic Viscosities, Densities, and Speed of Sound and Derived Properties of the Binary Systems Acetic Acid with Water, Methanol, Ethanol, Ethyl Acetate and Methyl Acetate at T = (293.15, 298.15, and 303.15) K at Atmospheric Pressure