Chemical Properties of Furan, tetrahydro-2-methyl- (CAS 96-47-9)

InChI

InChI=1S/C5H10O/c1-5-3-2-4-6-5/h5H,2-4H2,1H3

InChI Key

JWUJQDFVADABEY-UHFFFAOYSA-N

Formula

C5H10O

SMILES

CC1CCCO1

Molecular Weight¹

86.13

CAS

96-47-9

Other Names

• .alpha.-methyltetramethylene oxide
• 2-Methylfuranidine
• 2-Methyloxolane
• 2-Methyltetrahydrofuran
• 2-Methyltetrahydrofurane
• Furan, 2-methyl-tetrahydro-
• Methyltetrahydrofuran
• Tetrahydro-2-methylfuran
• Tetrahydrofuran, 2-methyl-
• Tetrahydrosylvan

• PAff : Proton affinity (kJ/mol).
• BasG : Gas basicity (kJ/mol).
• C_p,gas : Ideal gas heat capacity (J/mol×K).
• C_p,liquid : Liquid phase heat capacity (J/mol×K).
• η : Dynamic viscosity (Pa×s).
• Δ_fG° : Standard Gibbs free energy of formation (kJ/mol).
• Δ_fH°_gas : Enthalpy of formation at standard conditions (kJ/mol).
• Δ_fusH° : Enthalpy of fusion at standard conditions (kJ/mol).
• Δ_vapH° : Enthalpy of vaporization at standard conditions (kJ/mol).
• IE : Ionization energy (eV).
• ν : Kinematic viscosity (m²/s).
• log₁₀WS : Log10 of Water solubility in mol/l.
• logP_oct/wat : Octanol/Water partition coefficient.
• McVol : McGowan's characteristic volume (ml/mol).
• P_c : Critical Pressure (kPa).
• P_vap : Vapor pressure (kPa).
• n₀ : Refractive Index.
• ρ_l : Liquid Density (kg/m³).
• I_np : Non-polar retention indices.
• I : Polar retention indices.
• T_boil : Normal Boiling Point Temperature (K).
• T_c : Critical Temperature (K).
• T_fus : Normal melting (fusion) point (K).
• V_c : Critical Volume (m³/kmol).
• ¹: Molecular weight from the IUPAC atomic weights tables.

Physical Properties

Property	Value	Unit	Source
PAff	840.80	kJ/mol	NIST
BasG	811.60	kJ/mol	NIST
ΔfG°	-58.35	kJ/mol	Joback Calculated Property
ΔfH°gas	-218.05	kJ/mol	Joback Calculated Property
ΔfusH°	10.62	kJ/mol	Joback Calculated Property
ΔvapH°	[33.70; 34.00]	kJ/mol
ΔvapH°	34.00	kJ/mol	NIST
ΔvapH°	33.70	kJ/mol	NIST
IE	9.22 ± 0.05	eV	NIST
log10WS	[0.11; 0.11]
log10WS	0.11		Aq. Sol...
log10WS	0.11		Estimat...
logPoct/wat	1.185		Crippen Calculated Property
McVol	76.320	ml/mol	McGowan Calculated Property
Pc	3757.63 ± 68.94	kPa	NIST
Inp	[661.00; 682.00]
Inp	661.00		NIST
Inp	669.00		NIST
Inp	664.00		NIST
Inp	678.00		NIST
Inp	663.00		NIST
Inp	674.00		NIST
Inp	682.00		NIST
Inp	664.00		NIST
Inp	663.00		NIST
I	[876.00; 951.00]
I	925.00		NIST
I	935.00		NIST
I	876.00		NIST
I	876.00		NIST
I	951.00		NIST
I	925.00		NIST
Tboil	[338.15; 359.65]	K
Tboil	353.20	K	NIST
Tboil	352.65 ± 2.00	K	NIST
Tboil	353.10 ± 0.30	K	NIST
Tboil	353.15 ± 1.00	K	NIST
Tboil	359.65 ± 1.00	K	NIST
Tboil	Outlier 338.15 ± 2.00	K	NIST
Tc	537.00 ± 2.00	K	NIST
Tfus	137.05 ± 0.40	K	NIST
Vc	0.267 ± 0.005	m3/kmol	NIST

Temperature Dependent Properties

Property	Value	Unit	Temperature (K)	Source
Cp,gas	[129.20; 194.00]	J/mol×K	[356.03; 553.34]
T(K) Ideal gas heat capacity (J/mol×K) 130 140 150 160 170 180 190 200 400 450 500 550
Cp,gas	129.20	J/mol×K	356.03	Joback Calculated Property
Cp,gas	141.40	J/mol×K	388.92	Joback Calculated Property
Cp,gas	153.02	J/mol×K	421.80	Joback Calculated Property
Cp,gas	164.07	J/mol×K	454.69	Joback Calculated Property
Cp,gas	174.57	J/mol×K	487.57	Joback Calculated Property
Cp,gas	184.54	J/mol×K	520.46	Joback Calculated Property
Cp,gas	194.00	J/mol×K	553.34	Joback Calculated Property
Cp,liquid	[153.50; 166.20]	J/mol×K	[288.15; 323.15]
T(K) Liquid phase heat capacity (J/mol×K) 154 156 158 160 162 164 166 290 300 310 320
Cp,liquid	153.50	J/mol×K	288.15	Molar H...
Cp,liquid	155.30	J/mol×K	293.15	Molar H...
Cp,liquid	155.30	J/mol×K	293.15	Molar H...
Cp,liquid	156.90	J/mol×K	298.15	Molar H...
Cp,liquid	158.70	J/mol×K	303.15	Molar H...
Cp,liquid	158.60	J/mol×K	303.15	Molar H...
Cp,liquid	160.20	J/mol×K	308.15	Molar H...
Cp,liquid	162.10	J/mol×K	313.15	Molar H...
Cp,liquid	162.10	J/mol×K	313.15	Molar H...
Cp,liquid	164.20	J/mol×K	318.15	Molar H...
Cp,liquid	166.20	J/mol×K	323.15	Molar H...
η	[0.0004088; 0.0005618]	Pa×s	[283.15; 313.15]
η	0.0005618	Pa×s	283.15	Excess ...
η	0.0004776	Pa×s	298.15	Excess ...
η	0.0004088	Pa×s	313.15	Excess ...
ν	[0.0000005; 0.0000006]	m2/s	[298.15; 313.15]
ν	0.0000006	m2/s	298.15	Viscosi...
ν	0.0000005	m2/s	313.15	Viscosi...
Pvap	[4.93; 21.69]	kPa	[279.00; 310.11]
T(K) Vapor pressure (kPa) 5 10 15 20 280 290 300 310
Pvap	4.93	kPa	279.00	Vapor P...
Pvap	4.93	kPa	279.01	Vapor P...
Pvap	5.60	kPa	281.41	Vapor P...
Pvap	5.63	kPa	281.44	Vapor P...
Pvap	6.57	kPa	284.34	Vapor P...
Pvap	7.83	kPa	287.83	Vapor P...
Pvap	7.85	kPa	287.84	Vapor P...
Pvap	9.26	kPa	291.17	Vapor P...
Pvap	11.65	kPa	295.94	Vapor P...
Pvap	13.37	kPa	298.94	Vapor P...
Pvap	15.76	kPa	302.62	Vapor P...
Pvap	18.28	kPa	306.05	Vapor P...
Pvap	21.69	kPa	310.11	Vapor P...
n0	[1.40280; 1.40299]		[298.00; 298.15]
n0	1.40299		298.00	Quatern...
n0	1.40280		298.15	Ternary...
n0	1.40287		298.15	Thermop...
ρl	[848.10; 855.00]	kg/m3	[293.15; 298.15]
T(K) Liquid Density (kg/m3) 848 849 850 851 852 853 854 855 294 296 298
ρl	855.00	kg/m3	293.15	Isother...
ρl	851.60	kg/m3	295.00	High-pr...
ρl	848.10	kg/m3	298.15	Excess ...
ρl	848.10	kg/m3	298.15	Excess ...
ρl	848.10	kg/m3	298.15	Excess ...
ρl	849.20	kg/m3	298.15	Thermod...
ρl	849.40	kg/m3	298.15	Study o...

Correlations

Property	Value	Unit	Temperature (K)	Source
Pvap	[1.33; 202.64]	kPa	[258.70; 374.84]	The Yaw...
Equation			ln(Pvp) = A + B/(T + C)
Coefficient A			1.47976e+01
Coefficient B			-3.18218e+03
Coefficient C			-3.93870e+01
Temperature range, min.			258.70
Temperature range, max.			374.84
T(K) Vapor pressure (kPa) 0 50 100 150 200 300 350
Pvap	1.33	kPa	258.70	Calculated Property
Pvap	2.99	kPa	271.60	Calculated Property
Pvap	6.14	kPa	284.51	Calculated Property
Pvap	11.76	kPa	297.41	Calculated Property
Pvap	21.16	kPa	310.32	Calculated Property
Pvap	36.10	kPa	323.22	Calculated Property
Pvap	58.78	kPa	336.13	Calculated Property
Pvap	91.90	kPa	349.03	Calculated Property
Pvap	138.64	kPa	361.94	Calculated Property
Pvap	202.64	kPa	374.84	Calculated Property

Similar Compounds

Find more compounds similar to Furan, tetrahydro-2-methyl-.

Mixtures

• n-Butyl ether + Furan, tetrahydro-2-methyl-
• Propane, 2-methoxy-2-methyl- + Furan, tetrahydro-2-methyl-
• Dodecane + Propane, 2-methoxy-2-methyl- + Furan, tetrahydro-2-methyl-
• Octane + Propane, 2-methoxy-2-methyl- + Furan, tetrahydro-2-methyl-
• 1-Hexene + Propane, 2-methoxy-2-methyl- + Furan, tetrahydro-2-methyl-
• Water + Furan, tetrahydro-2-methyl-
• Furfural + Water + Furan, tetrahydro-2-methyl-
• Acetic acid + Water + Furan, tetrahydro-2-methyl-
• Butane, 2-chloro- + Furan, tetrahydro-2-methyl-
• Propane, 1-chloro-2-methyl- + Furan, tetrahydro-2-methyl-
• Butane, 1-chloro- + Furan, tetrahydro-2-methyl-
• Propane, 2-chloro-2-methyl- + Furan, tetrahydro-2-methyl-
• Benzene, fluoro- + Furan, tetrahydro-2-methyl-
• Benzene, chloro- + Furan, tetrahydro-2-methyl-
• Benzene + Furan, tetrahydro-2-methyl-
• Propene, hexafluoro- + Furan, tetrahydro-2-methyl-
• 1-Butanol + Furan, tetrahydro-2-methyl-
• 1-Propanol, 2-methyl- + Furan, tetrahydro-2-methyl-
• 2-Propanol, 2-methyl- + Furan, tetrahydro-2-methyl-
• Cyclohexane, chloro- + Furan, tetrahydro-2-methyl-

Find more mixtures with Furan, tetrahydro-2-methyl-.

Sources

• Crippen Method
• High-pressure vapor-liquid equilibria of the second generation biofuel blends (2-methylfuran + iso-octane) and (2-methyltetrahydrofuran + di-n-butyl ether): Experiments and PCP-SAFT modeling
• Liquid-liquid equilibrium of 2-methyltetrahydrofuran/water over wide temperature range: Measurements and rigorous regression
• Excess molar enthalpies of the ternary mixtures: (methyl tert-butyl ether or 2-methyltetrahydrofuran + cyclohexane + 2,2,4- trimethylpentane} at the temperature 298.15 K
• Excess molar enthalpies of the ternary mixtures: {tetrahydrofuran or 2-methyltetrahydrofuran + methyl tert-butyl ether + n-dodecane} at the temperature 298.15 K
• Excess molar enthalpies of the ternary mixtures: (tetrahydrofuran or 2-methyltetrahydrofuran + methyl tert-butyl ether + n-octane) at the temperature 298.15 K
• Excess molar enthalpies of the ternary mixtures (1-hexene + tetrahydrofuran or 2-methyltetrahydrofuran + methyl tert-butyl ether) at the temperature 298.15K.
• Ternary and binary LLE measurements for solvent (2-methyltetrahydrofuran and cyclopentyl methyl ether) + furfural + water between 298 and 343 K
• Quaternary and ternary LLE measurements for solvent (2-methyltetrahydrofuran and cyclopentyl methyl ether) + furfural + acetic acid + water between 298 and 343 K
• Thermodynamic study of 2-methyl-tetrahydrofuran with isomeric chlorobutanes
• Thermophysical properties of the binary mixtures of 2-methyl-tetrahydrofuran with benzene and halobenzenes
• Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
• Solubility Measurement and Thermodynamic Modeling of N-(4-Methylphenyl-Z-3-chloro-2-(phenylthio)propenamide in 12 Pure Solvents at Temperatures Ranging from 278.15 to 318.15 K
• Isothermal Vapor-Liquid Equilibrium Data for the Binary Systems Consisting of 1,1,2,3,3,3-Hexafluoro-1-propene and Either Methylcyclohexane, Cyclohexane, n-Hexane, 2-Methyltetrahydrofuran, or 2,2,3,3,4,4,4-Heptafluoro-1-butanol
• Viscosities of Binary Mixtures of Isomeric Butanols or Isomeric Chlorobutanes with 2-Methyltetrahydrofuran
• Study of the Surface Tension of Chlorocyclohexane or Bromocyclohexane with Some Cyclic Ethers
• Excess Enthalpy, Density, Speed of Sound, and Viscosity for 2-Methyltetrahydrofuran + 1-Butanol at (283.15, 298.15, and, 313.15) K
• Molar Heat Capacities, Densities, Viscosities, and Refractive Indices of Dimethyl Sulfoxide + Tetrahydropyran and + 2-Methyltetrahydrofuran at (293.15, 303.15, and 313.15) K
• Molar Heat Capacities, Densities, Viscosities, and Refractive Indices of Poly(ethylene glycols) + 2-Methyltetrahydrofuran at (293.15, 303.15, and 313.15) K
• Joback Method
• Aqueous Solubility Prediction Method
• Estimated Solubility Method
• McGowan Method
• NIST Webbook
• The Yaws Handbook of Vapor Pressure

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