Chemical Properties of Piperidine (CAS 110-89-4)

Piperidine

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InChI
InChI=1S/C5H11N/c1-2-4-6-5-3-1/h6H,1-5H2
InChI Key
NQRYJNQNLNOLGT-UHFFFAOYSA-N
Formula
C5H11N
SMILES
C1CCNCC1
Molecular Weight1
85.15
CAS
110-89-4
Other Names
  • Azacyclohexane
  • CYCLOPENTIMINE
  • CYPENTIL
  • HEXAZANE
  • Hexahydropyridine
  • Pentamethyleneamine
  • Pentamethyleneimine
  • Pentamethylenimine
  • Perhydropyridine
  • Piperidin
  • Pyridine, hexahydro-
  • UN 2401
  • hexahydroazine
  • perhydroazine
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Physical Properties

Property Value Unit Source
ω 0.2510 KDB
PAff 954.00 kJ/mol NIST
BasG 921.00 kJ/mol NIST
Δcliquid [-3453.20; -3451.50] kJ/mol Show Hide
Δcliquid -3453.20 ± 0.50 kJ/mol NIST
Δcliquid -3451.50 ± 2.30 kJ/mol NIST
μ 1.20 debye KDB
Δf 111.09 kJ/mol Joback Calculated Property
Δfgas [-49.03; -47.15] kJ/mol Show Hide
Δfgas -49.03 kJ/mol KDB
Δfgas -47.15 ± 0.63 kJ/mol NIST
Δfgas -47.15 ± 0.63 kJ/mol NIST
Δfliquid [-88.10; -86.44] kJ/mol Show Hide
Δfliquid -86.44 ± 0.59 kJ/mol NIST
Δfliquid -88.10 ± 2.30 kJ/mol NIST
Δfus 9.06 kJ/mol Joback Calculated Property
Δvap [39.30; 41.00] kJ/mol Show Hide
Δvap 39.30 kJ/mol NIST
Δvap 39.30 ± 0.20 kJ/mol NIST
Δvap 41.00 kJ/mol NIST
IE [7.80; 9.15] eV Show Hide
IE 8.03 ± 0.11 eV NIST
IE 8.20 ± 0.05 eV NIST
IE 8.05 ± 0.05 eV NIST
IE 7.80 eV NIST
IE 7.90 ± 0.10 eV NIST
IE 8.70 eV NIST
IE 9.15 eV NIST
IE 8.65 ± 0.10 eV NIST
IE 8.67 eV NIST
IE 8.64 ± 0.05 eV NIST
IE 8.66 ± 0.03 eV NIST
IE 8.66 eV NIST
IE 8.64 ± 0.02 eV NIST
log10WS 1.07 Aq. Sol...
logPoct/wat 0.760 Crippen Calculated Property
McVol 80.430 ml/mol McGowan Calculated Property
NFPA Fire 3 KDB
NFPA Health 2 KDB
NFPA Safety 3 KDB
Pc [4645.75; 4940.00] kPa Show Hide
Pc 4940.00 kPa KDB
Pc 4655.88 ± 202.65 kPa NIST
Pc 4645.75 ± 202.65 kPa NIST
Inp [742.00; 790.00]   Show Hide
Inp 762.00 NIST
Inp 769.00 NIST
Inp 771.00 NIST
Inp 762.00 NIST
Inp 766.00 NIST
Inp 764.00 NIST
Inp 775.00 NIST
Inp 770.00 NIST
Inp 742.00 NIST
Inp 751.00 NIST
Inp 761.00 NIST
Inp 790.00 NIST
Inp 775.00 NIST
Inp 767.00 NIST
Inp 750.00 NIST
Inp 755.00 NIST
Inp 755.00 NIST
Inp 782.00 NIST
Inp 790.00 NIST
Inp 790.00 NIST
I [1042.00; 1125.00]   Show Hide
I 1074.00 NIST
I 1097.00 NIST
I 1115.00 NIST
I 1088.00 NIST
I 1100.00 NIST
I 1125.00 NIST
I 1042.00 NIST
I 1049.00 NIST
liquid [209.94; 209.97] J/mol×K Show Hide
liquid 209.97 J/mol×K NIST
liquid 209.94 J/mol×K NIST
liquid 209.94 J/mol×K NIST
Tboil 379.37 K KDB
Tc [594.00; 594.10] K Show Hide
Tc 594.10 K KDB
Tc 594.10 ± 0.02 K NIST
Tc 594.00 ± 0.30 K NIST
Tfus 262.12 K KDB
Ttriple [262.10; 262.12] K Show Hide
Ttriple 262.10 ± 0.03 K NIST
Ttriple 262.12 ± 0.02 K NIST
Ttriple 262.12 ± 0.05 K NIST
Vc 0.288 m3/kmol KDB
Zc 0.2880200 KDB

Temperature Dependent Properties

Property Value Unit Temperature (K) Source
Cp,gas [135.73; 207.88] J/mol×K [386.57; 603.24] Show Hide
Cp,gas 135.73 J/mol×K 386.57 Joback Calculated Property
Cp,gas 149.38 J/mol×K 422.68 Joback Calculated Property
Cp,gas 162.36 J/mol×K 458.79 Joback Calculated Property
Cp,gas 174.68 J/mol×K 494.90 Joback Calculated Property
Cp,gas 186.37 J/mol×K 531.01 Joback Calculated Property
Cp,gas 197.43 J/mol×K 567.13 Joback Calculated Property
Cp,gas 207.88 J/mol×K 603.24 Joback Calculated Property
Cp,liquid [170.70; 186.20] J/mol×K [290.00; 298.15] Show Hide
Cp,liquid 170.70 J/mol×K 290.00 NIST
Cp,liquid 186.20 J/mol×K 290.00 NIST
Cp,liquid 182.76 J/mol×K 297.39 NIST
Cp,liquid 181.60 J/mol×K 298.00 NIST
Cp,liquid 179.85 J/mol×K 298.15 NIST
Cp,liquid 179.86 J/mol×K 298.15 NIST
Cp,liquid 179.86 J/mol×K 298.15 NIST
ΔfusH [14.85; 14.85] kJ/mol [262.10; 262.12] Show Hide
ΔfusH 14.85 kJ/mol 262.10 NIST
ΔfusH 14.85 kJ/mol 262.12 NIST
ΔfusH 14.85 kJ/mol 262.12 NIST
ΔvapH [35.30; 38.60] kJ/mol [298.15; 366.00] Show Hide
ΔvapH 38.60 kJ/mol 298.15 The vap...
ΔvapH 36.60 kJ/mol 338.00 NIST
ΔvapH 35.30 kJ/mol 357.00 NIST
ΔvapH 37.60 kJ/mol 366.00 NIST
ν [0.0000011; 0.0000018] m2/s [293.15; 323.15] Show Hide
ν 0.0000018 m2/s 293.15 Densiti...
ν 0.0000015 m2/s 303.15 Densiti...
ν 0.0000013 m2/s 313.15 Densiti...
ν 0.0000011 m2/s 323.15 Densiti...
Pvap [1.75; 10.73] kPa [283.64; 318.34] Show Hide
Pvap 1.75 kPa 283.64 Vapor P...
Pvap 2.29 kPa 288.07 Vapor P...
Pvap 3.06 kPa 293.12 Vapor P...
Pvap 3.13 kPa 293.55 Vapor P...
Pvap 3.13 kPa 293.59 Vapor P...
Pvap 3.79 kPa 297.05 Vapor P...
Pvap 4.68 kPa 300.97 Vapor P...
Pvap 5.06 kPa 302.66 Vapor P...
Pvap 6.01 kPa 305.98 Vapor P...
Pvap 6.05 kPa 306.01 Vapor P...
Pvap 8.34 kPa 312.85 Vapor P...
Pvap 10.73 kPa 318.34 Vapor P...
ρl [794.34; 879.98] kg/m3 [273.15; 363.15] Show Hide
ρl 879.98 kg/m3 273.15 Volumet...
ρl 879.53 kg/m3 273.65 Volumet...
ρl 879.08 kg/m3 274.15 Volumet...
ρl 878.62 kg/m3 274.65 Volumet...
ρl 878.17 kg/m3 275.15 Volumet...
ρl 877.71 kg/m3 275.65 Volumet...
ρl 877.26 kg/m3 276.15 Volumet...
ρl 876.80 kg/m3 276.65 Volumet...
ρl 876.35 kg/m3 277.15 Volumet...
ρl 875.89 kg/m3 277.65 Volumet...
ρl 875.44 kg/m3 278.15 Volumet...
ρl 874.98 kg/m3 278.65 Volumet...
ρl 874.52 kg/m3 279.15 Volumet...
ρl 874.07 kg/m3 279.65 Volumet...
ρl 873.61 kg/m3 280.15 Volumet...
ρl 873.15 kg/m3 280.65 Volumet...
ρl 872.69 kg/m3 281.15 Volumet...
ρl 872.24 kg/m3 281.65 Volumet...
ρl 871.78 kg/m3 282.15 Volumet...
ρl 871.32 kg/m3 282.65 Volumet...
ρl 870.86 kg/m3 283.15 Volumet...
ρl 870.40 kg/m3 283.65 Volumet...
ρl 869.94 kg/m3 284.15 Volumet...
ρl 869.49 kg/m3 284.65 Volumet...
ρl 869.03 kg/m3 285.15 Volumet...
ρl 868.57 kg/m3 285.65 Volumet...
ρl 868.11 kg/m3 286.15 Volumet...
ρl 867.65 kg/m3 286.65 Volumet...
ρl 867.18 kg/m3 287.15 Volumet...
ρl 866.72 kg/m3 287.66 Volumet...
ρl 866.26 kg/m3 288.15 Volumet...
ρl 865.80 kg/m3 288.66 Volumet...
ρl 865.34 kg/m3 289.16 Volumet...
ρl 864.88 kg/m3 289.66 Volumet...
ρl 864.42 kg/m3 290.16 Volumet...
ρl 863.96 kg/m3 290.65 Volumet...
ρl 863.49 kg/m3 291.15 Volumet...
ρl 863.03 kg/m3 291.65 Volumet...
ρl 862.57 kg/m3 292.15 Volumet...
ρl 862.10 kg/m3 292.65 Volumet...
ρl 862.00 kg/m3 293.00 KDB
ρl 861.64 kg/m3 293.15 Volumet...
ρl 873.50 kg/m3 293.65 Thermod...
ρl 861.18 kg/m3 293.65 Volumet...
ρl 860.71 kg/m3 294.15 Volumet...
ρl 860.25 kg/m3 294.64 Volumet...
ρl 859.79 kg/m3 295.15 Volumet...
ρl 859.32 kg/m3 295.65 Volumet...
ρl 867.10 kg/m3 296.05 Thermod...
ρl 858.86 kg/m3 296.15 Volumet...
ρl 858.39 kg/m3 296.65 Volumet...
ρl 857.93 kg/m3 297.15 Volumet...
ρl 857.46 kg/m3 297.65 Volumet...
ρl 857.00 kg/m3 298.15 Volumet...
ρl 864.60 kg/m3 298.15 Thermod...
ρl 856.53 kg/m3 298.65 Volumet...
ρl 856.06 kg/m3 299.15 Volumet...
ρl 855.60 kg/m3 299.65 Volumet...
ρl 856.30 kg/m3 300.05 Thermod...
ρl 855.13 kg/m3 300.15 Volumet...
ρl 854.66 kg/m3 300.65 Volumet...
ρl 854.20 kg/m3 301.15 Volumet...
ρl 853.73 kg/m3 301.65 Volumet...
ρl 853.26 kg/m3 302.15 Volumet...
ρl 852.40 kg/m3 302.65 Thermod...
ρl 852.79 kg/m3 302.65 Volumet...
ρl 852.33 kg/m3 303.15 Volumet...
ρl 851.86 kg/m3 303.65 Volumet...
ρl 851.39 kg/m3 304.15 Volumet...
ρl 852.60 kg/m3 304.55 Thermod...
ρl 850.92 kg/m3 304.65 Volumet...
ρl 850.45 kg/m3 305.15 Volumet...
ρl 849.98 kg/m3 305.65 Volumet...
ρl 849.51 kg/m3 306.15 Volumet...
ρl 852.50 kg/m3 306.45 Thermod...
ρl 849.04 kg/m3 306.65 Volumet...
ρl 848.57 kg/m3 307.15 Volumet...
ρl 848.10 kg/m3 307.65 Volumet...
ρl 847.63 kg/m3 308.15 Volumet...
ρl 850.60 kg/m3 308.25 Thermod...
ρl 847.16 kg/m3 308.65 Volumet...
ρl 846.69 kg/m3 309.15 Volumet...
ρl 846.22 kg/m3 309.65 Volumet...
ρl 845.75 kg/m3 310.15 Volumet...
ρl 846.30 kg/m3 310.35 Thermod...
ρl 845.28 kg/m3 310.65 Volumet...
ρl 844.81 kg/m3 311.15 Volumet...
ρl 844.33 kg/m3 311.65 Volumet...
ρl 843.86 kg/m3 312.15 Volumet...
ρl 843.39 kg/m3 312.65 Volumet...
ρl 842.92 kg/m3 313.15 Volumet...
ρl 842.45 kg/m3 313.65 Volumet...
ρl 842.20 kg/m3 313.75 Thermod...
ρl 841.97 kg/m3 314.15 Volumet...
ρl 841.50 kg/m3 314.65 Volumet...
ρl 841.03 kg/m3 315.15 Volumet...
ρl 840.80 kg/m3 315.15 Thermod...
ρl 840.54 kg/m3 315.65 Volumet...
ρl 840.07 kg/m3 316.15 Volumet...
ρl 839.60 kg/m3 316.65 Volumet...
ρl 839.12 kg/m3 317.15 Volumet...
ρl 837.70 kg/m3 317.35 Thermod...
ρl 838.64 kg/m3 317.65 Volumet...
ρl 837.69 kg/m3 318.65 Volumet...
ρl 837.22 kg/m3 319.15 Volumet...
ρl 835.30 kg/m3 319.15 Thermod...
ρl 836.74 kg/m3 319.65 Volumet...
ρl 836.27 kg/m3 320.15 Volumet...
ρl 835.79 kg/m3 320.65 Volumet...
ρl 835.31 kg/m3 321.15 Volumet...
ρl 833.50 kg/m3 321.15 Thermod...
ρl 834.84 kg/m3 321.65 Volumet...
ρl 834.36 kg/m3 322.15 Volumet...
ρl 833.88 kg/m3 322.65 Volumet...
ρl 831.40 kg/m3 323.05 Thermod...
ρl 833.41 kg/m3 323.15 Volumet...
ρl 832.93 kg/m3 323.65 Volumet...
ρl 832.45 kg/m3 324.15 Volumet...
ρl 831.97 kg/m3 324.65 Volumet...
ρl 831.49 kg/m3 325.15 Volumet...
ρl 831.02 kg/m3 325.65 Volumet...
ρl 830.54 kg/m3 326.15 Volumet...
ρl 830.06 kg/m3 326.65 Volumet...
ρl 829.58 kg/m3 327.15 Volumet...
ρl 829.10 kg/m3 327.65 Volumet...
ρl 828.62 kg/m3 328.15 Volumet...
ρl 828.14 kg/m3 328.65 Volumet...
ρl 827.66 kg/m3 329.15 Volumet...
ρl 827.18 kg/m3 329.65 Volumet...
ρl 826.70 kg/m3 330.15 Volumet...
ρl 826.22 kg/m3 330.65 Volumet...
ρl 825.74 kg/m3 331.15 Volumet...
ρl 825.25 kg/m3 331.65 Volumet...
ρl 824.77 kg/m3 332.15 Volumet...
ρl 824.29 kg/m3 332.65 Volumet...
ρl 823.81 kg/m3 333.15 Volumet...
ρl 823.32 kg/m3 333.65 Volumet...
ρl 822.84 kg/m3 334.15 Volumet...
ρl 822.36 kg/m3 334.65 Volumet...
ρl 821.87 kg/m3 335.15 Volumet...
ρl 821.39 kg/m3 335.65 Volumet...
ρl 820.91 kg/m3 336.15 Volumet...
ρl 820.42 kg/m3 336.65 Volumet...
ρl 819.94 kg/m3 337.15 Volumet...
ρl 819.45 kg/m3 337.65 Volumet...
ρl 818.97 kg/m3 338.15 Volumet...
ρl 818.48 kg/m3 338.65 Volumet...
ρl 818.00 kg/m3 339.15 Volumet...
ρl 817.51 kg/m3 339.65 Volumet...
ρl 817.03 kg/m3 340.15 Volumet...
ρl 816.54 kg/m3 340.65 Volumet...
ρl 816.05 kg/m3 341.15 Volumet...
ρl 815.57 kg/m3 341.65 Volumet...
ρl 815.08 kg/m3 342.15 Volumet...
ρl 814.59 kg/m3 342.65 Volumet...
ρl 814.10 kg/m3 343.15 Volumet...
ρl 813.62 kg/m3 343.65 Volumet...
ρl 813.13 kg/m3 344.15 Volumet...
ρl 812.64 kg/m3 344.65 Volumet...
ρl 812.15 kg/m3 345.16 Volumet...
ρl 811.66 kg/m3 345.66 Volumet...
ρl 811.17 kg/m3 346.16 Volumet...
ρl 810.68 kg/m3 346.66 Volumet...
ρl 810.19 kg/m3 347.16 Volumet...
ρl 809.70 kg/m3 347.66 Volumet...
ρl 809.21 kg/m3 348.16 Volumet...
ρl 808.72 kg/m3 348.65 Volumet...
ρl 808.23 kg/m3 349.16 Volumet...
ρl 807.74 kg/m3 349.65 Volumet...
ρl 807.25 kg/m3 350.16 Volumet...
ρl 806.75 kg/m3 350.66 Volumet...
ρl 806.26 kg/m3 351.16 Volumet...
ρl 805.77 kg/m3 351.66 Volumet...
ρl 805.28 kg/m3 352.16 Volumet...
ρl 804.78 kg/m3 352.66 Volumet...
ρl 804.29 kg/m3 353.16 Volumet...
ρl 803.79 kg/m3 353.66 Volumet...
ρl 803.30 kg/m3 354.16 Volumet...
ρl 802.80 kg/m3 354.66 Volumet...
ρl 802.31 kg/m3 355.15 Volumet...
ρl 801.81 kg/m3 355.66 Volumet...
ρl 801.32 kg/m3 356.16 Volumet...
ρl 800.82 kg/m3 356.65 Volumet...
ρl 800.33 kg/m3 357.16 Volumet...
ρl 799.83 kg/m3 357.66 Volumet...
ρl 799.33 kg/m3 358.15 Volumet...
ρl 798.83 kg/m3 358.66 Volumet...
ρl 798.34 kg/m3 359.15 Volumet...
ρl 797.84 kg/m3 359.66 Volumet...
ρl 797.34 kg/m3 360.15 Volumet...
ρl 796.84 kg/m3 360.66 Volumet...
ρl 796.34 kg/m3 361.16 Volumet...
ρl 795.84 kg/m3 361.65 Volumet...
ρl 795.34 kg/m3 362.15 Volumet...
ρl 794.84 kg/m3 362.65 Volumet...
ρl 794.34 kg/m3 363.15 Volumet...
ΔfusS [56.64; 56.67] J/mol×K [262.12; 262.12] Show Hide
ΔfusS 56.67 J/mol×K 262.12 NIST
ΔfusS 56.64 J/mol×K 262.12 NIST
csound,fluid [1257.40; 1384.40] m/s [293.00; 323.00] Show Hide
csound,fluid 1384.40 m/s 293.00 Speed o...
csound,fluid 1342.30 m/s 303.00 Speed o...
csound,fluid 1299.90 m/s 313.00 Speed o...
csound,fluid 1257.40 m/s 323.00 Speed o...
γ [0.03; 0.03] N/m [293.15; 323.15] Show Hide
γ 0.03 N/m 293.15 Surface...
γ 0.03 N/m 298.15 Surface...
γ 0.03 N/m 298.15 Densiti...
γ 0.03 N/m 303.15 Surface...
γ 0.03 N/m 313.15 Surface...
γ 0.03 N/m 323.15 Surface...

Pressure Dependent Properties

Property Value Unit Pressure (kPa) Source
Tboilr 290.90 K 2.70 NIST

Correlations

Property Value Unit Temperature (K) Source
Pvap [0.53; 202.63] kPa [262.65; 404.57] The Yaw... Show Hide
Equationln(Pvp) = A + B/(T + C)
Coefficient A1.44573e+01
Coefficient B-3.29413e+03
Coefficient C-4.43940e+01
Temperature range, min.262.65
Temperature range, max.404.57
Pvap 0.53 kPa 262.65 Calculated Property
Pvap 1.46 kPa 278.42 Calculated Property
Pvap 3.56 kPa 294.19 Calculated Property
Pvap 7.79 kPa 309.96 Calculated Property
Pvap 15.61 kPa 325.73 Calculated Property
Pvap 29.07 kPa 341.49 Calculated Property
Pvap 50.83 kPa 357.26 Calculated Property
Pvap 84.24 kPa 373.03 Calculated Property
Pvap 133.30 kPa 388.80 Calculated Property
Pvap 202.63 kPa 404.57 Calculated Property
Pvap [0.52; 4743.85] kPa [262.65; 594.05] KDB Vap... Show Hide
Equationln(Pvp) = A + B/T + C*ln(T) + D*T^2
Coefficient A5.93402e+01
Coefficient B-6.31943e+03
Coefficient C-6.49354e+00
Coefficient D3.50313e-06
Temperature range, min.262.65
Temperature range, max.594.05
Pvap 0.52 kPa 262.65 Calculated Property
Pvap 4.60 kPa 299.47 Calculated Property
Pvap 23.71 kPa 336.29 Calculated Property
Pvap 84.52 kPa 373.12 Calculated Property
Pvap 232.34 kPa 409.94 Calculated Property
Pvap 528.86 kPa 446.76 Calculated Property
Pvap 1046.82 kPa 483.58 Calculated Property
Pvap 1865.23 kPa 520.41 Calculated Property
Pvap 3067.60 kPa 557.23 Calculated Property
Pvap 4743.85 kPa 594.05 Calculated Property

Similar Compounds

1-Pentanamine, N-pentyl-. Hexamethylenimine. n-Amyl-n-butyl amine. 1-Pentanamine, N-ethyl-. Azocine, octahydro-. propylamyl-amine. azacyclotridecane. octamethylenimine. N,N'-Diethyl-1,6-hexanediamine. 1-Hexanamine, N-hexyl-. 1-Hexanamine, N-butyl-. N,N'-di-n-Butyl-1,6-hexanediamine. 1-Heptanamine, N-heptyl-. 1-Tridecanamine, N-tridecyl-. 1-Dodecanamine, N-dodecyl-.

Find more compounds similar to Piperidine.

Mixtures

Sources

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