Chemical Properties of Aluminum, tris(1,1,1-trifluoro-2,4-pentanedionato-O,O')- (CAS 14354-59-7)

InChI

InChI=1S/3C5H5F3O2.Al/c3*1-3(9)2-4(10)5(6,7)8;/h3*2,9H,1H3;/q;;;+3/p-3/b3-2+;2*3-2-;

InChI Key

NSAWTIQLFWITEH-PJFPACTGSA-K

Formula

C15H12AlF9O6

SMILES

CC(=CC(=O)C(F)(F)F)O[AlH3](OC(C)=CC(=O)C(F)(F)F)OC(C)=CC(=O)C(F)(F)F

Molecular Weight¹

486.22

CAS

14354-59-7

Other Names

• Aluminum trifluoroacetylacetonate
• Aluminum tris(trifluoroacetylacetonate)
• Aluminum, tris(1,1,1-trifluoro-2,4-pentanedionato)-
• Tris(1,1,1-trifluoro-2,4-pentanedionato)aluminum

• Δ_subH : Enthalpy of sublimation at a given temperature (kJ/mol).
• Δ_vapH : Enthalpy of vaporization at a given temperature (kJ/mol).
• IE : Ionization energy (eV).
• ¹: Molecular weight from the IUPAC atomic weights tables.

Physical Properties

Property	Value	Unit	Source
IE	[8.70; 9.22]	eV
IE	8.70 ± 0.20	eV	NIST
IE	8.81 ± 0.05	eV	NIST
IE	8.70	eV	NIST
IE	9.10 ± 0.10	eV	NIST
IE	9.22 ± 0.07	eV	NIST

Temperature Dependent Properties

Property	Value	Unit	Temperature (K)	Source
ΔsubH	[43.10; 113.40]	kJ/mol	[375.00; 443.00]
T(K) Enthalpy of sublimation at a given temperature (kJ/mol) 40 60 80 100 120 380 400 420 440
ΔsubH	93.70 ± 6.70	kJ/mol	375.00	NIST
ΔsubH	102.70 ± 3.20	kJ/mol	380.50	NIST
ΔsubH	74.00	kJ/mol	388.00	NIST
ΔsubH	113.40 ± 1.30	kJ/mol	393.00	NIST
ΔsubH	43.10	kJ/mol	443.00	NIST
ΔvapH	[58.70; 69.60]	kJ/mol	[380.00; 438.00]
ΔvapH	58.70 ± 0.70	kJ/mol	380.00	NIST
ΔvapH	69.60 ± 0.50	kJ/mol	438.00	NIST

Similar Compounds

Find more compounds similar to Aluminum, tris(1,1,1-trifluoro-2,4-pentanedionato-O,O')-.

Sources

• NIST Webbook

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