Chemical Properties of Butane, 1,4-dichloro- (CAS 110-56-5)

InChI

InChI=1S/C4H8Cl2/c5-3-1-2-4-6/h1-4H2

InChI Key

KJDRSWPQXHESDQ-UHFFFAOYSA-N

Formula

C4H8Cl2

SMILES

ClCCCCCl

Molecular Weight¹

127.01

CAS

110-56-5

Other Names

• 1,4-Dichlorobutane
• TETRAMETHYLENE CHLORIDE

• Δ_cH°_liquid : Standard liquid enthalpy of combustion (kJ/mol).
• C_p,gas : Ideal gas heat capacity (J/mol×K).
• C_p,liquid : Liquid phase heat capacity (J/mol×K).
• η : Dynamic viscosity (Pa×s).
• Δ_fG° : Standard Gibbs free energy of formation (kJ/mol).
• Δ_fH°_gas : Enthalpy of formation at standard conditions (kJ/mol).
• Δ_fH°_liquid : Liquid phase enthalpy of formation at standard conditions (kJ/mol).
• Δ_fusH° : Enthalpy of fusion at standard conditions (kJ/mol).
• Δ_vapH° : Enthalpy of vaporization at standard conditions (kJ/mol).
• Δ_vapH : Enthalpy of vaporization at a given temperature (kJ/mol).
• IE : Ionization energy (eV).
• log₁₀WS : Log10 of Water solubility in mol/l.
• logP_oct/wat : Octanol/Water partition coefficient.
• McVol : McGowan's characteristic volume (ml/mol).
• P_c : Critical Pressure (kPa).
• P_vap : Vapor pressure (kPa).
• n₀ : Refractive Index.
• ρ_l : Liquid Density (kg/m³).
• I_np : Non-polar retention indices.
• c_sound,fluid : Speed of sound in fluid (m/s).
• γ : Surface Tension (N/m).
• T_boil : Normal Boiling Point Temperature (K).
• T_c : Critical Temperature (K).
• T_fus : Normal melting (fusion) point (K).
• V_c : Critical Volume (m³/kmol).
• ¹: Molecular weight from the IUPAC atomic weights tables.

Contents

1. Physical Properties
2. Temperature Dependent Properties
3. Datasets
4. Correlations
5. Similar Compounds
6. Mixtures
7. Sources

Physical Properties

Property	Value	Unit	Source
ΔcH°liquid	-2534.80 ± 1.90	kJ/mol	NIST
ΔfG°	-41.06	kJ/mol	Joback Calculated Property
ΔfH°gas	-183.40 ± 1.90	kJ/mol	NIST
ΔfH°liquid	[-229.80; -229.50]	kJ/mol
ΔfH°liquid	-229.80 ± 1.90	kJ/mol	NIST
ΔfH°liquid	-229.50	kJ/mol	NIST
ΔfusH°	14.51	kJ/mol	Joback Calculated Property
ΔvapH°	33.27	kJ/mol	Joback Calculated Property
IE	11.03	eV	NIST
log10WS	-1.80		Crippen Calculated Property
logPoct/wat	2.244		Crippen Calculated Property
McVol	91.700	ml/mol	McGowan Calculated Property
Pc	3560.02	kPa	Joback Calculated Property
Inp	[867.40; 898.10]
Inp	867.40		NIST
Inp	895.00		NIST
Inp	874.00		NIST
Inp	874.00		NIST
Inp	874.00		NIST
Inp	874.00		NIST
Inp	898.10		NIST
Inp	894.10		NIST
Tboil	428.15	K	KDB
Tc	547.67	K	Joback Calculated Property
Tfus	234.50 ± 0.40	K	NIST
Vc	0.357	m3/kmol	Joback Calculated Property

Temperature Dependent Properties

Property	Value	Unit	Temperature (K)	Source
Cp,gas	[141.67; 181.25]	J/mol×K	[365.78; 547.67]
T(K) Ideal gas heat capacity (J/mol×K) 140 150 160 170 180 400 450 500 550
Cp,gas	141.67	J/mol×K	365.78	Joback Calculated Property
Cp,gas	149.02	J/mol×K	396.09	Joback Calculated Property
Cp,gas	156.05	J/mol×K	426.41	Joback Calculated Property
Cp,gas	162.78	J/mol×K	456.72	Joback Calculated Property
Cp,gas	169.22	J/mol×K	487.04	Joback Calculated Property
Cp,gas	175.37	J/mol×K	517.35	Joback Calculated Property
Cp,gas	181.25	J/mol×K	547.67	Joback Calculated Property
Cp,liquid	[183.59; 184.00]	J/mol×K	[298.15; 298.15]
Cp,liquid	184.00	J/mol×K	298.15	NIST
Cp,liquid	183.59	J/mol×K	298.15	NIST
η	[0.0003469; 0.0041179]	Pa×s	[194.68; 365.78]
T(K) Dynamic viscosity (Pa×s) 0 5.00e-4 1.00e-3 1.50e-3 2.00e-3 2.50e-3 3.00e-3 3.50e-3 4.00e-3 200 250 300 350
η	0.0041179	Pa×s	194.68	Joback Calculated Property
η	0.0020950	Pa×s	223.20	Joback Calculated Property
η	0.0012422	Pa×s	251.71	Joback Calculated Property
η	0.0008192	Pa×s	280.23	Joback Calculated Property
η	0.0005835	Pa×s	308.75	Joback Calculated Property
η	0.0004401	Pa×s	337.26	Joback Calculated Property
η	0.0003469	Pa×s	365.78	Joback Calculated Property
ΔvapH	43.40	kJ/mol	380.50	NIST
Pvap	[2.21; 2.21]	kPa	[323.15; 323.15]
Pvap	2.21	kPa	323.15	Excess ...
Pvap	2.21	kPa	323.15	Excess ...
n0	[1.45190; 1.45220]		[298.15; 298.15]
n0	1.45200		298.15	Thermod...
n0	1.45190		298.15	Isother...
n0	1.45220		298.15	Isother...
ρl	[1110.54; 1143.49]	kg/m3	[288.15; 318.15]
T(K) Liquid Density (kg/m3) 1110 1115 1120 1125 1130 1135 1140 1145 290 300 310
ρl	1143.43	kg/m3	288.15	Densiti...
ρl	1143.49	kg/m3	288.15	Densiti...
ρl	1135.00	kg/m3	298.15	Volumet...
ρl	1133.94	kg/m3	298.15	Volumet...
ρl	1132.50	kg/m3	298.15	Densiti...
ρl	1132.57	kg/m3	298.15	Densiti...
ρl	1121.61	kg/m3	308.15	Densiti...
ρl	1123.00	kg/m3	308.15	Volumet...
ρl	1121.54	kg/m3	308.15	Densiti...
ρl	1110.61	kg/m3	318.15	Densiti...
ρl	1112.00	kg/m3	318.15	Volumet...
ρl	1110.54	kg/m3	318.15	Densiti...
csound,fluid	[1215.66; 1286.64]	m/s	[298.15; 318.15]
csound,fluid	1286.64	m/s	298.15	Speeds ...
csound,fluid	1251.00	m/s	308.15	Speeds ...
csound,fluid	1215.66	m/s	318.15	Speeds ...
γ	[0.03; 0.03]	N/m	[293.15; 313.15]
T(K) Surface Tension (N/m) 0.03 0.03 0.03 0.03 0.03 295 300 305 310
γ	0.03	N/m	293.15	The add...
γ	0.03	N/m	298.15	The add...
γ	0.03	N/m	303.15	The add...
γ	0.03	N/m	308.15	The add...
γ	0.03	N/m	313.15	The add...

Datasets

Mass density, kg/m3

Fixed		Measured
Temperature, K - Liquid	Pressure, kPa - Liquid	Mass density, kg/m3 - Liquid
288.15	100.00	1143.7
288.15	500.00	1144.1
288.15	1000.00	1144.5
288.15	1500.00	1144.8
288.15	2000.00	1145.2
288.15	2500.00	1145.5
288.15	3000.00	1145.9
288.15	3600.00	1146.4
288.15	4100.00	1146.7
288.15	4600.00	1147.0
288.15	5100.00	1147.4
288.15	5600.00	1147.7
288.15	6100.00	1148.1
288.15	6600.00	1148.5
288.15	7100.00	1148.9
288.15	7600.00	1149.2
288.15	8100.00	1149.5
288.15	8600.00	1149.9
288.15	9200.00	1150.3
288.15	9600.00	1150.7
288.15	10100.00	1151.0
288.15	10600.00	1151.3
288.15	11100.00	1151.7
288.15	11600.00	1152.0
288.15	12100.00	1152.4
288.15	12600.00	1152.7
288.15	13100.00	1153.1
288.15	13500.00	1153.3
288.15	14200.00	1153.8
288.15	14700.00	1154.1
288.15	15200.00	1154.4
288.15	15700.00	1154.8
288.15	16300.00	1155.2
288.15	16800.00	1155.6
288.15	17300.00	1155.9
288.15	17800.00	1156.2
288.15	18300.00	1156.5
288.15	18800.00	1156.8
288.15	19100.00	1157.1
288.15	19700.00	1157.4
288.15	20200.00	1157.8
298.15	100.00	1133.7
298.15	500.00	1134.0
298.15	1000.00	1134.4
298.15	1500.00	1134.8
298.15	2000.00	1135.2
298.15	2500.00	1135.6
298.15	3100.00	1136.1
298.15	3600.00	1136.4
298.15	4100.00	1136.8
298.15	4600.00	1137.2
298.15	5100.00	1137.6
298.15	5600.00	1137.9
298.15	6100.00	1138.4
298.15	6600.00	1138.7
298.15	7100.00	1139.1
298.15	7600.00	1139.4
298.15	8100.00	1139.8
298.15	8600.00	1140.2
298.15	9200.00	1140.6
298.15	9600.00	1141.0
298.15	10100.00	1141.4
298.15	10700.00	1141.8
298.15	11100.00	1142.1
298.15	11600.00	1142.4
298.15	12100.00	1142.8
298.15	12600.00	1143.2
298.15	13100.00	1143.6
298.15	13600.00	1143.9
298.15	14100.00	1144.2
298.15	14700.00	1144.6
298.15	15200.00	1145.0
298.15	15700.00	1145.4
298.15	16200.00	1145.8
298.15	16700.00	1146.1
298.15	17200.00	1146.5
298.15	17800.00	1146.9
298.15	18300.00	1147.2
298.15	18800.00	1147.6
298.15	19200.00	1147.9
298.15	19700.00	1148.2
298.15	20200.00	1148.7
308.15	100.00	1122.3
308.15	500.00	1122.7
308.15	1000.00	1123.1
308.15	1500.00	1123.5
308.15	2000.00	1123.9
308.15	2500.00	1124.3
308.15	3100.00	1124.8
308.15	3600.00	1125.2
308.15	4100.00	1125.6
308.15	4600.00	1126.0
308.15	5100.00	1126.4
308.15	5600.00	1126.9
308.15	6100.00	1127.2
308.15	6600.00	1127.5
308.15	7100.00	1128.0
308.15	7600.00	1128.4
308.15	8100.00	1128.8
308.15	8600.00	1129.2
308.15	9200.00	1129.6
308.15	9600.00	1130.0
308.15	10100.00	1130.4
308.15	10600.00	1130.9
308.15	11100.00	1131.2
308.15	11600.00	1131.5
308.15	12100.00	1131.9
308.15	12600.00	1132.4
308.15	13100.00	1132.6
308.15	13600.00	1133.1
308.15	14100.00	1133.5
308.15	14700.00	1133.9
308.15	15100.00	1134.2
308.15	15700.00	1134.6
308.15	16200.00	1135.0
308.15	16700.00	1135.3
308.15	17200.00	1135.7
308.15	17800.00	1136.1
308.15	18300.00	1136.5
308.15	18800.00	1136.8
308.15	19200.00	1137.2
308.15	19700.00	1137.6
308.15	20200.00	1138.0
318.15	100.00	1112.0
318.15	500.00	1112.4
318.15	1000.00	1112.8
318.15	1500.00	1113.2
318.15	2000.00	1113.7
318.15	2500.00	1114.1
318.15	3100.00	1114.7
318.15	3500.00	1115.0
318.15	4100.00	1115.5
318.15	4600.00	1115.9
318.15	5100.00	1116.3
318.15	5600.00	1116.8
318.15	6100.00	1117.3
318.15	6600.00	1117.7
318.15	7100.00	1118.1
318.15	7600.00	1118.4
318.15	8100.00	1118.9
318.15	8600.00	1119.3
318.15	9200.00	1119.8
318.15	9600.00	1120.2
318.15	10100.00	1120.6
318.15	10600.00	1121.0
318.15	11100.00	1121.4
318.15	11600.00	1121.8
318.15	12100.00	1122.1
318.15	12600.00	1122.6
318.15	13000.00	1123.0
318.15	13600.00	1123.3
318.15	14200.00	1123.9
318.15	14700.00	1124.4
318.15	15200.00	1124.7
318.15	15700.00	1125.1
318.15	16300.00	1125.4
318.15	16800.00	1126.0
318.15	17300.00	1126.3
318.15	17800.00	1126.5
318.15	18300.00	1127.0
318.15	18800.00	1127.4
318.15	19200.00	1127.7
318.15	19700.00	1128.0
318.15	20200.00	1128.4
Reference

Fixed		Measured
Temperature, K - Liquid	Pressure, kPa - Liquid	Mass density, kg/m3 - Liquid
298.15	100.00	1133.7
Reference

Correlations

Property	Value	Unit	Temperature (K)	Source
Pvap	[1.33; 202.65]	kPa	[312.79; 432.68]	The Yaw...
Equation			ln(Pvp) = A + B/(T + C)
Coefficient A			1.62874e+01
Coefficient B			-4.19096e+03
Coefficient C			-5.08480e+01
Temperature range, min.			312.79
Temperature range, max.			432.68
T(K) Vapor pressure (kPa) 0 50 100 150 200 350 400
Pvap	1.33	kPa	312.79	Calculated Property
Pvap	2.89	kPa	326.11	Calculated Property
Pvap	5.84	kPa	339.43	Calculated Property
Pvap	11.09	kPa	352.75	Calculated Property
Pvap	19.93	kPa	366.07	Calculated Property
Pvap	34.17	kPa	379.40	Calculated Property
Pvap	56.17	kPa	392.72	Calculated Property
Pvap	88.96	kPa	406.04	Calculated Property
Pvap	136.28	kPa	419.36	Calculated Property
Pvap	202.65	kPa	432.68	Calculated Property
Pvap	[3.53e-03; 3577.43]	kPa	[235.85; 641.00]	KDB Vap...
Equation			ln(Pvp) = A + B/T + C*ln(T) + D*T^2
Coefficient A			7.77758e+01
Coefficient B			-7.95407e+03
Coefficient C			-9.14431e+00
Coefficient D			4.66169e-06
Temperature range, min.			235.85
Temperature range, max.			641.00
T(K) Vapor pressure (kPa) 0 500 1000 1500 2000 2500 3000 3500 300 400 500 600
Pvap	3.53e-03	kPa	235.85	Calculated Property
Pvap	0.18	kPa	280.87	Calculated Property
Pvap	2.58	kPa	325.88	Calculated Property
Pvap	17.72	kPa	370.90	Calculated Property
Pvap	74.69	kPa	415.92	Calculated Property
Pvap	227.10	kPa	460.93	Calculated Property
Pvap	550.91	kPa	505.95	Calculated Property
Pvap	1139.60	kPa	550.97	Calculated Property
Pvap	2103.57	kPa	595.98	Calculated Property
Pvap	3577.43	kPa	641.00	Calculated Property

Similar Compounds

Find more compounds similar to Butane, 1,4-dichloro-.

Mixtures

• Butane, 1,4-dichloro- + Methane, nitro-
• Butane, 1,4-dichloro- + Ethyl Acetate
• Butane, 1,4-dichloro- + Butanoic acid, ethyl ester
• Pentanoic acid, ethyl ester + Butane, 1,4-dichloro-
• Ethyl formate + Butane, 1,4-dichloro-
• Propanoic acid, ethyl ester + Butane, 1,4-dichloro-
• Formic acid, butyl ester + Butane, 1,4-dichloro-
• Propanoic acid, butyl ester + Butane, 1,4-dichloro-
• Butane, 1,4-dichloro- + Acetic acid, butyl ester
• Butanoic acid, butyl ester + Butane, 1,4-dichloro-
• Butane, 1,4-dichloro- + Cyclopentanone
• Formamide, N,N-dimethyl- + Butane, 1,4-dichloro-
• Butane, 1,4-dichloro- + N,N-Dimethylacetamide
• 2-Pyrrolidinone, 1-methyl- + Butane, 1,4-dichloro-
• Formic acid, propyl ester + Butane, 1,4-dichloro-
• Butane, 1,4-dichloro- + n-Propyl acetate
• Propanoic acid, propyl ester + Butane, 1,4-dichloro-
• Butane, 1,4-dichloro- + Butanoic acid, propyl ester
• Butane, 1,4-dichloro- + Ethane, nitro-
• 2-Butanone + Butane, 1,4-dichloro-

Find more mixtures with Butane, 1,4-dichloro-.

Sources

• KDB Pure (Korean Thermophysical Properties Databank)
• KDB Vapor Pressure Data
• Crippen Method
• Crippen Method
• Speeds of sound, isentropic compressibilities and refractive indices for some binary mixtures of nitromethane with chloroalkane at temperatures from 298.15 to 318.15 K. Comparison with theories
• Thermodynamic study of (alkyl esters + a,x-alkyl dihalides) I: HE and V E for 25 binary mixtures {xCu-1H2u-1CO2C2H5 + (1-x)a,x-ClCH2(CH2)v-2CH2Cl}, where u = 1 to 5, a = 1 and v = x = 2 to 6
• Thermodynamic study of (alkyl esters + a,x-alkyl dihalides)III. HE m and V E m for 20 binary mixtures {xCu-1H2u-1CO2C4H9 + (1 - x)a,x-ClCH2(CH2)v-2CH2Cl}, where u = 1 to 4, a = 1 and v = x = 2 to 6
• Thermodynamic study of (alkyl esters + a,x-alkyl dihalides) V. Hex and Vex for 25 binary mixtures {xCu-1H2u-1CO2CH3 + (1-x)a,x-ClCH2(CH2)v-2CH2Cl}, where u = 1 to 5, a = 1 and v = x = 2 to 6
• Isothermal (vapour + liquid) equilibria and excess Gibbs free energies in some binary (cyclopentanone + chloroalkane) mixtures at temperatures from 298.15 K to 318.15 K
• Excess molar enthalpies and (vapour + liquid) equilibria for mixtures containing N,N-dialkylamides and a,x-dichloroalkanes
• Excess enthalpies and isothermal (vapour + liquid) equilibria of (1-methyl-2-pyrrolidone + 1-chloroalkane or +,?-dichloroalkane) mixtures
• Thermodynamic study of (alkyl esters + a,x-alkyl dihalides) VII. HE m and VE m for 20 binary mixtures {xCu 1H2u 1CO2C3H7 + (1 x)a,x-ClCH2(CH2)v 2CH2Cl}, where u = 1 to 4, a = 1 and v = x = 2 to 6. An analysis of behavior using the COSMO-RS methodology
• Isothermal (vapour + liquid) equilibria for (nitromethane or nitroethane + 1,4-dichlorobutane) binary systems at temperatures between (343.15 and 363.15) K
• Volumetric and optical properties for some (2-butanone + chloroalkane) binary mixtures at T = 298.15 K
• The additivity of surface and volumetric properties of alpha,omega-dihalogenoalkanes
• Heat Capacities of alpha,omega-Dichloroalkanes at Temperatures from 284.15 K to 353.15 K and a Group Additivity Analysis
• Volumetric Study for the Binary Nitromethane with Chloroalkane Mixtures at Temperatures in the Range (298.15 to 318.15) K
• Densities and Isothermal Compressibilities at Pressures up to 20 MPa of the Systems N,N-Dimethylformamide or N,N-Dimethylacetamide + r,o-Dichloroalkane
• Densities and Isothermal Compressibilities at Pressures up to 20 MPa of the Systems 1-Methyl-2-pyrrolidone + 1-Chloroalkane or + r,u-Dichloroalkane
• Densities and Excess Molar Volumes of the Binary Mixtures of Cyclohexanone with Chloroalkanes at Temperatures between (288.15 and 318.15) K
• Densities and Excess Molar Volumes of the Binary Mixtures of Cyclopentanone with Chloroalkanes at T = (288.15, 298.15, 308.15, and 318.15) K
• Joback Method
• KDB
• McGowan Method
• NIST Webbook
• The Yaws Handbook of Vapor Pressure

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