Chemical Properties of Tetrachloroethylene (CAS 127-18-4)

Tetrachloroethylene

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InChI
InChI=1S/C2Cl4/c3-1(4)2(5)6
InChI Key
CYTYCFOTNPOANT-UHFFFAOYSA-N
Formula
C2Cl4
SMILES
ClC(Cl)=C(Cl)Cl
Molecular Weight1
165.83
CAS
127-18-4
Other Names
  • 1,1,2,2-Tetrachloroethene
  • 1,1,2,2-Tetrachloroethylene
  • Ankilostin
  • Antisal 1
  • Antisol 1
  • C2Cl4
  • Carbon bichloride
  • Carbon dichloride
  • Czterochloroetylen
  • Didakene
  • Dilatin PT
  • Dow-per
  • ENT 1,860
  • ETHYLENE TETRACHLORIDE
  • Ethene, tetrachloro-
  • Ethylene, tetrachloro-
  • F 1110
  • Fedal-Un
  • Freon 1110
  • NCI-C04580
  • Nema
  • Nema, veterinary
  • PERC
  • PERK
  • PerSec
  • Perawin
  • Perchloorethyleen, per
  • Perchlor
  • Perchloraethylen, per
  • Perchlorethylene
  • Perchlorethylene, per
  • Perchloroethene
  • Perchloroethylene
  • Perclene
  • Perclene D
  • Perclene TG
  • Percloroetilene
  • Percosolve
  • Perklone
  • RCRA Waste Number U210
  • TETLEN
  • TETRACHLOROETHENE
  • Tetracap
  • Tetrachlooretheen
  • Tetrachloraethen
  • Tetrachlorethylene
  • Tetracloroetene
  • Tetraguer
  • Tetraleno
  • Tetralex
  • Tetravec
  • Tetroguer
  • Tetropil
  • UN 1897
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Physical Properties

Property Value Unit Source
Δcliquid -830.00 ± 10.00 kJ/mol NIST
μ 0.00 debye KDB
η [0.0008474; 0.0008900] Pa×s Show Hide
η 0.0008474 Pa×s Densiti...
η 0.0008900 Pa×s Studies...
EA [0.50; 0.64] eV Show Hide
EA 0.64 ± 0.03 eV NIST
EA 0.50 eV NIST
Δf 22.61 kJ/mol KDB
Δfgas [-24.00; -12.14] kJ/mol Show Hide
Δfgas -12.14 kJ/mol KDB
Δfgas -24.00 ± 4.00 kJ/mol NIST
Δfgas -15.00 kJ/mol NIST
Δfliquid [-64.00; -54.40] kJ/mol Show Hide
Δfliquid -64.00 ± 4.00 kJ/mol NIST
Δfliquid -54.40 kJ/mol NIST
Δfus 15.31 kJ/mol Joback Calculated Property
Δvap [39.70; 39.72] kJ/mol Show Hide
Δvap 39.72 kJ/mol NIST
Δvap 39.72 ± 0.05 kJ/mol NIST
Δvap 39.70 ± 0.10 kJ/mol NIST
Δvap 39.70 ± 0.84 kJ/mol NIST
IE [9.32; 9.51] eV Show Hide
IE 9.33 ± 0.00 eV NIST
IE 9.33 ± 0.00 eV NIST
IE 9.51 eV NIST
IE 9.34 eV NIST
IE 9.32 ± 0.01 eV NIST
IE 9.32 eV NIST
IE 9.50 eV NIST
log10WS [-2.60; -2.54]   Show Hide
log10WS -2.60 Aq. Sol...
log10WS -2.54 Estimat...
logPoct/wat 3.068 Crippen Calculated Property
McVol 83.700 ml/mol McGowan Calculated Property
Pc 4760.00 kPa KDB
Inp [785.00; 832.30]   Show Hide
Inp 825.59 NIST
Inp Outlier 832.30 NIST
Inp 803.00 NIST
Inp 799.00 NIST
Inp 801.00 NIST
Inp 809.00 NIST
Inp 814.00 NIST
Inp 804.00 NIST
Inp 806.00 NIST
Inp 825.00 NIST
Inp 814.00 NIST
Inp 801.00 NIST
Inp 815.45 NIST
Inp 817.10 NIST
Inp 815.90 NIST
Inp 794.80 NIST
Inp 809.30 NIST
Inp 804.00 NIST
Inp 804.00 NIST
Inp 815.00 NIST
Inp 796.00 NIST
Inp 801.00 NIST
Inp 806.00 NIST
Inp 814.00 NIST
Inp 807.00 NIST
Inp 796.52 NIST
Inp 819.00 NIST
Inp 823.00 NIST
Inp 794.00 NIST
Inp 808.00 NIST
Inp 814.00 NIST
Inp 808.00 NIST
Inp 815.00 NIST
Inp 806.00 NIST
Inp 794.51 NIST
Inp 794.00 NIST
Inp 803.00 NIST
Inp 806.00 NIST
Inp 811.00 NIST
Inp 802.00 NIST
Inp 793.00 NIST
Inp 793.00 NIST
Inp 811.00 NIST
Inp 797.00 NIST
Inp 816.00 NIST
Inp 785.00 NIST
Inp 800.00 NIST
Inp 789.00 NIST
Inp 797.00 NIST
Inp 789.00 NIST
Inp 796.00 NIST
Inp 814.00 NIST
Inp 794.00 NIST
Inp 793.00 NIST
Inp 785.00 NIST
Inp 796.00 NIST
Inp 806.00 NIST
Inp 823.00 NIST
I [1012.00; 1059.96]   Show Hide
I 1044.00 NIST
I 1038.00 NIST
I 1050.23 NIST
I Outlier 1059.96 NIST
I 1036.20 NIST
I 1030.00 NIST
I 1024.00 NIST
I 1022.00 NIST
I 1022.00 NIST
I 1021.00 NIST
I 1026.00 NIST
I 1045.00 NIST
I 1012.00 NIST
I 1012.00 NIST
I 1018.00 NIST
I 1021.00 NIST
I 1024.00 NIST
I 1044.00 NIST
I 1030.00 NIST
liquid 240.60 J/mol×K NIST
Tboil [394.15; 394.45] K Show Hide
Tboil 394.40 K KDB
Tboil 394.45 K Excess ...
Tboil 394.15 K Excess ...
Tboil 394.15 K Vapor-L...
Tboil 394.15 K Isobari...
Tc [620.00; 620.20] K Show Hide
Tc 620.20 K KDB
Tc 620.00 K NIST
Tfus [250.60; 251.00] K Show Hide
Tfus 250.80 K KDB
Tfus 251.00 K Aq. Sol...
Tfus 250.97 ± 0.05 K NIST
Tfus 250.60 ± 0.60 K NIST
Ttriple 250.81 ± 0.02 K NIST
Vc 0.326 m3/kmol Joback Calculated Property

Temperature Dependent Properties

Property Value Unit Temperature (K) Source
Cp,gas [100.86; 114.10] J/mol×K [398.80; 620.38] Show Hide
Cp,gas 100.86 J/mol×K 398.80 Joback Calculated Property
Cp,gas 103.82 J/mol×K 435.73 Joback Calculated Property
Cp,gas 106.43 J/mol×K 472.66 Joback Calculated Property
Cp,gas 108.74 J/mol×K 509.59 Joback Calculated Property
Cp,gas 110.77 J/mol×K 546.52 Joback Calculated Property
Cp,gas 112.54 J/mol×K 583.45 Joback Calculated Property
Cp,gas 114.10 J/mol×K 620.38 Joback Calculated Property
Cp,liquid [139.70; 157.90] J/mol×K [298.00; 298.15] Show Hide
Cp,liquid 139.70 J/mol×K 298.00 NIST
Cp,liquid 146.90 J/mol×K 298.00 NIST
Cp,liquid 147.16 J/mol×K 298.15 NIST
Cp,liquid 157.90 J/mol×K 298.15 NIST
Cp,liquid 146.50 J/mol×K 298.15 NIST
ΔfusH [0.82; 10.88] kJ/mol [210.00; 250.81] Show Hide
ΔfusH 0.82 kJ/mol 210.00 NIST
ΔfusH 10.88 kJ/mol 250.80 NIST
ΔfusH 10.88 kJ/mol 250.80 NIST
ΔfusH 10.88 kJ/mol 250.81 NIST
ΔvapH [34.68; 38.90] kJ/mol [340.00; 394.20] Show Hide
ΔvapH 38.90 kJ/mol 340.00 NIST
ΔvapH 38.40 kJ/mol 350.00 NIST
ΔvapH 38.70 kJ/mol 351.50 NIST
ΔvapH 37.60 kJ/mol 353.00 NIST
ΔvapH 34.68 kJ/mol 394.10 NIST
ΔvapH 34.73 kJ/mol 394.20 KDB
Pvap [1.02; 8.29] kPa [283.15; 323.15] Show Hide
Pvap 1.02 kPa 283.15 Isother...
Pvap 1.02 kPa 283.15 Total v...
Pvap 1.02 kPa 283.15 Total v...
Pvap 1.40 kPa 288.15 Total v...
Pvap 1.40 kPa 288.15 Total v...
Pvap 1.40 kPa 288.15 Isother...
Pvap 1.86 kPa 293.15 Total v...
Pvap 1.86 kPa 293.15 Total v...
Pvap 1.86 kPa 293.15 Isother...
Pvap 2.46 kPa 298.15 Isother...
Pvap 2.46 kPa 298.15 Total v...
Pvap 2.46 kPa 298.15 Total v...
Pvap 3.21 kPa 303.15 Total v...
Pvap 3.21 kPa 303.15 Isother...
Pvap 3.21 kPa 303.15 Total v...
Pvap 4.12 kPa 308.15 Total v...
Pvap 4.12 kPa 308.15 Isother...
Pvap 4.12 kPa 308.15 Total v...
Pvap 5.25 kPa 313.15 Total v...
Pvap 5.25 kPa 313.15 Total v...
Pvap 5.25 kPa 313.15 Isother...
Pvap 6.62 kPa 318.15 Isother...
Pvap 6.62 kPa 318.15 Total v...
Pvap 6.62 kPa 318.15 Total v...
Pvap 8.29 kPa 323.15 Total v...
Pvap 8.29 kPa 323.15 Total v...
Pvap 8.29 kPa 323.15 Isother...
n0 [1.49780; 1.50580]   [293.15; 308.15] Show Hide
n0 1.50500 293.15 Activit...
n0 1.50580 293.15 Excess ...
n0 1.50500 293.15 Bubble ...
n0 1.50580 293.15 Vapor-L...
n0 1.50500 298.15 Bubble ...
n0 1.50320 298.15 Bubble-...
n0 1.50500 298.15 Bubble ...
n0 1.50360 298.15 Density...
n0 1.50360 298.15 Density...
n0 1.50050 303.15 Density...
n0 1.50100 303.15 Density...
n0 1.49780 308.15 Density...
n0 1.49800 308.15 Density...
ρl [1590.60; 1622.39] kg/m3 [293.00; 313.15] Show Hide
ρl 1620.00 kg/m3 293.00 KDB
ρl 1622.39 kg/m3 293.15 Thermop...
ρl 1614.49 kg/m3 298.15 Excess ...
ρl 1614.80 kg/m3 298.15 Excess ...
ρl 1607.20 kg/m3 303.15 Excess ...
ρl 1597.90 kg/m3 308.15 Excess ...
ρl 1590.60 kg/m3 313.15 Excess ...
ΔfusS [3.90; 43.38] J/mol×K [210.00; 250.81] Show Hide
ΔfusS 3.90 J/mol×K 210.00 NIST
ΔfusS 43.38 J/mol×K 250.80 NIST
ΔfusS 43.38 J/mol×K 250.81 NIST
csound,fluid [1038.97; 1054.03] m/s [293.15; 298.15] Show Hide
csound,fluid 1054.03 m/s 293.15 Densiti...
csound,fluid 1038.97 m/s 298.15 Densiti...
γ 0.03 N/m 293.20 KDB

Datasets

Viscosity, Pa*s

Fixed Measured
Temperature, K - Liquid Pressure, kPa - Liquid Viscosity, Pa*s - Liquid
308.15 101.00 0.0007
Reference

Correlations

Property Value Unit Temperature (K) Source
Pvap [1.33; 203.96] kPa [286.48; 421.37] The Yaw... Show Hide
Equationln(Pvp) = A + B/(T + C)
Coefficient A1.42797e+01
Coefficient B-3.36251e+03
Coefficient C-4.61640e+01
Temperature range, min.286.48
Temperature range, max.421.37
Pvap 1.33 kPa 286.48 Calculated Property
Pvap 3.03 kPa 301.47 Calculated Property
Pvap 6.29 kPa 316.46 Calculated Property
Pvap 12.10 kPa 331.44 Calculated Property
Pvap 21.79 kPa 346.43 Calculated Property
Pvap 37.10 kPa 361.42 Calculated Property
Pvap 60.21 kPa 376.41 Calculated Property
Pvap 93.67 kPa 391.39 Calculated Property
Pvap 140.48 kPa 406.38 Calculated Property
Pvap 203.96 kPa 421.37 Calculated Property
Pvap [0.11; 4603.17] kPa [250.80; 620.00] KDB Vap... Show Hide
Equationln(Pvp) = A + B/T + C*ln(T) + D*T^2
Coefficient A6.04740e+01
Coefficient B-6.53097e+03
Coefficient C-6.66587e+00
Coefficient D3.52238e-06
Temperature range, min.250.80
Temperature range, max.620.00
Pvap 0.11 kPa 250.80 Calculated Property
Pvap 1.75 kPa 291.82 Calculated Property
Pvap 12.55 kPa 332.84 Calculated Property
Pvap 55.13 kPa 373.87 Calculated Property
Pvap 173.62 kPa 414.89 Calculated Property
Pvap 432.94 kPa 455.91 Calculated Property
Pvap 912.80 kPa 496.93 Calculated Property
Pvap 1701.91 kPa 537.96 Calculated Property
Pvap 2896.38 kPa 578.98 Calculated Property
Pvap 4603.17 kPa 620.00 Calculated Property

Similar Compounds

Ethylene, bromo, trichloro. Trichloroethylene. Ethene, trichlorofluoro-. Ethene, 1,1-dichloro-2,2-difluoro-. Ethene, 1,1-dichloro-. Dichloromethylene. 1,2-Dichloroethylene. Ethylene, 1,2-dichloro-, (Z)-. Ethylene, 1,2-dichloro-, (E)-. Trichloromethyl radical. Carbon Tetrachloride. Hexachloropropene. Phosgene. Dichloromethyl radical. Thiophosgene.

Find more compounds similar to Tetrachloroethylene.

Mixtures

Find more mixtures with Tetrachloroethylene.

Sources

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Outlier This icon means that the value is more than 2 standard deviations away from the property mean.