Mixture of 1-Butanol + Phenol + Water

Datasets

1. Mass fraction (10)
2. n₀ - Refractive index (Na D-line) (4)
3. ρ_l - Mass density, kg/m3 (4)

Mass fraction of 1-Butanol (1) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 2)

Fixed		Measured
Temperature, K - Liquid mixture 2	Mass fraction of Water (3) - Liquid mixture 2	Mass fraction of 1-Butanol (1) - Liquid mixture 2
298.15	0.9176	0.0000
298.15	0.9235	0.0765
298.15	0.9249	0.0056
298.15	0.9293	0.0637
298.15	0.9304	0.0164
298.15	0.9378	0.0248
298.15	0.9404	0.0382
313.15	0.9005	0.0000
313.15	0.9203	0.0062
313.15	0.9298	0.0094
313.15	0.9382	0.0197
313.15	0.9407	0.0448
313.15	0.9433	0.0290
313.15	0.9298	0.0702

Mass fraction of 1-Butanol (1) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Fixed		Measured
Temperature, K - Liquid mixture 1	Mass fraction of Water (3) - Liquid mixture 1	Mass fraction of 1-Butanol (1) - Liquid mixture 1
298.15	0.1302	0.4366
298.15	0.1350	0.5183
298.15	0.1404	0.6009
298.15	0.1416	0.3425
298.15	0.1554	0.6796
298.15	0.1582	0.2539
298.15	0.1707	0.2043
298.15	0.1721	0.7388
298.15	0.1997	0.8003
298.15	0.2196	0.0875
298.15	0.2937	0.0000
313.15	0.1529	0.5127
313.15	0.1545	0.4238
313.15	0.1566	0.3362
313.15	0.1678	0.6583
313.15	0.1853	0.7334
313.15	0.1904	0.2054
313.15	0.2099	0.7901
313.15	0.2334	0.1087
313.15	0.3396	0.0000

Mass fraction of Phenol (2) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 2)

Fixed		Measured
Temperature, K - Liquid mixture 2	Mass fraction of Water (3) - Liquid mixture 2	Mass fraction of Phenol (2) - Liquid mixture 2
298.15	0.9176	0.0824
298.15	0.9235	0.0000
298.15	0.9249	0.0695
298.15	0.9293	0.0070
298.15	0.9304	0.0532
298.15	0.9378	0.0373
298.15	0.9404	0.0214
313.15	0.9005	0.0995
313.15	0.9203	0.0735
313.15	0.9298	0.0608
313.15	0.9382	0.0421
313.15	0.9407	0.0145
313.15	0.9433	0.0277
313.15	0.9298	0.0000

Mass fraction of Phenol (2) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Fixed		Measured
Temperature, K - Liquid mixture 1	Mass fraction of Water (3) - Liquid mixture 1	Mass fraction of Phenol (2) - Liquid mixture 1
298.15	0.1302	0.4332
298.15	0.1350	0.3467
298.15	0.1404	0.2587
298.15	0.1416	0.5159
298.15	0.1554	0.1650
298.15	0.1582	0.5880
298.15	0.1707	0.6250
298.15	0.1721	0.0890
298.15	0.1997	0.0000
298.15	0.2196	0.6929
298.15	0.2937	0.7063
313.15	0.1529	0.3344
313.15	0.1545	0.4217
313.15	0.1566	0.5073
313.15	0.1678	0.1738
313.15	0.1853	0.0812
313.15	0.1904	0.6043
313.15	0.2099	0.0000
313.15	0.2334	0.6579
313.15	0.3396	0.6604

Temperature, K x Mass fraction [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 2)

Fixed		Measured
Temperature, K - Liquid mixture 2	Mass fraction of Phenol (2) - Liquid mixture 1	Mass fraction of Water (3) - Liquid mixture 1	Mass fraction of Water (3) - Liquid mixture 2	Mass fraction of Phenol (2) - Liquid mixture 2
298.15	0.0652	0.1772	0.9271	0.0014
298.15	0.1683	0.1551	0.9296	0.0083
298.15	0.3026	0.1396	0.9348	0.0167
298.15	0.4434	0.1360	0.9356	0.0295
298.15	0.5524	0.1459	0.9341	0.0414
298.15	0.6757	0.1919	0.9264	0.0622
313.15	0.0552	0.1920	0.9372	0.0008
313.15	0.1979	0.1618	0.9379	0.0108
313.15	0.3238	0.1501	0.9405	0.0191
313.15	0.4899	0.1510	0.9379	0.0359
313.15	0.5926	0.1827	0.9347	0.0492
313.15	0.6718	0.2533	0.9190	0.0746

Mass fraction of 1-Butanol (1) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 2)

Fixed		Measured
Temperature, K - Liquid mixture 2	Mass fraction of Water (3) - Liquid mixture 2	Mass fraction of 1-Butanol (1) - Liquid mixture 2
298.15	0.9176	0.0000
298.15	0.9235	0.0765
298.15	0.9249	0.0056
298.15	0.9293	0.0637
298.15	0.9304	0.0164
298.15	0.9378	0.0248
298.15	0.9404	0.0382
313.15	0.9005	0.0000
313.15	0.9203	0.0062
313.15	0.9298	0.0094
313.15	0.9382	0.0197
313.15	0.9407	0.0448
313.15	0.9433	0.0290
313.15	0.9298	0.0702

Mass fraction of 1-Butanol (1) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Fixed		Measured
Temperature, K - Liquid mixture 1	Mass fraction of Water (3) - Liquid mixture 1	Mass fraction of 1-Butanol (1) - Liquid mixture 1
298.15	0.1302	0.4366
298.15	0.1350	0.5183
298.15	0.1404	0.6009
298.15	0.1416	0.3425
298.15	0.1554	0.6796
298.15	0.1582	0.2539
298.15	0.1707	0.2043
298.15	0.1721	0.7388
298.15	0.1997	0.8003
298.15	0.2196	0.0875
298.15	0.2937	0.0000
313.15	0.1529	0.5127
313.15	0.1545	0.4238
313.15	0.1566	0.3362
313.15	0.1678	0.6583
313.15	0.1853	0.7334
313.15	0.1904	0.2054
313.15	0.2099	0.7901
313.15	0.2334	0.1087
313.15	0.3396	0.0000

Mass fraction of Phenol (2) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 2)

Fixed		Measured
Temperature, K - Liquid mixture 2	Mass fraction of Water (3) - Liquid mixture 2	Mass fraction of Phenol (2) - Liquid mixture 2
298.15	0.9176	0.0824
298.15	0.9235	0.0000
298.15	0.9249	0.0695
298.15	0.9293	0.0070
298.15	0.9304	0.0532
298.15	0.9378	0.0373
298.15	0.9404	0.0214
313.15	0.9005	0.0995
313.15	0.9203	0.0735
313.15	0.9298	0.0608
313.15	0.9382	0.0421
313.15	0.9407	0.0145
313.15	0.9433	0.0277
313.15	0.9298	0.0000

Mass fraction of Phenol (2) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Fixed		Measured
Temperature, K - Liquid mixture 1	Mass fraction of Water (3) - Liquid mixture 1	Mass fraction of Phenol (2) - Liquid mixture 1
298.15	0.1302	0.4332
298.15	0.1350	0.3467
298.15	0.1404	0.2587
298.15	0.1416	0.5159
298.15	0.1554	0.1650
298.15	0.1582	0.5880
298.15	0.1707	0.6250
298.15	0.1721	0.0890
298.15	0.1997	0.0000
298.15	0.2196	0.6929
298.15	0.2937	0.7063
313.15	0.1529	0.3344
313.15	0.1545	0.4217
313.15	0.1566	0.5073
313.15	0.1678	0.1738
313.15	0.1853	0.0812
313.15	0.1904	0.6043
313.15	0.2099	0.0000
313.15	0.2334	0.6579
313.15	0.3396	0.6604

Temperature, K x Mass fraction [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 2)

Fixed		Measured
Temperature, K - Liquid mixture 2	Mass fraction of Phenol (2) - Liquid mixture 1	Mass fraction of Water (3) - Liquid mixture 1	Mass fraction of Water (3) - Liquid mixture 2	Mass fraction of Phenol (2) - Liquid mixture 2
298.15	0.0652	0.1772	0.9271	0.0014
298.15	0.1683	0.1551	0.9296	0.0083
298.15	0.3026	0.1396	0.9348	0.0167
298.15	0.4434	0.1360	0.9356	0.0295
298.15	0.5524	0.1459	0.9341	0.0414
298.15	0.6757	0.1919	0.9264	0.0622
313.15	0.0552	0.1920	0.9372	0.0008
313.15	0.1979	0.1618	0.9379	0.0108
313.15	0.3238	0.1501	0.9405	0.0191
313.15	0.4899	0.1510	0.9379	0.0359
313.15	0.5926	0.1827	0.9347	0.0492
313.15	0.6718	0.2533	0.9190	0.0746

Refractive index (Na D-line) [ref]

Fixed			Measured
Temperature, K - Liquid mixture 2	Mass fraction of Water (3) - Liquid mixture 2	Mass fraction of Phenol (2) - Liquid mixture 2	Refractive index (Na D-line) - Liquid mixture 2
298.15	0.9176	0.0824	1.3493
298.15	0.9235	0.0000	1.3401
298.15	0.9249	0.0695	1.3469
298.15	0.9293	0.0070	1.3399
298.15	0.9304	0.0532	1.3447
298.15	0.9378	0.0373	1.3423
298.15	0.9404	0.0214	1.3404
313.15	0.9005	0.0995	1.3503
313.15	0.9203	0.0735	1.3455
313.15	0.9298	0.0000	1.3386
313.15	0.9298	0.0608	1.3434
313.15	0.9382	0.0421	1.3407
313.15	0.9407	0.0145	1.3375
313.15	0.9433	0.0277	1.3387

Refractive index (Na D-line) [ref]

Fixed			Measured
Temperature, K - Liquid mixture 1	Mass fraction of Water (3) - Liquid mixture 1	Mass fraction of Phenol (2) - Liquid mixture 1	Refractive index (Na D-line) - Liquid mixture 1
298.15	0.1302	0.4332	1.4494
298.15	0.1350	0.3467	1.437
298.15	0.1404	0.2587	1.4245
298.15	0.1416	0.5159	1.4608
298.15	0.1554	0.1650	1.4118
298.15	0.1582	0.5880	1.4709
298.15	0.1707	0.6250	1.4753
298.15	0.1721	0.0890	1.4011
298.15	0.1997	0.0000	1.3885
298.15	0.2196	0.6929	1.4826
298.15	0.2937	0.7063	1.4798
313.15	0.1529	0.3344	1.4284
313.15	0.1545	0.4217	1.4409
313.15	0.1566	0.5073	1.4526
313.15	0.1678	0.1738	1.4062
313.15	0.1853	0.0812	1.3935
313.15	0.1904	0.6043	1.4654
313.15	0.2099	0.0000	1.3823
313.15	0.2334	0.6579	1.4708
313.15	0.3396	0.6604	1.466

Refractive index (Na D-line) [ref]

Fixed			Measured
Temperature, K - Liquid mixture 2	Mass fraction of Water (3) - Liquid mixture 2	Mass fraction of Phenol (2) - Liquid mixture 2	Refractive index (Na D-line) - Liquid mixture 2
298.15	0.9176	0.0824	1.3493
298.15	0.9235	0.0000	1.3401
298.15	0.9249	0.0695	1.3469
298.15	0.9293	0.0070	1.3399
298.15	0.9304	0.0532	1.3447
298.15	0.9378	0.0373	1.3423
298.15	0.9404	0.0214	1.3404
313.15	0.9005	0.0995	1.3503
313.15	0.9203	0.0735	1.3455
313.15	0.9298	0.0000	1.3386
313.15	0.9298	0.0608	1.3434
313.15	0.9382	0.0421	1.3407
313.15	0.9407	0.0145	1.3375
313.15	0.9433	0.0277	1.3387

Refractive index (Na D-line) [ref]

Fixed			Measured
Temperature, K - Liquid mixture 1	Mass fraction of Water (3) - Liquid mixture 1	Mass fraction of Phenol (2) - Liquid mixture 1	Refractive index (Na D-line) - Liquid mixture 1
298.15	0.1302	0.4332	1.4494
298.15	0.1350	0.3467	1.437
298.15	0.1404	0.2587	1.4245
298.15	0.1416	0.5159	1.4608
298.15	0.1554	0.1650	1.4118
298.15	0.1582	0.5880	1.4709
298.15	0.1707	0.6250	1.4753
298.15	0.1721	0.0890	1.4011
298.15	0.1997	0.0000	1.3885
298.15	0.2196	0.6929	1.4826
298.15	0.2937	0.7063	1.4798
313.15	0.1529	0.3344	1.4284
313.15	0.1545	0.4217	1.4409
313.15	0.1566	0.5073	1.4526
313.15	0.1678	0.1738	1.4062
313.15	0.1853	0.0812	1.3935
313.15	0.1904	0.6043	1.4654
313.15	0.2099	0.0000	1.3823
313.15	0.2334	0.6579	1.4708
313.15	0.3396	0.6604	1.466

Mass density, kg/m3 [ref]

Fixed			Measured
Temperature, K - Liquid mixture 2	Mass fraction of Water (3) - Liquid mixture 2	Mass fraction of Phenol (2) - Liquid mixture 2	Mass density, kg/m3 - Liquid mixture 2
298.15	0.9176	0.0824	1004.065
298.15	0.9235	0.0000	985.811
298.15	0.9249	0.0695	1002.078
298.15	0.9293	0.0070	988.525
298.15	0.9304	0.0532	998.818
298.15	0.9378	0.0373	996.342
298.15	0.9404	0.0214	993.072
313.15	0.9005	0.0995	999.245
313.15	0.9203	0.0735	996.506
313.15	0.9298	0.0000	980.718
313.15	0.9298	0.0608	995.074
313.15	0.9382	0.0421	992.012
313.15	0.9407	0.0145	986.079
313.15	0.9433	0.0277	989.46

Mass density, kg/m3 [ref]

Fixed			Measured
Temperature, K - Liquid mixture 1	Mass fraction of Water (3) - Liquid mixture 1	Mass fraction of Phenol (2) - Liquid mixture 1	Mass density, kg/m3 - Liquid mixture 1
298.15	0.1302	0.4332	936.395
298.15	0.1350	0.3467	913.918
298.15	0.1404	0.2587	893.105
298.15	0.1416	0.5159	959.376
298.15	0.1554	0.1650	873.638
298.15	0.1582	0.5880	982.464
298.15	0.1707	0.6250	995.639
298.15	0.1721	0.0890	858.986
298.15	0.1997	0.0000	844.544
298.15	0.2196	0.6929	1026.05
298.15	0.2937	0.7063	1046.818
313.15	0.1529	0.3344	901.651
313.15	0.1545	0.4217	924.481
313.15	0.1566	0.5073	947.802
313.15	0.1678	0.1738	865.547
313.15	0.1853	0.0812	847.458
313.15	0.1904	0.6043	981.911
313.15	0.2099	0.0000	834.14
313.15	0.2334	0.6579	1007.043
313.15	0.3396	0.6604	1032.591

Mass density, kg/m3 [ref]

Fixed			Measured
Temperature, K - Liquid mixture 2	Mass fraction of Water (3) - Liquid mixture 2	Mass fraction of Phenol (2) - Liquid mixture 2	Mass density, kg/m3 - Liquid mixture 2
298.15	0.9176	0.0824	1004.065
298.15	0.9235	0.0000	985.811
298.15	0.9249	0.0695	1002.078
298.15	0.9293	0.0070	988.525
298.15	0.9304	0.0532	998.818
298.15	0.9378	0.0373	996.342
298.15	0.9404	0.0214	993.072
313.15	0.9005	0.0995	999.245
313.15	0.9203	0.0735	996.506
313.15	0.9298	0.0000	980.718
313.15	0.9298	0.0608	995.074
313.15	0.9382	0.0421	992.012
313.15	0.9407	0.0145	986.079
313.15	0.9433	0.0277	989.46

Mass density, kg/m3 [ref]

Fixed			Measured
Temperature, K - Liquid mixture 1	Mass fraction of Water (3) - Liquid mixture 1	Mass fraction of Phenol (2) - Liquid mixture 1	Mass density, kg/m3 - Liquid mixture 1
298.15	0.1302	0.4332	936.395
298.15	0.1350	0.3467	913.918
298.15	0.1404	0.2587	893.105
298.15	0.1416	0.5159	959.376
298.15	0.1554	0.1650	873.638
298.15	0.1582	0.5880	982.464
298.15	0.1707	0.6250	995.639
298.15	0.1721	0.0890	858.986
298.15	0.1997	0.0000	844.544
298.15	0.2196	0.6929	1026.05
298.15	0.2937	0.7063	1046.818
313.15	0.1529	0.3344	901.651
313.15	0.1545	0.4217	924.481
313.15	0.1566	0.5073	947.802
313.15	0.1678	0.1738	865.547
313.15	0.1853	0.0812	847.458
313.15	0.1904	0.6043	981.911
313.15	0.2099	0.0000	834.14
313.15	0.2334	0.6579	1007.043
313.15	0.3396	0.6604	1032.591

Sources

• (Liquid + liquid) equilibrium of {water + phenol + (1-butanol, or 2-butanol, or tert-butanol)} systems