Mixture of Aniline + Cyclohexane, methyl- + Water

Datasets

1. Mole fraction (8)

Mole fraction of Cyclohexane, methyl- (2) [ref]

Operational conditions:

• Temperature, K = 323.15 (Liquid mixture 1)
• Pressure, kPa = 101 (Liquid mixture 1)

Mole fraction of Water (3) - Liquid mixture 1	Mole fraction of Cyclohexane, methyl- (2) - Liquid mixture 1
0.2626	0.0000
0.2260	0.0441
0.2047	0.0835
0.1797	0.1201
0.1245	0.2137
0.0585	0.3465
0.0521	0.3743
0.0398	0.4111
0.0305	0.5406

Temperature, K x Mole fraction [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 2)

Fixed		Measured
Temperature, K - Liquid mixture 2	Mole fraction of Water (3) - Liquid mixture 1	Mole fraction of Cyclohexane, methyl- (2) - Liquid mixture 1	Mole fraction of Cyclohexane, methyl- (2) - Liquid mixture 2	Mole fraction of Water (3) - Liquid mixture 2
298.15	0.0041	0.8970	0.1010	0.0748
298.15	0.0029	0.8979	0.1031	0.1046
298.15	0.0038	0.9570	0.0001	0.9944
298.15	0.9912	0.0001	0.0455	0.1760
323.15	0.0011	0.9700	0.0001	0.9976
323.15	0.0054	0.9617	0.0001	0.9969
323.15	0.0196	0.6513	0.2910	0.0817
323.15	0.0212	0.6374	0.3052	0.0645

Temperature, K x Mole fraction [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Fixed	Measured
Temperature, K - Liquid mixture 1	Mole fraction of Water (3) - Liquid mixture 3	Mole fraction of Cyclohexane, methyl- (2) - Liquid mixture 3	Mole fraction of Cyclohexane, methyl- (2) - Liquid mixture 2	Mole fraction of Water (3) - Liquid mixture 2	Mole fraction of Cyclohexane, methyl- (2) - Liquid mixture 1	Mole fraction of Water (3) - Liquid mixture 1
298.15	0.9929	0.0001	0.0883	0.1590	0.9053	0.0056
303.15	0.9931	0.0001	0.1064	0.1527	0.8898	0.0056
308.15	0.9877	0.0003	0.1179	0.1635	0.8626	0.0073
313.15	0.9903	0.0001	0.1280	0.1685	0.8377	0.0084
318.15	0.9914	0.0001	0.1490	0.1566	0.8080	0.0126
323.15	0.9915	0.0001	0.1660	0.1611	0.7421	0.0353
328.15	0.9914	0.0001	0.2161	0.1447	0.6677	0.0327
331.45	0.9900	0.0001	0.2888	0.1241	0.5778	0.0463
332.15	0.9899	0.0001	0.3587	0.1100	0.5071	0.0651

Temperature, K x Pressure, kPa x Mole fraction [ref]

Fixed			Measured
Temperature, K - Liquid	Pressure, kPa - Liquid	Mole fraction of Cyclohexane, methyl- (2) - Liquid	Mole fraction of Water (3) - Liquid	Mole fraction of Water (3) - Gas	Mole fraction of Cyclohexane, methyl- (2) - Gas
333.15	29.54	0.0584	0.1194	0.4534	0.5267
333.15	35.10	0.3430	0.0403	0.3348	0.6524
333.15	37.27	0.1218	0.1263	0.3606	0.6260
333.15	44.26	0.1043	0.1968	0.5017	0.4861
333.15	44.47	0.1812	0.1620	0.4160	0.5702
333.15	44.48	0.2501	0.1264	0.3427	0.6426
333.15	44.59	0.5726	0.0551	0.3354	0.6490
353.15	92.09	0.6158	0.0471	0.4785	0.5034
353.15	92.22	0.1986	0.1774	0.4726	0.5086
353.15	92.47	0.6851	0.0316	0.4438	0.5385
353.15	93.49	0.1537	0.1998	0.4610	0.5202
353.15	94.00	0.2350	0.1572	0.4540	0.5265
353.15	95.52	0.5050	0.0665	0.4897	0.4976
358.15	98.46	0.2798	0.0852	0.3778	0.6034
363.15	91.00	0.0814	0.1232	0.4933	0.4814
363.15	96.07	0.1253	0.1309	0.4659	0.5035

Mole fraction of Cyclohexane, methyl- (2) [ref]

Operational conditions:

• Temperature, K = 323.15 (Liquid mixture 1)
• Pressure, kPa = 101 (Liquid mixture 1)

Mole fraction of Water (3) - Liquid mixture 1	Mole fraction of Cyclohexane, methyl- (2) - Liquid mixture 1
0.2626	0.0000
0.2260	0.0441
0.2047	0.0835
0.1797	0.1201
0.1245	0.2137
0.0585	0.3465
0.0521	0.3743
0.0398	0.4111
0.0305	0.5406

Temperature, K x Mole fraction [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 2)

Fixed		Measured
Temperature, K - Liquid mixture 2	Mole fraction of Water (3) - Liquid mixture 1	Mole fraction of Cyclohexane, methyl- (2) - Liquid mixture 1	Mole fraction of Cyclohexane, methyl- (2) - Liquid mixture 2	Mole fraction of Water (3) - Liquid mixture 2
298.15	0.0041	0.8970	0.1010	0.0748
298.15	0.0029	0.8979	0.1031	0.1046
298.15	0.0038	0.9570	0.0001	0.9944
298.15	0.9912	0.0001	0.0455	0.1760
323.15	0.0011	0.9700	0.0001	0.9976
323.15	0.0054	0.9617	0.0001	0.9969
323.15	0.0196	0.6513	0.2910	0.0817
323.15	0.0212	0.6374	0.3052	0.0645

Temperature, K x Mole fraction [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Fixed	Measured
Temperature, K - Liquid mixture 1	Mole fraction of Water (3) - Liquid mixture 3	Mole fraction of Cyclohexane, methyl- (2) - Liquid mixture 3	Mole fraction of Cyclohexane, methyl- (2) - Liquid mixture 2	Mole fraction of Water (3) - Liquid mixture 2	Mole fraction of Cyclohexane, methyl- (2) - Liquid mixture 1	Mole fraction of Water (3) - Liquid mixture 1
298.15	0.9929	0.0001	0.0883	0.1590	0.9053	0.0056
303.15	0.9931	0.0001	0.1064	0.1527	0.8898	0.0056
308.15	0.9877	0.0003	0.1179	0.1635	0.8626	0.0073
313.15	0.9903	0.0001	0.1280	0.1685	0.8377	0.0084
318.15	0.9914	0.0001	0.1490	0.1566	0.8080	0.0126
323.15	0.9915	0.0001	0.1660	0.1611	0.7421	0.0353
328.15	0.9914	0.0001	0.2161	0.1447	0.6677	0.0327
331.45	0.9900	0.0001	0.2888	0.1241	0.5778	0.0463
332.15	0.9899	0.0001	0.3587	0.1100	0.5071	0.0651

Temperature, K x Pressure, kPa x Mole fraction [ref]

Fixed			Measured
Temperature, K - Liquid	Pressure, kPa - Liquid	Mole fraction of Cyclohexane, methyl- (2) - Liquid	Mole fraction of Water (3) - Liquid	Mole fraction of Water (3) - Gas	Mole fraction of Cyclohexane, methyl- (2) - Gas
333.15	29.54	0.0584	0.1194	0.4534	0.5267
333.15	35.10	0.3430	0.0403	0.3348	0.6524
333.15	37.27	0.1218	0.1263	0.3606	0.6260
333.15	44.26	0.1043	0.1968	0.5017	0.4861
333.15	44.47	0.1812	0.1620	0.4160	0.5702
333.15	44.48	0.2501	0.1264	0.3427	0.6426
333.15	44.59	0.5726	0.0551	0.3354	0.6490
353.15	92.09	0.6158	0.0471	0.4785	0.5034
353.15	92.22	0.1986	0.1774	0.4726	0.5086
353.15	92.47	0.6851	0.0316	0.4438	0.5385
353.15	93.49	0.1537	0.1998	0.4610	0.5202
353.15	94.00	0.2350	0.1572	0.4540	0.5265
353.15	95.52	0.5050	0.0665	0.4897	0.4976
358.15	98.46	0.2798	0.0852	0.3778	0.6034
363.15	91.00	0.0814	0.1232	0.4933	0.4814
363.15	96.07	0.1253	0.1309	0.4659	0.5035

Sources

• VLE and LLE in ternary systems of two associating components (water, aniline, and cyclohexylamine) and a hydrocarbon (cyclohexane or methylcyclohexane)