Mixture of Formic acid, butyl ester + Carbon dioxide

Datasets

1. Mole fraction (2)
2. P_vap - Vapor or sublimation pressure, kPa (2)

Mole fraction of Carbon dioxide (2) [ref]

Fixed		Measured
Mole fraction of Carbon dioxide (2) - Liquid	Temperature, K - Liquid	Mole fraction of Carbon dioxide (2) - Gas
0.1028	283.15	0.9968
0.2147	283.15	0.9969
0.3213	283.15	0.9969
0.3988	283.15	0.9972
0.5051	283.15	0.9971
0.6156	283.15	0.9970
0.7187	283.15	0.9976
0.8421	283.15	0.9979
0.1112	293.15	0.9959
0.1988	293.15	0.9959
0.3077	293.15	0.9958
0.3998	293.15	0.9960
0.5122	293.15	0.9965
0.6111	293.15	0.9962
0.7122	293.15	0.9966
0.8110	293.15	0.9966
0.8864	293.15	0.9969
0.1131	303.15	0.9950
0.1998	303.15	0.9952
0.3101	303.15	0.9949
0.3741	303.15	0.9953
0.4021	303.15	0.9958
0.4875	303.15	0.9958
0.6012	303.15	0.9957
0.7231	303.15	0.9959
0.8144	303.15	0.9959
0.8533	303.15	0.9962
0.0879	313.15	0.9939
0.1998	313.15	0.9943
0.3178	313.15	0.9943
0.4011	313.15	0.9941
0.4897	313.15	0.9946
0.0877	323.15	0.9912
0.1871	323.15	0.9913
0.2614	323.15	0.9915
0.3669	323.15	0.9913
0.4635	323.15	0.9916
0.5533	323.15	0.9917
0.6455	323.15	0.9918
0.7110	323.15	0.9920
0.0911	333.15	0.9900
0.2121	333.15	0.9900
0.2988	333.15	0.9900
0.3877	333.15	0.9890
0.4679	333.15	0.9910
0.5011	333.15	0.9911
0.5890	333.15	0.9912
0.6383	333.15	0.9900
0.0425	343.15	0.9860
0.1212	343.15	0.9860
0.2019	343.15	0.9850
0.2788	343.15	0.9860
0.3550	343.15	0.9870
0.4287	343.15	0.9850
0.4995	343.15	0.9880
0.5580	343.15	0.9880
0.5788	313.15	0.9946
0.6991	313.15	0.9947
0.7877	313.15	0.9948

Mole fraction of Carbon dioxide (2) [ref]

Fixed		Measured
Mole fraction of Carbon dioxide (2) - Liquid	Temperature, K - Liquid	Mole fraction of Carbon dioxide (2) - Gas
0.1028	283.15	0.9968
0.2147	283.15	0.9969
0.3213	283.15	0.9969
0.3988	283.15	0.9972
0.5051	283.15	0.9971
0.6156	283.15	0.9970
0.7187	283.15	0.9976
0.8421	283.15	0.9979
0.1112	293.15	0.9959
0.1988	293.15	0.9959
0.3077	293.15	0.9958
0.3998	293.15	0.9960
0.5122	293.15	0.9965
0.6111	293.15	0.9962
0.7122	293.15	0.9966
0.8110	293.15	0.9966
0.8864	293.15	0.9969
0.1131	303.15	0.9950
0.1998	303.15	0.9952
0.3101	303.15	0.9949
0.3741	303.15	0.9953
0.4021	303.15	0.9958
0.4875	303.15	0.9958
0.6012	303.15	0.9957
0.7231	303.15	0.9959
0.8144	303.15	0.9959
0.8533	303.15	0.9962
0.0879	313.15	0.9939
0.1998	313.15	0.9943
0.3178	313.15	0.9943
0.4011	313.15	0.9941
0.4897	313.15	0.9946
0.0877	323.15	0.9912
0.1871	323.15	0.9913
0.2614	323.15	0.9915
0.3669	323.15	0.9913
0.4635	323.15	0.9916
0.5533	323.15	0.9917
0.6455	323.15	0.9918
0.7110	323.15	0.9920
0.0911	333.15	0.9900
0.2121	333.15	0.9900
0.2988	333.15	0.9900
0.3877	333.15	0.9890
0.4679	333.15	0.9910
0.5011	333.15	0.9911
0.5890	333.15	0.9912
0.6383	333.15	0.9900
0.0425	343.15	0.9860
0.1212	343.15	0.9860
0.2019	343.15	0.9850
0.2788	343.15	0.9860
0.3550	343.15	0.9870
0.4287	343.15	0.9850
0.4995	343.15	0.9880
0.5580	343.15	0.9880
0.5788	313.15	0.9946
0.6991	313.15	0.9947
0.7877	313.15	0.9948

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Mole fraction of Carbon dioxide (2) - Liquid	Temperature, K - Liquid	Vapor or sublimation pressure, kPa - Liquid
0.1028	283.15	219.60
0.2147	283.15	516.30
0.3213	283.15	859.00
0.3988	283.15	1148.60
0.5051	283.15	1622.50
0.6156	283.15	2145.80
0.7187	283.15	2770.80
0.8421	283.15	3618.80
0.1112	293.15	329.40
0.1988	293.15	635.00
0.3077	293.15	1101.00
0.3998	293.15	1552.00
0.5122	293.15	2111.00
0.6111	293.15	2681.30
0.7122	293.15	3384.00
0.8110	293.15	4151.00
0.8864	293.15	4755.00
0.1131	303.15	403.20
0.1998	303.15	781.20
0.3101	303.15	1312.00
0.3741	303.15	1662.00
0.4021	303.15	1822.00
0.4875	303.15	2303.00
0.6012	303.15	3064.00
0.7231	303.15	3989.00
0.8144	303.15	4728.00
0.8533	303.15	5112.60
0.0879	313.15	336.10
0.1998	313.15	931.10
0.3178	313.15	1604.00
0.4011	313.15	2114.00
0.4897	313.15	2746.00
0.0877	323.15	421.30
0.1871	323.15	1007.40
0.2614	323.15	1450.60
0.3669	323.15	2207.80
0.4635	323.15	2950.50
0.5533	323.15	3760.20
0.6455	323.15	4702.50
0.7110	323.15	5350.10
0.0911	333.15	531.00
0.2121	333.15	1360.50
0.2988	333.15	2035.00
0.3877	333.15	2833.50
0.4679	333.15	3565.00
0.5011	333.15	3928.10
0.5890	333.15	4852.00
0.6383	333.15	5451.00
0.0425	343.15	325.20
0.1212	343.15	961.60
0.2019	343.15	1680.10
0.2788	343.15	2411.00
0.3550	343.15	3218.00
0.4287	343.15	4042.10
0.4995	343.15	4731.80
0.5580	343.15	5447.00
0.5788	313.15	3423.80
0.6991	313.15	4440.80
0.7877	313.15	5272.00

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Mole fraction of Carbon dioxide (2) - Liquid	Temperature, K - Liquid	Vapor or sublimation pressure, kPa - Liquid
0.1028	283.15	219.60
0.2147	283.15	516.30
0.3213	283.15	859.00
0.3988	283.15	1148.60
0.5051	283.15	1622.50
0.6156	283.15	2145.80
0.7187	283.15	2770.80
0.8421	283.15	3618.80
0.1112	293.15	329.40
0.1988	293.15	635.00
0.3077	293.15	1101.00
0.3998	293.15	1552.00
0.5122	293.15	2111.00
0.6111	293.15	2681.30
0.7122	293.15	3384.00
0.8110	293.15	4151.00
0.8864	293.15	4755.00
0.1131	303.15	403.20
0.1998	303.15	781.20
0.3101	303.15	1312.00
0.3741	303.15	1662.00
0.4021	303.15	1822.00
0.4875	303.15	2303.00
0.6012	303.15	3064.00
0.7231	303.15	3989.00
0.8144	303.15	4728.00
0.8533	303.15	5112.60
0.0879	313.15	336.10
0.1998	313.15	931.10
0.3178	313.15	1604.00
0.4011	313.15	2114.00
0.4897	313.15	2746.00
0.0877	323.15	421.30
0.1871	323.15	1007.40
0.2614	323.15	1450.60
0.3669	323.15	2207.80
0.4635	323.15	2950.50
0.5533	323.15	3760.20
0.6455	323.15	4702.50
0.7110	323.15	5350.10
0.0911	333.15	531.00
0.2121	333.15	1360.50
0.2988	333.15	2035.00
0.3877	333.15	2833.50
0.4679	333.15	3565.00
0.5011	333.15	3928.10
0.5890	333.15	4852.00
0.6383	333.15	5451.00
0.0425	343.15	325.20
0.1212	343.15	961.60
0.2019	343.15	1680.10
0.2788	343.15	2411.00
0.3550	343.15	3218.00
0.4287	343.15	4042.10
0.4995	343.15	4731.80
0.5580	343.15	5447.00
0.5788	313.15	3423.80
0.6991	313.15	4440.80
0.7877	313.15	5272.00

Sources

• Assessment, measurement and correlation of (vapour + liquid) equilibrium of (carbon dioxide + butyl, isobutyl, and amyl formate) systems