Mixture of Formic acid, butyl ester + Butane, 1,4-dibromo-

Name: Formic acid, butyl ester
InChI: InChI=1S/C5H10O2/c1-2-3-4-7-5-6/h5H,2-4H2,1H3
InChI Key: NMJJFJNHVMGPGM-UHFFFAOYSA-N
Formula: C5H10O2
SMILES: CCCCOC=O
Mol. Weight (g/mol): 102.13
CAS: 592-84-7

Name: Butane, 1,4-dibromo-
InChI: InChI=1S/C4H8Br2/c5-3-1-2-4-6/h1-4H2
InChI Key: ULTHEAFYOOPTTB-UHFFFAOYSA-N
Formula: C4H8Br2
SMILES: BrCCCCBr
Mol. Weight (g/mol): 215.91
CAS: 110-52-1

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Datasets

Excess molar enthalpy (molar enthalpy (2)
ρ_l - Mass density, kg/m3 (2)
Excess molar volume, m3/mol (2)

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational conditions:

Pressure, kPa = 101 (Liquid)
Temperature, K = 298.15 (Liquid)

Mole fraction of Formic acid, butyl ester (1) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.0646	0.0740
0.1478	0.1320
0.2392	0.1770
0.3291	0.2040
0.4058	0.2110
0.4726	0.2040
0.5295	0.1950
0.5817	0.1820
0.6425	0.1620
0.7078	0.1380
0.7787	0.1060
0.8648	0.0690
0.9404	0.0280

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational conditions:

Pressure, kPa = 101 (Liquid)
Temperature, K = 298.15 (Liquid)

Mole fraction of Formic acid, butyl ester (1) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.0646	0.0740
0.1478	0.1320
0.2392	0.1770
0.3291	0.2040
0.4058	0.2110
0.4726	0.2040
0.5295	0.1950
0.5817	0.1820
0.6425	0.1620
0.7078	0.1380
0.7787	0.1060
0.8648	0.0690
0.9404	0.0280

Mass density, kg/m3 [ref]

Operational conditions:

Temperature, K = 298.15 (Liquid)
Pressure, kPa = 101 (Liquid)

Mole fraction of Formic acid, butyl ester (1) - Liquid	Mass density, kg/m3 - Liquid
0.0702	1756.08
0.1221	1708.91
0.1836	1652.89
0.2410	1600.45
0.3018	1544.61
0.4249	1431.07
0.4765	1383.26
0.5374	1326.55
0.6529	1218.52
0.7677	1110.31
0.8248	1056.19
0.8824	1001.42
0.9353	950.88

Mass density, kg/m3 [ref]

Operational conditions:

Temperature, K = 298.15 (Liquid)
Pressure, kPa = 101 (Liquid)

Mole fraction of Formic acid, butyl ester (1) - Liquid	Mass density, kg/m3 - Liquid
0.0702	1756.08
0.1221	1708.91
0.1836	1652.89
0.2410	1600.45
0.3018	1544.61
0.4249	1431.07
0.4765	1383.26
0.5374	1326.55
0.6529	1218.52
0.7677	1110.31
0.8248	1056.19
0.8824	1001.42
0.9353	950.88

Excess molar volume, m3/mol [ref]

Operational conditions:

Temperature, K = 298.15 (Liquid)
Pressure, kPa = 101 (Liquid)

Mole fraction of Formic acid, butyl ester (1) - Liquid	Excess molar volume, m3/mol - Liquid
0.0702	0.0000
0.1221	1.1000e-08
0.1836	1.7000e-08
0.2410	2.0000e-08
0.3018	2.3000e-08
0.4249	2.6000e-08
0.4765	2.6000e-08
0.5374	2.5000e-08
0.6529	2.1000e-08
0.7677	1.6000e-08
0.8248	1.2000e-08
0.8824	1.0000e-08
0.9353	0.0000

Excess molar volume, m3/mol [ref]

Operational conditions:

Temperature, K = 298.15 (Liquid)
Pressure, kPa = 101 (Liquid)

Mole fraction of Formic acid, butyl ester (1) - Liquid	Excess molar volume, m3/mol - Liquid
0.0702	0.0000
0.1221	1.1000e-08
0.1836	1.7000e-08
0.2410	2.0000e-08
0.3018	2.3000e-08
0.4249	2.6000e-08
0.4765	2.6000e-08
0.5374	2.5000e-08
0.6529	2.1000e-08
0.7677	1.6000e-08
0.8248	1.2000e-08
0.8824	1.0000e-08
0.9353	0.0000

Sources

Thermodynamic study of (alkyl esters + alpha,beta-alkyl dihalides) VI.H and V for 20 binary mixtures {xCu-1H2u-1CO2(CH2)3CH3 + (1 - x)alpha,omega-BrCH2(CH2)v-2CH2Br}, where u = 1 to 5, alpha = 1, and v = omega = 2 to 6