Mixture of lithium chloride + Water + Lithium sulfate

Datasets

1. Mass fraction (8)
2. η - Viscosity, Pa*s (2)
3. σ_cond - Electrical conductivity, S/m (2)
4. n₀ - Refractive index (Na D-line) (6)
5. ρ_l - Mass density, kg/m3 (6)

Mass fraction of Lithium sulfate (3) [ref]

Operational condition: Pressure, kPa = 100 (Liquid)

Fixed		Measured
Mass fraction of lithium chloride (1) - Liquid	Temperature, K - Liquid	Mass fraction of Lithium sulfate (3) - Liquid
0.0000	288.15	0.2601
0.0317	288.15	0.2102
0.0612	288.15	0.1651
0.0901	288.15	0.1237
0.1206	288.15	0.0847
0.1488	288.15	0.0538
0.1997	288.15	0.0227
0.2399	288.15	0.0139
0.3008	288.15	0.0060
0.3438	288.15	0.0036
0.3786	288.15	0.0030
0.3883	288.15	0.0029
0.4397	288.15	0.0015
0.0000	308.15	0.2537
0.0410	308.15	0.1879
0.0788	308.15	0.1330
0.1230	308.15	0.0770
0.1516	308.15	0.0486
0.1969	308.15	0.0184
0.2280	308.15	0.0103
0.2652	308.15	0.0045
0.3085	308.15	0.0015
0.3537	308.15	0.0008
0.3913	308.15	0.0006
0.4480	308.15	0.0006
0.4651	308.15	0.0006

Mass fraction of Lithium sulfate (3) [ref]

Operational condition: Pressure, kPa = 100 (Liquid)

Fixed		Measured
Mass fraction of lithium chloride (1) - Liquid	Temperature, K - Liquid	Mass fraction of Lithium sulfate (3) - Liquid
0.4397	288.15	0.0015
0.4390	288.15	0.0010
0.4394	288.15	0.0004
0.4413	288.15	0.0000
0.4651	308.15	0.0006
0.4630	308.15	0.0006
0.4652	308.15	0.0005
0.4664	308.15	0.0000

Mass fraction of Lithium sulfate (3) [ref]

Operational conditions:

• Temperature, K = 288.15 (Liquid)
• Pressure, kPa = 77 (Liquid)

Mass fraction of lithium chloride (1) - Liquid	Mass fraction of Lithium sulfate (3) - Liquid
0.4408	0.0000
0.4410	0.0007
0.4428	0.0010

Mass fraction of Lithium sulfate (3) [ref]

Operational conditions:

• Temperature, K = 288.15 (Liquid)
• Pressure, kPa = 77 (Liquid)

Mass fraction of lithium chloride (1) - Liquid	Mass fraction of Lithium sulfate (3) - Liquid
0.4428	0.0010
0.3319	0.0082
0.2681	0.0164
0.2045	0.0477
0.1587	0.0925
0.0923	0.1544
0.0368	0.2173
0.0000	0.2598

Mass fraction of Lithium sulfate (3) [ref]

Operational condition: Pressure, kPa = 100 (Liquid)

Fixed		Measured
Mass fraction of lithium chloride (1) - Liquid	Temperature, K - Liquid	Mass fraction of Lithium sulfate (3) - Liquid
0.0000	288.15	0.2601
0.0317	288.15	0.2102
0.0612	288.15	0.1651
0.0901	288.15	0.1237
0.1206	288.15	0.0847
0.1488	288.15	0.0538
0.1997	288.15	0.0227
0.2399	288.15	0.0139
0.3008	288.15	0.0060
0.3438	288.15	0.0036
0.3786	288.15	0.0030
0.3883	288.15	0.0029
0.4397	288.15	0.0015
0.0000	308.15	0.2537
0.0410	308.15	0.1879
0.0788	308.15	0.1330
0.1230	308.15	0.0770
0.1516	308.15	0.0486
0.1969	308.15	0.0184
0.2280	308.15	0.0103
0.2652	308.15	0.0045
0.3085	308.15	0.0015
0.3537	308.15	0.0008
0.3913	308.15	0.0006
0.4480	308.15	0.0006
0.4651	308.15	0.0006

Mass fraction of Lithium sulfate (3) [ref]

Operational condition: Pressure, kPa = 100 (Liquid)

Fixed		Measured
Mass fraction of lithium chloride (1) - Liquid	Temperature, K - Liquid	Mass fraction of Lithium sulfate (3) - Liquid
0.4397	288.15	0.0015
0.4390	288.15	0.0010
0.4394	288.15	0.0004
0.4413	288.15	0.0000
0.4651	308.15	0.0006
0.4630	308.15	0.0006
0.4652	308.15	0.0005
0.4664	308.15	0.0000

Mass fraction of Lithium sulfate (3) [ref]

Operational conditions:

• Temperature, K = 288.15 (Liquid)
• Pressure, kPa = 77 (Liquid)

Mass fraction of lithium chloride (1) - Liquid	Mass fraction of Lithium sulfate (3) - Liquid
0.4408	0.0000
0.4410	0.0007
0.4428	0.0010

Mass fraction of Lithium sulfate (3) [ref]

Operational conditions:

• Temperature, K = 288.15 (Liquid)
• Pressure, kPa = 77 (Liquid)

Mass fraction of lithium chloride (1) - Liquid	Mass fraction of Lithium sulfate (3) - Liquid
0.4428	0.0010
0.3319	0.0082
0.2681	0.0164
0.2045	0.0477
0.1587	0.0925
0.0923	0.1544
0.0368	0.2173
0.0000	0.2598

Viscosity, Pa*s [ref]

Operational conditions:

• Pressure, kPa = 100 (Liquid)
• Temperature, K = 308.15 (Liquid)

Fixed		Measured
Mass fraction of Lithium sulfate (3) - Liquid	Mass fraction of lithium chloride (1) - Liquid	Viscosity, Pa*s - Liquid
0.2656	0.0000	0.0037
0.0003	0.4027	0.0063
0.0004	0.4706	0.0133
0.0000	0.4678	0.0128

Viscosity, Pa*s [ref]

Operational conditions:

• Pressure, kPa = 100 (Liquid)
• Temperature, K = 308.15 (Liquid)

Fixed		Measured
Mass fraction of Lithium sulfate (3) - Liquid	Mass fraction of lithium chloride (1) - Liquid	Viscosity, Pa*s - Liquid
0.2656	0.0000	0.0037
0.0003	0.4027	0.0063
0.0004	0.4706	0.0133
0.0000	0.4678	0.0128

Electrical conductivity, S/m [ref]

Operational conditions:

• Pressure, kPa = 100 (Liquid)
• Temperature, K = 308.15 (Liquid)

Fixed		Measured
Mass fraction of Lithium sulfate (3) - Liquid	Mass fraction of lithium chloride (1) - Liquid	Electrical conductivity, S/m - Liquid
0.2656	0.0000	9.04
0.0003	0.4027	11.26
0.0004	0.4706	7.95
0.0000	0.4678	7.96

Electrical conductivity, S/m [ref]

Operational conditions:

• Pressure, kPa = 100 (Liquid)
• Temperature, K = 308.15 (Liquid)

Fixed		Measured
Mass fraction of Lithium sulfate (3) - Liquid	Mass fraction of lithium chloride (1) - Liquid	Electrical conductivity, S/m - Liquid
0.2656	0.0000	9.04
0.0003	0.4027	11.26
0.0004	0.4706	7.95
0.0000	0.4678	7.96

Refractive index (Na D-line) [ref]

Operational conditions:

• Pressure, kPa = 100 (Liquid)
• Temperature, K = 308.15 (Liquid)

Fixed		Measured
Mass fraction of Lithium sulfate (3) - Liquid	Mass fraction of lithium chloride (1) - Liquid	Refractive index (Na D-line) - Liquid
0.2656	0.0000	1.3793
0.2435	0.0144	1.3761
0.2321	0.0175	1.3748
0.2206	0.0232	1.373
0.2060	0.0312	1.3726
0.1835	0.0461	1.3717
0.1525	0.0680	1.371
0.1272	0.0858	1.3706
0.0857	0.1185	1.3703
0.0337	0.1729	1.3737
0.0208	0.1982	1.377
0.0066	0.2416	1.3842
0.0022	0.2811	1.3928
0.0007	0.3288	1.4042
0.0004	0.3523	1.4095
0.0003	0.3809	1.4167
0.0003	0.4027	1.4232
0.0004	0.4706	1.4461
0.0000	0.4678	1.4398

Refractive index (Na D-line) [ref]

Operational condition: Pressure, kPa = 100 (Liquid)

Fixed			Measured
Mass fraction of lithium chloride (1) - Liquid	Mass fraction of Lithium sulfate (3) - Liquid	Temperature, K - Liquid	Refractive index (Na D-line) - Liquid
0.0000	0.2601	288.15	1.3845
0.0317	0.2102	288.15	1.3821
0.0612	0.1651	288.15	1.3809
0.0901	0.1237	288.15	1.3801
0.1206	0.0847	288.15	1.3799
0.1488	0.0538	288.15	1.3807
0.1997	0.0227	288.15	1.3858
0.2399	0.0139	288.15	1.3927
0.3008	0.0060	288.15	1.4076
0.3438	0.0036	288.15	1.4162
0.3786	0.0030	288.15	1.4259
0.3883	0.0029	288.15	1.4274
0.4397	0.0015	288.15	1.439
0.0000	0.2537	308.15	1.3738
0.0410	0.1879	308.15	1.3715
0.0788	0.1330	308.15	1.3703
0.1230	0.0770	308.15	1.3701
0.1516	0.0486	308.15	1.3721
0.1969	0.0184	308.15	1.3769
0.2280	0.0103	308.15	1.382
0.2652	0.0045	308.15	1.3901
0.3085	0.0015	308.15	1.3999
0.3537	0.0008	308.15	1.4108
0.3913	0.0006	308.15	1.4193
0.4480	0.0006	308.15	1.4324
0.4651	0.0006	308.15	1.4363

Refractive index (Na D-line) [ref]

Operational condition: Pressure, kPa = 100 (Liquid)

Fixed			Measured
Mass fraction of lithium chloride (1) - Liquid	Mass fraction of Lithium sulfate (3) - Liquid	Temperature, K - Liquid	Refractive index (Na D-line) - Liquid
0.4397	0.0015	288.15	1.439
0.4390	0.0010	288.15	1.4392
0.4394	0.0004	288.15	1.4384
0.4413	0.0000	288.15	1.4394
0.4651	0.0006	308.15	1.4363
0.4630	0.0006	308.15	1.4363
0.4652	0.0005	308.15	1.4364
0.4664	0.0000	308.15	1.4365

Refractive index (Na D-line) [ref]

Operational conditions:

• Pressure, kPa = 100 (Liquid)
• Temperature, K = 308.15 (Liquid)

Fixed		Measured
Mass fraction of Lithium sulfate (3) - Liquid	Mass fraction of lithium chloride (1) - Liquid	Refractive index (Na D-line) - Liquid
0.2656	0.0000	1.3793
0.2435	0.0144	1.3761
0.2321	0.0175	1.3748
0.2206	0.0232	1.373
0.2060	0.0312	1.3726
0.1835	0.0461	1.3717
0.1525	0.0680	1.371
0.1272	0.0858	1.3706
0.0857	0.1185	1.3703
0.0337	0.1729	1.3737
0.0208	0.1982	1.377
0.0066	0.2416	1.3842
0.0022	0.2811	1.3928
0.0007	0.3288	1.4042
0.0004	0.3523	1.4095
0.0003	0.3809	1.4167
0.0003	0.4027	1.4232
0.0004	0.4706	1.4461
0.0000	0.4678	1.4398

Refractive index (Na D-line) [ref]

Operational condition: Pressure, kPa = 100 (Liquid)

Fixed			Measured
Mass fraction of lithium chloride (1) - Liquid	Mass fraction of Lithium sulfate (3) - Liquid	Temperature, K - Liquid	Refractive index (Na D-line) - Liquid
0.0000	0.2601	288.15	1.3845
0.0317	0.2102	288.15	1.3821
0.0612	0.1651	288.15	1.3809
0.0901	0.1237	288.15	1.3801
0.1206	0.0847	288.15	1.3799
0.1488	0.0538	288.15	1.3807
0.1997	0.0227	288.15	1.3858
0.2399	0.0139	288.15	1.3927
0.3008	0.0060	288.15	1.4076
0.3438	0.0036	288.15	1.4162
0.3786	0.0030	288.15	1.4259
0.3883	0.0029	288.15	1.4274
0.4397	0.0015	288.15	1.439
0.0000	0.2537	308.15	1.3738
0.0410	0.1879	308.15	1.3715
0.0788	0.1330	308.15	1.3703
0.1230	0.0770	308.15	1.3701
0.1516	0.0486	308.15	1.3721
0.1969	0.0184	308.15	1.3769
0.2280	0.0103	308.15	1.382
0.2652	0.0045	308.15	1.3901
0.3085	0.0015	308.15	1.3999
0.3537	0.0008	308.15	1.4108
0.3913	0.0006	308.15	1.4193
0.4480	0.0006	308.15	1.4324
0.4651	0.0006	308.15	1.4363

Refractive index (Na D-line) [ref]

Operational condition: Pressure, kPa = 100 (Liquid)

Fixed			Measured
Mass fraction of lithium chloride (1) - Liquid	Mass fraction of Lithium sulfate (3) - Liquid	Temperature, K - Liquid	Refractive index (Na D-line) - Liquid
0.4397	0.0015	288.15	1.439
0.4390	0.0010	288.15	1.4392
0.4394	0.0004	288.15	1.4384
0.4413	0.0000	288.15	1.4394
0.4651	0.0006	308.15	1.4363
0.4630	0.0006	308.15	1.4363
0.4652	0.0005	308.15	1.4364
0.4664	0.0000	308.15	1.4365

Mass density, kg/m3 [ref]

Operational conditions:

• Pressure, kPa = 100 (Liquid)
• Temperature, K = 308.15 (Liquid)

Fixed		Measured
Mass fraction of Lithium sulfate (3) - Liquid	Mass fraction of lithium chloride (1) - Liquid	Mass density, kg/m3 - Liquid
0.2656	0.0000	1233.8
0.2435	0.0144	1223.7
0.2321	0.0175	1212.4
0.2206	0.0232	1206.4
0.2060	0.0312	1198.6
0.1835	0.0461	1185.0
0.1525	0.0680	1168.7
0.1272	0.0858	1156.1
0.0857	0.1185	1137.1
0.0337	0.1729	1124.2
0.0208	0.1982	1128.1
0.0066	0.2416	1142.0
0.0022	0.2811	1164.6
0.0007	0.3288	1197.1
0.0004	0.3523	1212.9
0.0003	0.3809	1235.6
0.0003	0.4027	1247.6
0.0004	0.4706	1304.1
0.0000	0.4678	1299.7

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 100 (Liquid)

Fixed			Measured
Mass fraction of lithium chloride (1) - Liquid	Mass fraction of Lithium sulfate (3) - Liquid	Temperature, K - Liquid	Mass density, kg/m3 - Liquid
0.0000	0.2601	288.15	1236.43
0.0317	0.2102	288.15	1206.92
0.0612	0.1651	288.15	1181.4
0.0901	0.1237	288.15	1160.8
0.1206	0.0847	288.15	1143.51
0.1488	0.0538	288.15	1133.24
0.1997	0.0227	288.15	1132.16
0.2399	0.0139	288.15	1147.02
0.3008	0.0060	288.15	1187.37
0.3438	0.0036	288.15	1213.54
0.3786	0.0030	288.15	1245.22
0.3883	0.0029	288.15	1252.81
0.4397	0.0015	288.15	1285.67
0.0000	0.2537	308.15	1226.22
0.0410	0.1879	308.15	1185.74
0.0788	0.1330	308.15	1157.56
0.1230	0.0770	308.15	1133.65
0.1516	0.0486	308.15	1125.22
0.1969	0.0184	308.15	1126.28
0.2280	0.0103	308.15	1136.64
0.2652	0.0045	308.15	1157.92
0.3085	0.0015	308.15	1184.58
0.3537	0.0008	308.15	1218.2
0.3913	0.0006	308.15	1245.41
0.4480	0.0006	308.15	1287.49
0.4651	0.0006	308.15	1303.57

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 100 (Liquid)

Fixed			Measured
Mass fraction of lithium chloride (1) - Liquid	Mass fraction of Lithium sulfate (3) - Liquid	Temperature, K - Liquid	Mass density, kg/m3 - Liquid
0.4397	0.0015	288.15	1285.67
0.4390	0.0010	288.15	1285.97
0.4394	0.0004	288.15	1289.55
0.4413	0.0000	288.15	1287.19
0.4651	0.0006	308.15	1303.57
0.4630	0.0006	308.15	1301.06
0.4652	0.0005	308.15	1301.07
0.4664	0.0000	308.15	1301.11

Mass density, kg/m3 [ref]

Operational conditions:

• Pressure, kPa = 100 (Liquid)
• Temperature, K = 308.15 (Liquid)

Fixed		Measured
Mass fraction of Lithium sulfate (3) - Liquid	Mass fraction of lithium chloride (1) - Liquid	Mass density, kg/m3 - Liquid
0.2656	0.0000	1233.8
0.2435	0.0144	1223.7
0.2321	0.0175	1212.4
0.2206	0.0232	1206.4
0.2060	0.0312	1198.6
0.1835	0.0461	1185.0
0.1525	0.0680	1168.7
0.1272	0.0858	1156.1
0.0857	0.1185	1137.1
0.0337	0.1729	1124.2
0.0208	0.1982	1128.1
0.0066	0.2416	1142.0
0.0022	0.2811	1164.6
0.0007	0.3288	1197.1
0.0004	0.3523	1212.9
0.0003	0.3809	1235.6
0.0003	0.4027	1247.6
0.0004	0.4706	1304.1
0.0000	0.4678	1299.7

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 100 (Liquid)

Fixed			Measured
Mass fraction of lithium chloride (1) - Liquid	Mass fraction of Lithium sulfate (3) - Liquid	Temperature, K - Liquid	Mass density, kg/m3 - Liquid
0.0000	0.2601	288.15	1236.43
0.0317	0.2102	288.15	1206.92
0.0612	0.1651	288.15	1181.4
0.0901	0.1237	288.15	1160.8
0.1206	0.0847	288.15	1143.51
0.1488	0.0538	288.15	1133.24
0.1997	0.0227	288.15	1132.16
0.2399	0.0139	288.15	1147.02
0.3008	0.0060	288.15	1187.37
0.3438	0.0036	288.15	1213.54
0.3786	0.0030	288.15	1245.22
0.3883	0.0029	288.15	1252.81
0.4397	0.0015	288.15	1285.67
0.0000	0.2537	308.15	1226.22
0.0410	0.1879	308.15	1185.74
0.0788	0.1330	308.15	1157.56
0.1230	0.0770	308.15	1133.65
0.1516	0.0486	308.15	1125.22
0.1969	0.0184	308.15	1126.28
0.2280	0.0103	308.15	1136.64
0.2652	0.0045	308.15	1157.92
0.3085	0.0015	308.15	1184.58
0.3537	0.0008	308.15	1218.2
0.3913	0.0006	308.15	1245.41
0.4480	0.0006	308.15	1287.49
0.4651	0.0006	308.15	1303.57

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 100 (Liquid)

Fixed			Measured
Mass fraction of lithium chloride (1) - Liquid	Mass fraction of Lithium sulfate (3) - Liquid	Temperature, K - Liquid	Mass density, kg/m3 - Liquid
0.4397	0.0015	288.15	1285.67
0.4390	0.0010	288.15	1285.97
0.4394	0.0004	288.15	1289.55
0.4413	0.0000	288.15	1287.19
0.4651	0.0006	308.15	1303.57
0.4630	0.0006	308.15	1301.06
0.4652	0.0005	308.15	1301.07
0.4664	0.0000	308.15	1301.11

Sources

• Phase equilibria in the ternary system (LiCl + Li2SO4+H2O) at T = 308.15 K and p = 0.1MPa: Experimental data and predictions using the Pitzer model
• Phase Equilibria in the Ternary System (LiCl + Li2SO4 + H2O) at T = (288.15 and 308.15) K: Experimental Determination and Model Simulation
• Measurement and Prediction of Solid + Liquid Equilibria in the Quaternary System LiCl-KCl-Li2SO4-K2SO4-H2O at 288.15 K