Mixture of Carbon dioxide + Methyl propionate

Datasets

1. Mole fraction (4)
2. P_c - Critical pressure, kPa (2)
3. P_vap - Vapor or sublimation pressure, kPa (2)
4. ρ_c - Critical density, kg/m3 (2)
5. ρ_g - Mass density, kg/m3 (2)
6. ρ_l - Mass density, kg/m3 (2)
7. T_c - Critical temperature, K (2)

Mole fraction of Carbon dioxide (1) [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Temperature, K - Liquid	Mole fraction of Carbon dioxide (1) - Liquid
283.15	0.0307
298.15	0.0214
313.15	0.0154
333.15	0.0100

Mole fraction of Carbon dioxide (1) [ref]

Fixed		Measured
Mole fraction of Carbon dioxide (1) - Liquid	Temperature, K - Gas	Mole fraction of Carbon dioxide (1) - Gas
0.3125	353.00	0.9422
0.3282	373.00	0.9213
0.3321	313.00	0.9812
0.3711	353.00	0.9502
0.3961	373.00	0.9255
0.4215	353.00	0.9486
0.4384	313.00	0.9852
0.4501	333.00	0.9870
0.4511	373.00	0.9228
0.4811	353.00	0.9456
0.5166	373.00	0.9246
0.5349	313.00	0.9819
0.5358	333.00	0.9874
0.5563	353.00	0.9460
0.5685	373.00	0.9222
0.6038	353.00	0.9420
0.6251	373.00	0.9189
0.6338	333.00	0.9887
0.6435	313.00	0.9819
0.6694	373.00	0.9123
0.6866	353.00	0.9352
0.7097	373.00	0.9011
0.7185	333.00	0.9774
0.7392	353.00	0.9023
0.7523	373.00	0.8845
0.7649	313.00	0.9753
0.7867	333.00	0.9716
0.8121	373.00	0.8432
0.8125	353.00	0.8601
0.8355	313.00	0.9660
0.8443	333.00	0.9495
0.8821	333.00	0.9025
0.9058	313.00	0.9137

Mole fraction of Carbon dioxide (1) [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Temperature, K - Liquid	Mole fraction of Carbon dioxide (1) - Liquid
283.15	0.0307
298.15	0.0214
313.15	0.0154
333.15	0.0100

Mole fraction of Carbon dioxide (1) [ref]

Fixed		Measured
Mole fraction of Carbon dioxide (1) - Liquid	Temperature, K - Gas	Mole fraction of Carbon dioxide (1) - Gas
0.3125	353.00	0.9422
0.3282	373.00	0.9213
0.3321	313.00	0.9812
0.3711	353.00	0.9502
0.3961	373.00	0.9255
0.4215	353.00	0.9486
0.4384	313.00	0.9852
0.4501	333.00	0.9870
0.4511	373.00	0.9228
0.4811	353.00	0.9456
0.5166	373.00	0.9246
0.5349	313.00	0.9819
0.5358	333.00	0.9874
0.5563	353.00	0.9460
0.5685	373.00	0.9222
0.6038	353.00	0.9420
0.6251	373.00	0.9189
0.6338	333.00	0.9887
0.6435	313.00	0.9819
0.6694	373.00	0.9123
0.6866	353.00	0.9352
0.7097	373.00	0.9011
0.7185	333.00	0.9774
0.7392	353.00	0.9023
0.7523	373.00	0.8845
0.7649	313.00	0.9753
0.7867	333.00	0.9716
0.8121	373.00	0.8432
0.8125	353.00	0.8601
0.8355	313.00	0.9660
0.8443	333.00	0.9495
0.8821	333.00	0.9025
0.9058	313.00	0.9137

Critical pressure, kPa [ref]

Mole fraction of Carbon dioxide (1) - Liquid	Critical pressure, kPa - Liquid
0.8275	12280.00
0.8377	10340.00
0.8921	9170.00
0.9103	7440.00

Critical pressure, kPa [ref]

Mole fraction of Carbon dioxide (1) - Liquid	Critical pressure, kPa - Liquid
0.8275	12280.00
0.8377	10340.00
0.8921	9170.00
0.9103	7440.00

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Mole fraction of Carbon dioxide (1) - Liquid	Temperature, K - Liquid	Vapor or sublimation pressure, kPa - Liquid
0.3125	353.00	2000.00
0.3282	373.00	3000.00
0.3321	313.00	1000.00
0.3711	353.00	3000.00
0.3961	373.00	4000.00
0.4215	353.00	4000.00
0.4384	313.00	2000.00
0.4501	333.00	3000.00
0.4511	373.00	5000.00
0.4811	353.00	5000.00
0.5166	373.00	6000.00
0.5349	313.00	3000.00
0.5358	333.00	4000.00
0.5563	353.00	6000.00
0.5685	373.00	7000.00
0.6038	353.00	7000.00
0.6251	373.00	8000.00
0.6338	333.00	5000.00
0.6435	313.00	4000.00
0.6694	373.00	9000.00
0.6866	353.00	8000.00
0.7097	373.00	10000.00
0.7185	333.00	6000.00
0.7392	353.00	9000.00
0.7523	373.00	11000.00
0.7649	313.00	5000.00
0.7867	333.00	7000.00
0.8121	373.00	12000.00
0.8125	353.00	10000.00
0.8355	313.00	6000.00
0.8443	333.00	8000.00
0.8821	333.00	9000.00
0.9058	313.00	7000.00

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Mole fraction of Carbon dioxide (1) - Liquid	Temperature, K - Liquid	Vapor or sublimation pressure, kPa - Liquid
0.3125	353.00	2000.00
0.3282	373.00	3000.00
0.3321	313.00	1000.00
0.3711	353.00	3000.00
0.3961	373.00	4000.00
0.4215	353.00	4000.00
0.4384	313.00	2000.00
0.4501	333.00	3000.00
0.4511	373.00	5000.00
0.4811	353.00	5000.00
0.5166	373.00	6000.00
0.5349	313.00	3000.00
0.5358	333.00	4000.00
0.5563	353.00	6000.00
0.5685	373.00	7000.00
0.6038	353.00	7000.00
0.6251	373.00	8000.00
0.6338	333.00	5000.00
0.6435	313.00	4000.00
0.6694	373.00	9000.00
0.6866	353.00	8000.00
0.7097	373.00	10000.00
0.7185	333.00	6000.00
0.7392	353.00	9000.00
0.7523	373.00	11000.00
0.7649	313.00	5000.00
0.7867	333.00	7000.00
0.8121	373.00	12000.00
0.8125	353.00	10000.00
0.8355	313.00	6000.00
0.8443	333.00	8000.00
0.8821	333.00	9000.00
0.9058	313.00	7000.00

Critical density, kg/m3 [ref]

Mole fraction of Carbon dioxide (1) - Liquid	Critical density, kg/m3 - Liquid
0.8275	574.2
0.8377	627.7
0.8921	670.7
0.9103	686.6

Critical density, kg/m3 [ref]

Mole fraction of Carbon dioxide (1) - Liquid	Critical density, kg/m3 - Liquid
0.8275	574.2
0.8377	627.7
0.8921	670.7
0.9103	686.6

Mass density, kg/m3 [ref]

Fixed		Measured
Temperature, K - Gas	Pressure, kPa - Gas	Mass density, kg/m3 - Gas
313.00	1000.00	24.5
313.00	2000.00	43.8
313.00	3000.00	72.6
313.00	4000.00	124.1
313.00	5000.00	180.1
313.00	6000.00	310.3
313.00	7000.00	546.3
333.00	3000.00	52.8
333.00	4000.00	82.2
333.00	5000.00	100.0
333.00	6000.00	154.1
333.00	7000.00	185.6
333.00	8000.00	243.6
333.00	9000.00	420.0
353.00	2000.00	41.2
353.00	3000.00	48.4
353.00	4000.00	68.9
353.00	5000.00	98.8
353.00	6000.00	116.5
353.00	7000.00	143.2
353.00	8000.00	196.5
353.00	9000.00	280.0
353.00	10000.00	389.4
373.00	3000.00	44.4
373.00	4000.00	61.6
373.00	5000.00	81.7
373.00	6000.00	98.3
373.00	7000.00	122.4
373.00	8000.00	148.4
373.00	9000.00	212.6
373.00	10000.00	283.3
373.00	11000.00	371.6
373.00	12000.00	451.2

Mass density, kg/m3 [ref]

Fixed		Measured
Temperature, K - Gas	Pressure, kPa - Gas	Mass density, kg/m3 - Gas
313.00	1000.00	24.5
313.00	2000.00	43.8
313.00	3000.00	72.6
313.00	4000.00	124.1
313.00	5000.00	180.1
313.00	6000.00	310.3
313.00	7000.00	546.3
333.00	3000.00	52.8
333.00	4000.00	82.2
333.00	5000.00	100.0
333.00	6000.00	154.1
333.00	7000.00	185.6
333.00	8000.00	243.6
333.00	9000.00	420.0
353.00	2000.00	41.2
353.00	3000.00	48.4
353.00	4000.00	68.9
353.00	5000.00	98.8
353.00	6000.00	116.5
353.00	7000.00	143.2
353.00	8000.00	196.5
353.00	9000.00	280.0
353.00	10000.00	389.4
373.00	3000.00	44.4
373.00	4000.00	61.6
373.00	5000.00	81.7
373.00	6000.00	98.3
373.00	7000.00	122.4
373.00	8000.00	148.4
373.00	9000.00	212.6
373.00	10000.00	283.3
373.00	11000.00	371.6
373.00	12000.00	451.2

Mass density, kg/m3 [ref]

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Carbon dioxide (1) - Liquid	Mass density, kg/m3 - Liquid
313.00	0.3321	987.0
313.00	0.4384	970.7
313.00	0.5349	946.0
313.00	0.6435	925.0
313.00	0.7649	886.9
313.00	0.8355	840.1
313.00	0.9058	767.6
333.00	0.4501	905.8
333.00	0.5358	910.2
333.00	0.6338	917.2
333.00	0.7185	916.2
333.00	0.7867	911.2
333.00	0.8443	870.0
333.00	0.8821	843.2
353.00	0.3125	870.2
353.00	0.3711	865.6
353.00	0.4215	866.4
353.00	0.4811	869.5
353.00	0.5563	857.9
353.00	0.6038	854.3
353.00	0.6866	851.0
353.00	0.7392	824.3
353.00	0.8125	791.0
373.00	0.3282	825.0
373.00	0.3961	821.4
373.00	0.4511	812.1
373.00	0.5166	798.2
373.00	0.5685	782.8
373.00	0.6251	763.7
373.00	0.6694	744.7
373.00	0.7097	722.6
373.00	0.7523	698.5
373.00	0.8121	675.0

Mass density, kg/m3 [ref]

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Carbon dioxide (1) - Liquid	Mass density, kg/m3 - Liquid
313.00	0.3321	987.0
313.00	0.4384	970.7
313.00	0.5349	946.0
313.00	0.6435	925.0
313.00	0.7649	886.9
313.00	0.8355	840.1
313.00	0.9058	767.6
333.00	0.4501	905.8
333.00	0.5358	910.2
333.00	0.6338	917.2
333.00	0.7185	916.2
333.00	0.7867	911.2
333.00	0.8443	870.0
333.00	0.8821	843.2
353.00	0.3125	870.2
353.00	0.3711	865.6
353.00	0.4215	866.4
353.00	0.4811	869.5
353.00	0.5563	857.9
353.00	0.6038	854.3
353.00	0.6866	851.0
353.00	0.7392	824.3
353.00	0.8125	791.0
373.00	0.3282	825.0
373.00	0.3961	821.4
373.00	0.4511	812.1
373.00	0.5166	798.2
373.00	0.5685	782.8
373.00	0.6251	763.7
373.00	0.6694	744.7
373.00	0.7097	722.6
373.00	0.7523	698.5
373.00	0.8121	675.0

Critical temperature, K [ref]

Mole fraction of Carbon dioxide (1) - Liquid	Critical temperature, K - Liquid
0.8275	373.20
0.8377	353.20
0.8921	332.20
0.9103	313.20

Critical temperature, K [ref]

Mole fraction of Carbon dioxide (1) - Liquid	Critical temperature, K - Liquid
0.8275	373.20
0.8377	353.20
0.8921	332.20
0.9103	313.20

Sources

• Experimental determination and calculation of the critical curves for the binary systems of CO2 containing ketone, alkane, ester and alcohol, respectively
• Low pressure carbon dioxide solubility in pure electrolyte solvents for lithium-ion batteries as a function of temperature. Measurement and prediction
• Vapor-Liquid Equilibrium Data of (Carbon Dioxide + Methyl Propionate) and (Carbon Dioxide + Propyl Propionate) at Pressures from (1.00 to 12.00) MPa and Temperatures from (313.0 to 373.0) K