Mixture of Hexane, tetradecafluoro- + Butane, 1-ethoxy-

Datasets

1. Mole fraction (4)
2. Excess molar enthalpy (molar enthalpy (2)
3. Liquid-liquid equilibrium temperature, K (2)
4. Azeotropic pressure, kPa (2)

Mole fraction of Hexane, tetradecafluoro- (1) [ref]

Operational condition: Temperature, K = 323.15 (Liquid)

Mole fraction of Hexane, tetradecafluoro- (1) - Liquid	Mole fraction of Hexane, tetradecafluoro- (1) - Gas
0.1150	0.7044
0.2161	0.7417
0.3344	0.7505
0.4655	0.7531
0.5470	0.7556
0.6510	0.7629
0.7549	0.7795
0.8232	0.8011
0.9575	0.9132

Azeotropic composition: mole fraction of Hexane, tetradecafluoro- (1) [ref]

Temperature, K - Liquid	Azeotropic composition: mole fraction of Hexane, tetradecafluoro- (1) - Liquid
323.15	0.7890

Mole fraction of Hexane, tetradecafluoro- (1) [ref]

Operational condition: Temperature, K = 323.15 (Liquid)

Mole fraction of Hexane, tetradecafluoro- (1) - Liquid	Mole fraction of Hexane, tetradecafluoro- (1) - Gas
0.1150	0.7044
0.2161	0.7417
0.3344	0.7505
0.4655	0.7531
0.5470	0.7556
0.6510	0.7629
0.7549	0.7795
0.8232	0.8011
0.9575	0.9132

Azeotropic composition: mole fraction of Hexane, tetradecafluoro- (1) [ref]

Temperature, K - Liquid	Azeotropic composition: mole fraction of Hexane, tetradecafluoro- (1) - Liquid
323.15	0.7890

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational condition: Temperature, K = 298.15 (Liquid)

Mole fraction of Hexane, tetradecafluoro- (1) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.0000	0.0000
0.0500	0.6110
0.1000	1.083
0.1500	1.444
0.2000	1.716
0.2500	1.919
0.3000	2.068
0.3500	2.173
0.4000	2.243
0.4500	2.284
0.5000	2.298
0.5500	2.284
0.6000	2.24
0.6500	2.162
0.7000	2.045
0.7500	1.879
0.8000	1.657
0.8500	1.369
0.9000	1.004
0.9500	0.5510
1.0000	0.0000

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational condition: Temperature, K = 298.15 (Liquid)

Mole fraction of Hexane, tetradecafluoro- (1) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.0000	0.0000
0.0500	0.6110
0.1000	1.083
0.1500	1.444
0.2000	1.716
0.2500	1.919
0.3000	2.068
0.3500	2.173
0.4000	2.243
0.4500	2.284
0.5000	2.298
0.5500	2.284
0.6000	2.24
0.6500	2.162
0.7000	2.045
0.7500	1.879
0.8000	1.657
0.8500	1.369
0.9000	1.004
0.9500	0.5510
1.0000	0.0000

Liquid-liquid equilibrium temperature, K [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Mole fraction of Hexane, tetradecafluoro- (1) - Liquid mixture 1	Liquid-liquid equilibrium temperature, K - Liquid mixture 1
0.1010	306.20
0.1740	317.50
0.2490	321.60
0.3560	322.20
0.4150	322.20
0.4530	322.00
0.4570	322.10
0.5040	321.40
0.5430	320.90
0.6170	318.80
0.7170	312.80
0.7810	306.90
0.8230	300.70

Liquid-liquid equilibrium temperature, K [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Mole fraction of Hexane, tetradecafluoro- (1) - Liquid mixture 1	Liquid-liquid equilibrium temperature, K - Liquid mixture 1
0.1010	306.20
0.1740	317.50
0.2490	321.60
0.3560	322.20
0.4150	322.20
0.4530	322.00
0.4570	322.10
0.5040	321.40
0.5430	320.90
0.6170	318.80
0.7170	312.80
0.7810	306.90
0.8230	300.70

Azeotropic pressure, kPa [ref]

Temperature, K - Liquid	Azeotropic pressure, kPa - Liquid
323.15	0.79

Azeotropic pressure, kPa [ref]

Temperature, K - Liquid	Azeotropic pressure, kPa - Liquid
323.15	0.79

Sources

• Thermodynamic study of perfluorohexane + ether mixtures VLE, LLE, and HE