Mixture of Pentanoic acid, ethyl ester + Carbon dioxide

Datasets

1. P_c - Critical pressure, kPa (2)
2. P_vap - Vapor or sublimation pressure, kPa (2)
3. T_c - Critical temperature, K (2)
4. Vapor or sublimation pressure, kPa (2)

Critical pressure, kPa [ref]

Mole fraction of Carbon dioxide (2) - Liquid	Critical pressure, kPa - Liquid
0.0000	2730.40
0.1489	4325.60
0.3071	6121.20
0.4418	7760.30
0.6015	9572.00
0.7502	11638.50
0.8082	13351.20
0.8476	14359.00
0.8729	15868.20
0.9100	16089.60
0.9336	14941.50
0.9523	13028.30
1.0000	7379.80

Critical pressure, kPa [ref]

Mole fraction of Carbon dioxide (2) - Liquid	Critical pressure, kPa - Liquid
0.0000	2730.40
0.1489	4325.60
0.3071	6121.20
0.4418	7760.30
0.6015	9572.00
0.7502	11638.50
0.8082	13351.20
0.8476	14359.00
0.8729	15868.20
0.9100	16089.60
0.9336	14941.50
0.9523	13028.30
1.0000	7379.80

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Carbon dioxide (2) - Liquid	Vapor or sublimation pressure, kPa - Liquid
303.15	0.3801	2510.00
303.15	0.5634	3640.00
303.15	0.7506	5150.00
303.15	0.7920	5320.00
303.15	0.8345	5510.00
303.15	0.8416	5560.00
303.15	0.8526	5640.00
303.15	0.9176	6180.00
303.15	0.9517	6320.00
303.15	0.9811	6670.00
313.15	0.3801	2810.00
313.15	0.5634	4250.00
313.15	0.7506	6040.00
313.15	0.7920	6480.00
313.15	0.8345	6700.00
313.15	0.8416	6710.00
313.15	0.8526	6840.00
313.15	0.9176	7550.00
313.15	0.9517	7640.00
313.15	0.9811	8220.00
323.15	0.3801	3190.00
323.15	0.5634	4970.00
323.15	0.7506	7220.00
323.15	0.7920	7560.00
323.15	0.8345	8030.00
323.15	0.8416	8040.00
323.15	0.8526	8130.00
323.15	0.9176	9000.00
323.15	0.9517	9080.00
333.15	0.3801	3640.00
333.15	0.5634	5610.00
333.15	0.7506	8300.00
333.15	0.7920	8730.00
333.15	0.8345	9260.00
333.15	0.8416	9400.00
333.15	0.8526	9470.00
333.15	0.9176	10310.00
333.15	0.9517	10390.00
343.15	0.3801	4010.00
343.15	0.5634	6320.00
343.15	0.7506	9400.00
343.15	0.7920	9880.00
343.15	0.8345	10580.00
343.15	0.8416	10690.00
343.15	0.8526	10800.00
343.15	0.9176	11610.00
353.15	0.3801	4460.00
353.15	0.5634	7010.00
353.15	0.7506	10480.00
353.15	0.7920	11140.00
353.15	0.8345	11770.00
353.15	0.8416	11950.00
353.15	0.8526	11960.00
353.15	0.9176	12680.00

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Carbon dioxide (2) - Liquid	Vapor or sublimation pressure, kPa - Liquid
303.15	0.3801	2510.00
303.15	0.5634	3640.00
303.15	0.7506	5150.00
303.15	0.7920	5320.00
303.15	0.8345	5510.00
303.15	0.8416	5560.00
303.15	0.8526	5640.00
303.15	0.9176	6180.00
303.15	0.9517	6320.00
303.15	0.9811	6670.00
313.15	0.3801	2810.00
313.15	0.5634	4250.00
313.15	0.7506	6040.00
313.15	0.7920	6480.00
313.15	0.8345	6700.00
313.15	0.8416	6710.00
313.15	0.8526	6840.00
313.15	0.9176	7550.00
313.15	0.9517	7640.00
313.15	0.9811	8220.00
323.15	0.3801	3190.00
323.15	0.5634	4970.00
323.15	0.7506	7220.00
323.15	0.7920	7560.00
323.15	0.8345	8030.00
323.15	0.8416	8040.00
323.15	0.8526	8130.00
323.15	0.9176	9000.00
323.15	0.9517	9080.00
333.15	0.3801	3640.00
333.15	0.5634	5610.00
333.15	0.7506	8300.00
333.15	0.7920	8730.00
333.15	0.8345	9260.00
333.15	0.8416	9400.00
333.15	0.8526	9470.00
333.15	0.9176	10310.00
333.15	0.9517	10390.00
343.15	0.3801	4010.00
343.15	0.5634	6320.00
343.15	0.7506	9400.00
343.15	0.7920	9880.00
343.15	0.8345	10580.00
343.15	0.8416	10690.00
343.15	0.8526	10800.00
343.15	0.9176	11610.00
353.15	0.3801	4460.00
353.15	0.5634	7010.00
353.15	0.7506	10480.00
353.15	0.7920	11140.00
353.15	0.8345	11770.00
353.15	0.8416	11950.00
353.15	0.8526	11960.00
353.15	0.9176	12680.00

Critical temperature, K [ref]

Mole fraction of Carbon dioxide (2) - Liquid	Critical temperature, K - Liquid
0.0000	594.02
0.1489	581.75
0.3071	569.48
0.4418	554.91
0.6015	539.64
0.7502	520.89
0.8082	501.41
0.8476	485.89
0.8729	452.88
0.9100	423.30
0.9336	387.94
0.9523	356.95
1.0000	304.30

Critical temperature, K [ref]

Mole fraction of Carbon dioxide (2) - Liquid	Critical temperature, K - Liquid
0.0000	594.02
0.1489	581.75
0.3071	569.48
0.4418	554.91
0.6015	539.64
0.7502	520.89
0.8082	501.41
0.8476	485.89
0.8729	452.88
0.9100	423.30
0.9336	387.94
0.9523	356.95
1.0000	304.30

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Temperature, K - Gas	Mole fraction of Carbon dioxide (2) - Gas	Vapor or sublimation pressure, kPa - Gas
323.15	0.9811	9340.00
333.15	0.9811	10440.00
343.15	0.9517	11630.00
353.15	0.9517	12540.00

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Temperature, K - Gas	Mole fraction of Carbon dioxide (2) - Gas	Vapor or sublimation pressure, kPa - Gas
323.15	0.9811	9340.00
333.15	0.9811	10440.00
343.15	0.9517	11630.00
353.15	0.9517	12540.00

Sources

• Phase equilibrium measurements and thermodynamic modelling for the systems involving valeric acid, ethanol, ethyl valerate and water plus CO2
• Development of a Predictive Equation of State for CO2 + Ethyl Ester Mixtures Based on Critical Points Measurements