Mixture of 1-Propanol + Ethyl Acetate

Datasets

1. Mole fraction (4)
2. Excess molar enthalpy (molar enthalpy (2)
3. P_vap - Vapor or sublimation pressure, kPa (2)
4. ρ_l - Mass density, kg/m3 (2)
5. T_boil - Boiling temperature at pressure P, K (2)

Mole fraction of Ethyl Acetate (2) [ref]

Fixed		Measured
Mole fraction of Ethyl Acetate (2) - Liquid	Temperature, K - Liquid	Mole fraction of Ethyl Acetate (2) - Gas
0.0000	323.15	0.0000
0.0000	348.15	0.0000
0.0407	323.15	0.2270
0.0540	348.15	0.1900
0.0697	323.15	0.3331
0.0832	348.15	0.2732
0.1119	323.15	0.4333
0.1241	348.15	0.3542
0.1723	323.15	0.5261
0.1908	348.15	0.4459
0.2385	323.15	0.5956
0.2519	348.15	0.5151
0.3453	348.15	0.5862
0.4244	323.15	0.7195
0.4416	348.15	0.6534
0.5355	323.15	0.7693
0.5496	348.15	0.7176
0.6526	323.15	0.8160
0.6613	348.15	0.7758
0.7552	323.15	0.8595
0.7628	348.15	0.8347
0.8448	323.15	0.9018
0.8494	348.15	0.8861
0.9313	323.15	0.9518
0.9328	348.15	0.9461
0.9769	323.15	0.9826
0.9773	348.15	0.9810
1.0000	323.15	1.0000
1.0000	348.15	1.0000

Mole fraction of Ethyl Acetate (2) [ref]

Operational condition: Pressure, kPa = 600 (Liquid)

Mole fraction of Ethyl Acetate (2) - Liquid	Mole fraction of Ethyl Acetate (2) - Gas
0.0000	0.0000
0.0040	0.0080
0.0060	0.0140
0.0270	0.0450
0.0480	0.0790
0.0560	0.0940
0.0810	0.1210
0.1020	0.1560
0.1250	0.1820
0.1290	0.1910
0.1570	0.2250
0.1780	0.2470
0.1940	0.2660
0.2240	0.3010
0.2600	0.3410
0.2930	0.3770
0.3050	0.3890
0.3220	0.4070
0.3450	0.4280
0.3920	0.4710
0.4930	0.5470
0.5420	0.5880
0.6050	0.6430
0.6280	0.6550
0.6990	0.7120
0.7160	0.7230
0.7500	0.7490
0.7770	0.7680
0.8510	0.8290
0.8710	0.8460
0.9290	0.9030
0.9600	0.9390
0.9790	0.9680
0.9980	0.9920
0.9990	0.9940
1.0000	1.0000

Mole fraction of Ethyl Acetate (2) [ref]

Fixed		Measured
Mole fraction of Ethyl Acetate (2) - Liquid	Temperature, K - Liquid	Mole fraction of Ethyl Acetate (2) - Gas
0.0000	323.15	0.0000
0.0000	348.15	0.0000
0.0407	323.15	0.2270
0.0540	348.15	0.1900
0.0697	323.15	0.3331
0.0832	348.15	0.2732
0.1119	323.15	0.4333
0.1241	348.15	0.3542
0.1723	323.15	0.5261
0.1908	348.15	0.4459
0.2385	323.15	0.5956
0.2519	348.15	0.5151
0.3453	348.15	0.5862
0.4244	323.15	0.7195
0.4416	348.15	0.6534
0.5355	323.15	0.7693
0.5496	348.15	0.7176
0.6526	323.15	0.8160
0.6613	348.15	0.7758
0.7552	323.15	0.8595
0.7628	348.15	0.8347
0.8448	323.15	0.9018
0.8494	348.15	0.8861
0.9313	323.15	0.9518
0.9328	348.15	0.9461
0.9769	323.15	0.9826
0.9773	348.15	0.9810
1.0000	323.15	1.0000
1.0000	348.15	1.0000

Mole fraction of Ethyl Acetate (2) [ref]

Operational condition: Pressure, kPa = 600 (Liquid)

Mole fraction of Ethyl Acetate (2) - Liquid	Mole fraction of Ethyl Acetate (2) - Gas
0.0000	0.0000
0.0040	0.0080
0.0060	0.0140
0.0270	0.0450
0.0480	0.0790
0.0560	0.0940
0.0810	0.1210
0.1020	0.1560
0.1250	0.1820
0.1290	0.1910
0.1570	0.2250
0.1780	0.2470
0.1940	0.2660
0.2240	0.3010
0.2600	0.3410
0.2930	0.3770
0.3050	0.3890
0.3220	0.4070
0.3450	0.4280
0.3920	0.4710
0.4930	0.5470
0.5420	0.5880
0.6050	0.6430
0.6280	0.6550
0.6990	0.7120
0.7160	0.7230
0.7500	0.7490
0.7770	0.7680
0.8510	0.8290
0.8710	0.8460
0.9290	0.9030
0.9600	0.9390
0.9790	0.9680
0.9980	0.9920
0.9990	0.9940
1.0000	1.0000

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 10000 (Liquid)

Mole fraction of Ethyl Acetate (2) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.0390	0.2506
0.0680	0.3971
0.0980	0.5416
0.1290	0.6742
0.1600	0.7963
0.1920	0.9191
0.2250	1.0174
0.2580	1.1204
0.2910	1.2049
0.3260	1.2803
0.3610	1.365
0.3960	1.4126
0.4330	1.4592
0.4700	1.4839
0.5080	1.5112
0.5470	1.5144
0.5860	1.503
0.6270	1.4637
0.6680	1.4184
0.7100	1.3441
0.7530	1.2364
0.7970	1.1084
0.8420	0.9322
0.8880	0.7247
0.9350	0.4574
0.9510	0.3509
0.9680	0.2396

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 10000 (Liquid)

Mole fraction of Ethyl Acetate (2) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.0390	0.2506
0.0680	0.3971
0.0980	0.5416
0.1290	0.6742
0.1600	0.7963
0.1920	0.9191
0.2250	1.0174
0.2580	1.1204
0.2910	1.2049
0.3260	1.2803
0.3610	1.365
0.3960	1.4126
0.4330	1.4592
0.4700	1.4839
0.5080	1.5112
0.5470	1.5144
0.5860	1.503
0.6270	1.4637
0.6680	1.4184
0.7100	1.3441
0.7530	1.2364
0.7970	1.1084
0.8420	0.9322
0.8880	0.7247
0.9350	0.4574
0.9510	0.3509
0.9680	0.2396

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Mole fraction of Ethyl Acetate (2) - Liquid	Temperature, K - Liquid	Vapor or sublimation pressure, kPa - Liquid
0.0000	323.15	12.17
0.0000	348.15	40.95
0.0407	323.15	15.11
0.0540	348.15	48.29
0.0697	323.15	17.06
0.0832	348.15	52.02
0.1119	323.15	19.35
0.1241	348.15	56.61
0.1723	323.15	22.15
0.1908	348.15	62.11
0.2385	323.15	24.53
0.2519	348.15	66.88
0.3453	348.15	72.73
0.4244	323.15	29.53
0.4416	348.15	77.63
0.5355	323.15	31.71
0.5496	348.15	82.18
0.6526	323.15	33.58
0.6613	348.15	86.25
0.7552	323.15	35.07
0.7628	348.15	89.35
0.8448	323.15	36.24
0.8494	348.15	91.64
0.9313	323.15	37.25
0.9328	348.15	93.50
0.9769	323.15	37.73
0.9773	348.15	94.29
1.0000	323.15	37.95
1.0000	348.15	94.62

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Mole fraction of Ethyl Acetate (2) - Liquid	Temperature, K - Liquid	Vapor or sublimation pressure, kPa - Liquid
0.0000	323.15	12.17
0.0000	348.15	40.95
0.0407	323.15	15.11
0.0540	348.15	48.29
0.0697	323.15	17.06
0.0832	348.15	52.02
0.1119	323.15	19.35
0.1241	348.15	56.61
0.1723	323.15	22.15
0.1908	348.15	62.11
0.2385	323.15	24.53
0.2519	348.15	66.88
0.3453	348.15	72.73
0.4244	323.15	29.53
0.4416	348.15	77.63
0.5355	323.15	31.71
0.5496	348.15	82.18
0.6526	323.15	33.58
0.6613	348.15	86.25
0.7552	323.15	35.07
0.7628	348.15	89.35
0.8448	323.15	36.24
0.8494	348.15	91.64
0.9313	323.15	37.25
0.9328	348.15	93.50
0.9769	323.15	37.73
0.9773	348.15	94.29
1.0000	323.15	37.95
1.0000	348.15	94.62

Mass density, kg/m3 [ref]

Operational condition: Temperature, K = 298.15 (Liquid)

Mole fraction of Ethyl Acetate (2) - Liquid	Mass density, kg/m3 - Liquid
0.0000	799.6
0.0442	804.5
0.0911	809.6
0.1433	815.2
0.2010	821.3
0.2417	825.5
0.2986	831.4
0.3435	835.9
0.4654	847.6
0.5534	855.8
0.6461	864.2
0.6917	868.2
0.7647	874.5
0.8037	877.9
0.8347	880.5
0.8535	882.1
0.9053	886.4
0.9649	891.4
1.0000	894.5

Mass density, kg/m3 [ref]

Operational condition: Temperature, K = 298.15 (Liquid)

Mole fraction of Ethyl Acetate (2) - Liquid	Mass density, kg/m3 - Liquid
0.0000	799.6
0.0442	804.5
0.0911	809.6
0.1433	815.2
0.2010	821.3
0.2417	825.5
0.2986	831.4
0.3435	835.9
0.4654	847.6
0.5534	855.8
0.6461	864.2
0.6917	868.2
0.7647	874.5
0.8037	877.9
0.8347	880.5
0.8535	882.1
0.9053	886.4
0.9649	891.4
1.0000	894.5

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 600 (Liquid)

Mole fraction of Ethyl Acetate (2) - Liquid	Boiling temperature at pressure P, K - Liquid
0.0000	427.20
0.0040	426.88
0.0060	426.86
0.0270	426.43
0.0480	425.89
0.0560	425.66
0.0810	425.07
0.1020	424.68
0.1250	424.18
0.1290	424.05
0.1570	423.44
0.1780	423.16
0.1940	422.81
0.2240	422.33
0.2600	421.59
0.2930	421.08
0.3050	420.95
0.3220	420.56
0.3450	420.29
0.3920	419.75
0.4930	418.53
0.5420	417.84
0.6050	417.19
0.6280	416.93
0.6990	416.67
0.7160	416.64
0.7500	416.65
0.7770	416.69
0.8510	416.80
0.8710	416.82
0.9290	416.92
0.9600	416.94
0.9790	416.95
0.9980	416.96
0.9990	416.96
1.0000	417.02

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 600 (Liquid)

Mole fraction of Ethyl Acetate (2) - Liquid	Boiling temperature at pressure P, K - Liquid
0.0000	427.20
0.0040	426.88
0.0060	426.86
0.0270	426.43
0.0480	425.89
0.0560	425.66
0.0810	425.07
0.1020	424.68
0.1250	424.18
0.1290	424.05
0.1570	423.44
0.1780	423.16
0.1940	422.81
0.2240	422.33
0.2600	421.59
0.2930	421.08
0.3050	420.95
0.3220	420.56
0.3450	420.29
0.3920	419.75
0.4930	418.53
0.5420	417.84
0.6050	417.19
0.6280	416.93
0.6990	416.67
0.7160	416.64
0.7500	416.65
0.7770	416.69
0.8510	416.80
0.8710	416.82
0.9290	416.92
0.9600	416.94
0.9790	416.95
0.9980	416.96
0.9990	416.96
1.0000	417.02

Sources

• Vapour-liquid and chemical equilibria in the ethyl ethanoate + ethanol + propyl ethanoate + propanol system accompanied with transesterification reaction
• Molar excess enthalpies of ethyl acetate + alkanols at T=298.15K, p=10MPa
• Experimental Determination of Vapor Liquid Equilibria. Binary Systems of Methyl Acetate, Ethyl Acetate, and Propyl Acetate with 1-Propanol at 0.6 MPa