Mixture of 1-Butene + 1-Propanol

Datasets

1. Activity coefficient (2)
2. Henry's Law constant (mole fraction scale), kPa (2)
3. P_vap - Vapor or sublimation pressure, kPa (4)

Activity coefficient of 1-Butene (1) [ref]

Operational condition: Mole fraction = 0 (Liquid)

Temperature, K - Liquid	Activity coefficient of 1-Butene (1) - Liquid
260.03	4.13
280.04	4.12
299.98	4.11
320.03	4.05
340.00	4.01

Activity coefficient of 1-Butene (1) [ref]

Operational condition: Mole fraction = 0 (Liquid)

Temperature, K - Liquid	Activity coefficient of 1-Butene (1) - Liquid
260.03	4.13
280.04	4.12
299.98	4.11
320.03	4.05
340.00	4.01

Henry's Law constant (mole fraction scale), kPa of 1-Butene (1) [ref]

Operational condition: Mole fraction = 0 (Liquid)

Temperature, K - Liquid	Henry's Law constant (mole fraction scale), kPa of 1-Butene (1) - Liquid
260.03	308.0
280.04	641.0
299.98	1177.0
320.03	1938.0
340.00	2951.0

Henry's Law constant (mole fraction scale), kPa of 1-Butene (1) [ref]

Operational condition: Mole fraction = 0 (Liquid)

Temperature, K - Liquid	Henry's Law constant (mole fraction scale), kPa of 1-Butene (1) - Liquid
260.03	308.0
280.04	641.0
299.98	1177.0
320.03	1938.0
340.00	2951.0

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Temperature, K - Liquid	Mole fraction of 1-Butene (1) - Liquid	Vapor or sublimation pressure, kPa - Liquid
323.26	0.0000	12.27
323.26	0.0130	38.87
323.26	0.0321	75.67
323.26	0.9680	584.44
323.27	0.0503	108.77
323.27	0.0978	185.66
323.27	0.1457	251.46
323.27	0.1948	307.66
323.27	0.2430	353.36
323.27	0.2934	392.85
323.27	0.3956	451.65
323.27	0.4463	472.85
323.27	0.6973	535.55
323.27	0.7473	544.24
323.27	0.7974	552.54
323.27	0.8475	560.84
323.27	0.8975	569.44
323.27	0.9474	579.24
323.27	0.9879	591.04
323.27	1.0000	596.14
323.28	0.3443	425.15
323.28	0.4974	490.35
323.28	0.5002	491.05
323.28	0.5492	504.65
323.28	0.5987	516.35
323.28	0.6481	526.55

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Mole fraction of 1-Butene (1) - Gas	Temperature, K - Liquid	Vapor or sublimation pressure, kPa - Liquid
0.0000	364.52	81.30
0.4018	364.52	135.60
0.5936	364.52	200.80
0.6981	364.51	270.90
0.8061	364.51	422.90
0.8550	364.52	565.10
0.8817	364.52	689.80
0.8984	364.53	797.70
0.9100	364.52	892.20
0.9183	364.52	972.10
0.9246	364.52	1039.90
0.9298	364.52	1098.60
0.9340	364.52	1146.40
0.9341	364.52	1148.80
0.9375	364.52	1187.10
0.9407	364.52	1223.30
0.9438	364.53	1257.30
0.9470	364.52	1288.80
0.9503	364.51	1319.00
0.9542	364.51	1349.40
0.9591	364.51	1380.90
0.9662	364.51	1415.10
0.9775	364.51	1455.90
0.9854	364.51	1478.40
0.9884	364.51	1485.70
0.9945	364.51	1499.40
1.0000	364.51	1510.70

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Temperature, K - Liquid	Mole fraction of 1-Butene (1) - Liquid	Vapor or sublimation pressure, kPa - Liquid
323.26	0.0000	12.27
323.26	0.0130	38.87
323.26	0.0321	75.67
323.26	0.9680	584.44
323.27	0.0503	108.77
323.27	0.0978	185.66
323.27	0.1457	251.46
323.27	0.1948	307.66
323.27	0.2430	353.36
323.27	0.2934	392.85
323.27	0.3956	451.65
323.27	0.4463	472.85
323.27	0.6973	535.55
323.27	0.7473	544.24
323.27	0.7974	552.54
323.27	0.8475	560.84
323.27	0.8975	569.44
323.27	0.9474	579.24
323.27	0.9879	591.04
323.27	1.0000	596.14
323.28	0.3443	425.15
323.28	0.4974	490.35
323.28	0.5002	491.05
323.28	0.5492	504.65
323.28	0.5987	516.35
323.28	0.6481	526.55

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Mole fraction of 1-Butene (1) - Gas	Temperature, K - Liquid	Vapor or sublimation pressure, kPa - Liquid
0.0000	364.52	81.30
0.4018	364.52	135.60
0.5936	364.52	200.80
0.6981	364.51	270.90
0.8061	364.51	422.90
0.8550	364.52	565.10
0.8817	364.52	689.80
0.8984	364.53	797.70
0.9100	364.52	892.20
0.9183	364.52	972.10
0.9246	364.52	1039.90
0.9298	364.52	1098.60
0.9340	364.52	1146.40
0.9341	364.52	1148.80
0.9375	364.52	1187.10
0.9407	364.52	1223.30
0.9438	364.53	1257.30
0.9470	364.52	1288.80
0.9503	364.51	1319.00
0.9542	364.51	1349.40
0.9591	364.51	1380.90
0.9662	364.51	1415.10
0.9775	364.51	1455.90
0.9854	364.51	1478.40
0.9884	364.51	1485.70
0.9945	364.51	1499.40
1.0000	364.51	1510.70

Sources

• Henry's constants and infinite dilution activity coefficients of propane, propene, butane, isobutene, 1-butene, isobutane, trans-2-butene and 1,3-butadiene in 1-propanol at T=(260 to 340) K
• Vapor-Liquid Equilibrium for 1-Propanol + 1-Butene, + cis-2-Butene, + 2-Methyl-propene, + trans-2-Butene, + n-Butane, and + 2-Methyl-propane
• Vapor-Liquid Equilibrium for 1-Butene + Methanol, + 1-Propanol, + 2-Propanol, + 2-Butanol, and 2-Methyl-2-propanol (TBA) at 364.5 K