Mixture of 1-Propene, 2-methyl- + Methyl Alcohol

Datasets

1. Activity coefficient (2)
2. Henry's Law constant (mole fraction scale), kPa (6)
3. P_vap - Vapor or sublimation pressure, kPa (4)

Activity coefficient of 1-Propene, 2-methyl- (1) [ref]

Operational condition: Mole fraction = 0 (Gas)

Temperature, K - Gas	Activity coefficient of 1-Propene, 2-methyl- (1) - Gas
374.00	6.5
393.30	6.0
412.50	5.4

Activity coefficient of 1-Propene, 2-methyl- (1) [ref]

Operational condition: Mole fraction = 0 (Gas)

Temperature, K - Gas	Activity coefficient of 1-Propene, 2-methyl- (1) - Gas
374.00	6.5
393.30	6.0
412.50	5.4

Henry's Law constant (mole fraction scale), kPa of 1-Propene, 2-methyl- (1) [ref]

Operational condition: Mole fraction = 0 (Liquid)

Temperature, K - Liquid	Henry's Law constant (mole fraction scale), kPa of 1-Propene, 2-methyl- (1) - Liquid
374.00	9400.0
393.30	11600.0
412.50	13500.0
431.60	14300.0
451.00	15300.0
470.10	14600.0
489.50	16000.0
513.38	10600.0

Azeotropic composition: mole fraction of 1-Propene, 2-methyl- (1) [ref]

Temperature, K - Liquid	Azeotropic composition: mole fraction of 1-Propene, 2-methyl- (1) - Liquid
323.14	0.9410

Azeotropic composition: mole fraction of 1-Propene, 2-methyl- (1) [ref]

Pressure, kPa - Liquid	Azeotropic composition: mole fraction of 1-Propene, 2-methyl- (1) - Liquid
623.10	0.9410

Henry's Law constant (mole fraction scale), kPa of 1-Propene, 2-methyl- (1) [ref]

Operational condition: Mole fraction = 0 (Liquid)

Temperature, K - Liquid	Henry's Law constant (mole fraction scale), kPa of 1-Propene, 2-methyl- (1) - Liquid
374.00	9400.0
393.30	11600.0
412.50	13500.0
431.60	14300.0
451.00	15300.0
470.10	14600.0
489.50	16000.0
513.38	10600.0

Azeotropic composition: mole fraction of 1-Propene, 2-methyl- (1) [ref]

Temperature, K - Liquid	Azeotropic composition: mole fraction of 1-Propene, 2-methyl- (1) - Liquid
323.14	0.9410

Azeotropic composition: mole fraction of 1-Propene, 2-methyl- (1) [ref]

Pressure, kPa - Liquid	Azeotropic composition: mole fraction of 1-Propene, 2-methyl- (1) - Liquid
623.10	0.9410

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Temperature, K - Liquid	Mole fraction of 1-Propene, 2-methyl- (1) - Liquid	Vapor or sublimation pressure, kPa - Liquid
323.13	0.0309	180.06
323.13	0.4024	581.74
323.13	0.4515	590.04
323.13	0.5008	596.34
323.13	0.5501	601.34
323.13	0.5995	605.34
323.13	0.7485	615.04
323.13	0.7975	618.04
323.14	0.0000	55.57
323.14	0.0503	242.86
323.14	0.4005	581.94
323.14	0.6488	608.84
323.14	0.6982	612.04
323.14	0.8473	621.04
323.14	0.8967	623.94
323.14	0.9468	625.94
323.14	1.0000	608.84
323.15	0.0971	357.26
323.15	0.1452	435.95
323.15	0.2469	527.85
323.15	0.2981	552.64
323.15	0.3493	569.84
323.15	0.9853	619.44
323.16	0.1956	490.75

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Temperature, K - Liquid	Mole fraction of 1-Propene, 2-methyl- (1) - Liquid	Vapor or sublimation pressure, kPa - Liquid
364.47	0.0000	267.00
364.47	0.0160	408.00
364.49	0.0304	522.50
364.49	0.9501	1615.10
364.49	0.9704	1595.80
364.49	0.9889	1567.10
364.49	1.0000	1546.00
364.50	0.0454	628.60
364.50	0.4419	1505.10
364.50	0.5474	1549.20
364.50	0.6962	1591.40
364.50	0.7463	1603.50
364.50	0.8471	1624.30
364.50	0.8969	1628.90
364.50	0.9771	1587.50
364.51	0.0860	865.10
364.51	0.1316	1056.20
364.51	0.1786	1196.70
364.51	0.2280	1301.20
364.51	0.2806	1378.80
364.51	0.4953	1528.50
364.51	0.4980	1531.90
364.51	0.5961	1564.70
364.51	0.6457	1578.40
364.51	0.7970	1615.10
364.52	0.3340	1435.00
364.52	0.3882	1475.60

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Temperature, K - Liquid	Mole fraction of 1-Propene, 2-methyl- (1) - Liquid	Vapor or sublimation pressure, kPa - Liquid
323.13	0.0309	180.06
323.13	0.4024	581.74
323.13	0.4515	590.04
323.13	0.5008	596.34
323.13	0.5501	601.34
323.13	0.5995	605.34
323.13	0.7485	615.04
323.13	0.7975	618.04
323.14	0.0000	55.57
323.14	0.0503	242.86
323.14	0.4005	581.94
323.14	0.6488	608.84
323.14	0.6982	612.04
323.14	0.8473	621.04
323.14	0.8967	623.94
323.14	0.9468	625.94
323.14	1.0000	608.84
323.15	0.0971	357.26
323.15	0.1452	435.95
323.15	0.2469	527.85
323.15	0.2981	552.64
323.15	0.3493	569.84
323.15	0.9853	619.44
323.16	0.1956	490.75

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Temperature, K - Liquid	Mole fraction of 1-Propene, 2-methyl- (1) - Liquid	Vapor or sublimation pressure, kPa - Liquid
364.47	0.0000	267.00
364.47	0.0160	408.00
364.49	0.0304	522.50
364.49	0.9501	1615.10
364.49	0.9704	1595.80
364.49	0.9889	1567.10
364.49	1.0000	1546.00
364.50	0.0454	628.60
364.50	0.4419	1505.10
364.50	0.5474	1549.20
364.50	0.6962	1591.40
364.50	0.7463	1603.50
364.50	0.8471	1624.30
364.50	0.8969	1628.90
364.50	0.9771	1587.50
364.51	0.0860	865.10
364.51	0.1316	1056.20
364.51	0.1786	1196.70
364.51	0.2280	1301.20
364.51	0.2806	1378.80
364.51	0.4953	1528.50
364.51	0.4980	1531.90
364.51	0.5961	1564.70
364.51	0.6457	1578.40
364.51	0.7970	1615.10
364.52	0.3340	1435.00
364.52	0.3882	1475.60

Sources

• Henry s law constants of 1-butene, 2-methylpropene, trans-2-butene, and 1,3-butadiene in methanol at 374 490K
• Isothermal Vapor Liquid Equilibrium for Binary 2-Methylpropene - C1-C4 Alcohol-Systems
• Isothermal Vapor Liquid Equilibrium for 2-Methylpropene + Methanol, + 1-Propanol, + 2-Propanol, + 2-Butanol, and + 2-Methyl-2-propanol Binary Systems at 364.5 K