Datasets
-
Mole fraction (2)
-
Excess molar enthalpy (molar enthalpy (2)
-
ρl - Mass density, kg/m3 (2)
-
Tboil - Boiling temperature at pressure P, K (4)
Mole fraction of 1-Butanol (2)
[ref]
Operational condition: Temperature, K =
333.15 (Gas)
Mole fraction of 1-Butanol (2) - Liquid |
Mole fraction of 1-Butanol (2) - Gas |
0.0169 |
0.1935 |
0.0340 |
0.3319 |
0.0500 |
0.3795 |
0.0980 |
0.5688 |
0.1505 |
0.6168 |
0.2007 |
0.6624 |
0.2511 |
0.6984 |
0.3012 |
0.7373 |
0.3513 |
0.7745 |
0.4015 |
0.7739 |
0.4514 |
0.7976 |
0.5014 |
0.8089 |
0.5515 |
0.8270 |
0.6015 |
0.8418 |
0.6514 |
0.8543 |
0.7014 |
0.8659 |
0.7512 |
0.8833 |
0.8012 |
0.8983 |
0.8509 |
0.9228 |
0.9006 |
0.9397 |
0.9505 |
0.9677 |
0.9663 |
0.9793 |
0.9830 |
0.9894 |
Mole fraction of 1-Butanol (2)
[ref]
Operational condition: Temperature, K =
333.15 (Gas)
Mole fraction of 1-Butanol (2) - Liquid |
Mole fraction of 1-Butanol (2) - Gas |
0.0169 |
0.1935 |
0.0340 |
0.3319 |
0.0500 |
0.3795 |
0.0980 |
0.5688 |
0.1505 |
0.6168 |
0.2007 |
0.6624 |
0.2511 |
0.6984 |
0.3012 |
0.7373 |
0.3513 |
0.7745 |
0.4015 |
0.7739 |
0.4514 |
0.7976 |
0.5014 |
0.8089 |
0.5515 |
0.8270 |
0.6015 |
0.8418 |
0.6514 |
0.8543 |
0.7014 |
0.8659 |
0.7512 |
0.8833 |
0.8012 |
0.8983 |
0.8509 |
0.9228 |
0.9006 |
0.9397 |
0.9505 |
0.9677 |
0.9663 |
0.9793 |
0.9830 |
0.9894 |
Excess molar enthalpy (molar enthalpy of mixing), kJ/mol
[ref]
Fixed |
Measured |
Temperature, K - Liquid |
Pressure, kPa - Liquid |
Mole fraction of Carbonic acid, dimethyl ester (1) - Liquid |
Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid |
298.15 |
1000.00 |
0.0500 |
0.5333 |
298.15 |
1000.00 |
0.1000 |
0.9722 |
298.15 |
1000.00 |
0.1500 |
1.3246 |
298.15 |
1000.00 |
0.2000 |
1.6041 |
298.15 |
1000.00 |
0.2500 |
1.8194 |
298.15 |
1000.00 |
0.3000 |
1.9804 |
298.15 |
1000.00 |
0.3500 |
2.0968 |
298.15 |
1000.00 |
0.4000 |
2.1602 |
298.15 |
1000.00 |
0.4500 |
2.1979 |
298.15 |
1000.00 |
0.5000 |
2.2001 |
298.15 |
1000.00 |
0.5500 |
2.1567 |
298.15 |
1000.00 |
0.6000 |
2.0691 |
298.15 |
1000.00 |
0.6500 |
1.9593 |
298.15 |
1000.00 |
0.7000 |
1.8215 |
298.15 |
1000.00 |
0.7500 |
1.6383 |
298.15 |
1000.00 |
0.8000 |
1.4073 |
298.15 |
1000.00 |
0.8500 |
1.1276 |
298.15 |
1000.00 |
0.9000 |
0.7979 |
298.15 |
1000.00 |
0.9500 |
0.4144 |
313.15 |
100.00 |
0.0490 |
0.5216 |
313.15 |
100.00 |
0.0990 |
0.9831 |
313.15 |
100.00 |
0.1490 |
1.3746 |
313.15 |
100.00 |
0.1990 |
1.6907 |
313.15 |
100.00 |
0.2500 |
1.9391 |
313.15 |
100.00 |
0.2990 |
2.1176 |
313.15 |
100.00 |
0.3510 |
2.2573 |
313.15 |
100.00 |
0.4000 |
2.3423 |
313.15 |
100.00 |
0.4490 |
2.3915 |
313.15 |
100.00 |
0.4990 |
2.3982 |
313.15 |
100.00 |
0.5490 |
2.371 |
313.15 |
100.00 |
0.6000 |
2.2839 |
313.15 |
100.00 |
0.6510 |
2.1578 |
313.15 |
100.00 |
0.6990 |
1.9924 |
313.15 |
100.00 |
0.7510 |
1.7865 |
313.15 |
100.00 |
0.8000 |
1.5396 |
313.15 |
100.00 |
0.8500 |
1.2493 |
313.15 |
100.00 |
0.8990 |
0.8527 |
313.15 |
100.00 |
0.9490 |
0.4522 |
313.15 |
1000.00 |
0.0490 |
0.5324 |
313.15 |
1000.00 |
0.0990 |
0.9963 |
313.15 |
1000.00 |
0.1490 |
1.3866 |
313.15 |
1000.00 |
0.1990 |
1.7004 |
313.15 |
1000.00 |
0.2500 |
1.9495 |
313.15 |
1000.00 |
0.2990 |
2.1262 |
313.15 |
1000.00 |
0.3500 |
2.2703 |
313.15 |
1000.00 |
0.3990 |
2.3534 |
313.15 |
1000.00 |
0.4490 |
2.3934 |
313.15 |
1000.00 |
0.4990 |
2.3964 |
313.15 |
1000.00 |
0.5490 |
2.3592 |
313.15 |
1000.00 |
0.6000 |
2.2711 |
313.15 |
1000.00 |
0.6510 |
2.1445 |
313.15 |
1000.00 |
0.6990 |
1.9806 |
313.15 |
1000.00 |
0.7510 |
1.7736 |
313.15 |
1000.00 |
0.8000 |
1.5409 |
313.15 |
1000.00 |
0.8490 |
1.2373 |
313.15 |
1000.00 |
0.8990 |
0.8622 |
313.15 |
1000.00 |
0.9490 |
0.4380 |
313.15 |
10000.00 |
0.0490 |
0.5175 |
313.15 |
10000.00 |
0.1010 |
1.005 |
313.15 |
10000.00 |
0.1510 |
1.3877 |
313.15 |
10000.00 |
0.2020 |
1.6939 |
313.15 |
10000.00 |
0.2490 |
1.9262 |
313.15 |
10000.00 |
0.3000 |
2.1174 |
313.15 |
10000.00 |
0.3490 |
2.2445 |
313.15 |
10000.00 |
0.4010 |
2.3373 |
313.15 |
10000.00 |
0.4510 |
2.3822 |
313.15 |
10000.00 |
0.5010 |
2.3896 |
313.15 |
10000.00 |
0.5510 |
2.3418 |
313.15 |
10000.00 |
0.6020 |
2.2629 |
313.15 |
10000.00 |
0.6500 |
2.1466 |
313.15 |
10000.00 |
0.7500 |
1.7771 |
313.15 |
10000.00 |
0.7990 |
1.5385 |
313.15 |
10000.00 |
0.8490 |
1.2245 |
313.15 |
10000.00 |
0.8990 |
0.8801 |
313.15 |
10000.00 |
0.9490 |
0.4373 |
328.15 |
1000.00 |
0.0500 |
0.5390 |
328.15 |
1000.00 |
0.1000 |
1.016 |
328.15 |
1000.00 |
0.1500 |
1.427 |
328.15 |
1000.00 |
0.2000 |
1.7496 |
328.15 |
1000.00 |
0.2500 |
2.0194 |
328.15 |
1000.00 |
0.3000 |
2.2216 |
328.15 |
1000.00 |
0.3500 |
2.3786 |
328.15 |
1000.00 |
0.4000 |
2.4925 |
328.15 |
1000.00 |
0.4500 |
2.5445 |
328.15 |
1000.00 |
0.5000 |
2.5498 |
328.15 |
1000.00 |
0.5500 |
2.5188 |
328.15 |
1000.00 |
0.6000 |
2.4399 |
328.15 |
1000.00 |
0.6500 |
2.3187 |
328.15 |
1000.00 |
0.7000 |
2.1463 |
328.15 |
1000.00 |
0.7500 |
1.9154 |
328.15 |
1000.00 |
0.8000 |
1.6393 |
328.15 |
1000.00 |
0.8500 |
1.335 |
328.15 |
1000.00 |
0.9000 |
0.9333 |
328.15 |
1000.00 |
0.9500 |
0.4768 |
Excess molar enthalpy (molar enthalpy of mixing), kJ/mol
[ref]
Fixed |
Measured |
Temperature, K - Liquid |
Pressure, kPa - Liquid |
Mole fraction of Carbonic acid, dimethyl ester (1) - Liquid |
Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid |
298.15 |
1000.00 |
0.0500 |
0.5333 |
298.15 |
1000.00 |
0.1000 |
0.9722 |
298.15 |
1000.00 |
0.1500 |
1.3246 |
298.15 |
1000.00 |
0.2000 |
1.6041 |
298.15 |
1000.00 |
0.2500 |
1.8194 |
298.15 |
1000.00 |
0.3000 |
1.9804 |
298.15 |
1000.00 |
0.3500 |
2.0968 |
298.15 |
1000.00 |
0.4000 |
2.1602 |
298.15 |
1000.00 |
0.4500 |
2.1979 |
298.15 |
1000.00 |
0.5000 |
2.2001 |
298.15 |
1000.00 |
0.5500 |
2.1567 |
298.15 |
1000.00 |
0.6000 |
2.0691 |
298.15 |
1000.00 |
0.6500 |
1.9593 |
298.15 |
1000.00 |
0.7000 |
1.8215 |
298.15 |
1000.00 |
0.7500 |
1.6383 |
298.15 |
1000.00 |
0.8000 |
1.4073 |
298.15 |
1000.00 |
0.8500 |
1.1276 |
298.15 |
1000.00 |
0.9000 |
0.7979 |
298.15 |
1000.00 |
0.9500 |
0.4144 |
313.15 |
100.00 |
0.0490 |
0.5216 |
313.15 |
100.00 |
0.0990 |
0.9831 |
313.15 |
100.00 |
0.1490 |
1.3746 |
313.15 |
100.00 |
0.1990 |
1.6907 |
313.15 |
100.00 |
0.2500 |
1.9391 |
313.15 |
100.00 |
0.2990 |
2.1176 |
313.15 |
100.00 |
0.3510 |
2.2573 |
313.15 |
100.00 |
0.4000 |
2.3423 |
313.15 |
100.00 |
0.4490 |
2.3915 |
313.15 |
100.00 |
0.4990 |
2.3982 |
313.15 |
100.00 |
0.5490 |
2.371 |
313.15 |
100.00 |
0.6000 |
2.2839 |
313.15 |
100.00 |
0.6510 |
2.1578 |
313.15 |
100.00 |
0.6990 |
1.9924 |
313.15 |
100.00 |
0.7510 |
1.7865 |
313.15 |
100.00 |
0.8000 |
1.5396 |
313.15 |
100.00 |
0.8500 |
1.2493 |
313.15 |
100.00 |
0.8990 |
0.8527 |
313.15 |
100.00 |
0.9490 |
0.4522 |
313.15 |
1000.00 |
0.0490 |
0.5324 |
313.15 |
1000.00 |
0.0990 |
0.9963 |
313.15 |
1000.00 |
0.1490 |
1.3866 |
313.15 |
1000.00 |
0.1990 |
1.7004 |
313.15 |
1000.00 |
0.2500 |
1.9495 |
313.15 |
1000.00 |
0.2990 |
2.1262 |
313.15 |
1000.00 |
0.3500 |
2.2703 |
313.15 |
1000.00 |
0.3990 |
2.3534 |
313.15 |
1000.00 |
0.4490 |
2.3934 |
313.15 |
1000.00 |
0.4990 |
2.3964 |
313.15 |
1000.00 |
0.5490 |
2.3592 |
313.15 |
1000.00 |
0.6000 |
2.2711 |
313.15 |
1000.00 |
0.6510 |
2.1445 |
313.15 |
1000.00 |
0.6990 |
1.9806 |
313.15 |
1000.00 |
0.7510 |
1.7736 |
313.15 |
1000.00 |
0.8000 |
1.5409 |
313.15 |
1000.00 |
0.8490 |
1.2373 |
313.15 |
1000.00 |
0.8990 |
0.8622 |
313.15 |
1000.00 |
0.9490 |
0.4380 |
313.15 |
10000.00 |
0.0490 |
0.5175 |
313.15 |
10000.00 |
0.1010 |
1.005 |
313.15 |
10000.00 |
0.1510 |
1.3877 |
313.15 |
10000.00 |
0.2020 |
1.6939 |
313.15 |
10000.00 |
0.2490 |
1.9262 |
313.15 |
10000.00 |
0.3000 |
2.1174 |
313.15 |
10000.00 |
0.3490 |
2.2445 |
313.15 |
10000.00 |
0.4010 |
2.3373 |
313.15 |
10000.00 |
0.4510 |
2.3822 |
313.15 |
10000.00 |
0.5010 |
2.3896 |
313.15 |
10000.00 |
0.5510 |
2.3418 |
313.15 |
10000.00 |
0.6020 |
2.2629 |
313.15 |
10000.00 |
0.6500 |
2.1466 |
313.15 |
10000.00 |
0.7500 |
1.7771 |
313.15 |
10000.00 |
0.7990 |
1.5385 |
313.15 |
10000.00 |
0.8490 |
1.2245 |
313.15 |
10000.00 |
0.8990 |
0.8801 |
313.15 |
10000.00 |
0.9490 |
0.4373 |
328.15 |
1000.00 |
0.0500 |
0.5390 |
328.15 |
1000.00 |
0.1000 |
1.016 |
328.15 |
1000.00 |
0.1500 |
1.427 |
328.15 |
1000.00 |
0.2000 |
1.7496 |
328.15 |
1000.00 |
0.2500 |
2.0194 |
328.15 |
1000.00 |
0.3000 |
2.2216 |
328.15 |
1000.00 |
0.3500 |
2.3786 |
328.15 |
1000.00 |
0.4000 |
2.4925 |
328.15 |
1000.00 |
0.4500 |
2.5445 |
328.15 |
1000.00 |
0.5000 |
2.5498 |
328.15 |
1000.00 |
0.5500 |
2.5188 |
328.15 |
1000.00 |
0.6000 |
2.4399 |
328.15 |
1000.00 |
0.6500 |
2.3187 |
328.15 |
1000.00 |
0.7000 |
2.1463 |
328.15 |
1000.00 |
0.7500 |
1.9154 |
328.15 |
1000.00 |
0.8000 |
1.6393 |
328.15 |
1000.00 |
0.8500 |
1.335 |
328.15 |
1000.00 |
0.9000 |
0.9333 |
328.15 |
1000.00 |
0.9500 |
0.4768 |
Mass density, kg/m3
[ref]
Operational conditions:
- Pressure, kPa = 101 (Liquid)
- Temperature, K = 298.15 (Liquid)
Mole fraction of 1-Butanol (2) - Liquid |
Mass density, kg/m3 - Liquid |
0.0000 |
1063.19 |
0.0502 |
1047.97 |
0.0999 |
1033.24 |
0.1499 |
1018.51 |
0.2003 |
1004.53 |
0.2501 |
990.53 |
0.2998 |
976.9 |
0.3499 |
963.39 |
0.4000 |
950.13 |
0.4501 |
937.02 |
0.5000 |
924.2 |
0.5500 |
911.58 |
0.6000 |
899.07 |
0.6500 |
886.83 |
0.7000 |
874.68 |
0.7499 |
862.98 |
0.7999 |
851.07 |
0.8500 |
839.53 |
0.8999 |
828.11 |
0.9499 |
817.0 |
1.0000 |
806.04 |
Mass density, kg/m3
[ref]
Operational conditions:
- Pressure, kPa = 101 (Liquid)
- Temperature, K = 298.15 (Liquid)
Mole fraction of 1-Butanol (2) - Liquid |
Mass density, kg/m3 - Liquid |
0.0000 |
1063.19 |
0.0502 |
1047.97 |
0.0999 |
1033.24 |
0.1499 |
1018.51 |
0.2003 |
1004.53 |
0.2501 |
990.53 |
0.2998 |
976.9 |
0.3499 |
963.39 |
0.4000 |
950.13 |
0.4501 |
937.02 |
0.5000 |
924.2 |
0.5500 |
911.58 |
0.6000 |
899.07 |
0.6500 |
886.83 |
0.7000 |
874.68 |
0.7499 |
862.98 |
0.7999 |
851.07 |
0.8500 |
839.53 |
0.8999 |
828.11 |
0.9499 |
817.0 |
1.0000 |
806.04 |
Boiling temperature at pressure P, K
[ref]
Fixed |
Measured |
Pressure, kPa - Liquid |
Mole fraction of 1-Butanol (2) - Liquid |
Boiling temperature at pressure P, K - Liquid |
40.00 |
0.0000 |
336.68 |
40.00 |
0.1010 |
337.45 |
40.00 |
0.2000 |
338.35 |
40.00 |
0.3010 |
339.36 |
40.00 |
0.3980 |
340.48 |
40.00 |
0.5000 |
341.88 |
40.00 |
0.5980 |
343.55 |
40.00 |
0.7000 |
345.91 |
40.00 |
0.7970 |
349.57 |
40.00 |
0.8980 |
356.16 |
40.00 |
1.0000 |
366.71 |
53.33 |
0.0000 |
344.38 |
53.33 |
0.1010 |
345.17 |
53.33 |
0.2000 |
346.08 |
53.33 |
0.3010 |
347.15 |
53.33 |
0.3980 |
348.31 |
53.33 |
0.5000 |
349.77 |
53.33 |
0.5980 |
351.54 |
53.33 |
0.7000 |
353.92 |
53.33 |
0.7970 |
357.60 |
53.33 |
0.8980 |
363.73 |
53.33 |
1.0000 |
373.72 |
66.66 |
0.0000 |
350.66 |
66.66 |
0.1010 |
351.46 |
66.66 |
0.2000 |
352.37 |
66.66 |
0.3010 |
353.46 |
66.66 |
0.3980 |
354.65 |
66.66 |
0.5000 |
356.17 |
66.66 |
0.5980 |
358.01 |
66.66 |
0.7000 |
360.38 |
66.66 |
0.7970 |
364.21 |
66.66 |
0.8980 |
369.77 |
66.66 |
1.0000 |
379.41 |
79.99 |
0.0000 |
356.01 |
79.99 |
0.1010 |
356.80 |
79.99 |
0.2000 |
357.71 |
79.99 |
0.3010 |
358.83 |
79.99 |
0.3980 |
360.07 |
79.99 |
0.5000 |
361.60 |
79.99 |
0.5980 |
363.47 |
79.99 |
0.7000 |
365.69 |
79.99 |
0.7970 |
369.75 |
79.99 |
0.8980 |
374.76 |
79.99 |
1.0000 |
384.24 |
93.32 |
0.0000 |
360.68 |
93.32 |
0.1010 |
361.46 |
93.32 |
0.2000 |
362.39 |
93.32 |
0.3010 |
363.51 |
93.32 |
0.3980 |
364.77 |
93.32 |
0.5000 |
366.34 |
93.32 |
0.5980 |
368.31 |
93.32 |
0.7000 |
370.28 |
93.32 |
0.7970 |
374.69 |
93.32 |
0.8980 |
378.75 |
93.32 |
1.0000 |
388.46 |
Boiling temperature at pressure P, K
[ref]
Operational condition: Pressure, kPa =
95.8 (Liquid)
Mole fraction of Carbonic acid, dimethyl ester (1) - Liquid |
Boiling temperature at pressure P, K - Liquid |
0.0000 |
389.45 |
0.0910 |
375.95 |
0.1651 |
372.35 |
0.2842 |
369.05 |
0.3721 |
367.65 |
0.4422 |
366.65 |
0.5760 |
364.95 |
0.6450 |
364.05 |
0.7311 |
363.15 |
0.8450 |
362.05 |
1.0000 |
361.25 |
Boiling temperature at pressure P, K
[ref]
Fixed |
Measured |
Pressure, kPa - Liquid |
Mole fraction of 1-Butanol (2) - Liquid |
Boiling temperature at pressure P, K - Liquid |
40.00 |
0.0000 |
336.68 |
40.00 |
0.1010 |
337.45 |
40.00 |
0.2000 |
338.35 |
40.00 |
0.3010 |
339.36 |
40.00 |
0.3980 |
340.48 |
40.00 |
0.5000 |
341.88 |
40.00 |
0.5980 |
343.55 |
40.00 |
0.7000 |
345.91 |
40.00 |
0.7970 |
349.57 |
40.00 |
0.8980 |
356.16 |
40.00 |
1.0000 |
366.71 |
53.33 |
0.0000 |
344.38 |
53.33 |
0.1010 |
345.17 |
53.33 |
0.2000 |
346.08 |
53.33 |
0.3010 |
347.15 |
53.33 |
0.3980 |
348.31 |
53.33 |
0.5000 |
349.77 |
53.33 |
0.5980 |
351.54 |
53.33 |
0.7000 |
353.92 |
53.33 |
0.7970 |
357.60 |
53.33 |
0.8980 |
363.73 |
53.33 |
1.0000 |
373.72 |
66.66 |
0.0000 |
350.66 |
66.66 |
0.1010 |
351.46 |
66.66 |
0.2000 |
352.37 |
66.66 |
0.3010 |
353.46 |
66.66 |
0.3980 |
354.65 |
66.66 |
0.5000 |
356.17 |
66.66 |
0.5980 |
358.01 |
66.66 |
0.7000 |
360.38 |
66.66 |
0.7970 |
364.21 |
66.66 |
0.8980 |
369.77 |
66.66 |
1.0000 |
379.41 |
79.99 |
0.0000 |
356.01 |
79.99 |
0.1010 |
356.80 |
79.99 |
0.2000 |
357.71 |
79.99 |
0.3010 |
358.83 |
79.99 |
0.3980 |
360.07 |
79.99 |
0.5000 |
361.60 |
79.99 |
0.5980 |
363.47 |
79.99 |
0.7000 |
365.69 |
79.99 |
0.7970 |
369.75 |
79.99 |
0.8980 |
374.76 |
79.99 |
1.0000 |
384.24 |
93.32 |
0.0000 |
360.68 |
93.32 |
0.1010 |
361.46 |
93.32 |
0.2000 |
362.39 |
93.32 |
0.3010 |
363.51 |
93.32 |
0.3980 |
364.77 |
93.32 |
0.5000 |
366.34 |
93.32 |
0.5980 |
368.31 |
93.32 |
0.7000 |
370.28 |
93.32 |
0.7970 |
374.69 |
93.32 |
0.8980 |
378.75 |
93.32 |
1.0000 |
388.46 |
Boiling temperature at pressure P, K
[ref]
Operational condition: Pressure, kPa =
95.8 (Liquid)
Mole fraction of Carbonic acid, dimethyl ester (1) - Liquid |
Boiling temperature at pressure P, K - Liquid |
0.0000 |
389.45 |
0.0910 |
375.95 |
0.1651 |
372.35 |
0.2842 |
369.05 |
0.3721 |
367.65 |
0.4422 |
366.65 |
0.5760 |
364.95 |
0.6450 |
364.05 |
0.7311 |
363.15 |
0.8450 |
362.05 |
1.0000 |
361.25 |
Sources