Mixture of Carbonic acid, dimethyl ester + 1-Butanol

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Carbonic acid, dimethyl ester

Name
Carbonic acid, dimethyl ester
InChI
InChI=1S/C3H6O3/c1-5-3(4)6-2/h1-2H3
InChI Key
IEJIGPNLZYLLBP-UHFFFAOYSA-N
Formula
C3H6O3
SMILES
COC(=O)OC
Mol. Weight (g/mol)
90.08
CAS
616-38-6

1-Butanol

Name
1-Butanol
InChI
InChI=1S/C4H10O/c1-2-3-4-5/h5H,2-4H2,1H3
InChI Key
LRHPLDYGYMQRHN-UHFFFAOYSA-N
Formula
C4H10O
SMILES
CCCCO
Mol. Weight (g/mol)
74.12
CAS
71-36-3
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Datasets

  1. Mole fraction (2)
  2. Excess molar enthalpy (molar enthalpy (2)
  3. ρl - Mass density, kg/m3 (2)
  4. Tboil - Boiling temperature at pressure P, K (4)

Mole fraction of 1-Butanol (2) [ref]

Operational condition: Temperature, K = 333.15 (Gas)

Mole fraction of 1-Butanol (2) - Liquid Mole fraction of 1-Butanol (2) - Gas
0.0169 0.1935
0.0340 0.3319
0.0500 0.3795
0.0980 0.5688
0.1505 0.6168
0.2007 0.6624
0.2511 0.6984
0.3012 0.7373
0.3513 0.7745
0.4015 0.7739
0.4514 0.7976
0.5014 0.8089
0.5515 0.8270
0.6015 0.8418
0.6514 0.8543
0.7014 0.8659
0.7512 0.8833
0.8012 0.8983
0.8509 0.9228
0.9006 0.9397
0.9505 0.9677
0.9663 0.9793
0.9830 0.9894

Mole fraction of 1-Butanol (2) [ref]

Operational condition: Temperature, K = 333.15 (Gas)

Mole fraction of 1-Butanol (2) - Liquid Mole fraction of 1-Butanol (2) - Gas
0.0169 0.1935
0.0340 0.3319
0.0500 0.3795
0.0980 0.5688
0.1505 0.6168
0.2007 0.6624
0.2511 0.6984
0.3012 0.7373
0.3513 0.7745
0.4015 0.7739
0.4514 0.7976
0.5014 0.8089
0.5515 0.8270
0.6015 0.8418
0.6514 0.8543
0.7014 0.8659
0.7512 0.8833
0.8012 0.8983
0.8509 0.9228
0.9006 0.9397
0.9505 0.9677
0.9663 0.9793
0.9830 0.9894

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Fixed Measured
Temperature, K - Liquid Pressure, kPa - Liquid Mole fraction of Carbonic acid, dimethyl ester (1) - Liquid Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
298.15 1000.00 0.0500 0.5333
298.15 1000.00 0.1000 0.9722
298.15 1000.00 0.1500 1.3246
298.15 1000.00 0.2000 1.6041
298.15 1000.00 0.2500 1.8194
298.15 1000.00 0.3000 1.9804
298.15 1000.00 0.3500 2.0968
298.15 1000.00 0.4000 2.1602
298.15 1000.00 0.4500 2.1979
298.15 1000.00 0.5000 2.2001
298.15 1000.00 0.5500 2.1567
298.15 1000.00 0.6000 2.0691
298.15 1000.00 0.6500 1.9593
298.15 1000.00 0.7000 1.8215
298.15 1000.00 0.7500 1.6383
298.15 1000.00 0.8000 1.4073
298.15 1000.00 0.8500 1.1276
298.15 1000.00 0.9000 0.7979
298.15 1000.00 0.9500 0.4144
313.15 100.00 0.0490 0.5216
313.15 100.00 0.0990 0.9831
313.15 100.00 0.1490 1.3746
313.15 100.00 0.1990 1.6907
313.15 100.00 0.2500 1.9391
313.15 100.00 0.2990 2.1176
313.15 100.00 0.3510 2.2573
313.15 100.00 0.4000 2.3423
313.15 100.00 0.4490 2.3915
313.15 100.00 0.4990 2.3982
313.15 100.00 0.5490 2.371
313.15 100.00 0.6000 2.2839
313.15 100.00 0.6510 2.1578
313.15 100.00 0.6990 1.9924
313.15 100.00 0.7510 1.7865
313.15 100.00 0.8000 1.5396
313.15 100.00 0.8500 1.2493
313.15 100.00 0.8990 0.8527
313.15 100.00 0.9490 0.4522
313.15 1000.00 0.0490 0.5324
313.15 1000.00 0.0990 0.9963
313.15 1000.00 0.1490 1.3866
313.15 1000.00 0.1990 1.7004
313.15 1000.00 0.2500 1.9495
313.15 1000.00 0.2990 2.1262
313.15 1000.00 0.3500 2.2703
313.15 1000.00 0.3990 2.3534
313.15 1000.00 0.4490 2.3934
313.15 1000.00 0.4990 2.3964
313.15 1000.00 0.5490 2.3592
313.15 1000.00 0.6000 2.2711
313.15 1000.00 0.6510 2.1445
313.15 1000.00 0.6990 1.9806
313.15 1000.00 0.7510 1.7736
313.15 1000.00 0.8000 1.5409
313.15 1000.00 0.8490 1.2373
313.15 1000.00 0.8990 0.8622
313.15 1000.00 0.9490 0.4380
313.15 10000.00 0.0490 0.5175
313.15 10000.00 0.1010 1.005
313.15 10000.00 0.1510 1.3877
313.15 10000.00 0.2020 1.6939
313.15 10000.00 0.2490 1.9262
313.15 10000.00 0.3000 2.1174
313.15 10000.00 0.3490 2.2445
313.15 10000.00 0.4010 2.3373
313.15 10000.00 0.4510 2.3822
313.15 10000.00 0.5010 2.3896
313.15 10000.00 0.5510 2.3418
313.15 10000.00 0.6020 2.2629
313.15 10000.00 0.6500 2.1466
313.15 10000.00 0.7500 1.7771
313.15 10000.00 0.7990 1.5385
313.15 10000.00 0.8490 1.2245
313.15 10000.00 0.8990 0.8801
313.15 10000.00 0.9490 0.4373
328.15 1000.00 0.0500 0.5390
328.15 1000.00 0.1000 1.016
328.15 1000.00 0.1500 1.427
328.15 1000.00 0.2000 1.7496
328.15 1000.00 0.2500 2.0194
328.15 1000.00 0.3000 2.2216
328.15 1000.00 0.3500 2.3786
328.15 1000.00 0.4000 2.4925
328.15 1000.00 0.4500 2.5445
328.15 1000.00 0.5000 2.5498
328.15 1000.00 0.5500 2.5188
328.15 1000.00 0.6000 2.4399
328.15 1000.00 0.6500 2.3187
328.15 1000.00 0.7000 2.1463
328.15 1000.00 0.7500 1.9154
328.15 1000.00 0.8000 1.6393
328.15 1000.00 0.8500 1.335
328.15 1000.00 0.9000 0.9333
328.15 1000.00 0.9500 0.4768

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Fixed Measured
Temperature, K - Liquid Pressure, kPa - Liquid Mole fraction of Carbonic acid, dimethyl ester (1) - Liquid Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
298.15 1000.00 0.0500 0.5333
298.15 1000.00 0.1000 0.9722
298.15 1000.00 0.1500 1.3246
298.15 1000.00 0.2000 1.6041
298.15 1000.00 0.2500 1.8194
298.15 1000.00 0.3000 1.9804
298.15 1000.00 0.3500 2.0968
298.15 1000.00 0.4000 2.1602
298.15 1000.00 0.4500 2.1979
298.15 1000.00 0.5000 2.2001
298.15 1000.00 0.5500 2.1567
298.15 1000.00 0.6000 2.0691
298.15 1000.00 0.6500 1.9593
298.15 1000.00 0.7000 1.8215
298.15 1000.00 0.7500 1.6383
298.15 1000.00 0.8000 1.4073
298.15 1000.00 0.8500 1.1276
298.15 1000.00 0.9000 0.7979
298.15 1000.00 0.9500 0.4144
313.15 100.00 0.0490 0.5216
313.15 100.00 0.0990 0.9831
313.15 100.00 0.1490 1.3746
313.15 100.00 0.1990 1.6907
313.15 100.00 0.2500 1.9391
313.15 100.00 0.2990 2.1176
313.15 100.00 0.3510 2.2573
313.15 100.00 0.4000 2.3423
313.15 100.00 0.4490 2.3915
313.15 100.00 0.4990 2.3982
313.15 100.00 0.5490 2.371
313.15 100.00 0.6000 2.2839
313.15 100.00 0.6510 2.1578
313.15 100.00 0.6990 1.9924
313.15 100.00 0.7510 1.7865
313.15 100.00 0.8000 1.5396
313.15 100.00 0.8500 1.2493
313.15 100.00 0.8990 0.8527
313.15 100.00 0.9490 0.4522
313.15 1000.00 0.0490 0.5324
313.15 1000.00 0.0990 0.9963
313.15 1000.00 0.1490 1.3866
313.15 1000.00 0.1990 1.7004
313.15 1000.00 0.2500 1.9495
313.15 1000.00 0.2990 2.1262
313.15 1000.00 0.3500 2.2703
313.15 1000.00 0.3990 2.3534
313.15 1000.00 0.4490 2.3934
313.15 1000.00 0.4990 2.3964
313.15 1000.00 0.5490 2.3592
313.15 1000.00 0.6000 2.2711
313.15 1000.00 0.6510 2.1445
313.15 1000.00 0.6990 1.9806
313.15 1000.00 0.7510 1.7736
313.15 1000.00 0.8000 1.5409
313.15 1000.00 0.8490 1.2373
313.15 1000.00 0.8990 0.8622
313.15 1000.00 0.9490 0.4380
313.15 10000.00 0.0490 0.5175
313.15 10000.00 0.1010 1.005
313.15 10000.00 0.1510 1.3877
313.15 10000.00 0.2020 1.6939
313.15 10000.00 0.2490 1.9262
313.15 10000.00 0.3000 2.1174
313.15 10000.00 0.3490 2.2445
313.15 10000.00 0.4010 2.3373
313.15 10000.00 0.4510 2.3822
313.15 10000.00 0.5010 2.3896
313.15 10000.00 0.5510 2.3418
313.15 10000.00 0.6020 2.2629
313.15 10000.00 0.6500 2.1466
313.15 10000.00 0.7500 1.7771
313.15 10000.00 0.7990 1.5385
313.15 10000.00 0.8490 1.2245
313.15 10000.00 0.8990 0.8801
313.15 10000.00 0.9490 0.4373
328.15 1000.00 0.0500 0.5390
328.15 1000.00 0.1000 1.016
328.15 1000.00 0.1500 1.427
328.15 1000.00 0.2000 1.7496
328.15 1000.00 0.2500 2.0194
328.15 1000.00 0.3000 2.2216
328.15 1000.00 0.3500 2.3786
328.15 1000.00 0.4000 2.4925
328.15 1000.00 0.4500 2.5445
328.15 1000.00 0.5000 2.5498
328.15 1000.00 0.5500 2.5188
328.15 1000.00 0.6000 2.4399
328.15 1000.00 0.6500 2.3187
328.15 1000.00 0.7000 2.1463
328.15 1000.00 0.7500 1.9154
328.15 1000.00 0.8000 1.6393
328.15 1000.00 0.8500 1.335
328.15 1000.00 0.9000 0.9333
328.15 1000.00 0.9500 0.4768

Mass density, kg/m3 [ref]

Operational conditions:

Mole fraction of 1-Butanol (2) - Liquid Mass density, kg/m3 - Liquid
0.0000 1063.19
0.0502 1047.97
0.0999 1033.24
0.1499 1018.51
0.2003 1004.53
0.2501 990.53
0.2998 976.9
0.3499 963.39
0.4000 950.13
0.4501 937.02
0.5000 924.2
0.5500 911.58
0.6000 899.07
0.6500 886.83
0.7000 874.68
0.7499 862.98
0.7999 851.07
0.8500 839.53
0.8999 828.11
0.9499 817.0
1.0000 806.04

Mass density, kg/m3 [ref]

Operational conditions:

Mole fraction of 1-Butanol (2) - Liquid Mass density, kg/m3 - Liquid
0.0000 1063.19
0.0502 1047.97
0.0999 1033.24
0.1499 1018.51
0.2003 1004.53
0.2501 990.53
0.2998 976.9
0.3499 963.39
0.4000 950.13
0.4501 937.02
0.5000 924.2
0.5500 911.58
0.6000 899.07
0.6500 886.83
0.7000 874.68
0.7499 862.98
0.7999 851.07
0.8500 839.53
0.8999 828.11
0.9499 817.0
1.0000 806.04

Boiling temperature at pressure P, K [ref]

Fixed Measured
Pressure, kPa - Liquid Mole fraction of 1-Butanol (2) - Liquid Boiling temperature at pressure P, K - Liquid
40.00 0.0000 336.68
40.00 0.1010 337.45
40.00 0.2000 338.35
40.00 0.3010 339.36
40.00 0.3980 340.48
40.00 0.5000 341.88
40.00 0.5980 343.55
40.00 0.7000 345.91
40.00 0.7970 349.57
40.00 0.8980 356.16
40.00 1.0000 366.71
53.33 0.0000 344.38
53.33 0.1010 345.17
53.33 0.2000 346.08
53.33 0.3010 347.15
53.33 0.3980 348.31
53.33 0.5000 349.77
53.33 0.5980 351.54
53.33 0.7000 353.92
53.33 0.7970 357.60
53.33 0.8980 363.73
53.33 1.0000 373.72
66.66 0.0000 350.66
66.66 0.1010 351.46
66.66 0.2000 352.37
66.66 0.3010 353.46
66.66 0.3980 354.65
66.66 0.5000 356.17
66.66 0.5980 358.01
66.66 0.7000 360.38
66.66 0.7970 364.21
66.66 0.8980 369.77
66.66 1.0000 379.41
79.99 0.0000 356.01
79.99 0.1010 356.80
79.99 0.2000 357.71
79.99 0.3010 358.83
79.99 0.3980 360.07
79.99 0.5000 361.60
79.99 0.5980 363.47
79.99 0.7000 365.69
79.99 0.7970 369.75
79.99 0.8980 374.76
79.99 1.0000 384.24
93.32 0.0000 360.68
93.32 0.1010 361.46
93.32 0.2000 362.39
93.32 0.3010 363.51
93.32 0.3980 364.77
93.32 0.5000 366.34
93.32 0.5980 368.31
93.32 0.7000 370.28
93.32 0.7970 374.69
93.32 0.8980 378.75
93.32 1.0000 388.46

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 95.8 (Liquid)

Mole fraction of Carbonic acid, dimethyl ester (1) - Liquid Boiling temperature at pressure P, K - Liquid
0.0000 389.45
0.0910 375.95
0.1651 372.35
0.2842 369.05
0.3721 367.65
0.4422 366.65
0.5760 364.95
0.6450 364.05
0.7311 363.15
0.8450 362.05
1.0000 361.25

Boiling temperature at pressure P, K [ref]

Fixed Measured
Pressure, kPa - Liquid Mole fraction of 1-Butanol (2) - Liquid Boiling temperature at pressure P, K - Liquid
40.00 0.0000 336.68
40.00 0.1010 337.45
40.00 0.2000 338.35
40.00 0.3010 339.36
40.00 0.3980 340.48
40.00 0.5000 341.88
40.00 0.5980 343.55
40.00 0.7000 345.91
40.00 0.7970 349.57
40.00 0.8980 356.16
40.00 1.0000 366.71
53.33 0.0000 344.38
53.33 0.1010 345.17
53.33 0.2000 346.08
53.33 0.3010 347.15
53.33 0.3980 348.31
53.33 0.5000 349.77
53.33 0.5980 351.54
53.33 0.7000 353.92
53.33 0.7970 357.60
53.33 0.8980 363.73
53.33 1.0000 373.72
66.66 0.0000 350.66
66.66 0.1010 351.46
66.66 0.2000 352.37
66.66 0.3010 353.46
66.66 0.3980 354.65
66.66 0.5000 356.17
66.66 0.5980 358.01
66.66 0.7000 360.38
66.66 0.7970 364.21
66.66 0.8980 369.77
66.66 1.0000 379.41
79.99 0.0000 356.01
79.99 0.1010 356.80
79.99 0.2000 357.71
79.99 0.3010 358.83
79.99 0.3980 360.07
79.99 0.5000 361.60
79.99 0.5980 363.47
79.99 0.7000 365.69
79.99 0.7970 369.75
79.99 0.8980 374.76
79.99 1.0000 384.24
93.32 0.0000 360.68
93.32 0.1010 361.46
93.32 0.2000 362.39
93.32 0.3010 363.51
93.32 0.3980 364.77
93.32 0.5000 366.34
93.32 0.5980 368.31
93.32 0.7000 370.28
93.32 0.7970 374.69
93.32 0.8980 378.75
93.32 1.0000 388.46

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 95.8 (Liquid)

Mole fraction of Carbonic acid, dimethyl ester (1) - Liquid Boiling temperature at pressure P, K - Liquid
0.0000 389.45
0.0910 375.95
0.1651 372.35
0.2842 369.05
0.3721 367.65
0.4422 366.65
0.5760 364.95
0.6450 364.05
0.7311 363.15
0.8450 362.05
1.0000 361.25

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