Mixture of 2-Propanol, 2-methyl- + Ethyl Acetate

Datasets

1. Mole fraction (6)
2. Excess molar enthalpy (molar enthalpy (2)
3. T_boil - Boiling temperature at pressure P, K (2)
4. Excess molar volume, m3/mol (2)

Mole fraction of Ethyl Acetate (2) [ref]

Operational condition: Pressure, kPa = 101.325 (Liquid)

Mole fraction of Ethyl Acetate (2) - Liquid	Mole fraction of Ethyl Acetate (2) - Gas
0.0234	0.0358
0.0334	0.0508
0.0447	0.0671
0.0686	0.1012
0.0947	0.1367
0.1235	0.1742
0.1417	0.1969
0.1573	0.2161
0.1668	0.2281
0.1857	0.2501
0.2009	0.2682
0.2139	0.2834
0.2369	0.3086
0.2599	0.3339
0.2823	0.3571
0.3063	0.3821
0.3339	0.4091
0.3625	0.4361
0.3991	0.4701
0.4386	0.5056
0.4771	0.5384
0.5052	0.5635
0.5619	0.6104
0.6098	0.6478
0.6629	0.6913
0.7244	0.7416
0.7679	0.7759
0.8102	0.8129
0.8428	0.8415
0.8878	0.8823
0.9322	0.9252
0.9778	0.9744

Azeotropic composition: mole fraction of Ethyl Acetate (2) [ref]

Temperature, K - Liquid	Azeotropic composition: mole fraction of Ethyl Acetate (2) - Liquid
349.59	0.8320

Azeotropic composition: mole fraction of Ethyl Acetate (2) [ref]

Pressure, kPa - Liquid	Azeotropic composition: mole fraction of Ethyl Acetate (2) - Liquid
101.32	0.8320

Mole fraction of Ethyl Acetate (2) [ref]

Operational condition: Pressure, kPa = 101.325 (Liquid)

Mole fraction of Ethyl Acetate (2) - Liquid	Mole fraction of Ethyl Acetate (2) - Gas
0.0234	0.0358
0.0334	0.0508
0.0447	0.0671
0.0686	0.1012
0.0947	0.1367
0.1235	0.1742
0.1417	0.1969
0.1573	0.2161
0.1668	0.2281
0.1857	0.2501
0.2009	0.2682
0.2139	0.2834
0.2369	0.3086
0.2599	0.3339
0.2823	0.3571
0.3063	0.3821
0.3339	0.4091
0.3625	0.4361
0.3991	0.4701
0.4386	0.5056
0.4771	0.5384
0.5052	0.5635
0.5619	0.6104
0.6098	0.6478
0.6629	0.6913
0.7244	0.7416
0.7679	0.7759
0.8102	0.8129
0.8428	0.8415
0.8878	0.8823
0.9322	0.9252
0.9778	0.9744

Azeotropic composition: mole fraction of Ethyl Acetate (2) [ref]

Temperature, K - Liquid	Azeotropic composition: mole fraction of Ethyl Acetate (2) - Liquid
349.59	0.8320

Azeotropic composition: mole fraction of Ethyl Acetate (2) [ref]

Pressure, kPa - Liquid	Azeotropic composition: mole fraction of Ethyl Acetate (2) - Liquid
101.32	0.8320

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Ethyl Acetate (2) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
299.15	0.0546	0.3761
299.15	0.1163	0.7463
299.15	0.1810	1.1004
299.15	0.2456	1.3907
299.15	0.3079	1.6109
299.15	0.3672	1.7674
299.15	0.4207	1.8621
299.15	0.4707	1.9211
299.15	0.5157	1.9395
299.15	0.5541	1.9324
299.15	0.5640	1.9257
299.15	0.6199	1.8558
299.15	0.6800	1.727
299.15	0.7438	1.5256
299.15	0.8091	1.2501
299.15	0.8769	0.8872
299.15	0.9385	0.4892
318.15	0.0538	0.3342
318.15	0.1146	0.6877
318.15	0.1733	1.0047
318.15	0.2313	1.2853
318.15	0.2953	1.5104
318.15	0.3487	1.6582
318.15	0.3987	1.7649
318.15	0.4461	1.8337
318.15	0.4878	1.8625
318.15	0.5176	1.873
318.15	0.5676	1.8575
318.15	0.6236	1.7939
318.15	0.6844	1.6633
318.15	0.7436	1.4708
318.15	0.8108	1.194
318.15	0.8797	0.8282
318.15	0.9442	0.4333

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Ethyl Acetate (2) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
299.15	0.0546	0.3761
299.15	0.1163	0.7463
299.15	0.1810	1.1004
299.15	0.2456	1.3907
299.15	0.3079	1.6109
299.15	0.3672	1.7674
299.15	0.4207	1.8621
299.15	0.4707	1.9211
299.15	0.5157	1.9395
299.15	0.5541	1.9324
299.15	0.5640	1.9257
299.15	0.6199	1.8558
299.15	0.6800	1.727
299.15	0.7438	1.5256
299.15	0.8091	1.2501
299.15	0.8769	0.8872
299.15	0.9385	0.4892
318.15	0.0538	0.3342
318.15	0.1146	0.6877
318.15	0.1733	1.0047
318.15	0.2313	1.2853
318.15	0.2953	1.5104
318.15	0.3487	1.6582
318.15	0.3987	1.7649
318.15	0.4461	1.8337
318.15	0.4878	1.8625
318.15	0.5176	1.873
318.15	0.5676	1.8575
318.15	0.6236	1.7939
318.15	0.6844	1.6633
318.15	0.7436	1.4708
318.15	0.8108	1.194
318.15	0.8797	0.8282
318.15	0.9442	0.4333

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 101.325 (Liquid)

Mole fraction of Ethyl Acetate (2) - Liquid	Boiling temperature at pressure P, K - Liquid
0.0234	355.18
0.0334	355.06
0.0447	354.90
0.0686	354.57
0.0947	354.21
0.1235	353.88
0.1417	353.61
0.1573	353.41
0.1668	353.30
0.1857	353.08
0.2009	352.91
0.2139	352.77
0.2369	352.52
0.2599	352.27
0.2823	352.05
0.3063	351.84
0.3339	351.60
0.3625	351.36
0.3991	351.08
0.4386	350.81
0.4771	350.58
0.5052	350.41
0.5619	350.14
0.6098	349.97
0.6629	349.81
0.7244	349.68
0.7679	349.63
0.8102	349.60
0.8428	349.59
0.8878	349.74
0.9322	349.88
0.9778	350.10

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 101.325 (Liquid)

Mole fraction of Ethyl Acetate (2) - Liquid	Boiling temperature at pressure P, K - Liquid
0.0234	355.18
0.0334	355.06
0.0447	354.90
0.0686	354.57
0.0947	354.21
0.1235	353.88
0.1417	353.61
0.1573	353.41
0.1668	353.30
0.1857	353.08
0.2009	352.91
0.2139	352.77
0.2369	352.52
0.2599	352.27
0.2823	352.05
0.3063	351.84
0.3339	351.60
0.3625	351.36
0.3991	351.08
0.4386	350.81
0.4771	350.58
0.5052	350.41
0.5619	350.14
0.6098	349.97
0.6629	349.81
0.7244	349.68
0.7679	349.63
0.8102	349.60
0.8428	349.59
0.8878	349.74
0.9322	349.88
0.9778	350.10

Excess molar volume, m3/mol [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Ethyl Acetate (2) - Liquid	Excess molar volume, m3/mol - Liquid
303.15	0.0458	1.1400e-06
303.15	0.0972	2.6500e-06
303.15	0.1702	4.4300e-06
303.15	0.1982	4.9900e-06
303.15	0.2483	5.7800e-06
303.15	0.2718	6.1200e-06
303.15	0.3074	6.6000e-06
303.15	0.3613	7.0800e-06
303.15	0.3973	7.3000e-06
303.15	0.4626	7.5200e-06
303.15	0.5178	7.5500e-06
303.15	0.5274	7.5400e-06
303.15	0.5449	7.5100e-06
303.15	0.5624	7.4800e-06
303.15	0.5722	7.4200e-06
303.15	0.5885	7.3500e-06
303.15	0.5998	7.3000e-06
303.15	0.6022	7.2700e-06
303.15	0.6086	7.2000e-06
303.15	0.6124	7.1700e-06
303.15	0.6336	7.0600e-06
303.15	0.6501	6.8700e-06
303.15	0.7084	6.2400e-06
303.15	0.7732	5.2900e-06
303.15	0.8111	4.6000e-06
303.15	0.8533	3.7200e-06
303.15	0.8915	2.8400e-06
303.15	0.9686	8.6000e-07
318.15	0.0796	2.3700e-06
318.15	0.1377	3.7000e-06
318.15	0.1899	4.8300e-06
318.15	0.2558	6.1400e-06
318.15	0.2985	6.8400e-06
318.15	0.3703	7.4400e-06
318.15	0.4344	7.8600e-06
318.15	0.4633	7.9300e-06
318.15	0.5377	7.9500e-06
318.15	0.5626	7.8700e-06
318.15	0.6284	7.5500e-06
318.15	0.6913	7.0000e-06
318.15	0.7670	5.9600e-06
318.15	0.8516	4.1800e-06
318.15	0.8891	3.6100e-06
318.15	0.9294	2.3700e-06

Excess molar volume, m3/mol [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Ethyl Acetate (2) - Liquid	Excess molar volume, m3/mol - Liquid
303.15	0.0458	1.1400e-06
303.15	0.0972	2.6500e-06
303.15	0.1702	4.4300e-06
303.15	0.1982	4.9900e-06
303.15	0.2483	5.7800e-06
303.15	0.2718	6.1200e-06
303.15	0.3074	6.6000e-06
303.15	0.3613	7.0800e-06
303.15	0.3973	7.3000e-06
303.15	0.4626	7.5200e-06
303.15	0.5178	7.5500e-06
303.15	0.5274	7.5400e-06
303.15	0.5449	7.5100e-06
303.15	0.5624	7.4800e-06
303.15	0.5722	7.4200e-06
303.15	0.5885	7.3500e-06
303.15	0.5998	7.3000e-06
303.15	0.6022	7.2700e-06
303.15	0.6086	7.2000e-06
303.15	0.6124	7.1700e-06
303.15	0.6336	7.0600e-06
303.15	0.6501	6.8700e-06
303.15	0.7084	6.2400e-06
303.15	0.7732	5.2900e-06
303.15	0.8111	4.6000e-06
303.15	0.8533	3.7200e-06
303.15	0.8915	2.8400e-06
303.15	0.9686	8.6000e-07
318.15	0.0796	2.3700e-06
318.15	0.1377	3.7000e-06
318.15	0.1899	4.8300e-06
318.15	0.2558	6.1400e-06
318.15	0.2985	6.8400e-06
318.15	0.3703	7.4400e-06
318.15	0.4344	7.8600e-06
318.15	0.4633	7.9300e-06
318.15	0.5377	7.9500e-06
318.15	0.5626	7.8700e-06
318.15	0.6284	7.5500e-06
318.15	0.6913	7.0000e-06
318.15	0.7670	5.9600e-06
318.15	0.8516	4.1800e-06
318.15	0.8891	3.6100e-06
318.15	0.9294	2.3700e-06

Sources

• Isobaric Vapor-Liquid Equilibria and Excess Quantities for Binary Mixtures of an Ethyl Ester + tert-Butanol and a New Approach to VLE Data Processing