Mixture of Toluene + Benzene, chloro- + Ethylbenzene
Datasets
-
Excess molar enthalpy (molar enthalpy (2)
-
Tboil - Boiling temperature at pressure P, K (2)
Excess molar enthalpy (molar enthalpy of mixing), kJ/mol
[ref]
Operational conditions:
- Temperature, K = 298.15 (Liquid)
- Pressure, kPa = 101.3 (Liquid)
Fixed |
Measured |
Mole fraction of Toluene (1) - Liquid |
Mole fraction of Ethylbenzene (3) - Liquid |
Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid |
0.0000 |
0.5000 |
-0.1530 |
0.1150 |
0.1150 |
-0.0970 |
0.1160 |
0.1160 |
-0.0980 |
0.1250 |
0.1250 |
-0.1010 |
0.1275 |
0.7450 |
-0.0720 |
0.1715 |
0.6570 |
-0.0890 |
0.1790 |
0.1790 |
-0.1230 |
0.1845 |
0.1845 |
-0.1270 |
0.2190 |
0.2190 |
-0.1310 |
0.2230 |
0.5540 |
-0.1070 |
0.2595 |
0.2595 |
-0.1340 |
0.2670 |
0.4660 |
-0.1180 |
0.2770 |
0.3615 |
-0.1350 |
0.2955 |
0.2955 |
-0.1330 |
0.3135 |
0.3730 |
-0.1260 |
0.3300 |
0.3350 |
-0.1280 |
0.3350 |
0.3300 |
-0.1280 |
0.3350 |
0.3350 |
-0.1280 |
0.3405 |
0.3405 |
-0.1260 |
0.3465 |
0.3465 |
-0.1250 |
0.3710 |
0.2580 |
-0.1310 |
0.3810 |
0.3810 |
-0.1070 |
0.5000 |
0.0000 |
-0.1190 |
0.5000 |
0.5000 |
-0.0092 |
0.5080 |
0.2460 |
-0.1040 |
0.5220 |
0.2390 |
-0.1020 |
0.7250 |
0.1375 |
-0.0650 |
Excess molar enthalpy (molar enthalpy of mixing), kJ/mol
[ref]
Operational conditions:
- Temperature, K = 298.15 (Liquid)
- Pressure, kPa = 101.3 (Liquid)
Fixed |
Measured |
Mole fraction of Toluene (1) - Liquid |
Mole fraction of Ethylbenzene (3) - Liquid |
Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid |
0.0000 |
0.5000 |
-0.1530 |
0.1150 |
0.1150 |
-0.0970 |
0.1160 |
0.1160 |
-0.0980 |
0.1250 |
0.1250 |
-0.1010 |
0.1275 |
0.7450 |
-0.0720 |
0.1715 |
0.6570 |
-0.0890 |
0.1790 |
0.1790 |
-0.1230 |
0.1845 |
0.1845 |
-0.1270 |
0.2190 |
0.2190 |
-0.1310 |
0.2230 |
0.5540 |
-0.1070 |
0.2595 |
0.2595 |
-0.1340 |
0.2670 |
0.4660 |
-0.1180 |
0.2770 |
0.3615 |
-0.1350 |
0.2955 |
0.2955 |
-0.1330 |
0.3135 |
0.3730 |
-0.1260 |
0.3300 |
0.3350 |
-0.1280 |
0.3350 |
0.3300 |
-0.1280 |
0.3350 |
0.3350 |
-0.1280 |
0.3405 |
0.3405 |
-0.1260 |
0.3465 |
0.3465 |
-0.1250 |
0.3710 |
0.2580 |
-0.1310 |
0.3810 |
0.3810 |
-0.1070 |
0.5000 |
0.0000 |
-0.1190 |
0.5000 |
0.5000 |
-0.0092 |
0.5080 |
0.2460 |
-0.1040 |
0.5220 |
0.2390 |
-0.1020 |
0.7250 |
0.1375 |
-0.0650 |
Boiling temperature at pressure P, K
[ref]
Fixed |
Measured |
Mole fraction of Toluene (1) - Liquid |
Mole fraction of Ethylbenzene (3) - Liquid |
Pressure, kPa - Liquid |
Boiling temperature at pressure P, K - Liquid |
0.1260 |
0.7480 |
26.66 |
361.87 |
0.1260 |
0.7480 |
53.33 |
382.79 |
0.1260 |
0.7480 |
79.99 |
396.47 |
0.1260 |
0.7480 |
101.32 |
405.01 |
0.1950 |
0.5370 |
26.66 |
359.41 |
0.1950 |
0.5370 |
53.33 |
380.30 |
0.1950 |
0.5370 |
79.99 |
393.99 |
0.1950 |
0.5370 |
101.32 |
402.53 |
0.2320 |
0.3840 |
26.66 |
358.04 |
0.2320 |
0.3840 |
53.33 |
378.78 |
0.2320 |
0.3840 |
79.99 |
392.40 |
0.2320 |
0.3840 |
101.32 |
400.88 |
0.2510 |
0.2500 |
26.66 |
357.40 |
0.2510 |
0.2500 |
53.33 |
378.12 |
0.2510 |
0.2500 |
79.99 |
391.72 |
0.2510 |
0.2500 |
101.32 |
400.23 |
0.3340 |
0.3330 |
26.66 |
355.69 |
0.3340 |
0.3330 |
53.33 |
376.39 |
0.3340 |
0.3330 |
79.99 |
389.97 |
0.3340 |
0.3330 |
101.32 |
398.45 |
0.3520 |
0.4320 |
26.66 |
355.27 |
0.3520 |
0.4320 |
53.33 |
376.13 |
0.3520 |
0.4320 |
79.99 |
389.68 |
0.3520 |
0.4320 |
101.32 |
398.16 |
0.4000 |
0.2000 |
26.66 |
353.73 |
0.4000 |
0.2000 |
53.33 |
374.39 |
0.4000 |
0.2000 |
79.99 |
387.88 |
0.4000 |
0.2000 |
101.32 |
396.29 |
0.4920 |
0.3390 |
26.66 |
352.11 |
0.4920 |
0.3390 |
53.33 |
372.77 |
0.4920 |
0.3390 |
79.99 |
386.22 |
0.4920 |
0.3390 |
101.32 |
394.62 |
0.5300 |
0.2350 |
26.66 |
351.03 |
0.5300 |
0.2350 |
53.33 |
371.67 |
0.5300 |
0.2350 |
79.99 |
385.11 |
0.5300 |
0.2350 |
101.32 |
393.46 |
0.6060 |
0.1310 |
26.66 |
349.48 |
0.6060 |
0.1310 |
53.33 |
369.92 |
0.6060 |
0.1310 |
79.99 |
383.23 |
0.6060 |
0.1310 |
101.32 |
391.50 |
0.7020 |
0.1990 |
26.66 |
347.87 |
0.7020 |
0.1990 |
53.33 |
368.24 |
0.7020 |
0.1990 |
79.99 |
381.52 |
0.7020 |
0.1990 |
101.32 |
389.83 |
0.7590 |
0.1200 |
26.66 |
346.64 |
0.7590 |
0.1200 |
53.33 |
366.90 |
0.7590 |
0.1200 |
79.99 |
380.12 |
0.7590 |
0.1200 |
101.32 |
388.35 |
Boiling temperature at pressure P, K
[ref]
Fixed |
Measured |
Mole fraction of Toluene (1) - Liquid |
Mole fraction of Ethylbenzene (3) - Liquid |
Pressure, kPa - Liquid |
Boiling temperature at pressure P, K - Liquid |
0.1260 |
0.7480 |
26.66 |
361.87 |
0.1260 |
0.7480 |
53.33 |
382.79 |
0.1260 |
0.7480 |
79.99 |
396.47 |
0.1260 |
0.7480 |
101.32 |
405.01 |
0.1950 |
0.5370 |
26.66 |
359.41 |
0.1950 |
0.5370 |
53.33 |
380.30 |
0.1950 |
0.5370 |
79.99 |
393.99 |
0.1950 |
0.5370 |
101.32 |
402.53 |
0.2320 |
0.3840 |
26.66 |
358.04 |
0.2320 |
0.3840 |
53.33 |
378.78 |
0.2320 |
0.3840 |
79.99 |
392.40 |
0.2320 |
0.3840 |
101.32 |
400.88 |
0.2510 |
0.2500 |
26.66 |
357.40 |
0.2510 |
0.2500 |
53.33 |
378.12 |
0.2510 |
0.2500 |
79.99 |
391.72 |
0.2510 |
0.2500 |
101.32 |
400.23 |
0.3340 |
0.3330 |
26.66 |
355.69 |
0.3340 |
0.3330 |
53.33 |
376.39 |
0.3340 |
0.3330 |
79.99 |
389.97 |
0.3340 |
0.3330 |
101.32 |
398.45 |
0.3520 |
0.4320 |
26.66 |
355.27 |
0.3520 |
0.4320 |
53.33 |
376.13 |
0.3520 |
0.4320 |
79.99 |
389.68 |
0.3520 |
0.4320 |
101.32 |
398.16 |
0.4000 |
0.2000 |
26.66 |
353.73 |
0.4000 |
0.2000 |
53.33 |
374.39 |
0.4000 |
0.2000 |
79.99 |
387.88 |
0.4000 |
0.2000 |
101.32 |
396.29 |
0.4920 |
0.3390 |
26.66 |
352.11 |
0.4920 |
0.3390 |
53.33 |
372.77 |
0.4920 |
0.3390 |
79.99 |
386.22 |
0.4920 |
0.3390 |
101.32 |
394.62 |
0.5300 |
0.2350 |
26.66 |
351.03 |
0.5300 |
0.2350 |
53.33 |
371.67 |
0.5300 |
0.2350 |
79.99 |
385.11 |
0.5300 |
0.2350 |
101.32 |
393.46 |
0.6060 |
0.1310 |
26.66 |
349.48 |
0.6060 |
0.1310 |
53.33 |
369.92 |
0.6060 |
0.1310 |
79.99 |
383.23 |
0.6060 |
0.1310 |
101.32 |
391.50 |
0.7020 |
0.1990 |
26.66 |
347.87 |
0.7020 |
0.1990 |
53.33 |
368.24 |
0.7020 |
0.1990 |
79.99 |
381.52 |
0.7020 |
0.1990 |
101.32 |
389.83 |
0.7590 |
0.1200 |
26.66 |
346.64 |
0.7590 |
0.1200 |
53.33 |
366.90 |
0.7590 |
0.1200 |
79.99 |
380.12 |
0.7590 |
0.1200 |
101.32 |
388.35 |
Sources