Mixture of 1,3-Dioxolane + Water

Datasets

1. Activity coefficient (10)
2. Mole fraction (4)
3. η - Viscosity, Pa*s (4)
4. ρ_l - Mass density, kg/m3 (4)
5. T_boil - Boiling temperature at pressure P, K (2)
6. Azeotropic temperature, K (2)
7. Partial molar volume, m3/mol (2)

Activity coefficient of 1,3-Dioxolane (1) [ref]

Fixed		Measured
Temperature, K - Liquid	Mole fraction of 1,3-Dioxolane (1) - Liquid	Activity coefficient of 1,3-Dioxolane (1) - Liquid
372.55	0.0000	11.2

Activity coefficient of 1,3-Dioxolane (1) [ref]

Fixed		Measured
Temperature, K - Liquid	Mole fraction of 1,3-Dioxolane (1) - Liquid	Activity coefficient of 1,3-Dioxolane (1) - Liquid
348.15	0.0000	11.3

Activity coefficient of 1,3-Dioxolane (1) [ref]

Operational conditions:

• Temperature, K = 338.15 (Liquid)
• Mole fraction = 0 (Liquid)

Activity coefficient of 1,3-Dioxolane (1) - Liquid
11.0
11.4

Activity coefficient of 1,3-Dioxolane (1) [ref]

Operational condition: Mole fraction = 0 (Liquid)

Temperature, K - Liquid	Activity coefficient of 1,3-Dioxolane (1) - Liquid
318.15	10.6
328.15	10.9

Activity coefficient of 1,3-Dioxolane (1) [ref]

Operational condition: Mole fraction = 0 (Liquid)

Temperature, K - Liquid	Activity coefficient of 1,3-Dioxolane (1) - Liquid
273.35	8.13
278.15	8.48
288.15	9.12
298.15	9.71
308.15	10.2

Activity coefficient of 1,3-Dioxolane (1) [ref]

Fixed		Measured
Temperature, K - Liquid	Mole fraction of 1,3-Dioxolane (1) - Liquid	Activity coefficient of 1,3-Dioxolane (1) - Liquid
372.55	0.0000	11.2

Activity coefficient of 1,3-Dioxolane (1) [ref]

Fixed		Measured
Temperature, K - Liquid	Mole fraction of 1,3-Dioxolane (1) - Liquid	Activity coefficient of 1,3-Dioxolane (1) - Liquid
348.15	0.0000	11.3

Activity coefficient of 1,3-Dioxolane (1) [ref]

Operational conditions:

• Temperature, K = 338.15 (Liquid)
• Mole fraction = 0 (Liquid)

Activity coefficient of 1,3-Dioxolane (1) - Liquid
11.0
11.4

Activity coefficient of 1,3-Dioxolane (1) [ref]

Operational condition: Mole fraction = 0 (Liquid)

Temperature, K - Liquid	Activity coefficient of 1,3-Dioxolane (1) - Liquid
318.15	10.6
328.15	10.9

Activity coefficient of 1,3-Dioxolane (1) [ref]

Operational condition: Mole fraction = 0 (Liquid)

Temperature, K - Liquid	Activity coefficient of 1,3-Dioxolane (1) - Liquid
273.35	8.13
278.15	8.48
288.15	9.12
298.15	9.71
308.15	10.2

Mole fraction of 1,3-Dioxolane (1) [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid)

Mole fraction of 1,3-Dioxolane (1) - Liquid	Mole fraction of 1,3-Dioxolane (1) - Gas
0.0050	0.1060
0.0080	0.1340
0.0150	0.2660
0.0220	0.3230
0.0330	0.4220
0.0400	0.4500
0.0520	0.5160
0.0820	0.5780
0.1170	0.6300
0.1920	0.6640
0.3040	0.6880
0.4440	0.7020
0.5730	0.7150
0.6800	0.7320
0.7420	0.7460
0.7790	0.7590
0.8460	0.7930
0.8760	0.8130
0.9060	0.8410
0.9370	0.8790
0.9850	0.9620

Azeotropic composition: mole fraction of 1,3-Dioxolane (1) [ref]

Pressure, kPa - Liquid	Azeotropic composition: mole fraction of 1,3-Dioxolane (1) - Liquid
101.30	0.7480

Mole fraction of 1,3-Dioxolane (1) [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid)

Mole fraction of 1,3-Dioxolane (1) - Liquid	Mole fraction of 1,3-Dioxolane (1) - Gas
0.0050	0.1060
0.0080	0.1340
0.0150	0.2660
0.0220	0.3230
0.0330	0.4220
0.0400	0.4500
0.0520	0.5160
0.0820	0.5780
0.1170	0.6300
0.1920	0.6640
0.3040	0.6880
0.4440	0.7020
0.5730	0.7150
0.6800	0.7320
0.7420	0.7460
0.7790	0.7590
0.8460	0.7930
0.8760	0.8130
0.9060	0.8410
0.9370	0.8790
0.9850	0.9620

Azeotropic composition: mole fraction of 1,3-Dioxolane (1) [ref]

Pressure, kPa - Liquid	Azeotropic composition: mole fraction of 1,3-Dioxolane (1) - Liquid
101.30	0.7480

Viscosity, Pa*s [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mass fraction of 1,3-Dioxolane (1) - Liquid	Viscosity, Pa*s - Liquid
303.15	0.1000	0.0008
303.15	0.2000	0.0009
303.15	0.3000	0.0009
303.15	1.0000	0.0005
313.15	0.1000	0.0007
313.15	0.2000	0.0007
313.15	0.3000	0.0008
313.15	1.0000	0.0005
323.15	0.1000	0.0006
323.15	0.2000	0.0006
323.15	0.3000	0.0006
323.15	1.0000	0.0004

Viscosity, Pa*s [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Volume fraction of Water (2) - Liquid	Viscosity, Pa*s - Liquid
298.15	0.3000	0.0010
308.15	0.3000	0.0009
298.15	0.6000	0.0014
308.15	0.6000	0.0011
298.15	0.9000	0.0009
308.15	0.9000	0.0008

Viscosity, Pa*s [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mass fraction of 1,3-Dioxolane (1) - Liquid	Viscosity, Pa*s - Liquid
303.15	0.1000	0.0008
303.15	0.2000	0.0009
303.15	0.3000	0.0009
303.15	1.0000	0.0005
313.15	0.1000	0.0007
313.15	0.2000	0.0007
313.15	0.3000	0.0008
313.15	1.0000	0.0005
323.15	0.1000	0.0006
323.15	0.2000	0.0006
323.15	0.3000	0.0006
323.15	1.0000	0.0004

Viscosity, Pa*s [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Volume fraction of Water (2) - Liquid	Viscosity, Pa*s - Liquid
298.15	0.3000	0.0010
308.15	0.3000	0.0009
298.15	0.6000	0.0014
308.15	0.6000	0.0011
298.15	0.9000	0.0009
308.15	0.9000	0.0008

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mass fraction of 1,3-Dioxolane (1) - Liquid	Mass density, kg/m3 - Liquid
303.15	0.1000	1007.2
303.15	0.2000	1018.5
303.15	0.3000	1028.0
303.15	1.0000	1051.8
313.15	0.1000	1001.2
313.15	0.2000	1012.5
313.15	0.3000	1021.0
313.15	1.0000	1042.2
323.15	0.1000	997.7
323.15	0.2000	1007.6
323.15	0.3000	1013.5
323.15	1.0000	1031.1

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Volume fraction of Water (2) - Liquid	Mass density, kg/m3 - Liquid
298.15	0.3000	1049.2
308.15	0.3000	1041.1
298.15	0.6000	1039.1
308.15	0.6000	1030.7
298.15	0.9000	1009.2
308.15	0.9000	1003.3

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mass fraction of 1,3-Dioxolane (1) - Liquid	Mass density, kg/m3 - Liquid
303.15	0.1000	1007.2
303.15	0.2000	1018.5
303.15	0.3000	1028.0
303.15	1.0000	1051.8
313.15	0.1000	1001.2
313.15	0.2000	1012.5
313.15	0.3000	1021.0
313.15	1.0000	1042.2
323.15	0.1000	997.7
323.15	0.2000	1007.6
323.15	0.3000	1013.5
323.15	1.0000	1031.1

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Volume fraction of Water (2) - Liquid	Mass density, kg/m3 - Liquid
298.15	0.3000	1049.2
308.15	0.3000	1041.1
298.15	0.6000	1039.1
308.15	0.6000	1030.7
298.15	0.9000	1009.2
308.15	0.9000	1003.3

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid)

Mole fraction of 1,3-Dioxolane (1) - Liquid	Boiling temperature at pressure P, K - Liquid
0.0050	370.14
0.0080	369.26
0.0150	365.38
0.0220	362.67
0.0330	359.66
0.0400	358.12
0.0520	355.53
0.0820	352.09
0.1170	349.31
0.1920	347.21
0.3040	346.12
0.4440	345.59
0.5730	345.23
0.6800	345.01
0.7420	344.95
0.7790	344.96
0.8460	345.19
0.8760	345.45
0.9060	345.84
0.9370	346.42
0.9850	347.69

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid)

Mole fraction of 1,3-Dioxolane (1) - Liquid	Boiling temperature at pressure P, K - Liquid
0.0050	370.14
0.0080	369.26
0.0150	365.38
0.0220	362.67
0.0330	359.66
0.0400	358.12
0.0520	355.53
0.0820	352.09
0.1170	349.31
0.1920	347.21
0.3040	346.12
0.4440	345.59
0.5730	345.23
0.6800	345.01
0.7420	344.95
0.7790	344.96
0.8460	345.19
0.8760	345.45
0.9060	345.84
0.9370	346.42
0.9850	347.69

Azeotropic temperature, K [ref]

Mole fraction of 1,3-Dioxolane (1) - Liquid	Azeotropic temperature, K - Liquid
0.7480	344.95

Azeotropic temperature, K [ref]

Mole fraction of 1,3-Dioxolane (1) - Liquid	Azeotropic temperature, K - Liquid
0.7480	344.95

Partial molar volume, m3/mol of 1,3-Dioxolane (1) [ref]

Operational condition: Mole fraction = 0 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Pressure, kPa - Liquid	Partial molar volume, m3/mol of 1,3-Dioxolane (1) - Liquid
298.15	30060.00	0.0001
298.17	15030.00	0.0001
318.16	15030.00	0.0001
318.16	30050.00	0.0001
338.15	15040.00	0.0001
338.15	30040.00	0.0001
358.17	15020.00	0.0001
358.17	30020.00	0.0001
373.18	30040.00	0.0001
373.19	15040.00	0.0001
398.18	2020.00	0.0001
398.18	15040.00	0.0001
398.18	30060.00	0.0001
423.17	2040.00	0.0001
423.17	15010.00	0.0001
423.18	30050.00	0.0001
448.16	2060.00	0.0001
448.17	15040.00	0.0001
448.17	30060.00	0.0001

Partial molar volume, m3/mol of 1,3-Dioxolane (1) [ref]

Operational condition: Mole fraction = 0 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Pressure, kPa - Liquid	Partial molar volume, m3/mol of 1,3-Dioxolane (1) - Liquid
298.15	30060.00	0.0001
298.17	15030.00	0.0001
318.16	15030.00	0.0001
318.16	30050.00	0.0001
338.15	15040.00	0.0001
338.15	30040.00	0.0001
358.17	15020.00	0.0001
358.17	30020.00	0.0001
373.18	30040.00	0.0001
373.19	15040.00	0.0001
398.18	2020.00	0.0001
398.18	15040.00	0.0001
398.18	30060.00	0.0001
423.17	2040.00	0.0001
423.17	15010.00	0.0001
423.18	30050.00	0.0001
448.16	2060.00	0.0001
448.17	15040.00	0.0001
448.17	30060.00	0.0001

Sources

• Partial Molar Volumes, Viscosity B-Coefficients, and Adiabatic Compressibilities of Sodium Molybdate in Aqueous 1,3-Dioxolane Mixtures from 303.15 to 323.15 K
• Temperature dependence of limiting activity coefficients and Henry s law constants of cyclic and open-chain ethers in water
• Partial molar volumes of organic solutes in water. XXII. Cyclic ethers at temperatures (298 to 573) K and pressures up to 30 MPa
• Vapor-Liquid Equilibrium Data for Methanol + 1,3-Dioxolane + Water and Constituent Binary Systems at 101.3 kPa.
• Study of Solution Properties of Some Alkali Bromides in Aqueous Binary Mixtures of 1,3-Dioxolane in View of Different Models