Mixture of iron + palladium

Datasets

1. (Relative) activity (4)
2. Excess molar Gibbs energy, kJ/mol (4)
3. ρ_l - Mass density, kg/m3 (2)

(Relative) activity of iron (1) [ref]

Fixed			Measured
Mole fraction of iron (1) - Liquid	Temperature, K - Liquid	Pressure, kPa - Liquid	(Relative) activity of iron (1) - Liquid
0.5000	1850.00	101.00	0.3300

(Relative) activity of palladium (2) [ref]

Fixed			Measured
Mole fraction of iron (1) - Liquid	Temperature, K - Liquid	Pressure, kPa - Liquid	(Relative) activity of palladium (2) - Liquid
0.5000	1850.00	101.00	0.2900

(Relative) activity of iron (1) [ref]

Fixed			Measured
Mole fraction of iron (1) - Liquid	Temperature, K - Liquid	Pressure, kPa - Liquid	(Relative) activity of iron (1) - Liquid
0.5000	1850.00	101.00	0.3300

(Relative) activity of palladium (2) [ref]

Fixed			Measured
Mole fraction of iron (1) - Liquid	Temperature, K - Liquid	Pressure, kPa - Liquid	(Relative) activity of palladium (2) - Liquid
0.5000	1850.00	101.00	0.2900

Excess molar Gibbs energy, kJ/mol [ref]

Fixed			Measured
Mole fraction of iron (1) - Liquid	Temperature, K - Liquid	Pressure, kPa - Liquid	Excess molar Gibbs energy, kJ/mol - Liquid
0.5000	1850.00	101.00	-7.21

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Fixed			Measured
Mole fraction of iron (1) - Liquid	Temperature, K - Liquid	Pressure, kPa - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.5000	1850.00	101.00	-25.1

Excess molar Gibbs energy, kJ/mol [ref]

Fixed			Measured
Mole fraction of iron (1) - Liquid	Temperature, K - Liquid	Pressure, kPa - Liquid	Excess molar Gibbs energy, kJ/mol - Liquid
0.5000	1850.00	101.00	-7.21

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Fixed			Measured
Mole fraction of iron (1) - Liquid	Temperature, K - Liquid	Pressure, kPa - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.5000	1850.00	101.00	-25.1

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 100 (Liquid)

Fixed		Measured
Mole fraction of palladium (2) - Liquid	Temperature, K - Liquid	Mass density, kg/m3 - Liquid
1.0000	1790.00	10670.0
1.0000	1795.00	10672.0
1.0000	1796.00	10652.0
1.0000	1802.00	10686.0
1.0000	1809.00	10670.0
1.0000	1820.00	10677.0
1.0000	1831.00	10627.0
1.0000	1843.00	10654.0
1.0000	1856.00	10601.0
1.0000	1878.00	10558.0
1.0000	1889.00	10592.0
1.0000	1890.00	10575.0
1.0000	1917.00	10529.0
1.0000	1935.00	10478.0
1.0000	1951.00	10465.0
0.8000	1440.00	9717.0
0.8000	1483.00	9676.0
0.8000	1543.00	9619.0
0.8000	1598.00	9769.0
0.8000	1613.00	9499.0
0.8000	1624.00	9547.0
0.8000	1625.00	9735.0
0.8000	1665.00	9694.0
0.8000	1672.00	9450.0
0.8000	1707.00	9656.0
0.8000	1749.00	9379.0
0.8000	1767.00	9602.0
0.8000	1832.00	9536.0
0.8000	1841.00	9278.0
0.8000	1916.00	9434.0
0.6000	1414.00	8979.0
0.6000	1437.00	8950.0
0.6000	1476.00	8899.0
0.6000	1483.00	8904.0
0.6000	1536.00	8856.0
0.6000	1551.00	8825.0
0.6000	1590.00	8791.0
0.6000	1613.00	8779.0
0.6000	1633.00	8756.0
0.6000	1663.00	8735.0
0.6000	1667.00	8709.0
0.6000	1715.00	8695.0
0.6000	1725.00	8660.0
0.6000	1789.00	8633.0
0.6000	1879.00	8530.0
0.6000	1889.00	8544.0
0.4000	1500.00	8297.0
0.4000	1512.00	8275.0
0.4000	1562.00	8208.0
0.4000	1625.00	8150.0
0.4000	1711.00	8076.0
0.4000	1829.00	7971.0
0.4000	1832.00	7965.0
0.2000	1630.00	7824.0
0.2000	1651.00	7615.0
0.2000	1668.00	7805.0
0.2000	1681.00	7789.0
0.2000	1681.00	7591.0
0.2000	1713.00	7775.0
0.2000	1721.00	7550.0
0.2000	1742.00	7739.0
0.2000	1772.00	7506.0
0.2000	1838.00	7700.0
0.2000	1864.00	7646.0
0.2000	1872.00	7426.0

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 100 (Liquid)

Fixed		Measured
Mole fraction of palladium (2) - Liquid	Temperature, K - Liquid	Mass density, kg/m3 - Liquid
1.0000	1790.00	10670.0
1.0000	1795.00	10672.0
1.0000	1796.00	10652.0
1.0000	1802.00	10686.0
1.0000	1809.00	10670.0
1.0000	1820.00	10677.0
1.0000	1831.00	10627.0
1.0000	1843.00	10654.0
1.0000	1856.00	10601.0
1.0000	1878.00	10558.0
1.0000	1889.00	10592.0
1.0000	1890.00	10575.0
1.0000	1917.00	10529.0
1.0000	1935.00	10478.0
1.0000	1951.00	10465.0
0.8000	1440.00	9717.0
0.8000	1483.00	9676.0
0.8000	1543.00	9619.0
0.8000	1598.00	9769.0
0.8000	1613.00	9499.0
0.8000	1624.00	9547.0
0.8000	1625.00	9735.0
0.8000	1665.00	9694.0
0.8000	1672.00	9450.0
0.8000	1707.00	9656.0
0.8000	1749.00	9379.0
0.8000	1767.00	9602.0
0.8000	1832.00	9536.0
0.8000	1841.00	9278.0
0.8000	1916.00	9434.0
0.6000	1414.00	8979.0
0.6000	1437.00	8950.0
0.6000	1476.00	8899.0
0.6000	1483.00	8904.0
0.6000	1536.00	8856.0
0.6000	1551.00	8825.0
0.6000	1590.00	8791.0
0.6000	1613.00	8779.0
0.6000	1633.00	8756.0
0.6000	1663.00	8735.0
0.6000	1667.00	8709.0
0.6000	1715.00	8695.0
0.6000	1725.00	8660.0
0.6000	1789.00	8633.0
0.6000	1879.00	8530.0
0.6000	1889.00	8544.0
0.4000	1500.00	8297.0
0.4000	1512.00	8275.0
0.4000	1562.00	8208.0
0.4000	1625.00	8150.0
0.4000	1711.00	8076.0
0.4000	1829.00	7971.0
0.4000	1832.00	7965.0
0.2000	1630.00	7824.0
0.2000	1651.00	7615.0
0.2000	1668.00	7805.0
0.2000	1681.00	7789.0
0.2000	1681.00	7591.0
0.2000	1713.00	7775.0
0.2000	1721.00	7550.0
0.2000	1742.00	7739.0
0.2000	1772.00	7506.0
0.2000	1838.00	7700.0
0.2000	1864.00	7646.0
0.2000	1872.00	7426.0

Sources

• Correlation between excess volume and thermodynamic functions of liquid Pd-X (X = Fe, Cu and Ni) binary systems
• Thermodynamic mixing effects of liquid ternary Au-Fe-Pd alloys by computer-aided Knudsen cell mass spectrometry