Mixture of lithium bromide + Water

Datasets

1. (Relative) activity (6)
2. Mass fraction (4)
3. σ_cond - Electrical conductivity, S/m (2)
4. P_vap - Vapor or sublimation pressure, kPa (4)
5. n₀ - Refractive index (Na D-line) (2)
6. ρ_l - Mass density, kg/m3 (2)
7. T_fus - Solid-liquid equilibrium temperature, K (4)
8. Vapor or sublimation pressure, kPa (2)

(Relative) activity of Water (2) [ref]

Operational condition: Temperature, K = 298.15 (Liquid)

Fixed		Measured
Pressure, kPa - Liquid	Molality, mol/kg of lithium bromide (1) - Liquid	(Relative) activity of Water (2) - Liquid
3.07	0.9228	0.9672
3.05	1.0531	0.9616
3.04	1.1457	0.9580
3.01	1.3221	0.9498
2.96	1.6917	0.9329
2.95	1.7495	0.9298
2.94	1.8433	0.9249
2.91	2.0223	0.9165
2.86	2.2984	0.9018
2.83	2.5087	0.8907
2.79	2.6711	0.8797
2.78	2.736	0.8762
2.74	2.9763	0.8618
2.62	3.5508	0.8252
2.48	4.2027	0.7810

Osmotic coefficient [ref]

Operational conditions:

• Pressure, kPa = 101 (Liquid)
• Temperature, K = 298.15 (Liquid)

Molality, mol/kg of lithium bromide (1) - Liquid	Osmotic coefficient - Liquid
0.5000	0.9780
1.0000	1.035
0.5000	0.9700
1.0000	1.038

(Relative) activity of Water (2) [ref]

Operational condition: Temperature, K = 373.15 (Liquid)

Molality, mol/kg of lithium bromide (1) - Liquid	(Relative) activity of Water (2) - Liquid
14.152	0.2275
13.1248	0.2663
11.98	0.3156
10.7478	0.3764
10.3846	0.3989
9.7437	0.4353
9.1878	0.4726
8.6054	0.5099
8.068	0.5435
7.3364	0.5940
6.8581	0.6262
6.5855	0.6459
6.2506	0.6684
5.9532	0.6888
5.6959	0.7067
5.3129	0.7326
5.0726	0.7488
4.5641	0.7814
4.1342	0.8062
3.6301	0.8364
3.2233	0.8592
2.7518	0.8850
2.2514	0.9096
1.9083	0.9258
1.5353	0.9424
1.2613	0.9537
1.0611	0.9623
0.8703	0.9692
0.7434	0.9742
0.6472	0.9775
0.5723	0.9803
0.5143	0.9823
0.4620	0.9840
0.4276	0.9855

(Relative) activity of Water (2) [ref]

Operational condition: Temperature, K = 298.15 (Liquid)

Fixed		Measured
Pressure, kPa - Liquid	Molality, mol/kg of lithium bromide (1) - Liquid	(Relative) activity of Water (2) - Liquid
3.07	0.9228	0.9672
3.05	1.0531	0.9616
3.04	1.1457	0.9580
3.01	1.3221	0.9498
2.96	1.6917	0.9329
2.95	1.7495	0.9298
2.94	1.8433	0.9249
2.91	2.0223	0.9165
2.86	2.2984	0.9018
2.83	2.5087	0.8907
2.79	2.6711	0.8797
2.78	2.736	0.8762
2.74	2.9763	0.8618
2.62	3.5508	0.8252
2.48	4.2027	0.7810

Osmotic coefficient [ref]

Operational conditions:

• Pressure, kPa = 101 (Liquid)
• Temperature, K = 298.15 (Liquid)

Molality, mol/kg of lithium bromide (1) - Liquid	Osmotic coefficient - Liquid
0.5000	0.9780
1.0000	1.035
0.5000	0.9700
1.0000	1.038

(Relative) activity of Water (2) [ref]

Operational condition: Temperature, K = 373.15 (Liquid)

Molality, mol/kg of lithium bromide (1) - Liquid	(Relative) activity of Water (2) - Liquid
14.152	0.2275
13.1248	0.2663
11.98	0.3156
10.7478	0.3764
10.3846	0.3989
9.7437	0.4353
9.1878	0.4726
8.6054	0.5099
8.068	0.5435
7.3364	0.5940
6.8581	0.6262
6.5855	0.6459
6.2506	0.6684
5.9532	0.6888
5.6959	0.7067
5.3129	0.7326
5.0726	0.7488
4.5641	0.7814
4.1342	0.8062
3.6301	0.8364
3.2233	0.8592
2.7518	0.8850
2.2514	0.9096
1.9083	0.9258
1.5353	0.9424
1.2613	0.9537
1.0611	0.9623
0.8703	0.9692
0.7434	0.9742
0.6472	0.9775
0.5723	0.9803
0.5143	0.9823
0.4620	0.9840
0.4276	0.9855

Mass fraction of lithium bromide (1) [ref]

Fixed		Measured
Temperature, K - Liquid	Pressure, kPa - Liquid	Mass fraction of lithium bromide (1) - Liquid
288.15	100.00	0.5929

Mass fraction of lithium bromide (1) [ref]

Operational condition: Pressure, kPa = 100 (Liquid)

Temperature, K - Liquid	Mass fraction of lithium bromide (1) - Liquid
273.00	0.5841
308.00	0.6393

Mass fraction of lithium bromide (1) [ref]

Fixed		Measured
Temperature, K - Liquid	Pressure, kPa - Liquid	Mass fraction of lithium bromide (1) - Liquid
288.15	100.00	0.5929

Mass fraction of lithium bromide (1) [ref]

Operational condition: Pressure, kPa = 100 (Liquid)

Temperature, K - Liquid	Mass fraction of lithium bromide (1) - Liquid
273.00	0.5841
308.00	0.6393

Electrical conductivity, S/m [ref]

Operational conditions:

• Temperature, K = 293.15 (Liquid)
• Pressure, kPa = 100 (Liquid)

Molality, mol/kg of lithium bromide (1) - Liquid	Electrical conductivity, S/m - Liquid
0.0500	0.4155
0.1000	0.8503
0.2900	2.333
0.5000	3.745
0.6600	4.922
1.0000	6.881
1.26	8.263
1.5	9.433
1.75	10.45
2.0	11.53
2.5	13.23
3.0	14.82
3.5	16.15
4.0	17.15
4.99	18.56
6.0	19.28
7.0	19.43
8.0	19.13
9.06	18.34

Electrical conductivity, S/m [ref]

Operational conditions:

• Temperature, K = 293.15 (Liquid)
• Pressure, kPa = 100 (Liquid)

Molality, mol/kg of lithium bromide (1) - Liquid	Electrical conductivity, S/m - Liquid
0.0500	0.4155
0.1000	0.8503
0.2900	2.333
0.5000	3.745
0.6600	4.922
1.0000	6.881
1.26	8.263
1.5	9.433
1.75	10.45
2.0	11.53
2.5	13.23
3.0	14.82
3.5	16.15
4.0	17.15
4.99	18.56
6.0	19.28
7.0	19.43
8.0	19.13
9.06	18.34

Vapor or sublimation pressure, kPa [ref]

Operational condition: Temperature, K = 373.15 (Liquid)

Molality, mol/kg of lithium bromide (1) - Liquid	Vapor or sublimation pressure, kPa - Liquid
14.152	20.33
13.1248	24.26
11.98	29.27
10.7478	35.28
10.3846	38.35
9.7437	42.37
9.1878	46.26
8.6054	50.71
8.068	53.74
7.3364	59.04
6.8581	62.61
6.5855	64.26
6.2506	66.53
5.9532	68.77
5.6959	70.59
5.3129	73.27
5.0726	75.01
4.5641	78.48
4.1342	81.12
3.6301	84.26
3.2233	86.68
2.7518	89.44
2.2514	91.81
1.9083	93.07
1.5353	94.97
1.2613	96.73
1.0611	97.55
0.8703	98.35
0.7434	99.08
0.6472	98.90
0.5723	99.85
0.5143	100.20
0.4620	100.31
0.4276	100.52

Vapor or sublimation pressure, kPa [ref]

Operational condition: Mass fraction = 0.2 (Liquid)

Temperature, K - Liquid	Vapor or sublimation pressure, kPa - Liquid
313.16	6.30
323.16	10.59
333.16	17.46
343.16	27.43
353.16	42.04
363.16	61.88
373.16	89.87

Vapor or sublimation pressure, kPa [ref]

Operational condition: Temperature, K = 373.15 (Liquid)

Molality, mol/kg of lithium bromide (1) - Liquid	Vapor or sublimation pressure, kPa - Liquid
14.152	20.33
13.1248	24.26
11.98	29.27
10.7478	35.28
10.3846	38.35
9.7437	42.37
9.1878	46.26
8.6054	50.71
8.068	53.74
7.3364	59.04
6.8581	62.61
6.5855	64.26
6.2506	66.53
5.9532	68.77
5.6959	70.59
5.3129	73.27
5.0726	75.01
4.5641	78.48
4.1342	81.12
3.6301	84.26
3.2233	86.68
2.7518	89.44
2.2514	91.81
1.9083	93.07
1.5353	94.97
1.2613	96.73
1.0611	97.55
0.8703	98.35
0.7434	99.08
0.6472	98.90
0.5723	99.85
0.5143	100.20
0.4620	100.31
0.4276	100.52

Vapor or sublimation pressure, kPa [ref]

Operational condition: Mass fraction = 0.2 (Liquid)

Temperature, K - Liquid	Vapor or sublimation pressure, kPa - Liquid
313.16	6.30
323.16	10.59
333.16	17.46
343.16	27.43
353.16	42.04
363.16	61.88
373.16	89.87

Refractive index (Na D-line) [ref]

Fixed			Measured
Mass fraction of lithium bromide (1) - Liquid	Pressure, kPa - Liquid	Temperature, K - Liquid	Refractive index (Na D-line) - Liquid
0.5929	100.00	288.15	1.4744

Refractive index (Na D-line) [ref]

Fixed			Measured
Mass fraction of lithium bromide (1) - Liquid	Pressure, kPa - Liquid	Temperature, K - Liquid	Refractive index (Na D-line) - Liquid
0.5929	100.00	288.15	1.4744

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 100 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of lithium bromide (1) - Liquid	Mass density, kg/m3 - Liquid
293.15	0.0100	1033.5
293.15	0.0300	1101.8
293.15	0.0500	1171.5
303.15	0.0100	1030.2
303.15	0.0300	1098.0
303.15	0.0500	1168.0
313.15	0.0100	1026.3
313.15	0.0300	1093.9
313.15	0.0500	1163.9
323.15	0.0100	1022.0
323.15	0.0300	1089.4
323.15	0.0500	1159.3
333.15	0.0100	1017.2
333.15	0.0300	1084.6
333.15	0.0500	1154.3

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 100 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of lithium bromide (1) - Liquid	Mass density, kg/m3 - Liquid
293.15	0.0100	1033.5
293.15	0.0300	1101.8
293.15	0.0500	1171.5
303.15	0.0100	1030.2
303.15	0.0300	1098.0
303.15	0.0500	1168.0
313.15	0.0100	1026.3
313.15	0.0300	1093.9
313.15	0.0500	1163.9
323.15	0.0100	1022.0
323.15	0.0300	1089.4
323.15	0.0500	1159.3
333.15	0.0100	1017.2
333.15	0.0300	1084.6
333.15	0.0500	1154.3

Solid-liquid equilibrium temperature, K [ref]

Operational condition: Pressure, kPa = 100 (Liquid)

Mass fraction of lithium bromide (1) - Liquid	Solid-liquid equilibrium temperature, K - Liquid
0.6150	302.30
0.6350	311.20
0.6490	319.50

Solid-liquid equilibrium temperature, K [ref]

Operational condition: Pressure, kPa = 100 (Liquid)

Mass fraction of lithium bromide (1) - Liquid	Solid-liquid equilibrium temperature, K - Liquid
0.6590	332.70
0.6650	338.50

Solid-liquid equilibrium temperature, K [ref]

Operational condition: Pressure, kPa = 100 (Liquid)

Mass fraction of lithium bromide (1) - Liquid	Solid-liquid equilibrium temperature, K - Liquid
0.6150	302.30
0.6350	311.20
0.6490	319.50

Solid-liquid equilibrium temperature, K [ref]

Operational condition: Pressure, kPa = 100 (Liquid)

Mass fraction of lithium bromide (1) - Liquid	Solid-liquid equilibrium temperature, K - Liquid
0.6590	332.70
0.6650	338.50

Vapor or sublimation pressure, kPa [ref]

Operational condition: Temperature, K = 298.15 (Gas)

Molality, mol/kg of lithium bromide (1) - Liquid	Vapor or sublimation pressure, kPa - Gas
0.9228	3.07
1.0531	3.05
1.1457	3.04
1.3221	3.01
1.6917	2.96
1.7495	2.95
1.8433	2.94
2.0223	2.91
2.2984	2.86
2.5087	2.83
2.6711	2.79
2.736	2.78
2.9763	2.74
3.5508	2.62
4.2027	2.48

Vapor or sublimation pressure, kPa [ref]

Operational condition: Temperature, K = 298.15 (Gas)

Molality, mol/kg of lithium bromide (1) - Liquid	Vapor or sublimation pressure, kPa - Gas
0.9228	3.07
1.0531	3.05
1.1457	3.04
1.3221	3.01
1.6917	2.96
1.7495	2.95
1.8433	2.94
2.0223	2.91
2.2984	2.86
2.5087	2.83
2.6711	2.79
2.736	2.78
2.9763	2.74
3.5508	2.62
4.2027	2.48

Sources

• Vapor-liquid equilibria and volumetric properties for new working fluid ([C6H11N2][HSO4] + LiBr + H2O) and corresponding binary systems at different temperatures and ambient pressure
• Measuring and modeling aqueous electrolyte/amino-acid solutions with ePC-SAFT
• Isopiestic measurements of thermodynamic properties for the aqueous system LiBr-CaBr2-H2O at 373.15 K
• Solid Liquid Phase Equilibria of Ternary Systems LiCl LiBr H2O and CaCl2 CaBr2 H2O at 288.15 K
• Thermophysical Properties of Ternary Systems Potassium Formate + Propylene Glycol/Glycerol + Water
• Experimental Investigation of Isothermal Vapor-Liquid Equilibrium and Estimation of Excess Thermodynamic Properties (hE) of CHO2K-H2O from 278.15 to 423.15 K
• Electrical Conductivity of Lithium Chloride, Lithium Bromide, and Lithium Iodide Electrolytes in Methanol, Water, and Their Binary Mixtures
• Solid-Liquid Phase Equilibria of Ternary System KBr-LiBr-H2O at 273 and 308 K
• Temperature Dependence of the Density of Aqueous Alkali Halide Salt Solutions by Experiment and Molecular Simulation