Mixture of 5-Hydroxymethylfurfural + 2-Pentanol + Water

Datasets

1. Mass fraction (6)
2. n₀ - Refractive index (Na D-line) (2)
3. ρ_l - Mass density, kg/m3 (2)

Mass fraction [ref]

Operational conditions:

• Temperature, K = 313.15 (Liquid mixture 2)
• Pressure, kPa = 101 (Liquid mixture 2)

Fixed	Measured
Mass fraction of 5-Hydroxymethylfurfural (1) - Liquid mixture 2	Mass fraction of 2-Pentanol (2) - Liquid mixture 2	Mass fraction of 5-Hydroxymethylfurfural (1) - Liquid mixture 1	Mass fraction of 2-Pentanol (2) - Liquid mixture 1
0.0208	0.0306	0.0403	0.8419
0.0339	0.0339	0.0649	0.8110
0.0482	0.0352	0.0898	0.7757
0.0754	0.0407	0.1347	0.7144
0.0783	0.0425	0.1394	0.7003
0.1117	0.0437	0.1852	0.6589
0.1326	0.0490	0.2095	0.6179
0.2127	0.0337	0.2803	0.4850

Mass fraction of 5-Hydroxymethylfurfural (1) [ref]

Operational conditions:

• Temperature, K = 298.2 (Liquid mixture 1)
• Pressure, kPa = 100 (Liquid mixture 1)

Mass fraction of Water (3) - Liquid mixture 1	Mass fraction of 5-Hydroxymethylfurfural (1) - Liquid mixture 1
0.9477	0.0000
0.9235	0.0238
0.8381	0.1039
0.7383	0.1834
0.5980	0.2642
0.4894	0.2970
0.4344	0.3073
0.3347	0.3138
0.2821	0.3010
0.2312	0.2668
0.1735	0.1839
0.1467	0.1178
0.1238	0.0376
0.1177	0.0000

Mass fraction [ref]

Operational conditions:

• Temperature, K = 298.2 (Liquid mixture 2)
• Pressure, kPa = 100 (Liquid mixture 2)

Fixed	Measured
Mass fraction of 5-Hydroxymethylfurfural (1) - Liquid mixture 2	Mass fraction of Water (3) - Liquid mixture 2	Mass fraction of Water (3) - Liquid mixture 1	Mass fraction of 5-Hydroxymethylfurfural (1) - Liquid mixture 1
0.0286	0.9134	0.1301	0.0529
0.0592	0.8847	0.1402	0.0933
0.0950	0.8487	0.1544	0.1391
0.1234	0.8190	0.1685	0.1739

Mass fraction [ref]

Operational conditions:

• Temperature, K = 313.15 (Liquid mixture 2)
• Pressure, kPa = 101 (Liquid mixture 2)

Fixed	Measured
Mass fraction of 5-Hydroxymethylfurfural (1) - Liquid mixture 2	Mass fraction of 2-Pentanol (2) - Liquid mixture 2	Mass fraction of 5-Hydroxymethylfurfural (1) - Liquid mixture 1	Mass fraction of 2-Pentanol (2) - Liquid mixture 1
0.0208	0.0306	0.0403	0.8419
0.0339	0.0339	0.0649	0.8110
0.0482	0.0352	0.0898	0.7757
0.0754	0.0407	0.1347	0.7144
0.0783	0.0425	0.1394	0.7003
0.1117	0.0437	0.1852	0.6589
0.1326	0.0490	0.2095	0.6179
0.2127	0.0337	0.2803	0.4850

Mass fraction of 5-Hydroxymethylfurfural (1) [ref]

Operational conditions:

• Temperature, K = 298.2 (Liquid mixture 1)
• Pressure, kPa = 100 (Liquid mixture 1)

Mass fraction of Water (3) - Liquid mixture 1	Mass fraction of 5-Hydroxymethylfurfural (1) - Liquid mixture 1
0.9477	0.0000
0.9235	0.0238
0.8381	0.1039
0.7383	0.1834
0.5980	0.2642
0.4894	0.2970
0.4344	0.3073
0.3347	0.3138
0.2821	0.3010
0.2312	0.2668
0.1735	0.1839
0.1467	0.1178
0.1238	0.0376
0.1177	0.0000

Mass fraction [ref]

Operational conditions:

• Temperature, K = 298.2 (Liquid mixture 2)
• Pressure, kPa = 100 (Liquid mixture 2)

Fixed	Measured
Mass fraction of 5-Hydroxymethylfurfural (1) - Liquid mixture 2	Mass fraction of Water (3) - Liquid mixture 2	Mass fraction of Water (3) - Liquid mixture 1	Mass fraction of 5-Hydroxymethylfurfural (1) - Liquid mixture 1
0.0286	0.9134	0.1301	0.0529
0.0592	0.8847	0.1402	0.0933
0.0950	0.8487	0.1544	0.1391
0.1234	0.8190	0.1685	0.1739

Refractive index (Na D-line) [ref]

Operational conditions:

• Temperature, K = 298.2 (Liquid)
• Pressure, kPa = 100 (Liquid)

Fixed		Measured
Mass fraction of Water (3) - Liquid	Mass fraction of 5-Hydroxymethylfurfural (1) - Liquid	Refractive index (Na D-line) - Liquid
0.9477	0.0000	1.3377
0.9235	0.0238	1.3426
0.8381	0.1039	1.3584
0.7383	0.1834	1.3758
0.5980	0.2642	1.3973
0.4894	0.2970	1.4077
0.4344	0.3073	1.4155
0.3347	0.3138	1.4232
0.2821	0.3010	1.425
0.2312	0.2668	1.4239
0.1735	0.1839	1.4169
0.1467	0.1178	1.4108
0.1238	0.0376	1.4028
0.1177	0.0000	1.3992

Refractive index (Na D-line) [ref]

Operational conditions:

• Temperature, K = 298.2 (Liquid)
• Pressure, kPa = 100 (Liquid)

Fixed		Measured
Mass fraction of Water (3) - Liquid	Mass fraction of 5-Hydroxymethylfurfural (1) - Liquid	Refractive index (Na D-line) - Liquid
0.9477	0.0000	1.3377
0.9235	0.0238	1.3426
0.8381	0.1039	1.3584
0.7383	0.1834	1.3758
0.5980	0.2642	1.3973
0.4894	0.2970	1.4077
0.4344	0.3073	1.4155
0.3347	0.3138	1.4232
0.2821	0.3010	1.425
0.2312	0.2668	1.4239
0.1735	0.1839	1.4169
0.1467	0.1178	1.4108
0.1238	0.0376	1.4028
0.1177	0.0000	1.3992

Mass density, kg/m3 [ref]

Operational conditions:

• Temperature, K = 298.2 (Liquid)
• Pressure, kPa = 100 (Liquid)

Fixed		Measured
Mass fraction of Water (3) - Liquid	Mass fraction of 5-Hydroxymethylfurfural (1) - Liquid	Mass density, kg/m3 - Liquid
0.9477	0.0000	989.77
0.9235	0.0238	995.17
0.8381	0.1039	1011.24
0.7383	0.1834	1024.86
0.5980	0.2642	1029.44
0.4894	0.2970	1018.53
0.4344	0.3073	1010.28
0.3347	0.3138	989.63
0.2821	0.3010	971.93
0.2312	0.2668	946.28
0.1735	0.1839	901.88
0.1467	0.1178	872.46
0.1238	0.0376	840.82
0.1177	0.0000	827.45

Mass density, kg/m3 [ref]

Operational conditions:

• Temperature, K = 298.2 (Liquid)
• Pressure, kPa = 100 (Liquid)

Fixed		Measured
Mass fraction of Water (3) - Liquid	Mass fraction of 5-Hydroxymethylfurfural (1) - Liquid	Mass density, kg/m3 - Liquid
0.9477	0.0000	989.77
0.9235	0.0238	995.17
0.8381	0.1039	1011.24
0.7383	0.1834	1024.86
0.5980	0.2642	1029.44
0.4894	0.2970	1018.53
0.4344	0.3073	1010.28
0.3347	0.3138	989.63
0.2821	0.3010	971.93
0.2312	0.2668	946.28
0.1735	0.1839	901.88
0.1467	0.1178	872.46
0.1238	0.0376	840.82
0.1177	0.0000	827.45

Sources

• Liquid-liquid equilibria of ternary and quaternary systems involving 5-hydroxymethylfurfural, water, organic solvents, and salts at 313.15 K and atmospheric pressure
• Liquid-liquid equilibrium in systems used for the production of 5-hydroxymethylfurfural from biomass using alcohols as solvents