Mixture of n-Hexane + Fluoroform

Datasets

1. Mole fraction (6)
2. P_c - Critical pressure, kPa (2)
3. P_vap - Vapor or sublimation pressure, kPa (4)
4. T_c - Critical temperature, K (2)

Mole fraction of Fluoroform (2) [ref]

Fixed		Measured
Mole fraction of Fluoroform (2) - Liquid	Temperature, K - Liquid	Mole fraction of Fluoroform (2) - Gas
0.1730	272.86	0.9886
0.2430	272.85	0.9888
0.2550	272.86	0.9865
0.3350	272.87	0.9889
0.4440	272.87	0.9896
0.8730	272.87	0.9896
0.9530	272.87	0.9919
0.9800	272.87	0.9949
0.9870	272.86	0.9970
0.1010	282.95	0.9754
0.1620	282.95	0.9807
0.2250	282.94	0.9819
0.2370	282.95	0.9837
0.4320	282.96	0.9861
0.6160	282.96	0.9868
0.6800	282.95	0.9898
0.8850	282.96	0.9911
0.9520	282.96	0.9900
0.9810	282.95	0.9911
0.9860	282.95	0.9946
0.0880	293.03	0.9644
0.1070	293.02	0.9650
0.1300	293.02	0.9624
0.1950	293.00	0.9715
0.2990	293.03	0.9775
0.3540	293.02	0.9789
0.5200	293.03	0.9818
0.8790	293.02	0.9861
0.9640	293.02	0.9918
0.9870	293.03	0.9951
0.0860	303.10	0.9625
0.2500	303.11	0.9793
0.3510	303.11	0.9807
0.3820	303.11	0.9770
0.5800	303.09	0.9801
0.6600	303.11	0.9798
0.7260	303.10	0.9788
0.8740	303.12	0.9820
0.9420	303.11	0.9810
0.9620	303.12	0.9859
0.9740	303.11	0.9914
0.0610	313.21	0.9640
0.2300	313.20	0.9748
0.3670	313.19	0.9749
0.4640	313.19	0.9762
0.5510	313.19	0.9730
0.6300	313.20	0.9706
0.7100	313.20	0.9722
0.8640	313.20	0.9735
0.9310	313.21	0.9688
0.9550	313.20	0.9615

Mole fraction of Fluoroform (2) [ref]

Fixed		Measured
Pressure, kPa - Liquid mixture 1	Temperature, K - Liquid mixture 1	Mole fraction of Fluoroform (2) - Liquid mixture 1
2324.00	272.87	0.4440

Mole fraction of Fluoroform (2) [ref]

Fixed		Measured
Pressure, kPa - Liquid mixture 2	Temperature, K - Liquid mixture 2	Mole fraction of Fluoroform (2) - Liquid mixture 2
2324.00	272.87	0.8730

Mole fraction of Fluoroform (2) [ref]

Fixed		Measured
Mole fraction of Fluoroform (2) - Liquid	Temperature, K - Liquid	Mole fraction of Fluoroform (2) - Gas
0.1730	272.86	0.9886
0.2430	272.85	0.9888
0.2550	272.86	0.9865
0.3350	272.87	0.9889
0.4440	272.87	0.9896
0.8730	272.87	0.9896
0.9530	272.87	0.9919
0.9800	272.87	0.9949
0.9870	272.86	0.9970
0.1010	282.95	0.9754
0.1620	282.95	0.9807
0.2250	282.94	0.9819
0.2370	282.95	0.9837
0.4320	282.96	0.9861
0.6160	282.96	0.9868
0.6800	282.95	0.9898
0.8850	282.96	0.9911
0.9520	282.96	0.9900
0.9810	282.95	0.9911
0.9860	282.95	0.9946
0.0880	293.03	0.9644
0.1070	293.02	0.9650
0.1300	293.02	0.9624
0.1950	293.00	0.9715
0.2990	293.03	0.9775
0.3540	293.02	0.9789
0.5200	293.03	0.9818
0.8790	293.02	0.9861
0.9640	293.02	0.9918
0.9870	293.03	0.9951
0.0860	303.10	0.9625
0.2500	303.11	0.9793
0.3510	303.11	0.9807
0.3820	303.11	0.9770
0.5800	303.09	0.9801
0.6600	303.11	0.9798
0.7260	303.10	0.9788
0.8740	303.12	0.9820
0.9420	303.11	0.9810
0.9620	303.12	0.9859
0.9740	303.11	0.9914
0.0610	313.21	0.9640
0.2300	313.20	0.9748
0.3670	313.19	0.9749
0.4640	313.19	0.9762
0.5510	313.19	0.9730
0.6300	313.20	0.9706
0.7100	313.20	0.9722
0.8640	313.20	0.9735
0.9310	313.21	0.9688
0.9550	313.20	0.9615

Mole fraction of Fluoroform (2) [ref]

Fixed		Measured
Pressure, kPa - Liquid mixture 1	Temperature, K - Liquid mixture 1	Mole fraction of Fluoroform (2) - Liquid mixture 1
2324.00	272.87	0.4440

Mole fraction of Fluoroform (2) [ref]

Fixed		Measured
Pressure, kPa - Liquid mixture 2	Temperature, K - Liquid mixture 2	Mole fraction of Fluoroform (2) - Liquid mixture 2
2324.00	272.87	0.8730

Critical pressure, kPa [ref]

Mole fraction of Fluoroform (2) - Liquid	Critical pressure, kPa - Liquid
0.1110	3660.00
0.3200	5340.00
0.5370	7910.00
0.6610	9180.00
0.7730	9820.00
0.8600	7980.00
0.9220	5950.00
0.9440	5410.00

Critical pressure, kPa [ref]

Mole fraction of Fluoroform (2) - Liquid	Critical pressure, kPa - Liquid
0.1110	3660.00
0.3200	5340.00
0.5370	7910.00
0.6610	9180.00
0.7730	9820.00
0.8600	7980.00
0.9220	5950.00
0.9440	5410.00

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Mole fraction of Fluoroform (2) - Liquid	Temperature, K - Liquid	Vapor or sublimation pressure, kPa - Liquid
0.1730	272.86	1545.00
0.2430	272.85	1891.00
0.2550	272.86	1943.00
0.3350	272.87	2167.00
0.4440	272.87	2324.00
0.8730	272.87	2324.00
0.9530	272.87	2396.00
0.9800	272.87	2436.00
0.9870	272.86	2469.00
0.1010	282.95	1197.00
0.1620	282.95	1693.00
0.2250	282.94	2114.00
0.2370	282.95	2196.00
0.4320	282.96	2798.00
0.6160	282.96	2906.00
0.6800	282.95	2908.00
0.8850	282.96	2948.00
0.9520	282.96	3071.00
0.9810	282.95	3149.00
0.9860	282.95	3189.00
0.0880	293.03	1192.00
0.1070	293.02	1395.00
0.1300	293.02	1623.00
0.1950	293.00	2201.00
0.2990	293.03	2872.00
0.3540	293.02	3116.00
0.5200	293.03	3491.00
0.8790	293.02	3681.00
0.9640	293.02	3943.00
0.9870	293.03	4065.00
0.0860	303.10	1270.00
0.2500	303.11	2925.00
0.3510	303.11	3589.00
0.3820	303.11	3744.00
0.5800	303.09	4256.00
0.6600	303.11	4333.00
0.7260	303.10	4380.00
0.8740	303.12	4500.00
0.9420	303.11	4726.00
0.9620	303.12	4884.00
0.9740	303.11	4929.00
0.0610	313.21	1060.00
0.2300	313.20	3059.00
0.3670	313.19	4156.00
0.4640	313.19	4634.00
0.5510	313.19	4942.00
0.6300	313.20	5099.00
0.7100	313.20	5209.00
0.8640	313.20	5381.00
0.9310	313.21	5590.00
0.9550	313.20	5770.00

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Fluoroform (2) - Liquid	Vapor or sublimation pressure, kPa - Liquid
293.17	0.1383	1669.20
293.15	0.4993	3456.90
293.14	0.7255	3600.30
293.16	0.8562	3671.00
303.16	0.1383	1761.00
303.17	0.4993	4075.70
303.13	0.7255	4373.60
303.18	0.8562	4503.80
313.17	0.1383	1904.30
313.21	0.4993	4721.30
313.16	0.7255	5233.20
313.23	0.8562	5425.10

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Mole fraction of Fluoroform (2) - Liquid	Temperature, K - Liquid	Vapor or sublimation pressure, kPa - Liquid
0.1730	272.86	1545.00
0.2430	272.85	1891.00
0.2550	272.86	1943.00
0.3350	272.87	2167.00
0.4440	272.87	2324.00
0.8730	272.87	2324.00
0.9530	272.87	2396.00
0.9800	272.87	2436.00
0.9870	272.86	2469.00
0.1010	282.95	1197.00
0.1620	282.95	1693.00
0.2250	282.94	2114.00
0.2370	282.95	2196.00
0.4320	282.96	2798.00
0.6160	282.96	2906.00
0.6800	282.95	2908.00
0.8850	282.96	2948.00
0.9520	282.96	3071.00
0.9810	282.95	3149.00
0.9860	282.95	3189.00
0.0880	293.03	1192.00
0.1070	293.02	1395.00
0.1300	293.02	1623.00
0.1950	293.00	2201.00
0.2990	293.03	2872.00
0.3540	293.02	3116.00
0.5200	293.03	3491.00
0.8790	293.02	3681.00
0.9640	293.02	3943.00
0.9870	293.03	4065.00
0.0860	303.10	1270.00
0.2500	303.11	2925.00
0.3510	303.11	3589.00
0.3820	303.11	3744.00
0.5800	303.09	4256.00
0.6600	303.11	4333.00
0.7260	303.10	4380.00
0.8740	303.12	4500.00
0.9420	303.11	4726.00
0.9620	303.12	4884.00
0.9740	303.11	4929.00
0.0610	313.21	1060.00
0.2300	313.20	3059.00
0.3670	313.19	4156.00
0.4640	313.19	4634.00
0.5510	313.19	4942.00
0.6300	313.20	5099.00
0.7100	313.20	5209.00
0.8640	313.20	5381.00
0.9310	313.21	5590.00
0.9550	313.20	5770.00

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Fluoroform (2) - Liquid	Vapor or sublimation pressure, kPa - Liquid
293.17	0.1383	1669.20
293.15	0.4993	3456.90
293.14	0.7255	3600.30
293.16	0.8562	3671.00
303.16	0.1383	1761.00
303.17	0.4993	4075.70
303.13	0.7255	4373.60
303.18	0.8562	4503.80
313.17	0.1383	1904.30
313.21	0.4993	4721.30
313.16	0.7255	5233.20
313.23	0.8562	5425.10

Critical temperature, K [ref]

Mole fraction of Fluoroform (2) - Liquid	Critical temperature, K - Liquid
0.1110	503.30
0.3200	486.90
0.5370	454.30
0.6610	427.80
0.7730	383.20
0.8600	343.00
0.9220	318.70
0.9440	310.80

Critical temperature, K [ref]

Mole fraction of Fluoroform (2) - Liquid	Critical temperature, K - Liquid
0.1110	503.30
0.3200	486.90
0.5370	454.30
0.6610	427.80
0.7730	383.20
0.8600	343.00
0.9220	318.70
0.9440	310.80

Sources

• Isothermal (vapour + liquid) equilibrium data for binary systems of (n-hexane + CO2 or CHF3)
• Experimental determination of the critical loci for R-23 + (npropane or n-hexane) and R-116 + n-propane binary mixtures