Mixture of Methyl formate + Methyl Alcohol

Excel

Methyl formate

Name
Methyl formate
InChI
InChI=1S/C2H4O2/c1-4-2-3/h2H,1H3
InChI Key
TZIHFWKZFHZASV-UHFFFAOYSA-N
Formula
C2H4O2
SMILES
COC=O
Mol. Weight (g/mol)
60.05
CAS
107-31-3

Methyl Alcohol

Name
Methyl Alcohol
InChI
InChI=1S/CH4O/c1-2/h2H,1H3
InChI Key
OKKJLVBELUTLKV-UHFFFAOYSA-N
Formula
CH4O
SMILES
CO
Mol. Weight (g/mol)
32.04
CAS
67-56-1
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Datasets

  1. Excess molar enthalpy (molar enthalpy (2)
  2. Pvap - Vapor or sublimation pressure, kPa (2)
  3. ρl - Mass density, kg/m3 (2)

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational conditions:

Mole fraction of Methyl formate (1) - Liquid Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.0200 0.0750
0.0487 0.1790
0.0833 0.3110
0.1225 0.4410
0.1670 0.5770
0.2135 0.7030
0.2613 0.8170
0.3086 0.9140
0.3501 0.9870
0.3644 1.01
0.3943 1.054
0.4077 1.074
0.4572 1.131
0.5127 1.179
0.5783 1.196
0.6460 1.178
0.7178 1.105
0.7842 0.9840
0.8517 0.8080
0.9098 0.5840
0.9505 0.3390

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational conditions:

Mole fraction of Methyl formate (1) - Liquid Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.0200 0.0750
0.0487 0.1790
0.0833 0.3110
0.1225 0.4410
0.1670 0.5770
0.2135 0.7030
0.2613 0.8170
0.3086 0.9140
0.3501 0.9870
0.3644 1.01
0.3943 1.054
0.4077 1.074
0.4572 1.131
0.5127 1.179
0.5783 1.196
0.6460 1.178
0.7178 1.105
0.7842 0.9840
0.8517 0.8080
0.9098 0.5840
0.9505 0.3390

Vapor or sublimation pressure, kPa [ref]

Fixed Measured
Temperature, K - Liquid Mole fraction of Methyl formate (1) - Liquid Vapor or sublimation pressure, kPa - Liquid
358.92 1.0000 550.40
358.93 0.0000 221.40
358.93 0.0976 321.20
358.93 0.2461 411.80
358.93 0.2959 432.90
358.93 0.3465 451.40
358.93 0.3961 467.10
358.93 0.4470 481.50
358.93 0.5482 504.80
358.93 0.9486 551.90
358.93 0.9690 551.80
358.93 0.9900 551.00
358.94 0.0108 235.90
358.94 0.0300 257.90
358.94 0.0488 277.70
358.94 0.1459 356.50
358.94 0.1962 386.90
358.94 0.4971 494.20
358.94 0.4988 494.20
358.94 0.5983 514.70
358.94 0.6483 523.40
358.94 0.6982 531.10
358.94 0.7484 537.90
358.94 0.7976 543.80
358.94 0.8486 548.30
358.94 0.8988 551.20

Vapor or sublimation pressure, kPa [ref]

Fixed Measured
Temperature, K - Liquid Mole fraction of Methyl formate (1) - Liquid Vapor or sublimation pressure, kPa - Liquid
358.92 1.0000 550.40
358.93 0.0000 221.40
358.93 0.0976 321.20
358.93 0.2461 411.80
358.93 0.2959 432.90
358.93 0.3465 451.40
358.93 0.3961 467.10
358.93 0.4470 481.50
358.93 0.5482 504.80
358.93 0.9486 551.90
358.93 0.9690 551.80
358.93 0.9900 551.00
358.94 0.0108 235.90
358.94 0.0300 257.90
358.94 0.0488 277.70
358.94 0.1459 356.50
358.94 0.1962 386.90
358.94 0.4971 494.20
358.94 0.4988 494.20
358.94 0.5983 514.70
358.94 0.6483 523.40
358.94 0.6982 531.10
358.94 0.7484 537.90
358.94 0.7976 543.80
358.94 0.8486 548.30
358.94 0.8988 551.20

Mass density, kg/m3 [ref]

Operational conditions:

Mole fraction of Methyl formate (1) - Liquid Mass density, kg/m3 - Liquid
0.0000 786.4
0.0337 795.73
0.0833 808.8
0.1557 826.74
0.1900 834.77
0.2499 848.14
0.3219 863.26
0.3906 876.73
0.4946 895.61
0.5416 903.58
0.6467 920.31
0.7271 932.1
0.7815 939.62
0.8533 949.01
0.8968 954.39
0.8968 954.39
0.9357 959.02
1.0000 966.28

Mass density, kg/m3 [ref]

Operational conditions:

Mole fraction of Methyl formate (1) - Liquid Mass density, kg/m3 - Liquid
0.0000 786.4
0.0337 795.73
0.0833 808.8
0.1557 826.74
0.1900 834.77
0.2499 848.14
0.3219 863.26
0.3906 876.73
0.4946 895.61
0.5416 903.58
0.6467 920.31
0.7271 932.1
0.7815 939.62
0.8533 949.01
0.8968 954.39
0.8968 954.39
0.9357 959.02
1.0000 966.28

Sources