Mixture of Cyclohexanone + Ethane, 1,1,2,2-tetrachloro-

Datasets

1. Azeotropic composition: mole fraction (4)
2. P_vap - Vapor or sublimation pressure, kPa (2)
3. ρ_l - Mass density, kg/m3 (2)
4. Azeotropic pressure, kPa (2)
5. Excess molar volume, m3/mol (2)

Azeotropic composition: mole fraction of Cyclohexanone (1) [ref]

Temperature, K - Liquid	Azeotropic composition: mole fraction of Cyclohexanone (1) - Liquid
343.15	0.6011
353.15	0.5983
363.15	0.6090

Mole fraction of Cyclohexanone (1) [ref]

Fixed		Measured
Mole fraction of Cyclohexanone (1) - Liquid	Temperature, K - Gas	Mole fraction of Cyclohexanone (1) - Gas
0.0000	343.15	0.0000
0.0000	353.15	0.0000
0.0695	343.15	0.0200
0.0723	353.15	0.0200
0.1446	343.15	0.0500
0.1474	353.15	0.0500
0.2229	343.15	0.0948
0.2256	353.15	0.0976
0.3117	353.15	0.1773
0.3142	343.15	0.1746
0.3921	343.15	0.2755
0.3946	353.15	0.2807
0.4577	343.15	0.3797
0.4577	353.15	0.3797
0.5281	343.15	0.5049
0.5281	353.15	0.5026
0.5915	343.15	0.6004
0.5915	353.15	0.5982
0.6462	353.15	0.6990
0.7032	343.15	0.7819
0.7094	353.15	0.7838
0.7779	343.15	0.8616
0.7779	353.15	0.8580
0.8337	343.15	0.9120
0.8356	353.15	0.9103
0.8871	343.15	0.9466
0.8907	353.15	0.9466
0.9312	343.15	0.9735
0.9312	353.15	0.9685
1.0000	343.15	1.0000
1.0000	353.15	1.0000

Azeotropic composition: mole fraction of Cyclohexanone (1) [ref]

Temperature, K - Liquid	Azeotropic composition: mole fraction of Cyclohexanone (1) - Liquid
343.15	0.6011
353.15	0.5983
363.15	0.6090

Mole fraction of Cyclohexanone (1) [ref]

Fixed		Measured
Mole fraction of Cyclohexanone (1) - Liquid	Temperature, K - Gas	Mole fraction of Cyclohexanone (1) - Gas
0.0000	343.15	0.0000
0.0000	353.15	0.0000
0.0695	343.15	0.0200
0.0723	353.15	0.0200
0.1446	343.15	0.0500
0.1474	353.15	0.0500
0.2229	343.15	0.0948
0.2256	353.15	0.0976
0.3117	353.15	0.1773
0.3142	343.15	0.1746
0.3921	343.15	0.2755
0.3946	353.15	0.2807
0.4577	343.15	0.3797
0.4577	353.15	0.3797
0.5281	343.15	0.5049
0.5281	353.15	0.5026
0.5915	343.15	0.6004
0.5915	353.15	0.5982
0.6462	353.15	0.6990
0.7032	343.15	0.7819
0.7094	353.15	0.7838
0.7779	343.15	0.8616
0.7779	353.15	0.8580
0.8337	343.15	0.9120
0.8356	353.15	0.9103
0.8871	343.15	0.9466
0.8907	353.15	0.9466
0.9312	343.15	0.9735
0.9312	353.15	0.9685
1.0000	343.15	1.0000
1.0000	353.15	1.0000

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Mole fraction of Cyclohexanone (1) - Liquid	Temperature, K - Liquid	Vapor or sublimation pressure, kPa - Liquid
0.0000	343.15	7.24
0.0000	353.15	11.23
0.0695	343.15	6.81
0.0723	353.15	10.43
0.1446	343.15	6.35
0.1474	353.15	9.77
0.2229	343.15	5.84
0.2256	353.15	8.92
0.3117	353.15	8.11
0.3142	343.15	5.23
0.3921	343.15	4.81
0.3946	353.15	7.48
0.4577	343.15	4.51
0.4577	353.15	7.07
0.5281	343.15	4.33
0.5281	353.15	6.81
0.5915	343.15	4.21
0.5915	353.15	6.81
0.6462	353.15	6.77
0.7032	343.15	4.41
0.7094	353.15	6.97
0.7779	343.15	4.59
0.7779	353.15	7.20
0.8337	343.15	4.80
0.8356	353.15	7.56
0.8871	343.15	5.03
0.8907	353.15	7.87
0.9312	343.15	5.25
0.9312	353.15	8.12
1.0000	343.15	5.57
1.0000	353.15	8.60

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Mole fraction of Cyclohexanone (1) - Liquid	Temperature, K - Liquid	Vapor or sublimation pressure, kPa - Liquid
0.0000	343.15	7.24
0.0000	353.15	11.23
0.0695	343.15	6.81
0.0723	353.15	10.43
0.1446	343.15	6.35
0.1474	353.15	9.77
0.2229	343.15	5.84
0.2256	353.15	8.92
0.3117	353.15	8.11
0.3142	343.15	5.23
0.3921	343.15	4.81
0.3946	353.15	7.48
0.4577	343.15	4.51
0.4577	353.15	7.07
0.5281	343.15	4.33
0.5281	353.15	6.81
0.5915	343.15	4.21
0.5915	353.15	6.81
0.6462	353.15	6.77
0.7032	343.15	4.41
0.7094	353.15	6.97
0.7779	343.15	4.59
0.7779	353.15	7.20
0.8337	343.15	4.80
0.8356	353.15	7.56
0.8871	343.15	5.03
0.8907	353.15	7.87
0.9312	343.15	5.25
0.9312	353.15	8.12
1.0000	343.15	5.57
1.0000	353.15	8.60

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Ethane, 1,1,2,2-tetrachloro- (2) - Liquid	Mass density, kg/m3 - Liquid
288.15	0.0000	951.69
288.15	0.1147	1029.34
288.15	0.2121	1094.87
288.15	0.3045	1156.78
288.15	0.4052	1223.8
288.15	0.4996	1286.07
288.15	0.5909	1345.8
288.15	0.6868	1407.73
288.15	0.7820	1468.5
288.15	0.8798	1530.11
288.15	1.0000	1604.75
298.15	0.0000	942.76
298.15	0.1147	1019.79
298.15	0.2121	1084.77
298.15	0.3045	1146.13
298.15	0.4052	1212.52
298.15	0.4996	1274.18
298.15	0.5909	1333.31
298.15	0.6868	1394.58
298.15	0.7820	1454.64
298.15	0.8798	1515.52
298.15	1.0000	1589.18
308.15	0.0000	933.8
308.15	0.1147	1010.2
308.15	0.2121	1074.62
308.15	0.3045	1135.43
308.15	0.4052	1201.2
308.15	0.4996	1262.26
308.15	0.5909	1320.77
308.15	0.6868	1381.38
308.15	0.7820	1440.76
308.15	0.8798	1500.89
308.15	1.0000	1573.57
318.15	0.0000	924.82
318.15	0.1147	1000.58
318.15	0.2121	1064.44
318.15	0.3045	1124.7
318.15	0.4052	1189.84
318.15	0.4996	1250.3
318.15	0.5909	1308.2
318.15	0.6868	1368.14
318.15	0.7820	1426.83
318.15	0.8798	1486.23
318.15	1.0000	1557.94

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Ethane, 1,1,2,2-tetrachloro- (2) - Liquid	Mass density, kg/m3 - Liquid
288.15	0.0000	951.69
288.15	0.1147	1029.34
288.15	0.2121	1094.87
288.15	0.3045	1156.78
288.15	0.4052	1223.8
288.15	0.4996	1286.07
288.15	0.5909	1345.8
288.15	0.6868	1407.73
288.15	0.7820	1468.5
288.15	0.8798	1530.11
288.15	1.0000	1604.75
298.15	0.0000	942.76
298.15	0.1147	1019.79
298.15	0.2121	1084.77
298.15	0.3045	1146.13
298.15	0.4052	1212.52
298.15	0.4996	1274.18
298.15	0.5909	1333.31
298.15	0.6868	1394.58
298.15	0.7820	1454.64
298.15	0.8798	1515.52
298.15	1.0000	1589.18
308.15	0.0000	933.8
308.15	0.1147	1010.2
308.15	0.2121	1074.62
308.15	0.3045	1135.43
308.15	0.4052	1201.2
308.15	0.4996	1262.26
308.15	0.5909	1320.77
308.15	0.6868	1381.38
308.15	0.7820	1440.76
308.15	0.8798	1500.89
308.15	1.0000	1573.57
318.15	0.0000	924.82
318.15	0.1147	1000.58
318.15	0.2121	1064.44
318.15	0.3045	1124.7
318.15	0.4052	1189.84
318.15	0.4996	1250.3
318.15	0.5909	1308.2
318.15	0.6868	1368.14
318.15	0.7820	1426.83
318.15	0.8798	1486.23
318.15	1.0000	1557.94

Azeotropic pressure, kPa [ref]

Temperature, K - Liquid	Azeotropic pressure, kPa - Liquid
343.15	4.30
353.15	6.78
363.15	10.44

Azeotropic pressure, kPa [ref]

Temperature, K - Liquid	Azeotropic pressure, kPa - Liquid
343.15	4.30
353.15	6.78
363.15	10.44

Excess molar volume, m3/mol [ref]

Fixed		Measured
Mole fraction of Cyclohexanone (1) - Liquid	Temperature, K - Liquid	Excess molar volume, m3/mol - Liquid
0.0548	288.15	-8.2000e-08
0.1103	288.15	-1.6740e-07
0.1612	288.15	-2.2480e-07
0.2162	288.15	-3.0920e-07
0.2603	288.15	-3.5080e-07
0.3207	288.15	-4.1000e-07
0.3721	288.15	-4.3650e-07
0.4232	288.15	-4.6950e-07
0.4725	288.15	-4.7710e-07
0.5243	288.15	-4.7490e-07
0.5735	288.15	-4.6950e-07
0.6229	288.15	-4.5300e-07
0.6719	288.15	-4.2870e-07
0.7195	288.15	-3.9140e-07
0.7673	288.15	-3.4630e-07
0.8146	288.15	-2.9700e-07
0.8619	288.15	-2.4770e-07
0.9080	288.15	-1.7570e-07
0.9542	288.15	-9.5700e-08
0.0548	293.15	-8.5800e-08
0.1103	293.15	-1.7440e-07
0.1612	293.15	-2.3310e-07
0.2162	293.15	-3.2080e-07
0.2603	293.15	-3.6210e-07
0.3207	293.15	-4.3060e-07
0.3721	293.15	-4.5020e-07
0.4232	293.15	-4.8640e-07
0.4725	293.15	-4.9290e-07
0.5243	293.15	-4.9250e-07
0.5735	293.15	-4.8710e-07
0.6229	293.15	-4.7010e-07
0.6719	293.15	-4.4500e-07
0.7195	293.15	-4.0660e-07
0.7673	293.15	-3.6010e-07
0.8146	293.15	-3.0910e-07
0.8619	293.15	-2.5750e-07
0.9080	293.15	-1.8280e-07
0.9542	293.15	-9.9500e-08
0.0548	298.15	-8.9100e-08
0.1103	298.15	-1.8040e-07
0.1612	298.15	-2.4190e-07
0.2162	298.15	-3.3240e-07
0.2603	298.15	-3.7610e-07
0.3207	298.15	-4.4950e-07
0.3721	298.15	-4.6750e-07
0.4232	298.15	-5.0360e-07
0.4725	298.15	-5.1150e-07
0.5243	298.15	-5.1040e-07
0.5735	298.15	-5.0450e-07
0.6229	298.15	-4.8730e-07
0.6719	298.15	-4.6160e-07
0.7195	298.15	-4.2190e-07
0.7673	298.15	-3.7330e-07
0.8146	298.15	-3.2040e-07
0.8619	298.15	-2.6700e-07
0.9080	298.15	-1.8940e-07
0.9542	298.15	-1.0300e-07
0.0548	303.15	-9.2900e-08
0.1103	303.15	-1.8790e-07
0.1612	303.15	-2.5110e-07
0.2162	303.15	-3.4420e-07
0.2603	303.15	-3.8920e-07
0.3207	303.15	-4.6470e-07
0.3721	303.15	-4.8330e-07
0.4232	303.15	-5.2070e-07
0.4725	303.15	-5.2880e-07
0.5243	303.15	-5.2770e-07
0.5735	303.15	-5.2260e-07
0.6229	303.15	-5.0450e-07
0.6719	303.15	-4.7780e-07
0.7195	303.15	-4.3730e-07
0.7673	303.15	-3.8750e-07
0.8146	303.15	-3.3230e-07
0.8619	303.15	-2.7660e-07
0.9080	303.15	-1.9630e-07
0.9542	303.15	-1.0670e-07
0.0548	308.15	-9.6400e-08
0.1103	308.15	-1.9460e-07
0.1612	308.15	-2.5970e-07
0.2162	308.15	-3.5560e-07
0.2603	308.15	-4.0200e-07
0.3207	308.15	-4.7970e-07
0.3721	308.15	-4.9900e-07
0.4232	308.15	-5.3780e-07
0.4725	308.15	-5.4630e-07
0.5243	308.15	-5.4560e-07
0.5735	308.15	-5.4060e-07
0.6229	308.15	-5.2170e-07
0.6719	308.15	-4.9400e-07
0.7195	308.15	-4.5240e-07
0.7673	308.15	-4.0120e-07
0.8146	308.15	-3.4380e-07
0.8619	308.15	-2.8600e-07
0.9080	308.15	-2.0290e-07
0.9542	308.15	-1.1030e-07
0.0548	313.15	-9.9900e-08
0.1103	313.15	-2.0140e-07
0.1612	313.15	-2.6860e-07
0.2162	313.15	-3.6750e-07
0.2603	313.15	-4.1530e-07
0.3207	313.15	-4.9550e-07
0.3721	313.15	-5.1540e-07
0.4232	313.15	-5.5510e-07
0.4725	313.15	-5.6420e-07
0.5243	313.15	-5.6430e-07
0.5735	313.15	-5.5850e-07
0.6229	313.15	-5.3900e-07
0.6719	313.15	-5.1050e-07
0.7195	313.15	-4.6770e-07
0.7673	313.15	-4.1500e-07
0.8146	313.15	-3.5590e-07
0.8619	313.15	-2.9560e-07
0.9080	313.15	-2.0980e-07
0.9542	313.15	-1.1400e-07

Excess molar volume, m3/mol [ref]

Fixed		Measured
Mole fraction of Cyclohexanone (1) - Liquid	Temperature, K - Liquid	Excess molar volume, m3/mol - Liquid
0.0548	288.15	-8.2000e-08
0.1103	288.15	-1.6740e-07
0.1612	288.15	-2.2480e-07
0.2162	288.15	-3.0920e-07
0.2603	288.15	-3.5080e-07
0.3207	288.15	-4.1000e-07
0.3721	288.15	-4.3650e-07
0.4232	288.15	-4.6950e-07
0.4725	288.15	-4.7710e-07
0.5243	288.15	-4.7490e-07
0.5735	288.15	-4.6950e-07
0.6229	288.15	-4.5300e-07
0.6719	288.15	-4.2870e-07
0.7195	288.15	-3.9140e-07
0.7673	288.15	-3.4630e-07
0.8146	288.15	-2.9700e-07
0.8619	288.15	-2.4770e-07
0.9080	288.15	-1.7570e-07
0.9542	288.15	-9.5700e-08
0.0548	293.15	-8.5800e-08
0.1103	293.15	-1.7440e-07
0.1612	293.15	-2.3310e-07
0.2162	293.15	-3.2080e-07
0.2603	293.15	-3.6210e-07
0.3207	293.15	-4.3060e-07
0.3721	293.15	-4.5020e-07
0.4232	293.15	-4.8640e-07
0.4725	293.15	-4.9290e-07
0.5243	293.15	-4.9250e-07
0.5735	293.15	-4.8710e-07
0.6229	293.15	-4.7010e-07
0.6719	293.15	-4.4500e-07
0.7195	293.15	-4.0660e-07
0.7673	293.15	-3.6010e-07
0.8146	293.15	-3.0910e-07
0.8619	293.15	-2.5750e-07
0.9080	293.15	-1.8280e-07
0.9542	293.15	-9.9500e-08
0.0548	298.15	-8.9100e-08
0.1103	298.15	-1.8040e-07
0.1612	298.15	-2.4190e-07
0.2162	298.15	-3.3240e-07
0.2603	298.15	-3.7610e-07
0.3207	298.15	-4.4950e-07
0.3721	298.15	-4.6750e-07
0.4232	298.15	-5.0360e-07
0.4725	298.15	-5.1150e-07
0.5243	298.15	-5.1040e-07
0.5735	298.15	-5.0450e-07
0.6229	298.15	-4.8730e-07
0.6719	298.15	-4.6160e-07
0.7195	298.15	-4.2190e-07
0.7673	298.15	-3.7330e-07
0.8146	298.15	-3.2040e-07
0.8619	298.15	-2.6700e-07
0.9080	298.15	-1.8940e-07
0.9542	298.15	-1.0300e-07
0.0548	303.15	-9.2900e-08
0.1103	303.15	-1.8790e-07
0.1612	303.15	-2.5110e-07
0.2162	303.15	-3.4420e-07
0.2603	303.15	-3.8920e-07
0.3207	303.15	-4.6470e-07
0.3721	303.15	-4.8330e-07
0.4232	303.15	-5.2070e-07
0.4725	303.15	-5.2880e-07
0.5243	303.15	-5.2770e-07
0.5735	303.15	-5.2260e-07
0.6229	303.15	-5.0450e-07
0.6719	303.15	-4.7780e-07
0.7195	303.15	-4.3730e-07
0.7673	303.15	-3.8750e-07
0.8146	303.15	-3.3230e-07
0.8619	303.15	-2.7660e-07
0.9080	303.15	-1.9630e-07
0.9542	303.15	-1.0670e-07
0.0548	308.15	-9.6400e-08
0.1103	308.15	-1.9460e-07
0.1612	308.15	-2.5970e-07
0.2162	308.15	-3.5560e-07
0.2603	308.15	-4.0200e-07
0.3207	308.15	-4.7970e-07
0.3721	308.15	-4.9900e-07
0.4232	308.15	-5.3780e-07
0.4725	308.15	-5.4630e-07
0.5243	308.15	-5.4560e-07
0.5735	308.15	-5.4060e-07
0.6229	308.15	-5.2170e-07
0.6719	308.15	-4.9400e-07
0.7195	308.15	-4.5240e-07
0.7673	308.15	-4.0120e-07
0.8146	308.15	-3.4380e-07
0.8619	308.15	-2.8600e-07
0.9080	308.15	-2.0290e-07
0.9542	308.15	-1.1030e-07
0.0548	313.15	-9.9900e-08
0.1103	313.15	-2.0140e-07
0.1612	313.15	-2.6860e-07
0.2162	313.15	-3.6750e-07
0.2603	313.15	-4.1530e-07
0.3207	313.15	-4.9550e-07
0.3721	313.15	-5.1540e-07
0.4232	313.15	-5.5510e-07
0.4725	313.15	-5.6420e-07
0.5243	313.15	-5.6430e-07
0.5735	313.15	-5.5850e-07
0.6229	313.15	-5.3900e-07
0.6719	313.15	-5.1050e-07
0.7195	313.15	-4.6770e-07
0.7673	313.15	-4.1500e-07
0.8146	313.15	-3.5590e-07
0.8619	313.15	-2.9560e-07
0.9080	313.15	-2.0980e-07
0.9542	313.15	-1.1400e-07

Sources

• Isothermal (vapour + liquid) equilibria for the binary (cyclopentanone or cyclohexanone with 1,1,2,2-tetrachloroethane) systems at temperatures of (343.15, 353.15, and 363.15) K
• Volumetric properties of binary liquid mixtures of ketones with chloroalkanes at different temperatures and atmospheric pressure
• Densities and Excess Molar Volumes of the Binary Mixtures of Cyclohexanone with Chloroalkanes at Temperatures between (288.15 and 318.15) K