Mixture of Methyl propionate + Nonane

Datasets

1. Mole fraction (2)
2. Excess molar enthalpy (molar enthalpy (2)
3. ρ_l - Mass density, kg/m3 (2)
4. T_boil - Boiling temperature at pressure P, K (2)
5. Excess molar volume, m3/mol (2)

Mole fraction of Methyl propionate (1) [ref]

Operational condition: Pressure, kPa = 101.32 (Liquid)

Mole fraction of Methyl propionate (1) - Liquid	Mole fraction of Methyl propionate (1) - Gas
0.0000	0.0000
0.0100	0.0760
0.0200	0.1490
0.0400	0.2710
0.0590	0.3660
0.0790	0.4530
0.0940	0.5060
0.1100	0.5520
0.1330	0.6080
0.1470	0.6340
0.1830	0.6990
0.2110	0.7350
0.2420	0.7620
0.2800	0.7940
0.3160	0.8180
0.3700	0.8460
0.4100	0.8630
0.4540	0.8770
0.4920	0.8900
0.5330	0.9020
0.5680	0.9100
0.6100	0.9190
0.6360	0.9240
0.6740	0.9320
0.7160	0.9390
0.7490	0.9460
0.7800	0.9520
0.8040	0.9570
0.8180	0.9600
0.8340	0.9630
0.8440	0.9650
0.8640	0.9680
0.8690	0.9690
0.8960	0.9750
0.9200	0.9800
0.9330	0.9830
0.9460	0.9860
0.9560	0.9880
0.9660	0.9900
0.9740	0.9920
0.9820	0.9950
0.9890	0.9960
0.9930	0.9980
1.0000	1.0000

Mole fraction of Methyl propionate (1) [ref]

Operational condition: Pressure, kPa = 101.32 (Liquid)

Mole fraction of Methyl propionate (1) - Liquid	Mole fraction of Methyl propionate (1) - Gas
0.0000	0.0000
0.0100	0.0760
0.0200	0.1490
0.0400	0.2710
0.0590	0.3660
0.0790	0.4530
0.0940	0.5060
0.1100	0.5520
0.1330	0.6080
0.1470	0.6340
0.1830	0.6990
0.2110	0.7350
0.2420	0.7620
0.2800	0.7940
0.3160	0.8180
0.3700	0.8460
0.4100	0.8630
0.4540	0.8770
0.4920	0.8900
0.5330	0.9020
0.5680	0.9100
0.6100	0.9190
0.6360	0.9240
0.6740	0.9320
0.7160	0.9390
0.7490	0.9460
0.7800	0.9520
0.8040	0.9570
0.8180	0.9600
0.8340	0.9630
0.8440	0.9650
0.8640	0.9680
0.8690	0.9690
0.8960	0.9750
0.9200	0.9800
0.9330	0.9830
0.9460	0.9860
0.9560	0.9880
0.9660	0.9900
0.9740	0.9920
0.9820	0.9950
0.9890	0.9960
0.9930	0.9980
1.0000	1.0000

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational conditions:

• Pressure, kPa = 101 (Liquid)
• Temperature, K = 318.15 (Liquid)

Mole fraction of Methyl propionate (1) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.0840	0.4626
0.1528	0.7940
0.2279	1.094
0.2957	1.3111
0.3549	1.4628
0.4111	1.5709
0.4611	1.636
0.5059	1.6742
0.5460	1.6827
0.5832	1.6708
0.6314	1.6151
0.6645	1.5529
0.7099	1.4451
0.7579	1.3031
0.8080	1.1203
0.8604	0.8891
0.9122	0.6206
0.9599	0.3217

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational conditions:

• Pressure, kPa = 101 (Liquid)
• Temperature, K = 318.15 (Liquid)

Mole fraction of Methyl propionate (1) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.0840	0.4626
0.1528	0.7940
0.2279	1.094
0.2957	1.3111
0.3549	1.4628
0.4111	1.5709
0.4611	1.636
0.5059	1.6742
0.5460	1.6827
0.5832	1.6708
0.6314	1.6151
0.6645	1.5529
0.7099	1.4451
0.7579	1.3031
0.8080	1.1203
0.8604	0.8891
0.9122	0.6206
0.9599	0.3217

Mass density, kg/m3 [ref]

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Methyl propionate (1) - Liquid	Mass density, kg/m3 - Liquid
288.15	0.0000	721.65
288.15	0.0638	727.45
288.15	0.0962	730.67
288.15	0.1483	736.11
288.15	0.2104	743.23
288.15	0.2364	746.3
288.15	0.2979	754.2
288.15	0.3526	761.75
288.15	0.4001	768.71
288.15	0.4322	773.78
288.15	0.4985	784.9
288.15	0.5504	794.42
288.15	0.5954	803.25
288.15	0.6449	813.66
288.15	0.6930	824.65
288.15	0.7454	837.57
288.15	0.7911	849.84
288.15	0.8391	863.79
288.15	0.8911	880.25
288.15	0.9477	900.31
288.15	1.0000	921.21
298.15	0.0000	713.85
298.15	0.0519	718.48
298.15	0.1041	723.58
298.15	0.1448	727.66
298.15	0.1889	732.52
298.15	0.2498	739.65
298.15	0.2949	745.26
298.15	0.3489	752.48
298.15	0.4090	761.11
298.15	0.4474	767.1
298.15	0.5033	776.37
298.15	0.6015	794.61
298.15	0.6609	807.17
298.15	0.7048	817.21
298.15	0.7510	828.64
298.15	0.7937	839.79
298.15	0.8444	854.36
298.15	0.9002	871.96
298.15	0.9516	890.02
298.15	1.0000	909.1
308.15	0.0000	705.96
308.15	0.0618	711.31
308.15	0.1007	715.02
308.15	0.1650	721.49
308.15	0.1941	724.61
308.15	0.2601	732.22
308.15	0.2902	735.94
308.15	0.3585	744.82
308.15	0.4102	752.25
308.15	0.4567	759.29
308.15	0.4962	765.69
308.15	0.5559	776.15
308.15	0.5986	784.17
308.15	0.6514	794.91
308.15	0.6990	805.43
308.15	0.7476	817.03
308.15	0.7960	829.48
308.15	0.8477	844.14
308.15	0.8947	858.8
308.15	0.9504	877.94
308.15	1.0000	896.91
318.15	0.0000	698.06
318.15	0.0587	703.05
318.15	0.1139	708.17
318.15	0.1410	710.78
318.15	0.2148	718.51
318.15	0.2624	723.9
318.15	0.3145	730.23
318.15	0.3621	736.39
318.15	0.3940	740.75
318.15	0.4491	748.79
318.15	0.4889	755.06
318.15	0.5458	764.61
318.15	0.6011	774.72
318.15	0.6538	785.15
318.15	0.6972	794.52
318.15	0.7464	805.96
318.15	0.7904	816.99
318.15	0.8414	831.04
318.15	0.8899	845.62
318.15	0.9498	865.72
318.15	1.0000	884.71
328.15	0.0000	690.17
328.15	0.0562	694.8
328.15	0.0989	698.61
328.15	0.1503	703.45
328.15	0.1813	706.43
328.15	0.1940	707.71
328.15	0.2651	715.48
328.15	0.3128	721.06
328.15	0.3582	726.72
328.15	0.4509	739.58
328.15	0.5045	747.9
328.15	0.5545	756.22
328.15	0.6005	764.42
328.15	0.6523	774.55
328.15	0.7484	795.44
328.15	0.7963	807.38
328.15	0.8469	821.01
328.15	0.9004	836.96
328.15	0.9501	853.63
328.15	1.0000	872.22

Mass density, kg/m3 [ref]

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Methyl propionate (1) - Liquid	Mass density, kg/m3 - Liquid
288.15	0.0000	721.65
288.15	0.0638	727.45
288.15	0.0962	730.67
288.15	0.1483	736.11
288.15	0.2104	743.23
288.15	0.2364	746.3
288.15	0.2979	754.2
288.15	0.3526	761.75
288.15	0.4001	768.71
288.15	0.4322	773.78
288.15	0.4985	784.9
288.15	0.5504	794.42
288.15	0.5954	803.25
288.15	0.6449	813.66
288.15	0.6930	824.65
288.15	0.7454	837.57
288.15	0.7911	849.84
288.15	0.8391	863.79
288.15	0.8911	880.25
288.15	0.9477	900.31
288.15	1.0000	921.21
298.15	0.0000	713.85
298.15	0.0519	718.48
298.15	0.1041	723.58
298.15	0.1448	727.66
298.15	0.1889	732.52
298.15	0.2498	739.65
298.15	0.2949	745.26
298.15	0.3489	752.48
298.15	0.4090	761.11
298.15	0.4474	767.1
298.15	0.5033	776.37
298.15	0.6015	794.61
298.15	0.6609	807.17
298.15	0.7048	817.21
298.15	0.7510	828.64
298.15	0.7937	839.79
298.15	0.8444	854.36
298.15	0.9002	871.96
298.15	0.9516	890.02
298.15	1.0000	909.1
308.15	0.0000	705.96
308.15	0.0618	711.31
308.15	0.1007	715.02
308.15	0.1650	721.49
308.15	0.1941	724.61
308.15	0.2601	732.22
308.15	0.2902	735.94
308.15	0.3585	744.82
308.15	0.4102	752.25
308.15	0.4567	759.29
308.15	0.4962	765.69
308.15	0.5559	776.15
308.15	0.5986	784.17
308.15	0.6514	794.91
308.15	0.6990	805.43
308.15	0.7476	817.03
308.15	0.7960	829.48
308.15	0.8477	844.14
308.15	0.8947	858.8
308.15	0.9504	877.94
308.15	1.0000	896.91
318.15	0.0000	698.06
318.15	0.0587	703.05
318.15	0.1139	708.17
318.15	0.1410	710.78
318.15	0.2148	718.51
318.15	0.2624	723.9
318.15	0.3145	730.23
318.15	0.3621	736.39
318.15	0.3940	740.75
318.15	0.4491	748.79
318.15	0.4889	755.06
318.15	0.5458	764.61
318.15	0.6011	774.72
318.15	0.6538	785.15
318.15	0.6972	794.52
318.15	0.7464	805.96
318.15	0.7904	816.99
318.15	0.8414	831.04
318.15	0.8899	845.62
318.15	0.9498	865.72
318.15	1.0000	884.71
328.15	0.0000	690.17
328.15	0.0562	694.8
328.15	0.0989	698.61
328.15	0.1503	703.45
328.15	0.1813	706.43
328.15	0.1940	707.71
328.15	0.2651	715.48
328.15	0.3128	721.06
328.15	0.3582	726.72
328.15	0.4509	739.58
328.15	0.5045	747.9
328.15	0.5545	756.22
328.15	0.6005	764.42
328.15	0.6523	774.55
328.15	0.7484	795.44
328.15	0.7963	807.38
328.15	0.8469	821.01
328.15	0.9004	836.96
328.15	0.9501	853.63
328.15	1.0000	872.22

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 101.32 (Liquid)

Mole fraction of Methyl propionate (1) - Liquid	Boiling temperature at pressure P, K - Liquid
0.0000	423.90
0.0100	420.88
0.0200	418.00
0.0400	412.86
0.0590	408.40
0.0790	403.88
0.0940	400.83
0.1100	398.08
0.1330	394.50
0.1470	392.60
0.1830	387.71
0.2110	384.71
0.2420	382.29
0.2800	379.14
0.3160	376.09
0.3700	372.60
0.4100	370.15
0.4540	368.03
0.4920	366.24
0.5330	364.62
0.5680	363.30
0.6100	361.90
0.6360	361.07
0.6740	360.03
0.7160	358.96
0.7490	358.14
0.7800	357.41
0.8040	356.75
0.8180	356.34
0.8340	356.12
0.8440	355.89
0.8640	355.53
0.8690	355.40
0.8960	354.85
0.9200	354.39
0.9330	354.13
0.9460	353.89
0.9560	353.69
0.9660	353.53
0.9740	353.37
0.9820	353.17
0.9890	352.99
0.9930	352.79
1.0000	352.75

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 101.32 (Liquid)

Mole fraction of Methyl propionate (1) - Liquid	Boiling temperature at pressure P, K - Liquid
0.0000	423.90
0.0100	420.88
0.0200	418.00
0.0400	412.86
0.0590	408.40
0.0790	403.88
0.0940	400.83
0.1100	398.08
0.1330	394.50
0.1470	392.60
0.1830	387.71
0.2110	384.71
0.2420	382.29
0.2800	379.14
0.3160	376.09
0.3700	372.60
0.4100	370.15
0.4540	368.03
0.4920	366.24
0.5330	364.62
0.5680	363.30
0.6100	361.90
0.6360	361.07
0.6740	360.03
0.7160	358.96
0.7490	358.14
0.7800	357.41
0.8040	356.75
0.8180	356.34
0.8340	356.12
0.8440	355.89
0.8640	355.53
0.8690	355.40
0.8960	354.85
0.9200	354.39
0.9330	354.13
0.9460	353.89
0.9560	353.69
0.9660	353.53
0.9740	353.37
0.9820	353.17
0.9890	352.99
0.9930	352.79
1.0000	352.75

Excess molar volume, m3/mol [ref]

Operational conditions:

• Pressure, kPa = 101 (Liquid)
• Temperature, K = 318.15 (Liquid)

Mole fraction of Methyl propionate (1) - Liquid	Excess molar volume, m3/mol - Liquid
0.0470	2.8000e-07
0.1110	5.7000e-07
0.2022	9.2700e-07
0.2873	1.1640e-06
0.3671	1.3330e-06
0.4381	1.4060e-06
0.5037	1.4250e-06
0.5664	1.4230e-06
0.6242	1.3590e-06
0.6768	1.2780e-06
0.7271	1.1660e-06
0.7724	1.0370e-06
0.8170	8.7800e-07
0.8560	7.5000e-07
0.8960	5.8900e-07
0.9315	3.9300e-07
0.9661	1.9800e-07

Excess molar volume, m3/mol [ref]

Operational conditions:

• Pressure, kPa = 101 (Liquid)
• Temperature, K = 318.15 (Liquid)

Mole fraction of Methyl propionate (1) - Liquid	Excess molar volume, m3/mol - Liquid
0.0470	2.8000e-07
0.1110	5.7000e-07
0.2022	9.2700e-07
0.2873	1.1640e-06
0.3671	1.3330e-06
0.4381	1.4060e-06
0.5037	1.4250e-06
0.5664	1.4230e-06
0.6242	1.3590e-06
0.6768	1.2780e-06
0.7271	1.1660e-06
0.7724	1.0370e-06
0.8170	8.7800e-07
0.8560	7.5000e-07
0.8960	5.8900e-07
0.9315	3.9300e-07
0.9661	1.9800e-07

Sources

• Thermodynamic properties of (an ester + and alkane). XVII. Experimental He and Ve values for (an alkyl propanoate + an alkane) at 318.15K
• Improvements in the Experimentation and the Representation of Thermodynamic Properties (iso-p VLE and yE) of Alkyl Propanoate + Alkane Binaries