Mixture of 1-Butanol, 3-methyl- + Water

Datasets

1. Activity coefficient (2)
2. Mole fraction (14)
3. T_boil - Boiling temperature at pressure P, K (4)

Activity coefficient of 1-Butanol, 3-methyl- (1) [ref]

Operational conditions:

• Pressure, kPa = 101 (Liquid)
• Mole fraction = 0 (Liquid)

Temperature, K - Liquid	Activity coefficient of 1-Butanol, 3-methyl- (1) - Liquid
273.35	94.9
283.15	126.0
293.15	148.0
293.15	146.0
303.15	161.0
303.15	164.0
313.15	173.0
313.15	175.0
323.15	179.0
323.15	184.0
333.15	182.0
333.15	178.0
343.15	179.0
353.15	164.0
371.15	149.0

Activity coefficient of 1-Butanol, 3-methyl- (1) [ref]

Operational conditions:

• Pressure, kPa = 101 (Liquid)
• Mole fraction = 0 (Liquid)

Temperature, K - Liquid	Activity coefficient of 1-Butanol, 3-methyl- (1) - Liquid
273.35	94.9
283.15	126.0
293.15	148.0
293.15	146.0
303.15	161.0
303.15	164.0
313.15	173.0
313.15	175.0
323.15	179.0
323.15	184.0
333.15	182.0
333.15	178.0
343.15	179.0
353.15	164.0
371.15	149.0

Mole fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 95 (Liquid mixture 1)

Temperature, K - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 1
293.20	0.3283
293.20	0.9941
313.20	0.3461
313.20	0.9950

Mass fraction of 1-Butanol, 3-methyl- (1) [ref]

Operational condition: Pressure, kPa = 100.41 (Liquid mixture 1)

Temperature, K - Liquid mixture 1	Mass fraction of 1-Butanol, 3-methyl- (1) - Liquid mixture 1
288.20	0.9022
298.20	0.9019
308.20	0.8953
318.20	0.8835

Mass fraction of 1-Butanol, 3-methyl- (1) [ref]

Operational condition: Pressure, kPa = 100.41 (Liquid mixture 1)

Temperature, K - Liquid mixture 1	Mass fraction of 1-Butanol, 3-methyl- (1) - Liquid mixture 2
288.20	0.0253
298.20	0.0219
308.20	0.0202
318.20	0.0184

Mole fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid mixture 2)

Temperature, K - Liquid mixture 2	Mole fraction of Water (2) - Liquid mixture 1
303.15	0.2990
313.15	0.3080
368.06	0.4460

Mole fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid mixture 2)

Temperature, K - Liquid mixture 2	Mole fraction of Water (2) - Liquid mixture 2
303.15	0.9950
313.15	0.9950
368.06	0.9950

Mole fraction of 1-Butanol, 3-methyl- (1) [ref]

Fixed		Measured
Pressure, kPa - Liquid mixture 1	Temperature, K - Liquid mixture 1	Mole fraction of 1-Butanol, 3-methyl- (1) - Liquid mixture 1
101.00	293.15	0.6620

Mole fraction of 1-Butanol, 3-methyl- (1) [ref]

Fixed		Measured
Temperature, K - Liquid mixture 1	Pressure, kPa - Liquid mixture 1	Mole fraction of 1-Butanol, 3-methyl- (1) - Liquid mixture 2
293.15	101.00	0.0060

Mole fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 95 (Liquid mixture 1)

Temperature, K - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 1
293.20	0.3283
293.20	0.9941
313.20	0.3461
313.20	0.9950

Mass fraction of 1-Butanol, 3-methyl- (1) [ref]

Operational condition: Pressure, kPa = 100.41 (Liquid mixture 1)

Temperature, K - Liquid mixture 1	Mass fraction of 1-Butanol, 3-methyl- (1) - Liquid mixture 1
288.20	0.9022
298.20	0.9019
308.20	0.8953
318.20	0.8835

Mass fraction of 1-Butanol, 3-methyl- (1) [ref]

Operational condition: Pressure, kPa = 100.41 (Liquid mixture 1)

Temperature, K - Liquid mixture 1	Mass fraction of 1-Butanol, 3-methyl- (1) - Liquid mixture 2
288.20	0.0253
298.20	0.0219
308.20	0.0202
318.20	0.0184

Mole fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid mixture 2)

Temperature, K - Liquid mixture 2	Mole fraction of Water (2) - Liquid mixture 1
303.15	0.2990
313.15	0.3080
368.06	0.4460

Mole fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid mixture 2)

Temperature, K - Liquid mixture 2	Mole fraction of Water (2) - Liquid mixture 2
303.15	0.9950
313.15	0.9950
368.06	0.9950

Mole fraction of 1-Butanol, 3-methyl- (1) [ref]

Fixed		Measured
Pressure, kPa - Liquid mixture 1	Temperature, K - Liquid mixture 1	Mole fraction of 1-Butanol, 3-methyl- (1) - Liquid mixture 1
101.00	293.15	0.6620

Mole fraction of 1-Butanol, 3-methyl- (1) [ref]

Fixed		Measured
Temperature, K - Liquid mixture 1	Pressure, kPa - Liquid mixture 1	Mole fraction of 1-Butanol, 3-methyl- (1) - Liquid mixture 2
293.15	101.00	0.0060

Boiling temperature at pressure P, K [ref]

Fixed		Measured
Mole fraction of Water (2) - Liquid mixture 1	Pressure, kPa - Liquid mixture 1	Boiling temperature at pressure P, K - Liquid mixture 1
0.4460	101.30	368.06

Boiling temperature at pressure P, K [ref]

Fixed		Measured
Mole fraction of Water (2) - Gas	Pressure, kPa - Liquid mixture 1	Boiling temperature at pressure P, K - Liquid mixture 1
0.8080	101.30	368.06

Boiling temperature at pressure P, K [ref]

Fixed		Measured
Mole fraction of Water (2) - Liquid mixture 1	Pressure, kPa - Liquid mixture 1	Boiling temperature at pressure P, K - Liquid mixture 1
0.4460	101.30	368.06

Boiling temperature at pressure P, K [ref]

Fixed		Measured
Mole fraction of Water (2) - Gas	Pressure, kPa - Liquid mixture 1	Boiling temperature at pressure P, K - Liquid mixture 1
0.8080	101.30	368.06

Sources

• Liquid-liquid equilibrium data and thermophysical properties for ternary systems composed of water, acetic acid and different solvents
• Measurement and thermodynamic modelling of ternary liquid-liquid equilibrium for extraction of (1R,2R)-(-)-1,2-Diaminocyclohexane from aqueous solution with C4-C5 alcohols at different temperatures
• Study of the LLE, VLE, and VLLE of the Ternary System Water + 1-Butanol + Isoamyl Alcohol at 101.3 kPa
• Liquid Liquid Equilibria of the Ternary Systems 3-Methyl-1-butanol + Ethanol + Water and 2-Methyl-1-propanol + Ethanol + Water at 293.15 K
• Temperature Dependence of Limiting Activity Coefficients, Henry s Law Constants, and Related Infinite Dilution Properties of Branched Pentanols in Water. Measurement, Critical Compilation, Correlation, and Recommended Data