Mixture of Ethyl formate + Nonane

Datasets

1. Mole fraction (2)
2. Excess molar enthalpy (molar enthalpy (2)
3. ρ_l - Mass density, kg/m3 (2)
4. T_boil - Boiling temperature at pressure P, K (2)

Mole fraction of Ethyl formate (1) [ref]

Operational condition: Pressure, kPa = 101.32 (Gas)

Mole fraction of Ethyl formate (1) - Liquid	Mole fraction of Ethyl formate (1) - Gas
0.0000	0.0000
0.0060	0.1240
0.0100	0.1930
0.0180	0.2990
0.0330	0.4730
0.0460	0.5720
0.0600	0.6550
0.0790	0.7330
0.1150	0.8210
0.1510	0.8730
0.1910	0.9060
0.2150	0.9170
0.2570	0.9340
0.2880	0.9420
0.3430	0.9550
0.3950	0.9610
0.4380	0.9640
0.4820	0.9680
0.5230	0.9710
0.5630	0.9740
0.6260	0.9780
0.6790	0.9800
0.7320	0.9820
0.7570	0.9840
0.8050	0.9860
0.8580	0.9880
0.9050	0.9910
0.9430	0.9930
0.9750	0.9950
1.0000	1.0000

Mole fraction of Ethyl formate (1) [ref]

Operational condition: Pressure, kPa = 101.32 (Gas)

Mole fraction of Ethyl formate (1) - Liquid	Mole fraction of Ethyl formate (1) - Gas
0.0000	0.0000
0.0060	0.1240
0.0100	0.1930
0.0180	0.2990
0.0330	0.4730
0.0460	0.5720
0.0600	0.6550
0.0790	0.7330
0.1150	0.8210
0.1510	0.8730
0.1910	0.9060
0.2150	0.9170
0.2570	0.9340
0.2880	0.9420
0.3430	0.9550
0.3950	0.9610
0.4380	0.9640
0.4820	0.9680
0.5230	0.9710
0.5630	0.9740
0.6260	0.9780
0.6790	0.9800
0.7320	0.9820
0.7570	0.9840
0.8050	0.9860
0.8580	0.9880
0.9050	0.9910
0.9430	0.9930
0.9750	0.9950
1.0000	1.0000

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Ethyl formate (1) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
291.15	0.1390	0.7920
291.15	0.2480	1.203
291.15	0.3320	1.482
291.15	0.3940	1.621
291.15	0.4550	1.712
291.15	0.5040	1.747
291.15	0.5470	1.757
291.15	0.5780	1.734
291.15	0.6020	1.709
291.15	0.6600	1.603
291.15	0.7040	1.504
291.15	0.7500	1.369
291.15	0.7950	1.198
291.15	0.8420	0.9990
291.15	0.8860	0.7740
291.15	0.9290	0.5100
291.15	0.9670	0.2540
318.15	0.1150	0.7210
318.15	0.2200	1.252
318.15	0.2930	1.528
318.15	0.3510	1.694
318.15	0.4040	1.832
318.15	0.4460	1.882
318.15	0.4820	1.921
318.15	0.5150	1.929
318.15	0.5430	1.914
318.15	0.6150	1.866
318.15	0.6560	1.807
318.15	0.6980	1.723
318.15	0.7410	1.603
318.15	0.7850	1.454
318.15	0.8300	1.257
318.15	0.8760	1.009
318.15	0.9180	0.7100
318.15	0.9610	0.3780

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Ethyl formate (1) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
291.15	0.1390	0.7920
291.15	0.2480	1.203
291.15	0.3320	1.482
291.15	0.3940	1.621
291.15	0.4550	1.712
291.15	0.5040	1.747
291.15	0.5470	1.757
291.15	0.5780	1.734
291.15	0.6020	1.709
291.15	0.6600	1.603
291.15	0.7040	1.504
291.15	0.7500	1.369
291.15	0.7950	1.198
291.15	0.8420	0.9990
291.15	0.8860	0.7740
291.15	0.9290	0.5100
291.15	0.9670	0.2540
318.15	0.1150	0.7210
318.15	0.2200	1.252
318.15	0.2930	1.528
318.15	0.3510	1.694
318.15	0.4040	1.832
318.15	0.4460	1.882
318.15	0.4820	1.921
318.15	0.5150	1.929
318.15	0.5430	1.914
318.15	0.6150	1.866
318.15	0.6560	1.807
318.15	0.6980	1.723
318.15	0.7410	1.603
318.15	0.7850	1.454
318.15	0.8300	1.257
318.15	0.8760	1.009
318.15	0.9180	0.7100
318.15	0.9610	0.3780

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Ethyl formate (1) - Liquid	Mass density, kg/m3 - Liquid
291.15	0.0000	719.27
291.15	0.0586	723.39
291.15	0.1164	727.9
291.15	0.1724	732.81
291.15	0.2140	736.84
291.15	0.2626	741.96
291.15	0.3015	746.15
291.15	0.3593	753.34
291.15	0.4077	759.91
291.15	0.4542	766.57
291.15	0.5045	774.56
291.15	0.5465	781.94
291.15	0.5937	790.85
291.15	0.6502	802.7
291.15	0.7008	814.5
291.15	0.7490	826.95
291.15	0.7991	841.72
291.15	0.8489	857.68
291.15	0.8971	875.77
291.15	0.9471	897.1
291.15	1.0000	923.66
298.15	0.0000	713.85
298.15	0.0770	719.03
298.15	0.1217	722.77
298.15	0.1634	726.26
298.15	0.2058	730.02
298.15	0.2608	735.67
298.15	0.3061	740.63
298.15	0.3561	746.62
298.15	0.4039	752.8
298.15	0.4477	759.06
298.15	0.5015	767.34
298.15	0.5478	775.21
298.15	0.6016	785.23
298.15	0.6492	795.16
298.15	0.7004	807.09
298.15	0.7501	819.62
298.15	0.7986	833.66
298.15	0.8484	849.71
298.15	0.8972	867.53
298.15	0.9481	888.5
298.15	1.0000	914.7
308.15	0.0000	705.97
308.15	0.0554	709.73
308.15	0.1171	713.95
308.15	0.1651	718.06
308.15	0.2047	721.44
308.15	0.2559	726.35
308.15	0.3135	732.4
308.15	0.3556	737.37
308.15	0.3999	742.9
308.15	0.4509	749.87
308.15	0.4986	757.06
308.15	0.5516	765.72
308.15	0.6014	774.89
308.15	0.6527	785.29
308.15	0.6980	795.33
308.15	0.7496	808.2
308.15	0.8033	823.22
308.15	0.8485	837.71
308.15	0.8982	855.3
308.15	0.9473	875.3
308.15	1.0000	901.03
318.15	0.0000	698.04
318.15	0.0738	702.6
318.15	0.1178	705.65
318.15	0.1679	709.7
318.15	0.2133	713.45
318.15	0.2557	717.54
318.15	0.3047	722.45
318.15	0.3469	727.13
318.15	0.4105	734.71
318.15	0.4507	740.1
318.15	0.5022	747.67
318.15	0.5498	755.22
318.15	0.5998	764.01
318.15	0.6510	774.17
318.15	0.6969	783.98
318.15	0.7490	796.69
318.15	0.8021	811.15
318.15	0.8479	825.07
318.15	0.9008	843.84
318.15	0.9473	862.62
318.15	1.0000	887.76

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Ethyl formate (1) - Liquid	Mass density, kg/m3 - Liquid
291.15	0.0000	719.27
291.15	0.0586	723.39
291.15	0.1164	727.9
291.15	0.1724	732.81
291.15	0.2140	736.84
291.15	0.2626	741.96
291.15	0.3015	746.15
291.15	0.3593	753.34
291.15	0.4077	759.91
291.15	0.4542	766.57
291.15	0.5045	774.56
291.15	0.5465	781.94
291.15	0.5937	790.85
291.15	0.6502	802.7
291.15	0.7008	814.5
291.15	0.7490	826.95
291.15	0.7991	841.72
291.15	0.8489	857.68
291.15	0.8971	875.77
291.15	0.9471	897.1
291.15	1.0000	923.66
298.15	0.0000	713.85
298.15	0.0770	719.03
298.15	0.1217	722.77
298.15	0.1634	726.26
298.15	0.2058	730.02
298.15	0.2608	735.67
298.15	0.3061	740.63
298.15	0.3561	746.62
298.15	0.4039	752.8
298.15	0.4477	759.06
298.15	0.5015	767.34
298.15	0.5478	775.21
298.15	0.6016	785.23
298.15	0.6492	795.16
298.15	0.7004	807.09
298.15	0.7501	819.62
298.15	0.7986	833.66
298.15	0.8484	849.71
298.15	0.8972	867.53
298.15	0.9481	888.5
298.15	1.0000	914.7
308.15	0.0000	705.97
308.15	0.0554	709.73
308.15	0.1171	713.95
308.15	0.1651	718.06
308.15	0.2047	721.44
308.15	0.2559	726.35
308.15	0.3135	732.4
308.15	0.3556	737.37
308.15	0.3999	742.9
308.15	0.4509	749.87
308.15	0.4986	757.06
308.15	0.5516	765.72
308.15	0.6014	774.89
308.15	0.6527	785.29
308.15	0.6980	795.33
308.15	0.7496	808.2
308.15	0.8033	823.22
308.15	0.8485	837.71
308.15	0.8982	855.3
308.15	0.9473	875.3
308.15	1.0000	901.03
318.15	0.0000	698.04
318.15	0.0738	702.6
318.15	0.1178	705.65
318.15	0.1679	709.7
318.15	0.2133	713.45
318.15	0.2557	717.54
318.15	0.3047	722.45
318.15	0.3469	727.13
318.15	0.4105	734.71
318.15	0.4507	740.1
318.15	0.5022	747.67
318.15	0.5498	755.22
318.15	0.5998	764.01
318.15	0.6510	774.17
318.15	0.6969	783.98
318.15	0.7490	796.69
318.15	0.8021	811.15
318.15	0.8479	825.07
318.15	0.9008	843.84
318.15	0.9473	862.62
318.15	1.0000	887.76

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 101.32 (Liquid)

Mole fraction of Ethyl formate (1) - Liquid	Boiling temperature at pressure P, K - Liquid
0.0000	423.94
0.0060	418.52
0.0100	415.58
0.0180	410.63
0.0330	401.14
0.0460	394.64
0.0600	388.33
0.0790	381.15
0.1150	370.97
0.1510	362.90
0.1910	356.60
0.2150	353.98
0.2570	349.39
0.2880	346.80
0.3430	342.47
0.3950	340.26
0.4380	339.28
0.4820	337.66
0.5230	336.96
0.5630	335.93
0.6260	334.40
0.6790	333.45
0.7320	332.55
0.7570	332.08
0.8050	331.38
0.8580	330.66
0.9050	329.83
0.9430	329.01
0.9750	327.90
1.0000	327.33

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 101.32 (Liquid)

Mole fraction of Ethyl formate (1) - Liquid	Boiling temperature at pressure P, K - Liquid
0.0000	423.94
0.0060	418.52
0.0100	415.58
0.0180	410.63
0.0330	401.14
0.0460	394.64
0.0600	388.33
0.0790	381.15
0.1150	370.97
0.1510	362.90
0.1910	356.60
0.2150	353.98
0.2570	349.39
0.2880	346.80
0.3430	342.47
0.3950	340.26
0.4380	339.28
0.4820	337.66
0.5230	336.96
0.5630	335.93
0.6260	334.40
0.6790	333.45
0.7320	332.55
0.7570	332.08
0.8050	331.38
0.8580	330.66
0.9050	329.83
0.9430	329.01
0.9750	327.90
1.0000	327.33

Sources

• Solutions of alkyl methanoates and alkanes: Simultaneous modeling of phase equilibria and mixing properties. Estimation of behavior by UNIFAC with recalculation of parameters