Mixture of Methane, dibromo- + Methane, bromotrichloro-

Datasets

1. Azeotropic composition: mole fraction (4)
2. ρ_l - Mass density, kg/m3 (2)
3. c_sound,fluid - Speed of Sound, m/s (2)
4. Azeotropic pressure, kPa (4)

Azeotropic composition: mole fraction of Methane, bromotrichloro- (2) [ref]

Temperature, K - Liquid	Azeotropic composition: mole fraction of Methane, bromotrichloro- (2) - Liquid
308.15	0.2581

Mole fraction of Methane, bromotrichloro- (2) [ref]

Operational condition: Temperature, K = 308.15 (Liquid)

Mole fraction of Methane, bromotrichloro- (2) - Liquid	Mole fraction of Methane, bromotrichloro- (2) - Gas
0.0252	0.0445
0.0585	0.0776
0.0824	0.1042
0.1494	0.1540
0.2256	0.2285
0.2607	0.2615
0.2972	0.2966
0.3263	0.3121
0.3583	0.3429
0.4204	0.3927
0.4544	0.4163
0.5279	0.4683
0.5930	0.5179
0.6711	0.5778
0.7426	0.6530
0.8370	0.7696
0.9007	0.8595

Azeotropic composition: mole fraction of Methane, bromotrichloro- (2) [ref]

Temperature, K - Liquid	Azeotropic composition: mole fraction of Methane, bromotrichloro- (2) - Liquid
308.15	0.2581

Mole fraction of Methane, bromotrichloro- (2) [ref]

Operational condition: Temperature, K = 308.15 (Liquid)

Mole fraction of Methane, bromotrichloro- (2) - Liquid	Mole fraction of Methane, bromotrichloro- (2) - Gas
0.0252	0.0445
0.0585	0.0776
0.0824	0.1042
0.1494	0.1540
0.2256	0.2285
0.2607	0.2615
0.2972	0.2966
0.3263	0.3121
0.3583	0.3429
0.4204	0.3927
0.4544	0.4163
0.5279	0.4683
0.5930	0.5179
0.6711	0.5778
0.7426	0.6530
0.8370	0.7696
0.9007	0.8595

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Methane, bromotrichloro- (2) - Liquid	Mass density, kg/m3 - Liquid
293.15	0.0000	2491.67
293.15	0.0506	2455.57
293.15	0.0993	2424.17
293.15	0.1491	2392.98
293.15	0.1991	2363.17
293.15	0.2473	2335.59
293.15	0.2986	2307.34
293.15	0.3465	2281.89
293.15	0.3979	2255.64
293.15	0.4468	2231.41
293.15	0.4967	2207.74
293.15	0.5462	2185.38
293.15	0.5975	2162.89
293.15	0.6479	2141.49
293.15	0.6947	2122.35
293.15	0.7469	2101.9
293.15	0.7959	2083.33
293.15	0.8494	2063.55
293.15	0.8980	2046.2
293.15	0.9469	2029.71
293.15	1.0000	2013.06
298.15	0.0000	2478.61
298.15	0.0506	2442.67
298.15	0.0993	2411.4
298.15	0.1491	2380.34
298.15	0.1991	2350.66
298.15	0.2473	2323.21
298.15	0.2986	2295.08
298.15	0.3465	2269.75
298.15	0.3979	2243.64
298.15	0.4468	2219.49
298.15	0.4967	2195.91
298.15	0.5462	2173.66
298.15	0.5975	2151.29
298.15	0.6479	2130.01
298.15	0.6947	2110.96
298.15	0.7469	2090.59
298.15	0.7959	2072.08
298.15	0.8494	2052.39
298.15	0.8980	2035.13
298.15	0.9469	2018.65
298.15	1.0000	2002.14
303.15	0.0000	2465.53
303.15	0.0506	2429.69
303.15	0.0993	2398.59
303.15	0.1491	2367.61
303.15	0.1991	2338.13
303.15	0.2473	2310.8
303.15	0.2986	2282.77
303.15	0.3465	2257.58
303.15	0.3979	2231.57
303.15	0.4468	2207.52
303.15	0.4967	2184.02
303.15	0.5462	2161.9
303.15	0.5975	2139.5
303.15	0.6479	2118.46
303.15	0.6947	2099.49
303.15	0.7469	2079.21
303.15	0.7959	2060.79
303.15	0.8494	2041.21
303.15	0.8980	2024.04
303.15	0.9469	2007.69
303.15	1.0000	1991.2
308.15	0.0000	2452.42
308.15	0.0506	2416.74
308.15	0.0993	2385.75
308.15	0.1491	2354.94
308.15	0.1991	2325.48
308.15	0.2473	2298.33
308.15	0.2986	2270.45
308.15	0.3465	2245.37
308.15	0.3979	2219.48
308.15	0.4468	2195.5
308.15	0.4967	2172.16
308.15	0.5462	2150.12
308.15	0.5975	2128.0
308.15	0.6479	2106.9
308.15	0.6947	2087.96
308.15	0.7469	2067.83
308.15	0.7959	2049.47
308.15	0.8494	2030.02
308.15	0.8980	2012.93
308.15	0.9469	1996.65
308.15	1.0000	1980.24
313.15	0.0000	2439.26
313.15	0.0506	2403.73
313.15	0.0993	2372.87
313.15	0.1491	2342.21
313.15	0.1991	2312.93
313.15	0.2473	2285.84
313.15	0.2986	2258.08
313.15	0.3465	2233.11
313.15	0.3979	2207.34
313.15	0.4468	2183.5
313.15	0.4967	2160.25
313.15	0.5462	2138.31
313.15	0.5975	2116.3
313.15	0.6479	2095.25
313.15	0.6947	2076.47
313.15	0.7469	2056.41
313.15	0.7959	2038.17
313.15	0.8494	2018.79
313.15	0.8980	2001.78
313.15	0.9469	1985.57
313.15	1.0000	1969.25

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Methane, bromotrichloro- (2) - Liquid	Mass density, kg/m3 - Liquid
293.15	0.0000	2491.67
293.15	0.0506	2455.57
293.15	0.0993	2424.17
293.15	0.1491	2392.98
293.15	0.1991	2363.17
293.15	0.2473	2335.59
293.15	0.2986	2307.34
293.15	0.3465	2281.89
293.15	0.3979	2255.64
293.15	0.4468	2231.41
293.15	0.4967	2207.74
293.15	0.5462	2185.38
293.15	0.5975	2162.89
293.15	0.6479	2141.49
293.15	0.6947	2122.35
293.15	0.7469	2101.9
293.15	0.7959	2083.33
293.15	0.8494	2063.55
293.15	0.8980	2046.2
293.15	0.9469	2029.71
293.15	1.0000	2013.06
298.15	0.0000	2478.61
298.15	0.0506	2442.67
298.15	0.0993	2411.4
298.15	0.1491	2380.34
298.15	0.1991	2350.66
298.15	0.2473	2323.21
298.15	0.2986	2295.08
298.15	0.3465	2269.75
298.15	0.3979	2243.64
298.15	0.4468	2219.49
298.15	0.4967	2195.91
298.15	0.5462	2173.66
298.15	0.5975	2151.29
298.15	0.6479	2130.01
298.15	0.6947	2110.96
298.15	0.7469	2090.59
298.15	0.7959	2072.08
298.15	0.8494	2052.39
298.15	0.8980	2035.13
298.15	0.9469	2018.65
298.15	1.0000	2002.14
303.15	0.0000	2465.53
303.15	0.0506	2429.69
303.15	0.0993	2398.59
303.15	0.1491	2367.61
303.15	0.1991	2338.13
303.15	0.2473	2310.8
303.15	0.2986	2282.77
303.15	0.3465	2257.58
303.15	0.3979	2231.57
303.15	0.4468	2207.52
303.15	0.4967	2184.02
303.15	0.5462	2161.9
303.15	0.5975	2139.5
303.15	0.6479	2118.46
303.15	0.6947	2099.49
303.15	0.7469	2079.21
303.15	0.7959	2060.79
303.15	0.8494	2041.21
303.15	0.8980	2024.04
303.15	0.9469	2007.69
303.15	1.0000	1991.2
308.15	0.0000	2452.42
308.15	0.0506	2416.74
308.15	0.0993	2385.75
308.15	0.1491	2354.94
308.15	0.1991	2325.48
308.15	0.2473	2298.33
308.15	0.2986	2270.45
308.15	0.3465	2245.37
308.15	0.3979	2219.48
308.15	0.4468	2195.5
308.15	0.4967	2172.16
308.15	0.5462	2150.12
308.15	0.5975	2128.0
308.15	0.6479	2106.9
308.15	0.6947	2087.96
308.15	0.7469	2067.83
308.15	0.7959	2049.47
308.15	0.8494	2030.02
308.15	0.8980	2012.93
308.15	0.9469	1996.65
308.15	1.0000	1980.24
313.15	0.0000	2439.26
313.15	0.0506	2403.73
313.15	0.0993	2372.87
313.15	0.1491	2342.21
313.15	0.1991	2312.93
313.15	0.2473	2285.84
313.15	0.2986	2258.08
313.15	0.3465	2233.11
313.15	0.3979	2207.34
313.15	0.4468	2183.5
313.15	0.4967	2160.25
313.15	0.5462	2138.31
313.15	0.5975	2116.3
313.15	0.6479	2095.25
313.15	0.6947	2076.47
313.15	0.7469	2056.41
313.15	0.7959	2038.17
313.15	0.8494	2018.79
313.15	0.8980	2001.78
313.15	0.9469	1985.57
313.15	1.0000	1969.25

Speed of sound, m/s [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Methane, bromotrichloro- (2) - Liquid	Speed of sound, m/s - Liquid
293.15	0.0000	961.8
293.15	0.0506	957.0
293.15	0.0993	953.0
293.15	0.1491	948.9
293.15	0.1991	945.3
293.15	0.2473	942.1
293.15	0.2986	939.1
293.15	0.3465	936.3
293.15	0.3979	933.6
293.15	0.4468	931.3
293.15	0.4967	929.1
293.15	0.5462	927.2
293.15	0.5975	925.3
293.15	0.6479	923.7
293.15	0.6947	922.4
293.15	0.7469	921.0
293.15	0.7959	919.9
293.15	0.8494	918.8
293.15	0.8980	918.0
293.15	0.9469	917.4
293.15	1.0000	917.1
298.15	0.0000	949.2
298.15	0.0506	944.4
298.15	0.0993	940.3
298.15	0.1491	936.2
298.15	0.1991	932.6
298.15	0.2473	929.3
298.15	0.2986	926.2
298.15	0.3465	923.3
298.15	0.3979	920.7
298.15	0.4468	918.3
298.15	0.4967	916.1
298.15	0.5462	914.1
298.15	0.5975	912.2
298.15	0.6479	910.6
298.15	0.6947	909.2
298.15	0.7469	907.7
298.15	0.7959	906.6
298.15	0.8494	905.5
298.15	0.8980	904.6
298.15	0.9469	904.0
298.15	1.0000	903.6
303.15	0.0000	936.6
303.15	0.0506	931.7
303.15	0.0993	927.6
303.15	0.1491	923.4
303.15	0.1991	919.8
303.15	0.2473	916.5
303.15	0.2986	913.2
303.15	0.3465	910.5
303.15	0.3979	907.7
303.15	0.4468	905.3
303.15	0.4967	903.1
303.15	0.5462	901.1
303.15	0.5975	899.1
303.15	0.6479	897.4
303.15	0.6947	896.0
303.15	0.7469	894.5
303.15	0.7959	893.4
303.15	0.8494	892.2
303.15	0.8980	891.3
303.15	0.9469	890.6
303.15	1.0000	890.2
308.15	0.0000	924.0
308.15	0.0506	919.1
308.15	0.0993	914.8
308.15	0.1491	910.7
308.15	0.1991	907.1
308.15	0.2473	903.7
308.15	0.2986	900.4
308.15	0.3465	897.6
308.15	0.3979	894.8
308.15	0.4468	892.4
308.15	0.4967	890.1
308.15	0.5462	888.0
308.15	0.5975	886.1
308.15	0.6479	884.4
308.15	0.6947	882.8
308.15	0.7469	881.4
308.15	0.7959	880.2
308.15	0.8494	879.0
308.15	0.8980	878.1
308.15	0.9469	877.3
308.15	1.0000	876.8
313.15	0.0000	911.4
313.15	0.0506	906.4
313.15	0.0993	902.2
313.15	0.1491	898.1
313.15	0.1991	894.4
313.15	0.2473	891.0
313.15	0.2986	887.7
313.15	0.3465	884.8
313.15	0.3979	882.0
313.15	0.4468	879.5
313.15	0.4967	877.1
313.15	0.5462	875.1
313.15	0.5975	873.1
313.15	0.6479	871.4
313.15	0.6947	869.9
313.15	0.7469	868.4
313.15	0.7959	867.1
313.15	0.8494	865.9
313.15	0.8980	865.0
313.15	0.9469	864.1
313.15	1.0000	863.6

Speed of sound, m/s [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Methane, bromotrichloro- (2) - Liquid	Speed of sound, m/s - Liquid
293.15	0.0000	961.8
293.15	0.0506	957.0
293.15	0.0993	953.0
293.15	0.1491	948.9
293.15	0.1991	945.3
293.15	0.2473	942.1
293.15	0.2986	939.1
293.15	0.3465	936.3
293.15	0.3979	933.6
293.15	0.4468	931.3
293.15	0.4967	929.1
293.15	0.5462	927.2
293.15	0.5975	925.3
293.15	0.6479	923.7
293.15	0.6947	922.4
293.15	0.7469	921.0
293.15	0.7959	919.9
293.15	0.8494	918.8
293.15	0.8980	918.0
293.15	0.9469	917.4
293.15	1.0000	917.1
298.15	0.0000	949.2
298.15	0.0506	944.4
298.15	0.0993	940.3
298.15	0.1491	936.2
298.15	0.1991	932.6
298.15	0.2473	929.3
298.15	0.2986	926.2
298.15	0.3465	923.3
298.15	0.3979	920.7
298.15	0.4468	918.3
298.15	0.4967	916.1
298.15	0.5462	914.1
298.15	0.5975	912.2
298.15	0.6479	910.6
298.15	0.6947	909.2
298.15	0.7469	907.7
298.15	0.7959	906.6
298.15	0.8494	905.5
298.15	0.8980	904.6
298.15	0.9469	904.0
298.15	1.0000	903.6
303.15	0.0000	936.6
303.15	0.0506	931.7
303.15	0.0993	927.6
303.15	0.1491	923.4
303.15	0.1991	919.8
303.15	0.2473	916.5
303.15	0.2986	913.2
303.15	0.3465	910.5
303.15	0.3979	907.7
303.15	0.4468	905.3
303.15	0.4967	903.1
303.15	0.5462	901.1
303.15	0.5975	899.1
303.15	0.6479	897.4
303.15	0.6947	896.0
303.15	0.7469	894.5
303.15	0.7959	893.4
303.15	0.8494	892.2
303.15	0.8980	891.3
303.15	0.9469	890.6
303.15	1.0000	890.2
308.15	0.0000	924.0
308.15	0.0506	919.1
308.15	0.0993	914.8
308.15	0.1491	910.7
308.15	0.1991	907.1
308.15	0.2473	903.7
308.15	0.2986	900.4
308.15	0.3465	897.6
308.15	0.3979	894.8
308.15	0.4468	892.4
308.15	0.4967	890.1
308.15	0.5462	888.0
308.15	0.5975	886.1
308.15	0.6479	884.4
308.15	0.6947	882.8
308.15	0.7469	881.4
308.15	0.7959	880.2
308.15	0.8494	879.0
308.15	0.8980	878.1
308.15	0.9469	877.3
308.15	1.0000	876.8
313.15	0.0000	911.4
313.15	0.0506	906.4
313.15	0.0993	902.2
313.15	0.1491	898.1
313.15	0.1991	894.4
313.15	0.2473	891.0
313.15	0.2986	887.7
313.15	0.3465	884.8
313.15	0.3979	882.0
313.15	0.4468	879.5
313.15	0.4967	877.1
313.15	0.5462	875.1
313.15	0.5975	873.1
313.15	0.6479	871.4
313.15	0.6947	869.9
313.15	0.7469	868.4
313.15	0.7959	867.1
313.15	0.8494	865.9
313.15	0.8980	865.0
313.15	0.9469	864.1
313.15	1.0000	863.6

Azeotropic pressure, kPa [ref]

Temperature, K - Liquid	Azeotropic pressure, kPa - Liquid
308.15	10.36

Vapor or sublimation pressure, kPa [ref]

Operational condition: Temperature, K = 308.15 (Liquid)

Mole fraction of Methane, bromotrichloro- (2) - Liquid	Vapor or sublimation pressure, kPa - Gas
0.0252	10.08
0.0585	10.18
0.0824	10.23
0.1494	10.30
0.2256	10.33
0.2607	10.34
0.2972	10.36
0.3263	10.36
0.3583	10.34
0.4204	10.27
0.4544	10.24
0.5279	10.12
0.5930	9.98
0.6711	9.73
0.7426	9.46
0.8370	9.05
0.9007	8.73

Azeotropic pressure, kPa [ref]

Temperature, K - Liquid	Azeotropic pressure, kPa - Liquid
308.15	10.36

Vapor or sublimation pressure, kPa [ref]

Operational condition: Temperature, K = 308.15 (Liquid)

Mole fraction of Methane, bromotrichloro- (2) - Liquid	Vapor or sublimation pressure, kPa - Gas
0.0252	10.08
0.0585	10.18
0.0824	10.23
0.1494	10.30
0.2256	10.33
0.2607	10.34
0.2972	10.36
0.3263	10.36
0.3583	10.34
0.4204	10.27
0.4544	10.24
0.5279	10.12
0.5930	9.98
0.6711	9.73
0.7426	9.46
0.8370	9.05
0.9007	8.73

Sources

• Vapour liquid equilibrium at T = 308.15 K for binary systems: Dibromomethane + n-heptane, bromotrichloromethane + n-heptane, bromotrichloromethane + dibromomethane, bromotrichloromethane + bromochloromethane and dibromomethane + bromochloromethane. Experimental data and modelling
• Excess Molar Volumes and Speed of Sound in Bromotrichloromethane + n-Heptane, Dibromomethane + n-Heptane, Bromotrichloromethane + Dibromomethane, and Bromotrichloromethane + Bromochloromethane at Temperatures from (293.15 to 313.15) K