Mixture of Methane, bromotrichloro- + Heptane

Datasets

1. Azeotropic composition: mole fraction (4)
2. ρ_l - Mass density, kg/m3 (2)
3. c_sound,fluid - Speed of Sound, m/s (2)
4. Azeotropic pressure, kPa (4)

Azeotropic composition: mole fraction of Methane, bromotrichloro- (1) [ref]

Temperature, K - Liquid	Azeotropic composition: mole fraction of Methane, bromotrichloro- (1) - Liquid
308.15	0.2584

Mole fraction of Methane, bromotrichloro- (1) [ref]

Operational condition: Temperature, K = 308.15 (Liquid)

Mole fraction of Methane, bromotrichloro- (1) - Liquid	Mole fraction of Methane, bromotrichloro- (1) - Gas
0.1003	0.1067
0.2018	0.2049
0.2853	0.2810
0.3934	0.3738
0.4648	0.4347
0.5150	0.4767
0.5709	0.5236
0.6080	0.5576
0.6150	0.5610
0.6769	0.6147
0.7103	0.6452
0.7289	0.6627
0.7877	0.7208
0.8322	0.7661
0.8985	0.8471

Azeotropic composition: mole fraction of Methane, bromotrichloro- (1) [ref]

Temperature, K - Liquid	Azeotropic composition: mole fraction of Methane, bromotrichloro- (1) - Liquid
308.15	0.2584

Mole fraction of Methane, bromotrichloro- (1) [ref]

Operational condition: Temperature, K = 308.15 (Liquid)

Mole fraction of Methane, bromotrichloro- (1) - Liquid	Mole fraction of Methane, bromotrichloro- (1) - Gas
0.1003	0.1067
0.2018	0.2049
0.2853	0.2810
0.3934	0.3738
0.4648	0.4347
0.5150	0.4767
0.5709	0.5236
0.6080	0.5576
0.6150	0.5610
0.6769	0.6147
0.7103	0.6452
0.7289	0.6627
0.7877	0.7208
0.8322	0.7661
0.8985	0.8471

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Methane, bromotrichloro- (1) - Liquid	Mass density, kg/m3 - Liquid
293.15	0.0000	683.84
293.15	0.0527	731.54
293.15	0.1116	786.88
293.15	0.1520	826.09
293.15	0.2038	878.08
293.15	0.2512	927.29
293.15	0.2988	978.53
293.15	0.3556	1041.97
293.15	0.4027	1096.65
293.15	0.4603	1166.3
293.15	0.4989	1214.82
293.15	0.5537	1286.16
293.15	0.5961	1343.68
293.15	0.6562	1428.79
293.15	0.7088	1506.86
293.15	0.7486	1568.29
293.15	0.8001	1651.09
293.15	0.8456	1727.53
293.15	0.8990	1821.57
293.15	0.9521	1919.55
293.15	1.0000	2013.06
298.15	0.0000	679.6
298.15	0.0527	727.03
298.15	0.1116	782.07
298.15	0.1520	821.09
298.15	0.2038	872.78
298.15	0.2512	921.75
298.15	0.2988	972.69
298.15	0.3556	1035.81
298.15	0.4027	1090.21
298.15	0.4603	1159.5
298.15	0.4989	1207.8
298.15	0.5537	1278.76
298.15	0.5961	1336.0
298.15	0.6562	1420.68
298.15	0.7088	1498.38
298.15	0.7486	1559.53
298.15	0.8001	1641.91
298.15	0.8456	1717.98
298.15	0.8990	1811.56
298.15	0.9521	1909.09
298.15	1.0000	2002.14
303.15	0.0000	675.33
303.15	0.0527	722.5
303.15	0.1116	777.25
303.15	0.1520	816.04
303.15	0.2038	867.43
303.15	0.2512	916.16
303.15	0.2988	966.84
303.15	0.3556	1029.61
303.15	0.4027	1083.75
303.15	0.4603	1152.66
303.15	0.4989	1200.71
303.15	0.5537	1271.34
303.15	0.5961	1328.29
303.15	0.6562	1412.54
303.15	0.7088	1489.86
303.15	0.7486	1550.71
303.15	0.8001	1632.7
303.15	0.8456	1708.38
303.15	0.8990	1801.52
303.15	0.9521	1898.58
303.15	1.0000	1991.2
308.15	0.0000	671.04
308.15	0.0527	717.94
308.15	0.1116	772.39
308.15	0.1520	810.96
308.15	0.2038	862.07
308.15	0.2512	910.53
308.15	0.2988	960.93
308.15	0.3556	1023.38
308.15	0.4027	1077.23
308.15	0.4603	1145.8
308.15	0.4989	1193.57
308.15	0.5537	1263.88
308.15	0.5961	1320.53
308.15	0.6562	1404.37
308.15	0.7088	1481.3
308.15	0.7486	1541.85
308.15	0.8001	1623.44
308.15	0.8456	1698.77
308.15	0.8990	1791.47
308.15	0.9521	1888.06
308.15	1.0000	1980.24
313.15	0.0000	666.71
313.15	0.0527	713.35
313.15	0.1116	767.5
313.15	0.1520	805.84
313.15	0.2038	856.67
313.15	0.2512	904.88
313.15	0.2988	955.01
313.15	0.3556	1017.12
313.15	0.4027	1070.68
313.15	0.4603	1138.9
313.15	0.4989	1186.41
313.15	0.5537	1256.37
313.15	0.5961	1312.74
313.15	0.6562	1396.16
313.15	0.7088	1472.71
313.15	0.7486	1532.96
313.15	0.8001	1614.16
313.15	0.8456	1689.12
313.15	0.8990	1781.35
313.15	0.9521	1877.49
313.15	1.0000	1969.25

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Methane, bromotrichloro- (1) - Liquid	Mass density, kg/m3 - Liquid
293.15	0.0000	683.84
293.15	0.0527	731.54
293.15	0.1116	786.88
293.15	0.1520	826.09
293.15	0.2038	878.08
293.15	0.2512	927.29
293.15	0.2988	978.53
293.15	0.3556	1041.97
293.15	0.4027	1096.65
293.15	0.4603	1166.3
293.15	0.4989	1214.82
293.15	0.5537	1286.16
293.15	0.5961	1343.68
293.15	0.6562	1428.79
293.15	0.7088	1506.86
293.15	0.7486	1568.29
293.15	0.8001	1651.09
293.15	0.8456	1727.53
293.15	0.8990	1821.57
293.15	0.9521	1919.55
293.15	1.0000	2013.06
298.15	0.0000	679.6
298.15	0.0527	727.03
298.15	0.1116	782.07
298.15	0.1520	821.09
298.15	0.2038	872.78
298.15	0.2512	921.75
298.15	0.2988	972.69
298.15	0.3556	1035.81
298.15	0.4027	1090.21
298.15	0.4603	1159.5
298.15	0.4989	1207.8
298.15	0.5537	1278.76
298.15	0.5961	1336.0
298.15	0.6562	1420.68
298.15	0.7088	1498.38
298.15	0.7486	1559.53
298.15	0.8001	1641.91
298.15	0.8456	1717.98
298.15	0.8990	1811.56
298.15	0.9521	1909.09
298.15	1.0000	2002.14
303.15	0.0000	675.33
303.15	0.0527	722.5
303.15	0.1116	777.25
303.15	0.1520	816.04
303.15	0.2038	867.43
303.15	0.2512	916.16
303.15	0.2988	966.84
303.15	0.3556	1029.61
303.15	0.4027	1083.75
303.15	0.4603	1152.66
303.15	0.4989	1200.71
303.15	0.5537	1271.34
303.15	0.5961	1328.29
303.15	0.6562	1412.54
303.15	0.7088	1489.86
303.15	0.7486	1550.71
303.15	0.8001	1632.7
303.15	0.8456	1708.38
303.15	0.8990	1801.52
303.15	0.9521	1898.58
303.15	1.0000	1991.2
308.15	0.0000	671.04
308.15	0.0527	717.94
308.15	0.1116	772.39
308.15	0.1520	810.96
308.15	0.2038	862.07
308.15	0.2512	910.53
308.15	0.2988	960.93
308.15	0.3556	1023.38
308.15	0.4027	1077.23
308.15	0.4603	1145.8
308.15	0.4989	1193.57
308.15	0.5537	1263.88
308.15	0.5961	1320.53
308.15	0.6562	1404.37
308.15	0.7088	1481.3
308.15	0.7486	1541.85
308.15	0.8001	1623.44
308.15	0.8456	1698.77
308.15	0.8990	1791.47
308.15	0.9521	1888.06
308.15	1.0000	1980.24
313.15	0.0000	666.71
313.15	0.0527	713.35
313.15	0.1116	767.5
313.15	0.1520	805.84
313.15	0.2038	856.67
313.15	0.2512	904.88
313.15	0.2988	955.01
313.15	0.3556	1017.12
313.15	0.4027	1070.68
313.15	0.4603	1138.9
313.15	0.4989	1186.41
313.15	0.5537	1256.37
313.15	0.5961	1312.74
313.15	0.6562	1396.16
313.15	0.7088	1472.71
313.15	0.7486	1532.96
313.15	0.8001	1614.16
313.15	0.8456	1689.12
313.15	0.8990	1781.35
313.15	0.9521	1877.49
313.15	1.0000	1969.25

Speed of sound, m/s [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Methane, bromotrichloro- (1) - Liquid	Speed of sound, m/s - Liquid
293.15	0.0000	1152.6
293.15	0.0527	1126.6
293.15	0.1116	1100.3
293.15	0.1520	1083.8
293.15	0.2038	1064.1
293.15	0.2512	1047.4
293.15	0.2988	1031.9
293.15	0.3556	1015.0
293.15	0.4027	1001.9
293.15	0.4603	987.5
293.15	0.4989	978.4
293.15	0.5537	966.7
293.15	0.5961	958.4
293.15	0.6562	948.0
293.15	0.7088	940.1
293.15	0.7486	934.8
293.15	0.8001	929.0
293.15	0.8456	924.6
293.15	0.8990	920.6
293.15	0.9521	918.0
293.15	1.0000	917.1
298.15	0.0000	1131.0
298.15	0.0527	1105.8
298.15	0.1116	1080.2
298.15	0.1520	1064.4
298.15	0.2038	1045.2
298.15	0.2512	1028.9
298.15	0.2988	1013.7
298.15	0.3556	997.3
298.15	0.4027	984.7
298.15	0.4603	970.6
298.15	0.4989	962.0
298.15	0.5537	950.6
298.15	0.5961	942.8
298.15	0.6562	932.8
298.15	0.7088	925.2
298.15	0.7486	920.0
298.15	0.8001	914.5
298.15	0.8456	910.4
298.15	0.8990	906.7
298.15	0.9521	904.4
298.15	1.0000	903.6
303.15	0.0000	1109.6
303.15	0.0527	1085.1
303.15	0.1116	1060.4
303.15	0.1520	1044.9
303.15	0.2038	1026.0
303.15	0.2512	1010.4
303.15	0.2988	995.8
303.15	0.3556	979.7
303.15	0.4027	967.5
303.15	0.4603	953.9
303.15	0.4989	945.5
303.15	0.5537	934.7
303.15	0.5961	927.1
303.15	0.6562	917.4
303.15	0.7088	910.3
303.15	0.7486	905.3
303.15	0.8001	900.1
303.15	0.8456	896.2
303.15	0.8990	892.8
303.15	0.9521	890.7
303.15	1.0000	890.2
308.15	0.0000	1088.2
308.15	0.0527	1064.5
308.15	0.1116	1040.5
308.15	0.1520	1025.3
308.15	0.2038	1007.0
308.15	0.2512	992.0
308.15	0.2988	977.7
308.15	0.3556	962.2
308.15	0.4027	950.4
308.15	0.4603	937.2
308.15	0.4989	929.2
308.15	0.5537	918.8
308.15	0.5961	911.3
308.15	0.6562	902.2
308.15	0.7088	895.4
308.15	0.7486	890.7
308.15	0.8001	885.8
308.15	0.8456	882.2
308.15	0.8990	879.0
308.15	0.9521	877.2
308.15	1.0000	876.8
313.15	0.0000	1067.1
313.15	0.0527	1044.0
313.15	0.1116	1020.7
313.15	0.1520	1005.8
313.15	0.2038	988.3
313.15	0.2512	973.6
313.15	0.2988	959.8
313.15	0.3556	944.8
313.15	0.4027	933.3
313.15	0.4603	920.7
313.15	0.4989	912.9
313.15	0.5537	902.9
313.15	0.5961	895.9
313.15	0.6562	887.1
313.15	0.7088	880.6
313.15	0.7486	876.2
313.15	0.8001	871.5
313.15	0.8456	868.2
313.15	0.8990	865.3
313.15	0.9521	863.7
313.15	1.0000	863.6

Speed of sound, m/s [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Methane, bromotrichloro- (1) - Liquid	Speed of sound, m/s - Liquid
293.15	0.0000	1152.6
293.15	0.0527	1126.6
293.15	0.1116	1100.3
293.15	0.1520	1083.8
293.15	0.2038	1064.1
293.15	0.2512	1047.4
293.15	0.2988	1031.9
293.15	0.3556	1015.0
293.15	0.4027	1001.9
293.15	0.4603	987.5
293.15	0.4989	978.4
293.15	0.5537	966.7
293.15	0.5961	958.4
293.15	0.6562	948.0
293.15	0.7088	940.1
293.15	0.7486	934.8
293.15	0.8001	929.0
293.15	0.8456	924.6
293.15	0.8990	920.6
293.15	0.9521	918.0
293.15	1.0000	917.1
298.15	0.0000	1131.0
298.15	0.0527	1105.8
298.15	0.1116	1080.2
298.15	0.1520	1064.4
298.15	0.2038	1045.2
298.15	0.2512	1028.9
298.15	0.2988	1013.7
298.15	0.3556	997.3
298.15	0.4027	984.7
298.15	0.4603	970.6
298.15	0.4989	962.0
298.15	0.5537	950.6
298.15	0.5961	942.8
298.15	0.6562	932.8
298.15	0.7088	925.2
298.15	0.7486	920.0
298.15	0.8001	914.5
298.15	0.8456	910.4
298.15	0.8990	906.7
298.15	0.9521	904.4
298.15	1.0000	903.6
303.15	0.0000	1109.6
303.15	0.0527	1085.1
303.15	0.1116	1060.4
303.15	0.1520	1044.9
303.15	0.2038	1026.0
303.15	0.2512	1010.4
303.15	0.2988	995.8
303.15	0.3556	979.7
303.15	0.4027	967.5
303.15	0.4603	953.9
303.15	0.4989	945.5
303.15	0.5537	934.7
303.15	0.5961	927.1
303.15	0.6562	917.4
303.15	0.7088	910.3
303.15	0.7486	905.3
303.15	0.8001	900.1
303.15	0.8456	896.2
303.15	0.8990	892.8
303.15	0.9521	890.7
303.15	1.0000	890.2
308.15	0.0000	1088.2
308.15	0.0527	1064.5
308.15	0.1116	1040.5
308.15	0.1520	1025.3
308.15	0.2038	1007.0
308.15	0.2512	992.0
308.15	0.2988	977.7
308.15	0.3556	962.2
308.15	0.4027	950.4
308.15	0.4603	937.2
308.15	0.4989	929.2
308.15	0.5537	918.8
308.15	0.5961	911.3
308.15	0.6562	902.2
308.15	0.7088	895.4
308.15	0.7486	890.7
308.15	0.8001	885.8
308.15	0.8456	882.2
308.15	0.8990	879.0
308.15	0.9521	877.2
308.15	1.0000	876.8
313.15	0.0000	1067.1
313.15	0.0527	1044.0
313.15	0.1116	1020.7
313.15	0.1520	1005.8
313.15	0.2038	988.3
313.15	0.2512	973.6
313.15	0.2988	959.8
313.15	0.3556	944.8
313.15	0.4027	933.3
313.15	0.4603	920.7
313.15	0.4989	912.9
313.15	0.5537	902.9
313.15	0.5961	895.9
313.15	0.6562	887.1
313.15	0.7088	880.6
313.15	0.7486	876.2
313.15	0.8001	871.5
313.15	0.8456	868.2
313.15	0.8990	865.3
313.15	0.9521	863.7
313.15	1.0000	863.6

Azeotropic pressure, kPa [ref]

Temperature, K - Liquid	Azeotropic pressure, kPa - Liquid
308.15	10.04

Vapor or sublimation pressure, kPa [ref]

Operational condition: Temperature, K = 308.15 (Liquid)

Mole fraction of Methane, bromotrichloro- (1) - Liquid	Vapor or sublimation pressure, kPa - Gas
0.1003	10.00
0.2018	10.05
0.2853	10.03
0.3934	10.01
0.4648	9.95
0.5150	9.87
0.5709	9.78
0.6080	9.71
0.6150	9.71
0.6769	9.58
0.7103	9.49
0.7289	9.42
0.7877	9.26
0.8322	9.13
0.8985	8.90

Azeotropic pressure, kPa [ref]

Temperature, K - Liquid	Azeotropic pressure, kPa - Liquid
308.15	10.04

Vapor or sublimation pressure, kPa [ref]

Operational condition: Temperature, K = 308.15 (Liquid)

Mole fraction of Methane, bromotrichloro- (1) - Liquid	Vapor or sublimation pressure, kPa - Gas
0.1003	10.00
0.2018	10.05
0.2853	10.03
0.3934	10.01
0.4648	9.95
0.5150	9.87
0.5709	9.78
0.6080	9.71
0.6150	9.71
0.6769	9.58
0.7103	9.49
0.7289	9.42
0.7877	9.26
0.8322	9.13
0.8985	8.90

Sources

• Vapour liquid equilibrium at T = 308.15 K for binary systems: Dibromomethane + n-heptane, bromotrichloromethane + n-heptane, bromotrichloromethane + dibromomethane, bromotrichloromethane + bromochloromethane and dibromomethane + bromochloromethane. Experimental data and modelling
• Excess Molar Volumes and Speed of Sound in Bromotrichloromethane + n-Heptane, Dibromomethane + n-Heptane, Bromotrichloromethane + Dibromomethane, and Bromotrichloromethane + Bromochloromethane at Temperatures from (293.15 to 313.15) K