Mixture of 1-Butanol + Pyrrole

Datasets

1. Mole fraction (4)
2. Excess molar enthalpy (molar enthalpy (2)
3. P_vap - Vapor or sublimation pressure, kPa (2)
4. T_boil - Boiling temperature at pressure P, K (2)

Mole fraction of Pyrrole (2) [ref]

Fixed		Measured
Mole fraction of Pyrrole (2) - Liquid	Temperature, K - Liquid	Mole fraction of Pyrrole (2) - Gas
0.0000	353.20	0.0000
0.0000	363.20	0.0000
0.0000	373.20	0.0000
0.0150	363.20	0.0210
0.0290	353.20	0.0410
0.0370	363.20	0.0400
0.0520	353.20	0.0750
0.0590	373.20	0.0600
0.0670	363.20	0.0680
0.0710	353.20	0.0970
0.0710	373.20	0.0610
0.0960	373.20	0.0910
0.0980	353.20	0.1080
0.1000	363.20	0.1040
0.1100	353.20	0.1230
0.1240	363.20	0.1250
0.1500	373.20	0.1410
0.1530	363.20	0.1510
0.1590	353.20	0.1710
0.2040	363.20	0.2040
0.2070	353.20	0.2150
0.2130	353.20	0.2230
0.2690	373.20	0.2500
0.2740	353.20	0.2780
0.2920	373.20	0.2670
0.3060	363.20	0.2880
0.3660	373.20	0.3260
0.3760	353.20	0.3520
0.3830	353.20	0.3680
0.3990	363.20	0.3640
0.4600	353.20	0.4240
0.4720	363.20	0.4200
0.5160	353.20	0.4690
0.5380	363.20	0.4700
0.5590	373.20	0.4810
0.5820	373.20	0.4930
0.5970	353.20	0.5280
0.6070	363.20	0.5250
0.6280	373.20	0.5380
0.6480	353.20	0.5690
0.6720	363.20	0.5780
0.6720	373.20	0.5800
0.7120	373.20	0.6160
0.7190	353.20	0.6290
0.7190	363.20	0.6160
0.7290	363.20	0.6290
0.7400	373.20	0.6350
0.7590	373.20	0.6620
0.7630	353.20	0.6700
0.7870	363.20	0.6860
0.8090	373.20	0.7190
0.8230	353.20	0.7310
0.8270	353.20	0.7390
0.8360	363.20	0.7400
0.8780	373.20	0.7970
0.8790	353.20	0.8010
0.8800	363.20	0.7950
0.9140	373.20	0.8520
0.9210	363.20	0.8520
0.9230	353.20	0.8670
0.9420	373.20	0.8960
0.9430	363.20	0.8890
0.9500	363.20	0.9000
0.9530	373.20	0.9120
0.9650	373.20	0.9330
0.9680	353.20	0.9390
0.9690	363.20	0.9330
1.0000	353.20	1.0000
1.0000	363.20	1.0000
1.0000	373.20	1.0000

Mole fraction of Pyrrole (2) [ref]

Operational condition: Pressure, kPa = 40 (Liquid)

Mole fraction of Pyrrole (2) - Liquid	Mole fraction of Pyrrole (2) - Gas
0.0000	0.0000
0.0480	0.0470
0.0490	0.0490
0.0720	0.0710
0.0900	0.0890
0.1050	0.1090
0.1680	0.1640
0.2100	0.1950
0.2230	0.2110
0.3120	0.2780
0.4050	0.3620
0.4950	0.4310
0.5640	0.4850
0.6100	0.5200
0.6250	0.5320
0.6900	0.5890
0.7710	0.6630
0.8380	0.7370
0.8730	0.7940
0.9120	0.8370
0.9410	0.8820
0.9540	0.9140
0.9800	0.9520
1.0000	1.0000

Mole fraction of Pyrrole (2) [ref]

Fixed		Measured
Mole fraction of Pyrrole (2) - Liquid	Temperature, K - Liquid	Mole fraction of Pyrrole (2) - Gas
0.0000	353.20	0.0000
0.0000	363.20	0.0000
0.0000	373.20	0.0000
0.0150	363.20	0.0210
0.0290	353.20	0.0410
0.0370	363.20	0.0400
0.0520	353.20	0.0750
0.0590	373.20	0.0600
0.0670	363.20	0.0680
0.0710	353.20	0.0970
0.0710	373.20	0.0610
0.0960	373.20	0.0910
0.0980	353.20	0.1080
0.1000	363.20	0.1040
0.1100	353.20	0.1230
0.1240	363.20	0.1250
0.1500	373.20	0.1410
0.1530	363.20	0.1510
0.1590	353.20	0.1710
0.2040	363.20	0.2040
0.2070	353.20	0.2150
0.2130	353.20	0.2230
0.2690	373.20	0.2500
0.2740	353.20	0.2780
0.2920	373.20	0.2670
0.3060	363.20	0.2880
0.3660	373.20	0.3260
0.3760	353.20	0.3520
0.3830	353.20	0.3680
0.3990	363.20	0.3640
0.4600	353.20	0.4240
0.4720	363.20	0.4200
0.5160	353.20	0.4690
0.5380	363.20	0.4700
0.5590	373.20	0.4810
0.5820	373.20	0.4930
0.5970	353.20	0.5280
0.6070	363.20	0.5250
0.6280	373.20	0.5380
0.6480	353.20	0.5690
0.6720	363.20	0.5780
0.6720	373.20	0.5800
0.7120	373.20	0.6160
0.7190	353.20	0.6290
0.7190	363.20	0.6160
0.7290	363.20	0.6290
0.7400	373.20	0.6350
0.7590	373.20	0.6620
0.7630	353.20	0.6700
0.7870	363.20	0.6860
0.8090	373.20	0.7190
0.8230	353.20	0.7310
0.8270	353.20	0.7390
0.8360	363.20	0.7400
0.8780	373.20	0.7970
0.8790	353.20	0.8010
0.8800	363.20	0.7950
0.9140	373.20	0.8520
0.9210	363.20	0.8520
0.9230	353.20	0.8670
0.9420	373.20	0.8960
0.9430	363.20	0.8890
0.9500	363.20	0.9000
0.9530	373.20	0.9120
0.9650	373.20	0.9330
0.9680	353.20	0.9390
0.9690	363.20	0.9330
1.0000	353.20	1.0000
1.0000	363.20	1.0000
1.0000	373.20	1.0000

Mole fraction of Pyrrole (2) [ref]

Operational condition: Pressure, kPa = 40 (Liquid)

Mole fraction of Pyrrole (2) - Liquid	Mole fraction of Pyrrole (2) - Gas
0.0000	0.0000
0.0480	0.0470
0.0490	0.0490
0.0720	0.0710
0.0900	0.0890
0.1050	0.1090
0.1680	0.1640
0.2100	0.1950
0.2230	0.2110
0.3120	0.2780
0.4050	0.3620
0.4950	0.4310
0.5640	0.4850
0.6100	0.5200
0.6250	0.5320
0.6900	0.5890
0.7710	0.6630
0.8380	0.7370
0.8730	0.7940
0.9120	0.8370
0.9410	0.8820
0.9540	0.9140
0.9800	0.9520
1.0000	1.0000

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational conditions:

• Pressure, kPa = 101 (Liquid)
• Temperature, K = 298.15 (Liquid)

Mole fraction of Pyrrole (2) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.0262	0.0190
0.0776	0.1038
0.1154	0.1898
0.1526	0.2841
0.1890	0.3807
0.2248	0.4754
0.2599	0.5659
0.2944	0.6503
0.3283	0.7274
0.3616	0.7965
0.3943	0.8572
0.4265	0.9093
0.4581	0.9527
0.4891	0.9873
0.5196	1.0132
0.5497	1.0304
0.5703	1.0284
0.5792	1.039
0.5803	1.0304
0.6003	1.0314
0.6082	1.0391
0.6203	1.0283
0.6225	1.0359
0.6403	1.0211
0.6603	1.0097
0.6803	0.9939
0.7003	0.9737
0.7203	0.9488
0.7403	0.9192
0.7603	0.8847
0.7803	0.8451
0.8002	0.8002
0.8202	0.7497
0.8403	0.6935
0.8603	0.6314
0.8802	0.5629
0.9002	0.4884
0.9201	0.4067
0.9401	0.3183
0.9601	0.2226
0.9800	0.1192

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational conditions:

• Pressure, kPa = 101 (Liquid)
• Temperature, K = 298.15 (Liquid)

Mole fraction of Pyrrole (2) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.0262	0.0190
0.0776	0.1038
0.1154	0.1898
0.1526	0.2841
0.1890	0.3807
0.2248	0.4754
0.2599	0.5659
0.2944	0.6503
0.3283	0.7274
0.3616	0.7965
0.3943	0.8572
0.4265	0.9093
0.4581	0.9527
0.4891	0.9873
0.5196	1.0132
0.5497	1.0304
0.5703	1.0284
0.5792	1.039
0.5803	1.0304
0.6003	1.0314
0.6082	1.0391
0.6203	1.0283
0.6225	1.0359
0.6403	1.0211
0.6603	1.0097
0.6803	0.9939
0.7003	0.9737
0.7203	0.9488
0.7403	0.9192
0.7603	0.8847
0.7803	0.8451
0.8002	0.8002
0.8202	0.7497
0.8403	0.6935
0.8603	0.6314
0.8802	0.5629
0.9002	0.4884
0.9201	0.4067
0.9401	0.3183
0.9601	0.2226
0.9800	0.1192

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Mole fraction of Pyrrole (2) - Liquid	Temperature, K - Liquid	Vapor or sublimation pressure, kPa - Liquid
0.0000	353.20	21.84
0.0000	363.20	34.50
0.0000	373.20	52.31
0.0150	363.20	34.45
0.0290	353.20	21.88
0.0370	363.20	34.45
0.0520	353.20	21.97
0.0590	373.20	52.45
0.0670	363.20	34.41
0.0710	353.20	22.02
0.0710	373.20	52.61
0.0960	373.20	52.71
0.0980	353.20	22.11
0.1000	363.20	34.35
0.1100	353.20	22.14
0.1240	363.20	34.31
0.1500	373.20	52.67
0.1530	363.20	34.31
0.1590	353.20	22.21
0.2040	363.20	34.28
0.2070	353.20	22.28
0.2130	353.20	22.30
0.2690	373.20	52.30
0.2740	353.20	22.30
0.2920	373.20	52.13
0.3060	363.20	34.28
0.3660	373.20	51.39
0.3760	353.20	22.33
0.3830	353.20	22.30
0.3990	363.20	33.98
0.4600	353.20	22.21
0.4720	363.20	33.65
0.5160	353.20	22.08
0.5380	363.20	33.31
0.5590	373.20	49.07
0.5820	373.20	48.86
0.5970	353.20	21.91
0.6070	363.20	32.75
0.6280	373.20	48.17
0.6480	353.20	21.69
0.6720	363.20	32.23
0.6720	373.20	47.48
0.7120	373.20	46.77
0.7190	353.20	21.13
0.7190	363.20	31.80
0.7290	363.20	31.63
0.7400	373.20	46.42
0.7590	373.20	45.97
0.7630	353.20	20.90
0.7870	363.20	30.92
0.8090	373.20	44.66
0.8230	353.20	20.40
0.8270	353.20	20.31
0.8360	363.20	30.25
0.8780	373.20	43.20
0.8790	353.20	19.86
0.8800	363.20	29.43
0.9140	373.20	42.24
0.9210	363.20	28.63
0.9230	353.20	19.24
0.9420	373.20	41.29
0.9430	363.20	28.22
0.9500	363.20	28.01
0.9530	373.20	40.69
0.9650	373.20	40.25
0.9680	353.20	18.54
0.9690	363.20	27.59
1.0000	353.20	18.02
1.0000	363.20	26.88
1.0000	373.20	38.24

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Mole fraction of Pyrrole (2) - Liquid	Temperature, K - Liquid	Vapor or sublimation pressure, kPa - Liquid
0.0000	353.20	21.84
0.0000	363.20	34.50
0.0000	373.20	52.31
0.0150	363.20	34.45
0.0290	353.20	21.88
0.0370	363.20	34.45
0.0520	353.20	21.97
0.0590	373.20	52.45
0.0670	363.20	34.41
0.0710	353.20	22.02
0.0710	373.20	52.61
0.0960	373.20	52.71
0.0980	353.20	22.11
0.1000	363.20	34.35
0.1100	353.20	22.14
0.1240	363.20	34.31
0.1500	373.20	52.67
0.1530	363.20	34.31
0.1590	353.20	22.21
0.2040	363.20	34.28
0.2070	353.20	22.28
0.2130	353.20	22.30
0.2690	373.20	52.30
0.2740	353.20	22.30
0.2920	373.20	52.13
0.3060	363.20	34.28
0.3660	373.20	51.39
0.3760	353.20	22.33
0.3830	353.20	22.30
0.3990	363.20	33.98
0.4600	353.20	22.21
0.4720	363.20	33.65
0.5160	353.20	22.08
0.5380	363.20	33.31
0.5590	373.20	49.07
0.5820	373.20	48.86
0.5970	353.20	21.91
0.6070	363.20	32.75
0.6280	373.20	48.17
0.6480	353.20	21.69
0.6720	363.20	32.23
0.6720	373.20	47.48
0.7120	373.20	46.77
0.7190	353.20	21.13
0.7190	363.20	31.80
0.7290	363.20	31.63
0.7400	373.20	46.42
0.7590	373.20	45.97
0.7630	353.20	20.90
0.7870	363.20	30.92
0.8090	373.20	44.66
0.8230	353.20	20.40
0.8270	353.20	20.31
0.8360	363.20	30.25
0.8780	373.20	43.20
0.8790	353.20	19.86
0.8800	363.20	29.43
0.9140	373.20	42.24
0.9210	363.20	28.63
0.9230	353.20	19.24
0.9420	373.20	41.29
0.9430	363.20	28.22
0.9500	363.20	28.01
0.9530	373.20	40.69
0.9650	373.20	40.25
0.9680	353.20	18.54
0.9690	363.20	27.59
1.0000	353.20	18.02
1.0000	363.20	26.88
1.0000	373.20	38.24

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 40 (Liquid)

Mole fraction of Pyrrole (2) - Liquid	Boiling temperature at pressure P, K - Liquid
0.0000	366.80
0.0480	366.50
0.0490	366.40
0.0720	366.40
0.0900	366.40
0.1050	366.30
0.1680	366.40
0.2100	366.40
0.2230	366.40
0.3120	366.60
0.4050	366.90
0.4950	367.30
0.5640	367.70
0.6100	367.90
0.6250	368.10
0.6900	368.70
0.7710	369.60
0.8380	370.50
0.8730	371.20
0.9120	371.80
0.9410	372.40
0.9540	372.90
0.9800	373.40
1.0000	374.70

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 40 (Liquid)

Mole fraction of Pyrrole (2) - Liquid	Boiling temperature at pressure P, K - Liquid
0.0000	366.80
0.0480	366.50
0.0490	366.40
0.0720	366.40
0.0900	366.40
0.1050	366.30
0.1680	366.40
0.2100	366.40
0.2230	366.40
0.3120	366.60
0.4050	366.90
0.4950	367.30
0.5640	367.70
0.6100	367.90
0.6250	368.10
0.6900	368.70
0.7710	369.60
0.8380	370.50
0.8730	371.20
0.9120	371.80
0.9410	372.40
0.9540	372.90
0.9800	373.40
1.0000	374.70

Sources

• Phase equilibria and excess molar enthalpies study of the binary systems (pyrrole + hydrocarbon, or an alcohol) and modeling
• Vapor Liquid Equilibrium Data for Binary Systems of 1H-Pyrrole with Butan-1-ol, Propan-1-ol, or Pentan-1-ol