Mixture of Toluene + Carbonic acid, dimethyl ester

Datasets

1. Mole fraction (2)
2. n₀ - Refractive index (Na D-line) (2)
3. ρ_l - Mass density, kg/m3 (4)
4. Excess molar volume, m3/mol (2)

Mole fraction of Carbonic acid, dimethyl ester (2) [ref]

Operational condition: Temperature, K = 333.15 (Liquid)

Mole fraction of Carbonic acid, dimethyl ester (2) - Liquid	Mole fraction of Carbonic acid, dimethyl ester (2) - Gas
0.0170	0.0530
0.0343	0.0979
0.0501	0.1328
0.1000	0.2322
0.1495	0.3150
0.1996	0.3866
0.2496	0.4403
0.2997	0.4994
0.3496	0.5381
0.3996	0.5887
0.4497	0.6276
0.4997	0.6633
0.5498	0.6907
0.5998	0.7263
0.6499	0.7586
0.6996	0.7828
0.7499	0.8201
0.8000	0.8517
0.8500	0.8801
0.9000	0.9149
0.9502	0.9550
0.9661	0.9703
0.9830	0.9840

Mole fraction of Carbonic acid, dimethyl ester (2) [ref]

Operational condition: Temperature, K = 333.15 (Liquid)

Mole fraction of Carbonic acid, dimethyl ester (2) - Liquid	Mole fraction of Carbonic acid, dimethyl ester (2) - Gas
0.0170	0.0530
0.0343	0.0979
0.0501	0.1328
0.1000	0.2322
0.1495	0.3150
0.1996	0.3866
0.2496	0.4403
0.2997	0.4994
0.3496	0.5381
0.3996	0.5887
0.4497	0.6276
0.4997	0.6633
0.5498	0.6907
0.5998	0.7263
0.6499	0.7586
0.6996	0.7828
0.7499	0.8201
0.8000	0.8517
0.8500	0.8801
0.9000	0.9149
0.9502	0.9550
0.9661	0.9703
0.9830	0.9840

Refractive index (Na D-line) [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Mole fraction of Carbonic acid, dimethyl ester (2) - Liquid	Refractive index (Na D-line) - Liquid
0.0496	1.4883
0.0998	1.4827
0.2001	1.4715
0.3003	1.4597
0.3998	1.4475
0.5002	1.4352
0.5999	1.4224
0.6999	1.4091
0.7998	1.3954
0.8988	1.3814
0.9487	1.3741

Refractive index (Na D-line) [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Mole fraction of Carbonic acid, dimethyl ester (2) - Liquid	Refractive index (Na D-line) - Liquid
0.0496	1.4883
0.0998	1.4827
0.2001	1.4715
0.3003	1.4597
0.3998	1.4475
0.5002	1.4352
0.5999	1.4224
0.6999	1.4091
0.7998	1.3954
0.8988	1.3814
0.9487	1.3741

Mass density, kg/m3 [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Mole fraction of Carbonic acid, dimethyl ester (2) - Liquid	Mass density, kg/m3 - Liquid
0.0496	869.6
0.0998	877.39
0.2001	893.69
0.3003	910.85
0.3998	928.88
0.5002	948.0
0.5999	968.16
0.6999	989.62
0.7998	1012.35
0.8988	1036.61
0.9487	1049.29

Mass density, kg/m3 [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Mole fraction of Carbonic acid, dimethyl ester (2) - Liquid	Mass density, kg/m3 - Liquid
0.0000	862.5
0.0498	869.9
0.0998	877.68
0.1500	885.75
0.1999	893.96
0.2498	902.39
0.2999	911.1
0.3498	919.98
0.4000	929.22
0.4498	938.57
0.4999	948.26
0.5499	958.27
0.5999	968.51
0.6500	979.06
0.7000	989.94
0.7499	1001.14
0.8001	1012.77
0.8501	1024.73
0.8998	1037.03
0.9502	1049.89
1.0000	1063.19

Mass density, kg/m3 [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Mole fraction of Carbonic acid, dimethyl ester (2) - Liquid	Mass density, kg/m3 - Liquid
0.0496	869.6
0.0998	877.39
0.2001	893.69
0.3003	910.85
0.3998	928.88
0.5002	948.0
0.5999	968.16
0.6999	989.62
0.7998	1012.35
0.8988	1036.61
0.9487	1049.29

Mass density, kg/m3 [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Mole fraction of Carbonic acid, dimethyl ester (2) - Liquid	Mass density, kg/m3 - Liquid
0.0000	862.5
0.0498	869.9
0.0998	877.68
0.1500	885.75
0.1999	893.96
0.2498	902.39
0.2999	911.1
0.3498	919.98
0.4000	929.22
0.4498	938.57
0.4999	948.26
0.5499	958.27
0.5999	968.51
0.6500	979.06
0.7000	989.94
0.7499	1001.14
0.8001	1012.77
0.8501	1024.73
0.8998	1037.03
0.9502	1049.89
1.0000	1063.19

Excess molar volume, m3/mol [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Mole fraction of Carbonic acid, dimethyl ester (2) - Liquid	Excess molar volume, m3/mol - Liquid
0.0496	7.0100e-08
0.0998	1.2250e-07
0.2001	2.0080e-07
0.3003	2.5610e-07
0.3998	2.8870e-07
0.5002	3.0870e-07
0.5999	3.0110e-07
0.6999	2.7040e-07
0.7998	2.2070e-07
0.8988	1.2260e-07
0.9487	7.6300e-08

Excess molar volume, m3/mol [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Mole fraction of Carbonic acid, dimethyl ester (2) - Liquid	Excess molar volume, m3/mol - Liquid
0.0496	7.0100e-08
0.0998	1.2250e-07
0.2001	2.0080e-07
0.3003	2.5610e-07
0.3998	2.8870e-07
0.5002	3.0870e-07
0.5999	3.0110e-07
0.6999	2.7040e-07
0.7998	2.2070e-07
0.8988	1.2260e-07
0.9487	7.6300e-08

Sources

• Isothermal vapor-liquid equilibrium at T = 333.15 K and excess volumes and molar refractivity deviation at T = 298.15 K for the ternary mixtures {di-methyl carbonate (DMC) + ethanol + benzene} and {DMC+ ethanol + toluene}
• Excess Molar Volumes at 298.15 K and Isothermal Vapor-Liquid Equilibria at 333.15 K for the Binary Mixtures of Dimethyl Carbonate with Benzene, Toluene, n-Heptane, and Isooctane