Mixture of Cyclohexanol + Cyclohexanone

Datasets

1. Mole fraction (2)
2. Excess molar enthalpy (molar enthalpy (2)
3. P_vap - Vapor or sublimation pressure, kPa (2)
4. T_fus - Solid-liquid equilibrium temperature, K (2)

Mole fraction of Cyclohexanol (1) [ref]

Operational condition: Pressure, kPa = 99 (Gas)

Mole fraction of Cyclohexanol (1) - Liquid	Mole fraction of Cyclohexanol (1) - Gas
0.0920	0.0820
0.1000	0.1270
0.1590	0.1440
0.2270	0.2080
0.3600	0.3280
0.5450	0.5040
0.6810	0.6420
0.7990	0.7690
0.8840	0.8610

Mole fraction of Cyclohexanol (1) [ref]

Operational condition: Pressure, kPa = 99 (Gas)

Mole fraction of Cyclohexanol (1) - Liquid	Mole fraction of Cyclohexanol (1) - Gas
0.0920	0.0820
0.1000	0.1270
0.1590	0.1440
0.2270	0.2080
0.3600	0.3280
0.5450	0.5040
0.6810	0.6420
0.7990	0.7690
0.8840	0.8610

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Fixed			Measured
Temperature, K - Liquid	Pressure, kPa - Liquid	Mole fraction of Cyclohexanone (2) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
363.15	1651.00	0.0510	0.2721
363.15	1651.00	0.1020	0.5205
363.15	1651.00	0.1530	0.7339
363.15	1651.00	0.2040	0.9195
363.15	1651.00	0.2540	1.0686
363.15	1651.00	0.3050	1.1913
363.15	1651.00	0.3550	1.2828
363.15	1651.00	0.4060	1.3449
363.15	1651.00	0.4560	1.3788
363.15	1651.00	0.5060	1.3958
363.15	1651.00	0.5550	1.3707
363.15	1651.00	0.6050	1.3235
363.15	1651.00	0.6550	1.2501
363.15	1651.00	0.7050	1.1489
363.15	1651.00	0.7540	1.0196
363.15	1651.00	0.8030	0.8698
363.15	1651.00	0.8530	0.6881
363.15	1651.00	0.9020	0.4823
363.15	1651.00	0.9510	0.2491
413.15	1582.00	0.0510	0.1625
413.15	1582.00	0.1020	0.3111
413.15	1582.00	0.1530	0.4437
413.15	1582.00	0.2030	0.5613
413.15	1582.00	0.2540	0.6567
413.15	1582.00	0.3040	0.7327
413.15	1582.00	0.3550	0.7943
413.15	1582.00	0.4050	0.8315
413.15	1582.00	0.4550	0.8523
413.15	1582.00	0.5050	0.8632
413.15	1582.00	0.5550	0.8464
413.15	1582.00	0.6050	0.8165
413.15	1582.00	0.6550	0.7660
413.15	1582.00	0.7040	0.7014
413.15	1582.00	0.7540	0.6207
413.15	1582.00	0.8030	0.5262
413.15	1582.00	0.8530	0.4120
413.15	1582.00	0.9020	0.2849
413.15	1582.00	0.9510	0.1463

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Fixed			Measured
Temperature, K - Liquid	Pressure, kPa - Liquid	Mole fraction of Cyclohexanone (2) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
363.15	1651.00	0.0510	0.2721
363.15	1651.00	0.1020	0.5205
363.15	1651.00	0.1530	0.7339
363.15	1651.00	0.2040	0.9195
363.15	1651.00	0.2540	1.0686
363.15	1651.00	0.3050	1.1913
363.15	1651.00	0.3550	1.2828
363.15	1651.00	0.4060	1.3449
363.15	1651.00	0.4560	1.3788
363.15	1651.00	0.5060	1.3958
363.15	1651.00	0.5550	1.3707
363.15	1651.00	0.6050	1.3235
363.15	1651.00	0.6550	1.2501
363.15	1651.00	0.7050	1.1489
363.15	1651.00	0.7540	1.0196
363.15	1651.00	0.8030	0.8698
363.15	1651.00	0.8530	0.6881
363.15	1651.00	0.9020	0.4823
363.15	1651.00	0.9510	0.2491
413.15	1582.00	0.0510	0.1625
413.15	1582.00	0.1020	0.3111
413.15	1582.00	0.1530	0.4437
413.15	1582.00	0.2030	0.5613
413.15	1582.00	0.2540	0.6567
413.15	1582.00	0.3040	0.7327
413.15	1582.00	0.3550	0.7943
413.15	1582.00	0.4050	0.8315
413.15	1582.00	0.4550	0.8523
413.15	1582.00	0.5050	0.8632
413.15	1582.00	0.5550	0.8464
413.15	1582.00	0.6050	0.8165
413.15	1582.00	0.6550	0.7660
413.15	1582.00	0.7040	0.7014
413.15	1582.00	0.7540	0.6207
413.15	1582.00	0.8030	0.5262
413.15	1582.00	0.8530	0.4120
413.15	1582.00	0.9020	0.2849
413.15	1582.00	0.9510	0.1463

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Cyclohexanone (2) - Liquid	Vapor or sublimation pressure, kPa - Liquid
323.15	0.0000	0.74
323.15	0.0011	0.75
323.15	0.0032	0.76
323.15	0.0056	0.77
323.15	0.0092	0.79
323.15	0.0138	0.81
323.15	0.0198	0.83
323.15	0.0287	0.86
323.15	0.0425	0.90
323.15	0.0602	0.95
323.15	0.0827	1.01
323.15	0.1100	1.07
323.15	0.1410	1.14
323.15	0.1810	1.22
323.15	0.2230	1.30
323.15	0.2690	1.37
323.15	0.3160	1.45
323.15	0.3640	1.52
323.15	0.4120	1.59
323.15	0.4400	1.66
323.15	0.4640	1.66
323.15	0.5050	1.72
323.15	0.5070	1.71
323.15	0.5480	1.77
323.15	0.5990	1.82
323.15	0.6470	1.87
323.15	0.6940	1.92
323.15	0.7400	1.97
323.15	0.7850	2.02
323.15	0.8270	2.07
323.15	0.8650	2.11
323.15	0.8950	2.14
323.15	0.9220	2.16
323.15	0.9430	2.18
323.15	0.9600	2.20
323.15	0.9740	2.21
323.15	0.9830	2.22
323.15	0.9980	2.23
323.15	0.9990	2.23
323.15	1.0000	2.23
363.15	0.0000	6.88
363.15	0.0012	6.91
363.15	0.0035	6.96
363.15	0.0061	7.01
363.15	0.0100	7.07
363.15	0.0140	7.12
363.15	0.0198	7.21
363.15	0.0290	7.31
363.15	0.0427	7.46
363.15	0.0604	7.64
363.15	0.0828	7.85
363.15	0.1100	8.10
363.15	0.1410	8.37
363.15	0.1800	8.70
363.15	0.2230	9.03
363.15	0.2690	9.37
363.15	0.3160	9.70
363.15	0.3640	10.02
363.15	0.4120	10.32
363.15	0.4590	10.60
363.15	0.4640	10.68
363.15	0.5050	10.87
363.15	0.5070	10.86
363.15	0.5520	11.06
363.15	0.5990	11.27
363.15	0.6470	11.48
363.15	0.6940	11.69
363.15	0.7400	11.90
363.15	0.7850	12.10
363.15	0.8260	12.28
363.15	0.8640	12.46
363.15	0.8950	12.59
363.15	0.9210	12.70
363.15	0.9430	12.80
363.15	0.9600	12.86
363.15	0.9730	12.93
363.15	0.9820	12.96
363.15	0.9880	12.99
363.15	0.9910	13.00
363.15	0.9950	13.02
363.15	0.9980	13.03
363.15	0.9990	13.04
363.15	1.0000	13.05

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Cyclohexanone (2) - Liquid	Vapor or sublimation pressure, kPa - Liquid
323.15	0.0000	0.74
323.15	0.0011	0.75
323.15	0.0032	0.76
323.15	0.0056	0.77
323.15	0.0092	0.79
323.15	0.0138	0.81
323.15	0.0198	0.83
323.15	0.0287	0.86
323.15	0.0425	0.90
323.15	0.0602	0.95
323.15	0.0827	1.01
323.15	0.1100	1.07
323.15	0.1410	1.14
323.15	0.1810	1.22
323.15	0.2230	1.30
323.15	0.2690	1.37
323.15	0.3160	1.45
323.15	0.3640	1.52
323.15	0.4120	1.59
323.15	0.4400	1.66
323.15	0.4640	1.66
323.15	0.5050	1.72
323.15	0.5070	1.71
323.15	0.5480	1.77
323.15	0.5990	1.82
323.15	0.6470	1.87
323.15	0.6940	1.92
323.15	0.7400	1.97
323.15	0.7850	2.02
323.15	0.8270	2.07
323.15	0.8650	2.11
323.15	0.8950	2.14
323.15	0.9220	2.16
323.15	0.9430	2.18
323.15	0.9600	2.20
323.15	0.9740	2.21
323.15	0.9830	2.22
323.15	0.9980	2.23
323.15	0.9990	2.23
323.15	1.0000	2.23
363.15	0.0000	6.88
363.15	0.0012	6.91
363.15	0.0035	6.96
363.15	0.0061	7.01
363.15	0.0100	7.07
363.15	0.0140	7.12
363.15	0.0198	7.21
363.15	0.0290	7.31
363.15	0.0427	7.46
363.15	0.0604	7.64
363.15	0.0828	7.85
363.15	0.1100	8.10
363.15	0.1410	8.37
363.15	0.1800	8.70
363.15	0.2230	9.03
363.15	0.2690	9.37
363.15	0.3160	9.70
363.15	0.3640	10.02
363.15	0.4120	10.32
363.15	0.4590	10.60
363.15	0.4640	10.68
363.15	0.5050	10.87
363.15	0.5070	10.86
363.15	0.5520	11.06
363.15	0.5990	11.27
363.15	0.6470	11.48
363.15	0.6940	11.69
363.15	0.7400	11.90
363.15	0.7850	12.10
363.15	0.8260	12.28
363.15	0.8640	12.46
363.15	0.8950	12.59
363.15	0.9210	12.70
363.15	0.9430	12.80
363.15	0.9600	12.86
363.15	0.9730	12.93
363.15	0.9820	12.96
363.15	0.9880	12.99
363.15	0.9910	13.00
363.15	0.9950	13.02
363.15	0.9980	13.03
363.15	0.9990	13.04
363.15	1.0000	13.05

Solid-liquid equilibrium temperature, K [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Mole fraction of Cyclohexanone (2) - Liquid	Solid-liquid equilibrium temperature, K - Liquid
0.0000	297.20
0.0480	293.70
0.1030	289.40
0.1520	286.60
0.2020	282.80
0.2500	279.70
0.3010	276.60
0.3500	273.70
0.4000	271.20
0.4500	268.80
0.5020	267.30
0.5500	264.10
0.6180	260.70
0.6490	259.70
0.6990	258.00
0.7500	255.90
0.8020	253.50
0.8530	251.40
0.9030	249.20
0.9530	247.10
1.0000	245.90

Solid-liquid equilibrium temperature, K [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Mole fraction of Cyclohexanone (2) - Liquid	Solid-liquid equilibrium temperature, K - Liquid
0.0000	297.20
0.0480	293.70
0.1030	289.40
0.1520	286.60
0.2020	282.80
0.2500	279.70
0.3010	276.60
0.3500	273.70
0.4000	271.20
0.4500	268.80
0.5020	267.30
0.5500	264.10
0.6180	260.70
0.6490	259.70
0.6990	258.00
0.7500	255.90
0.8020	253.50
0.8530	251.40
0.9030	249.20
0.9530	247.10
1.0000	245.90

Sources

• Vapour liquid equilibria, azeotropic data, excess enthalpies, activity coefficients at infinite dilution and solid liquid equilibria for binary alcohol ketone systems
• Vapor-Liquid Equilibria of Cyclohexanone + 2-Cyclohexen-1-one and Cyclohexanol + 2-Cyclohexen-1-one, Validated in a Packed Column Distillation.