Mixture of n-Hexane + Triethylamine + 1-Butanol

Datasets

1. Excess molar enthalpy (molar enthalpy (2)
2. Excess molar volume, m3/mol (2)

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101.325 (Liquid)

Fixed		Measured
Mole fraction of 1-Butanol (3) - Liquid	Mole fraction of Triethylamine (2) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.0100	0.9500	-0.0178
0.0200	0.9500	-0.0529
0.0201	0.8999	-0.0419
0.0301	0.8499	-0.0667
0.0301	0.9499	-0.1034
0.0401	0.8000	-0.0895
0.0401	0.8999	-0.1197
0.0401	0.9499	-0.1352
0.0501	0.4746	0.0258
0.0501	0.7501	-0.1070
0.0600	0.8501	-0.1779
0.0600	0.9001	-0.2031
0.0601	0.7000	-0.1282
0.0701	0.6500	-0.1462
0.0800	0.8001	-0.2360
0.0801	0.6001	-0.1622
0.0801	0.8999	-0.2788
0.0900	0.8501	-0.2999
0.0902	0.5500	-0.1745
0.1000	0.4496	-0.0916
0.1000	0.7501	-0.2894
0.1002	0.5000	-0.1824
0.1102	0.4501	-0.1871
0.1200	0.8500	-0.4128
0.1200	0.8500	-0.4166
0.1201	0.7000	-0.3372
0.1202	0.4001	-0.1865
0.1202	0.7999	-0.3891
0.1302	0.3500	-0.1785
0.1402	0.6499	-0.3803
0.1403	0.3000	-0.1598
0.1500	0.4246	-0.2336
0.1501	0.7500	-0.4776
0.1503	0.2499	-0.1291
0.1599	0.8001	-0.5444
0.1602	0.5999	-0.4175
0.1603	0.2000	-0.0801
0.1710	0.1464	0.0007
0.1801	0.5501	-0.4466
0.1801	0.7001	-0.5528
0.1803	0.1001	0.1020
0.1844	0.0799	0.1573
0.1884	0.0599	0.2262
0.1903	0.0501	0.2628
0.1924	0.0400	0.3067
0.1964	0.0199	0.4032
0.1999	0.7501	-0.6645
0.2000	0.3997	-0.3622
0.2000	0.3997	-0.3648
0.2002	0.4999	-0.4685
0.2101	0.6501	-0.6171
0.2202	0.4500	-0.4707
0.2399	0.7001	-0.7739
0.2399	0.7001	-0.7639
0.2402	0.4000	-0.4672
0.2403	0.5999	-0.6747
0.2501	0.3746	-0.4564
0.2603	0.3499	-0.4615
0.2703	0.5499	-0.7211
0.2799	0.6500	-0.8572
0.2803	0.2999	-0.4315
0.3001	0.3497	-0.5368
0.3001	0.3497	-0.5357
0.3003	0.2500	-0.3698
0.3003	0.5000	-0.7542
0.3199	0.6000	-0.9384
0.3203	0.1999	-0.2893
0.3303	0.4500	-0.7718
0.3403	0.1499	-0.1656
0.3501	0.3247	-0.6017
0.3599	0.5500	-1.0042
0.3603	0.1001	-0.0013
0.3604	0.3999	-0.7698
0.3683	0.0801	0.0818
0.3763	0.0601	0.1739
0.3804	0.0499	0.2245
0.3843	0.0400	0.2736
0.3904	0.3499	-0.7490
0.3924	0.0199	0.4091
0.3999	0.5000	-1.0517
0.4000	0.2998	-0.6543
0.4205	0.2999	-0.7097
0.4399	0.4500	-1.0781
0.4500	0.2748	-0.6895
0.4504	0.2501	-0.6299
0.4798	0.4001	-1.0817
0.4804	0.2001	-0.5119
0.5000	0.2498	-0.7159
0.5105	0.1500	-0.3649
0.5199	0.3500	-1.0611
0.5399	0.1011	-0.1729
0.5405	0.1001	-0.1650
0.5499	0.2249	-0.7250
0.5599	0.2999	-1.0094
0.5706	0.0500	0.0886
0.5999	0.1999	-0.7186
0.5999	0.2500	-0.9262
0.6398	0.2000	-0.8053
0.6500	0.1749	-0.6956
0.6799	0.1499	-0.6420
0.6999	0.1499	-0.6553
0.7198	0.1000	-0.4387
0.7357	0.0801	-0.3320
0.7499	0.1249	-0.5977
0.7517	0.0601	-0.2211
0.7598	0.0500	-0.1490
0.7678	0.0400	-0.0866
0.7839	0.0199	0.0630
0.7999	0.1000	-0.5211
0.8500	0.0749	-0.4249
0.9000	0.0500	-0.3074
0.9499	0.0250	-0.1615
0.9499	0.0250	-0.1504

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101.325 (Liquid)

Fixed		Measured
Mole fraction of 1-Butanol (3) - Liquid	Mole fraction of Triethylamine (2) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.0100	0.9500	-0.0178
0.0200	0.9500	-0.0529
0.0201	0.8999	-0.0419
0.0301	0.8499	-0.0667
0.0301	0.9499	-0.1034
0.0401	0.8000	-0.0895
0.0401	0.8999	-0.1197
0.0401	0.9499	-0.1352
0.0501	0.4746	0.0258
0.0501	0.7501	-0.1070
0.0600	0.8501	-0.1779
0.0600	0.9001	-0.2031
0.0601	0.7000	-0.1282
0.0701	0.6500	-0.1462
0.0800	0.8001	-0.2360
0.0801	0.6001	-0.1622
0.0801	0.8999	-0.2788
0.0900	0.8501	-0.2999
0.0902	0.5500	-0.1745
0.1000	0.4496	-0.0916
0.1000	0.7501	-0.2894
0.1002	0.5000	-0.1824
0.1102	0.4501	-0.1871
0.1200	0.8500	-0.4128
0.1200	0.8500	-0.4166
0.1201	0.7000	-0.3372
0.1202	0.4001	-0.1865
0.1202	0.7999	-0.3891
0.1302	0.3500	-0.1785
0.1402	0.6499	-0.3803
0.1403	0.3000	-0.1598
0.1500	0.4246	-0.2336
0.1501	0.7500	-0.4776
0.1503	0.2499	-0.1291
0.1599	0.8001	-0.5444
0.1602	0.5999	-0.4175
0.1603	0.2000	-0.0801
0.1710	0.1464	0.0007
0.1801	0.5501	-0.4466
0.1801	0.7001	-0.5528
0.1803	0.1001	0.1020
0.1844	0.0799	0.1573
0.1884	0.0599	0.2262
0.1903	0.0501	0.2628
0.1924	0.0400	0.3067
0.1964	0.0199	0.4032
0.1999	0.7501	-0.6645
0.2000	0.3997	-0.3622
0.2000	0.3997	-0.3648
0.2002	0.4999	-0.4685
0.2101	0.6501	-0.6171
0.2202	0.4500	-0.4707
0.2399	0.7001	-0.7739
0.2399	0.7001	-0.7639
0.2402	0.4000	-0.4672
0.2403	0.5999	-0.6747
0.2501	0.3746	-0.4564
0.2603	0.3499	-0.4615
0.2703	0.5499	-0.7211
0.2799	0.6500	-0.8572
0.2803	0.2999	-0.4315
0.3001	0.3497	-0.5368
0.3001	0.3497	-0.5357
0.3003	0.2500	-0.3698
0.3003	0.5000	-0.7542
0.3199	0.6000	-0.9384
0.3203	0.1999	-0.2893
0.3303	0.4500	-0.7718
0.3403	0.1499	-0.1656
0.3501	0.3247	-0.6017
0.3599	0.5500	-1.0042
0.3603	0.1001	-0.0013
0.3604	0.3999	-0.7698
0.3683	0.0801	0.0818
0.3763	0.0601	0.1739
0.3804	0.0499	0.2245
0.3843	0.0400	0.2736
0.3904	0.3499	-0.7490
0.3924	0.0199	0.4091
0.3999	0.5000	-1.0517
0.4000	0.2998	-0.6543
0.4205	0.2999	-0.7097
0.4399	0.4500	-1.0781
0.4500	0.2748	-0.6895
0.4504	0.2501	-0.6299
0.4798	0.4001	-1.0817
0.4804	0.2001	-0.5119
0.5000	0.2498	-0.7159
0.5105	0.1500	-0.3649
0.5199	0.3500	-1.0611
0.5399	0.1011	-0.1729
0.5405	0.1001	-0.1650
0.5499	0.2249	-0.7250
0.5599	0.2999	-1.0094
0.5706	0.0500	0.0886
0.5999	0.1999	-0.7186
0.5999	0.2500	-0.9262
0.6398	0.2000	-0.8053
0.6500	0.1749	-0.6956
0.6799	0.1499	-0.6420
0.6999	0.1499	-0.6553
0.7198	0.1000	-0.4387
0.7357	0.0801	-0.3320
0.7499	0.1249	-0.5977
0.7517	0.0601	-0.2211
0.7598	0.0500	-0.1490
0.7678	0.0400	-0.0866
0.7839	0.0199	0.0630
0.7999	0.1000	-0.5211
0.8500	0.0749	-0.4249
0.9000	0.0500	-0.3074
0.9499	0.0250	-0.1615
0.9499	0.0250	-0.1504

Excess molar volume, m3/mol [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101.325 (Liquid)

Fixed		Measured
Mole fraction of 1-Butanol (3) - Liquid	Mole fraction of Triethylamine (2) - Liquid	Excess molar volume, m3/mol - Liquid
0.0000	0.5005	7.7000e-08
0.0099	0.9506	-6.9000e-08
0.0197	0.9507	-1.4300e-07
0.0204	0.8980	-1.3400e-07
0.0273	0.9546	-2.0900e-07
0.0299	0.8504	-1.8900e-07
0.0383	0.9521	-2.8500e-07
0.0393	0.9017	-2.7500e-07
0.0405	0.7973	-2.5300e-07
0.0504	0.7475	-3.0900e-07
0.0509	0.4750	-2.6200e-07
0.0573	0.9045	-4.1000e-07
0.0595	0.7018	-3.6200e-07
0.0609	0.8477	-4.1000e-07
0.0691	0.6539	-4.0900e-07
0.0780	0.9026	-5.4500e-07
0.0795	0.6019	-4.6000e-07
0.0812	0.7969	-5.3200e-07
0.0816	0.5912	-4.7100e-07
0.0884	0.8529	-6.0800e-07
0.0895	0.5518	-5.0500e-07
0.0978	0.4515	-5.1900e-07
0.0987	0.5060	-5.4200e-07
0.1043	0.7392	-6.5900e-07
0.1096	0.4513	-5.7900e-07
0.1181	0.8524	-7.8900e-07
0.1196	0.8010	-7.7600e-07
0.1200	0.3993	-6.0600e-07
0.1213	0.6966	-7.4400e-07
0.1293	0.3525	-6.2700e-07
0.1390	0.3041	-6.3100e-07
0.1409	0.6478	-8.3200e-07
0.1460	0.4274	-7.4400e-07
0.1490	0.7520	-9.3800e-07
0.1494	0.2521	-6.2100e-07
0.1575	0.8033	-1.0070e-06
0.1588	0.6028	-9.0700e-07
0.1596	0.2008	-5.7800e-07
0.1690	0.1535	-5.0600e-07
0.1798	0.7006	-1.0710e-06
0.1801	0.0983	-3.6800e-07
0.1802	0.5493	-9.8600e-07
0.1895	0.0511	-1.8200e-07
0.1957	0.7556	-1.1890e-06
0.1964	0.4022	-9.3700e-07
0.1984	0.5040	-1.0400e-06
0.1997	0.0000	1.3700e-07
0.2005	0.4986	-1.0450e-06
0.2103	0.6500	-1.1930e-06
0.2217	0.4456	-1.0800e-06
0.2378	0.7030	-1.3590e-06
0.2390	0.6022	-1.2910e-06
0.2393	0.4016	-1.1040e-06
0.2502	0.3753	-1.1000e-06
0.2610	0.3474	-1.1010e-06
0.2655	0.5581	-1.3690e-06
0.2777	0.3055	-1.0830e-06
0.2787	0.6519	-1.5160e-06
0.2799	0.6505	-1.5090e-06
0.2979	0.5041	-1.4380e-06
0.2982	0.2542	-1.0290e-06
0.3094	0.3456	-1.2350e-06
0.3204	0.5998	-1.6310e-06
0.3211	0.1971	-9.2100e-07
0.3325	0.4466	-1.4770e-06
0.3383	0.1539	-8.0000e-07
0.3523	0.3242	-1.3050e-06
0.3596	0.5509	-1.7140e-06
0.3609	0.0976	-5.6800e-07
0.3624	0.3969	-1.4850e-06
0.3818	0.0453	-2.7200e-07
0.3897	0.3514	-1.4650e-06
0.3978	0.3014	-1.3550e-06
0.3997	0.5008	-1.7720e-06
0.3999	0.0000	8.9000e-08
0.4172	0.3056	-1.4210e-06
0.4367	0.4546	-1.7990e-06
0.4487	0.2759	-1.3850e-06
0.4502	0.2506	-1.3210e-06
0.4777	0.4034	-1.7900e-06
0.4780	0.2043	-1.1960e-06
0.5042	0.2481	-1.3860e-06
0.5101	0.1510	-9.9900e-07
0.5121	0.1477	-9.8200e-07
0.5208	0.3495	-1.7480e-06
0.5394	0.1022	-7.5700e-07
0.5556	0.2224	-1.3540e-06
0.5600	0.3006	-1.6630e-06
0.5686	0.0536	-4.5300e-07
0.5994	0.2005	-1.3030e-06
0.6008	0.0000	-1.4000e-08
0.6019	0.2482	-1.5250e-06
0.6422	0.1979	-1.3440e-06
0.6491	0.1756	-1.2240e-06
0.6799	0.1509	-1.1230e-06
0.7029	0.1487	-1.1090e-06
0.7242	0.0955	-8.0400e-07
0.7496	0.1253	-9.8700e-07
0.7626	0.0476	-4.6500e-07
0.8006	0.0998	-8.2900e-07
0.8007	0.0000	-5.8000e-08
0.8530	0.0736	-6.4200e-07
0.9008	0.0496	-4.5100e-07
0.9532	0.0234	-2.2100e-07

Excess molar volume, m3/mol [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101.325 (Liquid)

Fixed		Measured
Mole fraction of 1-Butanol (3) - Liquid	Mole fraction of Triethylamine (2) - Liquid	Excess molar volume, m3/mol - Liquid
0.0000	0.5005	7.7000e-08
0.0099	0.9506	-6.9000e-08
0.0197	0.9507	-1.4300e-07
0.0204	0.8980	-1.3400e-07
0.0273	0.9546	-2.0900e-07
0.0299	0.8504	-1.8900e-07
0.0383	0.9521	-2.8500e-07
0.0393	0.9017	-2.7500e-07
0.0405	0.7973	-2.5300e-07
0.0504	0.7475	-3.0900e-07
0.0509	0.4750	-2.6200e-07
0.0573	0.9045	-4.1000e-07
0.0595	0.7018	-3.6200e-07
0.0609	0.8477	-4.1000e-07
0.0691	0.6539	-4.0900e-07
0.0780	0.9026	-5.4500e-07
0.0795	0.6019	-4.6000e-07
0.0812	0.7969	-5.3200e-07
0.0816	0.5912	-4.7100e-07
0.0884	0.8529	-6.0800e-07
0.0895	0.5518	-5.0500e-07
0.0978	0.4515	-5.1900e-07
0.0987	0.5060	-5.4200e-07
0.1043	0.7392	-6.5900e-07
0.1096	0.4513	-5.7900e-07
0.1181	0.8524	-7.8900e-07
0.1196	0.8010	-7.7600e-07
0.1200	0.3993	-6.0600e-07
0.1213	0.6966	-7.4400e-07
0.1293	0.3525	-6.2700e-07
0.1390	0.3041	-6.3100e-07
0.1409	0.6478	-8.3200e-07
0.1460	0.4274	-7.4400e-07
0.1490	0.7520	-9.3800e-07
0.1494	0.2521	-6.2100e-07
0.1575	0.8033	-1.0070e-06
0.1588	0.6028	-9.0700e-07
0.1596	0.2008	-5.7800e-07
0.1690	0.1535	-5.0600e-07
0.1798	0.7006	-1.0710e-06
0.1801	0.0983	-3.6800e-07
0.1802	0.5493	-9.8600e-07
0.1895	0.0511	-1.8200e-07
0.1957	0.7556	-1.1890e-06
0.1964	0.4022	-9.3700e-07
0.1984	0.5040	-1.0400e-06
0.1997	0.0000	1.3700e-07
0.2005	0.4986	-1.0450e-06
0.2103	0.6500	-1.1930e-06
0.2217	0.4456	-1.0800e-06
0.2378	0.7030	-1.3590e-06
0.2390	0.6022	-1.2910e-06
0.2393	0.4016	-1.1040e-06
0.2502	0.3753	-1.1000e-06
0.2610	0.3474	-1.1010e-06
0.2655	0.5581	-1.3690e-06
0.2777	0.3055	-1.0830e-06
0.2787	0.6519	-1.5160e-06
0.2799	0.6505	-1.5090e-06
0.2979	0.5041	-1.4380e-06
0.2982	0.2542	-1.0290e-06
0.3094	0.3456	-1.2350e-06
0.3204	0.5998	-1.6310e-06
0.3211	0.1971	-9.2100e-07
0.3325	0.4466	-1.4770e-06
0.3383	0.1539	-8.0000e-07
0.3523	0.3242	-1.3050e-06
0.3596	0.5509	-1.7140e-06
0.3609	0.0976	-5.6800e-07
0.3624	0.3969	-1.4850e-06
0.3818	0.0453	-2.7200e-07
0.3897	0.3514	-1.4650e-06
0.3978	0.3014	-1.3550e-06
0.3997	0.5008	-1.7720e-06
0.3999	0.0000	8.9000e-08
0.4172	0.3056	-1.4210e-06
0.4367	0.4546	-1.7990e-06
0.4487	0.2759	-1.3850e-06
0.4502	0.2506	-1.3210e-06
0.4777	0.4034	-1.7900e-06
0.4780	0.2043	-1.1960e-06
0.5042	0.2481	-1.3860e-06
0.5101	0.1510	-9.9900e-07
0.5121	0.1477	-9.8200e-07
0.5208	0.3495	-1.7480e-06
0.5394	0.1022	-7.5700e-07
0.5556	0.2224	-1.3540e-06
0.5600	0.3006	-1.6630e-06
0.5686	0.0536	-4.5300e-07
0.5994	0.2005	-1.3030e-06
0.6008	0.0000	-1.4000e-08
0.6019	0.2482	-1.5250e-06
0.6422	0.1979	-1.3440e-06
0.6491	0.1756	-1.2240e-06
0.6799	0.1509	-1.1230e-06
0.7029	0.1487	-1.1090e-06
0.7242	0.0955	-8.0400e-07
0.7496	0.1253	-9.8700e-07
0.7626	0.0476	-4.6500e-07
0.8006	0.0998	-8.2900e-07
0.8007	0.0000	-5.8000e-08
0.8530	0.0736	-6.4200e-07
0.9008	0.0496	-4.5100e-07
0.9532	0.0234	-2.2100e-07

Sources

• Excess molar volumes and excess molar enthalpies of binary and ternary mixtures of (ethanol or 1-butanol), triethylamine and n-hexane