Mixture of n-Hexane + Ethanol + Triethylamine

Datasets

1. Excess molar enthalpy (molar enthalpy (2)
2. Excess molar volume, m3/mol (2)

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101.325 (Liquid)

Fixed		Measured
Mole fraction of Ethanol (2) - Liquid	Mole fraction of Triethylamine (3) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.0177	0.9115	-0.0239
0.0293	0.8540	-0.0516
0.0401	0.9001	-0.0715
0.0406	0.7975	-0.0676
0.0463	0.9227	-0.1020
0.0517	0.7421	-0.0844
0.0560	0.4656	0.0087
0.0571	0.7148	-0.0944
0.0679	0.6609	-0.1163
0.0732	0.6344	-0.1129
0.0781	0.8055	-0.1568
0.0785	0.6081	-0.0906
0.0889	0.5562	-0.1166
0.0904	0.7750	-0.1820
0.0991	0.5052	-0.1334
0.1076	0.8657	-0.2931
0.1085	0.4397	-0.0791
0.1091	0.4552	-0.1270
0.1110	0.8147	-0.2213
0.1142	0.7156	-0.2276
0.1190	0.4060	-0.1260
0.1258	0.6867	-0.2503
0.1287	0.3577	-0.1207
0.1382	0.3103	-0.1196
0.1475	0.2636	-0.0632
0.1512	0.7475	-0.3064
0.1567	0.2178	-0.0320
0.1579	0.4153	-0.1617
0.1595	0.6028	-0.2942
0.1612	0.1952	-0.0070
0.1657	0.1728	0.0242
0.1702	0.1505	0.0560
0.1705	0.7153	-0.3571
0.1720	0.7853	-0.4485
0.1746	0.1285	0.0894
0.1790	0.1066	0.1423
0.1811	0.5491	-0.3209
0.1876	0.0634	0.2561
0.2020	0.4971	-0.3287
0.2045	0.3924	-0.2464
0.2076	0.6532	-0.4376
0.2222	0.4468	-0.3171
0.2314	0.7113	-0.5922
0.2320	0.4222	-0.3076
0.2418	0.3980	-0.3017
0.2429	0.5944	-0.4858
0.2484	0.3707	-0.3179
0.2608	0.3507	-0.2792
0.2764	0.5384	-0.5325
0.2792	0.3048	-0.2452
0.2899	0.3503	-0.3843
0.2925	0.5114	-0.5514
0.2971	0.2602	-0.1975
0.3121	0.6105	-0.7144
0.3229	0.1958	-0.0961
0.3237	0.4593	-0.5749
0.3292	0.3309	-0.4320
0.3313	0.1750	-0.0545
0.3477	0.1342	0.0447
0.3534	0.4097	-0.5882
0.3557	0.1142	0.1019
0.3611	0.5494	-0.7762
0.3636	0.0945	0.1533
0.3678	0.3857	-0.6091
0.3714	0.0751	0.2338
0.3791	0.0559	0.2979
0.3818	0.3623	-0.5944
0.3843	0.5204	-0.8059
0.4018	0.2951	-0.4794
0.4067	0.4925	-0.8379
0.4089	0.3170	-0.5612
0.4283	0.4655	-0.8617
0.4349	0.2737	-0.4968
0.4474	0.2527	-0.4784
0.4718	0.2121	-0.3634
0.4890	0.3897	-0.9029
0.4951	0.1731	-0.2583
0.4978	0.2477	-0.5439
0.5175	0.1357	-0.1805
0.5263	0.3432	-0.8935
0.5283	0.1175	-0.1164
0.5494	0.0823	0.0790
0.5547	0.2196	-0.5567
0.5780	0.2786	-0.8154
0.5796	0.0320	0.3058
0.6066	0.1940	-0.5601
0.6100	0.2387	-0.7524
0.6402	0.2010	-0.6529
0.6824	0.1483	-0.4826
0.6982	0.1489	-0.5362
0.7087	0.1155	-0.3505
0.7213	0.0998	-0.2762
0.7456	0.0695	-0.1163
0.7573	0.0549	-0.0289
0.7579	0.1194	-0.4659
0.7687	0.0406	0.0631
0.7798	0.0268	0.1587
0.7940	0.1016	-0.4349
0.8277	0.0850	-0.3690
0.8591	0.0695	-0.3129
0.8885	0.0550	-0.2710
0.9160	0.0414	-0.1971
0.9418	0.0287	-0.1464
0.9661	0.0167	-0.0792

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101.325 (Liquid)

Fixed		Measured
Mole fraction of Ethanol (2) - Liquid	Mole fraction of Triethylamine (3) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.0177	0.9115	-0.0239
0.0293	0.8540	-0.0516
0.0401	0.9001	-0.0715
0.0406	0.7975	-0.0676
0.0463	0.9227	-0.1020
0.0517	0.7421	-0.0844
0.0560	0.4656	0.0087
0.0571	0.7148	-0.0944
0.0679	0.6609	-0.1163
0.0732	0.6344	-0.1129
0.0781	0.8055	-0.1568
0.0785	0.6081	-0.0906
0.0889	0.5562	-0.1166
0.0904	0.7750	-0.1820
0.0991	0.5052	-0.1334
0.1076	0.8657	-0.2931
0.1085	0.4397	-0.0791
0.1091	0.4552	-0.1270
0.1110	0.8147	-0.2213
0.1142	0.7156	-0.2276
0.1190	0.4060	-0.1260
0.1258	0.6867	-0.2503
0.1287	0.3577	-0.1207
0.1382	0.3103	-0.1196
0.1475	0.2636	-0.0632
0.1512	0.7475	-0.3064
0.1567	0.2178	-0.0320
0.1579	0.4153	-0.1617
0.1595	0.6028	-0.2942
0.1612	0.1952	-0.0070
0.1657	0.1728	0.0242
0.1702	0.1505	0.0560
0.1705	0.7153	-0.3571
0.1720	0.7853	-0.4485
0.1746	0.1285	0.0894
0.1790	0.1066	0.1423
0.1811	0.5491	-0.3209
0.1876	0.0634	0.2561
0.2020	0.4971	-0.3287
0.2045	0.3924	-0.2464
0.2076	0.6532	-0.4376
0.2222	0.4468	-0.3171
0.2314	0.7113	-0.5922
0.2320	0.4222	-0.3076
0.2418	0.3980	-0.3017
0.2429	0.5944	-0.4858
0.2484	0.3707	-0.3179
0.2608	0.3507	-0.2792
0.2764	0.5384	-0.5325
0.2792	0.3048	-0.2452
0.2899	0.3503	-0.3843
0.2925	0.5114	-0.5514
0.2971	0.2602	-0.1975
0.3121	0.6105	-0.7144
0.3229	0.1958	-0.0961
0.3237	0.4593	-0.5749
0.3292	0.3309	-0.4320
0.3313	0.1750	-0.0545
0.3477	0.1342	0.0447
0.3534	0.4097	-0.5882
0.3557	0.1142	0.1019
0.3611	0.5494	-0.7762
0.3636	0.0945	0.1533
0.3678	0.3857	-0.6091
0.3714	0.0751	0.2338
0.3791	0.0559	0.2979
0.3818	0.3623	-0.5944
0.3843	0.5204	-0.8059
0.4018	0.2951	-0.4794
0.4067	0.4925	-0.8379
0.4089	0.3170	-0.5612
0.4283	0.4655	-0.8617
0.4349	0.2737	-0.4968
0.4474	0.2527	-0.4784
0.4718	0.2121	-0.3634
0.4890	0.3897	-0.9029
0.4951	0.1731	-0.2583
0.4978	0.2477	-0.5439
0.5175	0.1357	-0.1805
0.5263	0.3432	-0.8935
0.5283	0.1175	-0.1164
0.5494	0.0823	0.0790
0.5547	0.2196	-0.5567
0.5780	0.2786	-0.8154
0.5796	0.0320	0.3058
0.6066	0.1940	-0.5601
0.6100	0.2387	-0.7524
0.6402	0.2010	-0.6529
0.6824	0.1483	-0.4826
0.6982	0.1489	-0.5362
0.7087	0.1155	-0.3505
0.7213	0.0998	-0.2762
0.7456	0.0695	-0.1163
0.7573	0.0549	-0.0289
0.7579	0.1194	-0.4659
0.7687	0.0406	0.0631
0.7798	0.0268	0.1587
0.7940	0.1016	-0.4349
0.8277	0.0850	-0.3690
0.8591	0.0695	-0.3129
0.8885	0.0550	-0.2710
0.9160	0.0414	-0.1971
0.9418	0.0287	-0.1464
0.9661	0.0167	-0.0792

Excess molar volume, m3/mol [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101.325 (Liquid)

Fixed		Measured
Mole fraction of Ethanol (2) - Liquid	Mole fraction of Triethylamine (3) - Liquid	Excess molar volume, m3/mol - Liquid
0.0000	0.5000	7.2000e-08
0.0050	0.9749	-3.0000e-08
0.0194	0.9513	-1.2200e-07
0.0202	0.8989	-1.0800e-07
0.0275	0.9543	-1.6900e-07
0.0294	0.8527	-1.6100e-07
0.0341	0.9574	-2.1800e-07
0.0398	0.8009	-2.0900e-07
0.0402	0.8990	-2.4300e-07
0.0493	0.7530	-2.5400e-07
0.0543	0.4728	-2.1800e-07
0.0574	0.9046	-3.4500e-07
0.0584	0.8535	-3.4000e-07
0.0599	0.7002	-2.9900e-07
0.0687	0.6560	-3.3800e-07
0.0713	0.9109	-4.3500e-07
0.0791	0.8016	-4.4500e-07
0.0799	0.6001	-3.7600e-07
0.0881	0.8535	-5.1300e-07
0.0903	0.8499	-5.2500e-07
0.0910	0.5445	-4.0800e-07
0.0996	0.7500	-5.4100e-07
0.1003	0.4498	-4.2000e-07
0.1007	0.4958	-4.3500e-07
0.1099	0.4497	-4.5400e-07
0.1131	0.8588	-6.6100e-07
0.1188	0.7018	-6.2400e-07
0.1207	0.3958	-4.7000e-07
0.1213	0.7983	-6.7600e-07
0.1304	0.3474	-4.7200e-07
0.1396	0.3012	-4.6100e-07
0.1406	0.6471	-7.0200e-07
0.1491	0.2534	-4.2900e-07
0.1503	0.7501	-8.0100e-07
0.1516	0.8107	-8.4300e-07
0.1548	0.4226	-6.2300e-07
0.1596	0.5994	-7.6000e-07
0.1598	0.1998	-3.7700e-07
0.1698	0.1502	-2.9200e-07
0.1777	0.5540	-8.1200e-07
0.1785	0.7032	-9.1400e-07
0.1798	0.0997	-1.5800e-07
0.1874	0.0618	-1.3000e-08
0.1875	0.0614	-1.1000e-08
0.1929	0.0344	1.2500e-07
0.1929	0.7592	-1.0230e-06
0.1950	0.4025	-7.4300e-07
0.1965	0.5068	-8.4500e-07
0.1998	0.0000	3.5400e-07
0.2110	0.6493	-1.0230e-06
0.2172	0.4549	-8.7200e-07
0.2383	0.4020	-8.7800e-07
0.2387	0.6032	-1.1010e-06
0.2392	0.7014	-1.1930e-06
0.2395	0.3990	-8.8300e-07
0.2504	0.3748	-8.7600e-07
0.2601	0.3474	-8.5800e-07
0.2699	0.5512	-1.1690e-06
0.2739	0.6580	-1.3040e-06
0.2785	0.3011	-8.1600e-07
0.2988	0.3506	-9.6700e-07
0.3000	0.2470	-7.3600e-07
0.3005	0.5005	-1.2130e-06
0.3056	0.3472	-9.7800e-07
0.3192	0.1988	-6.2800e-07
0.3195	0.6011	-1.4190e-06
0.3317	0.4486	-1.2400e-06
0.3398	0.1473	-4.6700e-07
0.3437	0.3282	-1.0240e-06
0.3454	0.5687	-1.4710e-06
0.3600	0.0966	-2.4600e-07
0.3614	0.5488	-1.5000e-06
0.3650	0.3933	-1.2300e-06
0.3697	0.0722	-1.1700e-07
0.3783	0.0506	1.9000e-08
0.3893	0.0230	2.1300e-07
0.3929	0.3467	-1.1920e-06
0.3940	0.5080	-1.5400e-06
0.3985	0.0000	4.0900e-07
0.4021	0.2989	-1.0770e-06
0.4213	0.2996	-1.1240e-06
0.4331	0.4592	-1.5610e-06
0.4447	0.2777	-1.0950e-06
0.4529	0.2470	-1.0070e-06
0.4783	0.4029	-1.5500e-06
0.4794	0.4014	-1.5560e-06
0.4833	0.1965	-8.4300e-07
0.4970	0.2515	-1.0940e-06
0.5125	0.1479	-6.4100e-07
0.5219	0.3484	-1.5010e-06
0.5424	0.0983	-3.7100e-07
0.5518	0.2241	-1.0700e-06
0.5578	0.0727	-2.1600e-07
0.5593	0.3017	-1.4170e-06
0.5710	0.0507	-4.7000e-08
0.5878	0.0229	1.6500e-07
0.5983	0.2530	-1.2880e-06
0.6005	0.1997	-1.0260e-06
0.6015	0.0000	3.8100e-07
0.6395	0.2015	-1.0990e-06
0.6503	0.1748	-9.6000e-07
0.6812	0.1495	-8.4800e-07
0.7049	0.1475	-8.6300e-07
0.7209	0.0999	-5.5000e-07
0.7428	0.1286	-7.8200e-07
0.7618	0.0488	-1.7100e-07
0.7982	0.1009	-6.4400e-07
0.8009	0.0000	2.7000e-07
0.8488	0.0756	-5.0000e-07
0.9031	0.0484	-3.2900e-07
0.9521	0.0240	-1.6600e-07

Excess molar volume, m3/mol [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101.325 (Liquid)

Fixed		Measured
Mole fraction of Ethanol (2) - Liquid	Mole fraction of Triethylamine (3) - Liquid	Excess molar volume, m3/mol - Liquid
0.0000	0.5000	7.2000e-08
0.0050	0.9749	-3.0000e-08
0.0194	0.9513	-1.2200e-07
0.0202	0.8989	-1.0800e-07
0.0275	0.9543	-1.6900e-07
0.0294	0.8527	-1.6100e-07
0.0341	0.9574	-2.1800e-07
0.0398	0.8009	-2.0900e-07
0.0402	0.8990	-2.4300e-07
0.0493	0.7530	-2.5400e-07
0.0543	0.4728	-2.1800e-07
0.0574	0.9046	-3.4500e-07
0.0584	0.8535	-3.4000e-07
0.0599	0.7002	-2.9900e-07
0.0687	0.6560	-3.3800e-07
0.0713	0.9109	-4.3500e-07
0.0791	0.8016	-4.4500e-07
0.0799	0.6001	-3.7600e-07
0.0881	0.8535	-5.1300e-07
0.0903	0.8499	-5.2500e-07
0.0910	0.5445	-4.0800e-07
0.0996	0.7500	-5.4100e-07
0.1003	0.4498	-4.2000e-07
0.1007	0.4958	-4.3500e-07
0.1099	0.4497	-4.5400e-07
0.1131	0.8588	-6.6100e-07
0.1188	0.7018	-6.2400e-07
0.1207	0.3958	-4.7000e-07
0.1213	0.7983	-6.7600e-07
0.1304	0.3474	-4.7200e-07
0.1396	0.3012	-4.6100e-07
0.1406	0.6471	-7.0200e-07
0.1491	0.2534	-4.2900e-07
0.1503	0.7501	-8.0100e-07
0.1516	0.8107	-8.4300e-07
0.1548	0.4226	-6.2300e-07
0.1596	0.5994	-7.6000e-07
0.1598	0.1998	-3.7700e-07
0.1698	0.1502	-2.9200e-07
0.1777	0.5540	-8.1200e-07
0.1785	0.7032	-9.1400e-07
0.1798	0.0997	-1.5800e-07
0.1874	0.0618	-1.3000e-08
0.1875	0.0614	-1.1000e-08
0.1929	0.0344	1.2500e-07
0.1929	0.7592	-1.0230e-06
0.1950	0.4025	-7.4300e-07
0.1965	0.5068	-8.4500e-07
0.1998	0.0000	3.5400e-07
0.2110	0.6493	-1.0230e-06
0.2172	0.4549	-8.7200e-07
0.2383	0.4020	-8.7800e-07
0.2387	0.6032	-1.1010e-06
0.2392	0.7014	-1.1930e-06
0.2395	0.3990	-8.8300e-07
0.2504	0.3748	-8.7600e-07
0.2601	0.3474	-8.5800e-07
0.2699	0.5512	-1.1690e-06
0.2739	0.6580	-1.3040e-06
0.2785	0.3011	-8.1600e-07
0.2988	0.3506	-9.6700e-07
0.3000	0.2470	-7.3600e-07
0.3005	0.5005	-1.2130e-06
0.3056	0.3472	-9.7800e-07
0.3192	0.1988	-6.2800e-07
0.3195	0.6011	-1.4190e-06
0.3317	0.4486	-1.2400e-06
0.3398	0.1473	-4.6700e-07
0.3437	0.3282	-1.0240e-06
0.3454	0.5687	-1.4710e-06
0.3600	0.0966	-2.4600e-07
0.3614	0.5488	-1.5000e-06
0.3650	0.3933	-1.2300e-06
0.3697	0.0722	-1.1700e-07
0.3783	0.0506	1.9000e-08
0.3893	0.0230	2.1300e-07
0.3929	0.3467	-1.1920e-06
0.3940	0.5080	-1.5400e-06
0.3985	0.0000	4.0900e-07
0.4021	0.2989	-1.0770e-06
0.4213	0.2996	-1.1240e-06
0.4331	0.4592	-1.5610e-06
0.4447	0.2777	-1.0950e-06
0.4529	0.2470	-1.0070e-06
0.4783	0.4029	-1.5500e-06
0.4794	0.4014	-1.5560e-06
0.4833	0.1965	-8.4300e-07
0.4970	0.2515	-1.0940e-06
0.5125	0.1479	-6.4100e-07
0.5219	0.3484	-1.5010e-06
0.5424	0.0983	-3.7100e-07
0.5518	0.2241	-1.0700e-06
0.5578	0.0727	-2.1600e-07
0.5593	0.3017	-1.4170e-06
0.5710	0.0507	-4.7000e-08
0.5878	0.0229	1.6500e-07
0.5983	0.2530	-1.2880e-06
0.6005	0.1997	-1.0260e-06
0.6015	0.0000	3.8100e-07
0.6395	0.2015	-1.0990e-06
0.6503	0.1748	-9.6000e-07
0.6812	0.1495	-8.4800e-07
0.7049	0.1475	-8.6300e-07
0.7209	0.0999	-5.5000e-07
0.7428	0.1286	-7.8200e-07
0.7618	0.0488	-1.7100e-07
0.7982	0.1009	-6.4400e-07
0.8009	0.0000	2.7000e-07
0.8488	0.0756	-5.0000e-07
0.9031	0.0484	-3.2900e-07
0.9521	0.0240	-1.6600e-07

Sources

• Excess molar volumes and excess molar enthalpies of binary and ternary mixtures of (ethanol or 1-butanol), triethylamine and n-hexane