Datasets
-
Excess molar enthalpy (molar enthalpy (2)
-
Tboil - Boiling temperature at pressure P, K (2)
-
Vapor Liquid Equilibrium at Constant Pressure
-
Vapor Liquid Equilibrium at Constant Temperature (2)
-
Excess molar volume, m3/mol (2)
Excess molar enthalpy (molar enthalpy of mixing), kJ/mol
[ref]
Operational conditions:
- Temperature, K = 308.15 (Liquid)
- Pressure, kPa = 101.3 (Liquid)
Mole fraction of Acetic acid, butyl ester (1) - Liquid |
Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid |
0.1409 |
0.8169 |
0.1975 |
1.0714 |
0.2672 |
1.2865 |
0.3389 |
1.3921 |
0.4035 |
1.3858 |
0.4961 |
1.2542 |
0.5517 |
1.1201 |
0.6466 |
0.8582 |
0.7965 |
0.4704 |
0.8311 |
0.3962 |
0.9061 |
0.2364 |
Excess molar enthalpy (molar enthalpy of mixing), kJ/mol
[ref]
Operational conditions:
- Temperature, K = 308.15 (Liquid)
- Pressure, kPa = 101.3 (Liquid)
Mole fraction of Acetic acid, butyl ester (1) - Liquid |
Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid |
0.1409 |
0.8169 |
0.1975 |
1.0714 |
0.2672 |
1.2865 |
0.3389 |
1.3921 |
0.4035 |
1.3858 |
0.4961 |
1.2542 |
0.5517 |
1.1201 |
0.6466 |
0.8582 |
0.7965 |
0.4704 |
0.8311 |
0.3962 |
0.9061 |
0.2364 |
Boiling temperature at pressure P, K
[ref]
Fixed |
Measured |
Pressure, kPa - Liquid |
Mole fraction of Acetic acid, butyl ester (1) - Liquid |
Boiling temperature at pressure P, K - Liquid |
29.77 |
0.0000 |
317.95 |
29.77 |
0.0375 |
318.45 |
29.77 |
0.0769 |
319.05 |
29.77 |
0.1219 |
319.80 |
29.77 |
0.1664 |
320.60 |
29.77 |
0.2125 |
321.35 |
29.77 |
0.2570 |
322.15 |
29.77 |
0.2954 |
323.20 |
29.77 |
0.3539 |
324.25 |
29.77 |
0.4081 |
325.45 |
29.77 |
0.4544 |
326.75 |
29.77 |
0.4949 |
327.85 |
29.77 |
0.5512 |
330.20 |
29.77 |
0.6079 |
331.75 |
29.77 |
0.6622 |
334.25 |
29.77 |
0.7040 |
336.75 |
29.77 |
0.7590 |
339.40 |
29.77 |
0.8006 |
342.65 |
29.77 |
0.8442 |
346.05 |
29.77 |
0.8956 |
350.20 |
29.77 |
0.9425 |
354.85 |
29.77 |
1.0000 |
361.65 |
58.85 |
0.0000 |
336.85 |
58.85 |
0.0375 |
337.65 |
58.85 |
0.0769 |
338.35 |
58.85 |
0.1219 |
339.20 |
58.85 |
0.1664 |
340.05 |
58.85 |
0.2125 |
340.95 |
58.85 |
0.2570 |
341.85 |
58.85 |
0.2954 |
342.65 |
58.85 |
0.3539 |
344.00 |
58.85 |
0.4081 |
345.45 |
58.85 |
0.4544 |
346.90 |
58.85 |
0.4949 |
348.20 |
58.85 |
0.5512 |
350.65 |
58.85 |
0.6079 |
352.40 |
58.85 |
0.6622 |
354.85 |
58.85 |
0.7040 |
357.40 |
58.85 |
0.7590 |
360.50 |
58.85 |
0.8006 |
363.20 |
58.85 |
0.8442 |
366.90 |
58.85 |
0.8956 |
370.70 |
58.85 |
0.9425 |
375.55 |
58.85 |
1.0000 |
381.35 |
87.65 |
0.0000 |
349.15 |
87.65 |
0.0375 |
350.25 |
87.65 |
0.0769 |
351.00 |
87.65 |
0.1219 |
351.85 |
87.65 |
0.1664 |
352.75 |
87.65 |
0.2125 |
353.55 |
87.65 |
0.2570 |
354.55 |
87.65 |
0.2954 |
355.55 |
87.65 |
0.3539 |
356.85 |
87.65 |
0.4081 |
358.30 |
87.65 |
0.4544 |
359.90 |
87.65 |
0.4949 |
361.15 |
87.65 |
0.5512 |
363.65 |
87.65 |
0.6079 |
365.65 |
87.65 |
0.6622 |
367.85 |
87.65 |
0.7040 |
370.45 |
87.65 |
0.7590 |
374.75 |
87.65 |
0.8006 |
377.50 |
87.65 |
0.8442 |
380.95 |
87.65 |
0.8956 |
384.55 |
87.65 |
0.9425 |
388.55 |
87.65 |
1.0000 |
394.25 |
Boiling temperature at pressure P, K
[ref]
Fixed |
Measured |
Pressure, kPa - Liquid |
Mole fraction of Acetic acid, butyl ester (1) - Liquid |
Boiling temperature at pressure P, K - Liquid |
29.77 |
0.0000 |
317.95 |
29.77 |
0.0375 |
318.45 |
29.77 |
0.0769 |
319.05 |
29.77 |
0.1219 |
319.80 |
29.77 |
0.1664 |
320.60 |
29.77 |
0.2125 |
321.35 |
29.77 |
0.2570 |
322.15 |
29.77 |
0.2954 |
323.20 |
29.77 |
0.3539 |
324.25 |
29.77 |
0.4081 |
325.45 |
29.77 |
0.4544 |
326.75 |
29.77 |
0.4949 |
327.85 |
29.77 |
0.5512 |
330.20 |
29.77 |
0.6079 |
331.75 |
29.77 |
0.6622 |
334.25 |
29.77 |
0.7040 |
336.75 |
29.77 |
0.7590 |
339.40 |
29.77 |
0.8006 |
342.65 |
29.77 |
0.8442 |
346.05 |
29.77 |
0.8956 |
350.20 |
29.77 |
0.9425 |
354.85 |
29.77 |
1.0000 |
361.65 |
58.85 |
0.0000 |
336.85 |
58.85 |
0.0375 |
337.65 |
58.85 |
0.0769 |
338.35 |
58.85 |
0.1219 |
339.20 |
58.85 |
0.1664 |
340.05 |
58.85 |
0.2125 |
340.95 |
58.85 |
0.2570 |
341.85 |
58.85 |
0.2954 |
342.65 |
58.85 |
0.3539 |
344.00 |
58.85 |
0.4081 |
345.45 |
58.85 |
0.4544 |
346.90 |
58.85 |
0.4949 |
348.20 |
58.85 |
0.5512 |
350.65 |
58.85 |
0.6079 |
352.40 |
58.85 |
0.6622 |
354.85 |
58.85 |
0.7040 |
357.40 |
58.85 |
0.7590 |
360.50 |
58.85 |
0.8006 |
363.20 |
58.85 |
0.8442 |
366.90 |
58.85 |
0.8956 |
370.70 |
58.85 |
0.9425 |
375.55 |
58.85 |
1.0000 |
381.35 |
87.65 |
0.0000 |
349.15 |
87.65 |
0.0375 |
350.25 |
87.65 |
0.0769 |
351.00 |
87.65 |
0.1219 |
351.85 |
87.65 |
0.1664 |
352.75 |
87.65 |
0.2125 |
353.55 |
87.65 |
0.2570 |
354.55 |
87.65 |
0.2954 |
355.55 |
87.65 |
0.3539 |
356.85 |
87.65 |
0.4081 |
358.30 |
87.65 |
0.4544 |
359.90 |
87.65 |
0.4949 |
361.15 |
87.65 |
0.5512 |
363.65 |
87.65 |
0.6079 |
365.65 |
87.65 |
0.6622 |
367.85 |
87.65 |
0.7040 |
370.45 |
87.65 |
0.7590 |
374.75 |
87.65 |
0.8006 |
377.50 |
87.65 |
0.8442 |
380.95 |
87.65 |
0.8956 |
384.55 |
87.65 |
0.9425 |
388.55 |
87.65 |
1.0000 |
394.25 |
Vapor Liquid Equilibrium at Constant Pressure
[ref]
Operational condition: Pressure, kPa =
101.33 (VLE)
Fixed |
Measured |
T [K] - VLE |
x1[mol/mol] of Cyclohexane (2) - Liquid |
y1[mol/mol] of Cyclohexane (2) - Vapour |
396.65 |
0.0230 |
0.1020 |
390.05 |
0.0850 |
0.3090 |
384.25 |
0.1520 |
0.4640 |
378.45 |
0.2370 |
0.6020 |
373.75 |
0.3230 |
0.6880 |
370.35 |
0.3830 |
0.7450 |
368.15 |
0.4410 |
0.7770 |
363.55 |
0.5780 |
0.8420 |
360.75 |
0.6870 |
0.8860 |
357.85 |
0.8100 |
0.9280 |
357.75 |
0.8260 |
0.9340 |
355.25 |
0.9430 |
0.9750 |
Vapor Liquid Equilibrium at Constant Temperature
[ref]
Operational condition: Temperature, K =
335 (VLE)
Fixed |
Measured |
P [kPa] - VLE |
x1[mol/mol] of Cyclohexane (2) - Liquid |
y1[mol/mol] of Cyclohexane (2) - Vapour |
9.895 |
0.0000 |
0.0000 |
16.136 |
0.0768 |
0.4149 |
21.793 |
0.1608 |
0.6052 |
22.12 |
0.1656 |
0.6137 |
27.694 |
0.2575 |
0.7211 |
30.656 |
0.3154 |
0.7652 |
35.834 |
0.4265 |
0.8235 |
40.423 |
0.5389 |
0.8640 |
44.454 |
0.6553 |
0.8979 |
48.055 |
0.7693 |
0.9276 |
51.316 |
0.8737 |
0.9565 |
53.644 |
0.9518 |
0.9810 |
54.727 |
0.9850 |
0.9930 |
55.195 |
1.0000 |
1.0000 |
Vapor Liquid Equilibrium at Constant Temperature
[ref]
Operational condition: Temperature, K =
350 (VLE)
Fixed |
Measured |
P [kPa] - VLE |
x1[mol/mol] of Cyclohexane (2) - Liquid |
y1[mol/mol] of Cyclohexane (2) - Vapour |
18.94 |
0.0000 |
0.0000 |
29.071 |
0.0816 |
0.3890 |
38.358 |
0.1728 |
0.5825 |
47.283 |
0.2700 |
0.6988 |
50.968 |
0.3187 |
0.7333 |
59.336 |
0.4342 |
0.8036 |
66.892 |
0.5478 |
0.8488 |
73.289 |
0.6627 |
0.8866 |
78.923 |
0.7787 |
0.9207 |
83.81 |
0.8771 |
0.9516 |
87.662 |
0.9532 |
0.9795 |
89.33 |
0.9852 |
0.9923 |
89.99 |
1.0000 |
1.0000 |
Excess molar volume, m3/mol
[ref]
Operational conditions:
- Temperature, K = 308.15 (Liquid)
- Pressure, kPa = 101.3 (Liquid)
Mole fraction of Acetic acid, butyl ester (1) - Liquid |
Excess molar volume, m3/mol - Liquid |
0.1062 |
3.4700e-07 |
0.1575 |
4.3500e-07 |
0.2230 |
5.2100e-07 |
0.3004 |
6.0400e-07 |
0.4851 |
6.7400e-07 |
0.4863 |
6.8500e-07 |
0.5412 |
6.5400e-07 |
0.6489 |
6.0700e-07 |
0.7350 |
4.9800e-07 |
0.7661 |
4.0600e-07 |
0.8854 |
1.9500e-07 |
Excess molar volume, m3/mol
[ref]
Operational conditions:
- Temperature, K = 308.15 (Liquid)
- Pressure, kPa = 101.3 (Liquid)
Mole fraction of Acetic acid, butyl ester (1) - Liquid |
Excess molar volume, m3/mol - Liquid |
0.1062 |
3.4700e-07 |
0.1575 |
4.3500e-07 |
0.2230 |
5.2100e-07 |
0.3004 |
6.0400e-07 |
0.4851 |
6.7400e-07 |
0.4863 |
6.8500e-07 |
0.5412 |
6.5400e-07 |
0.6489 |
6.0700e-07 |
0.7350 |
4.9800e-07 |
0.7661 |
4.0600e-07 |
0.8854 |
1.9500e-07 |
Sources