Mixture of 1-Butanol + Ethyl Acetate

Datasets

1. Mole fraction (2)
2. η - Viscosity, Pa*s (2)
3. ρ_l - Mass density, kg/m3 (6)
4. T_boil - Boiling temperature at pressure P, K (2)
5. Vapor Liquid Equilibrium at Constant Pressure (3)

Mole fraction of Ethyl Acetate (2) [ref]

Operational condition: Pressure, kPa = 300 (Liquid)

Mole fraction of Ethyl Acetate (2) - Liquid	Mole fraction of Ethyl Acetate (2) - Gas
0.0000	0.0000
0.0390	0.1570
0.1040	0.2990
0.1490	0.3720
0.2100	0.4730
0.2350	0.5170
0.3410	0.6450
0.3720	0.6740
0.4520	0.7440
0.4770	0.7630
0.5560	0.8060
0.6180	0.8440
0.7350	0.8930
0.7780	0.9000
0.8260	0.9160
0.8580	0.9270
0.8960	0.9400
0.9440	0.9670
0.9660	0.9810
0.9830	0.9930
0.9890	0.9960
1.0000	1.0000

Mole fraction of Ethyl Acetate (2) [ref]

Operational condition: Pressure, kPa = 300 (Liquid)

Mole fraction of Ethyl Acetate (2) - Liquid	Mole fraction of Ethyl Acetate (2) - Gas
0.0000	0.0000
0.0390	0.1570
0.1040	0.2990
0.1490	0.3720
0.2100	0.4730
0.2350	0.5170
0.3410	0.6450
0.3720	0.6740
0.4520	0.7440
0.4770	0.7630
0.5560	0.8060
0.6180	0.8440
0.7350	0.8930
0.7780	0.9000
0.8260	0.9160
0.8580	0.9270
0.8960	0.9400
0.9440	0.9670
0.9660	0.9810
0.9830	0.9930
0.9890	0.9960
1.0000	1.0000

Viscosity, Pa*s [ref]

Operational conditions:

• Temperature, K = 303.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Mole fraction of 1-Butanol (1) - Liquid	Viscosity, Pa*s - Liquid
0.1411	0.0005
0.3184	0.0006
0.3797	0.0006
0.4659	0.0007
0.5634	0.0008
0.6782	0.0009
0.7595	0.0011
0.8312	0.0013
0.9291	0.0017

Viscosity, Pa*s [ref]

Operational conditions:

• Temperature, K = 303.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Mole fraction of 1-Butanol (1) - Liquid	Viscosity, Pa*s - Liquid
0.1411	0.0005
0.3184	0.0006
0.3797	0.0006
0.4659	0.0007
0.5634	0.0008
0.6782	0.0009
0.7595	0.0011
0.8312	0.0013
0.9291	0.0017

Mass density, kg/m3 [ref]

Operational conditions:

• Pressure, kPa = 101 (Liquid)
• Temperature, K = 298.15 (Liquid)

Mole fraction of Ethyl Acetate (2) - Liquid	Mass density, kg/m3 - Liquid
0.0000	805.9
0.0589	810.8
0.0898	813.4
0.1537	818.8
0.1810	821.2
0.2553	827.6
0.2999	831.5
0.3496	835.8
0.3987	840.1
0.4498	844.6
0.5037	849.4
0.5476	853.3
0.6025	858.2
0.6560	863.0
0.6928	866.3
0.7384	870.4
0.7995	876.0
0.8486	880.4
0.8901	884.2
0.9522	890.0
1.0000	894.6

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of 1-Butanol (1) - Liquid	Mass density, kg/m3 - Liquid
298.15	0.0904	886.5
298.15	0.1337	882.3
298.15	0.2525	871.5
298.15	0.3723	860.7
298.15	0.4807	851.0
298.15	0.5955	840.9
298.15	0.7032	831.5
298.15	0.8009	823.0
298.15	0.8916	815.1
298.15	0.9641	808.6
298.15	0.9795	807.3
303.15	0.0904	880.4
303.15	0.1337	876.8
303.15	0.2525	866.7
303.15	0.3723	856.6
303.15	0.4807	847.5
303.15	0.5955	838.0
303.15	0.7032	828.8
303.15	0.8009	820.6
303.15	0.8916	813.0
303.15	0.9641	806.7
303.15	0.9795	805.3
313.15	0.0904	869.6
313.15	0.1337	866.0
313.15	0.2525	856.6
313.15	0.3723	846.8
313.15	0.4807	838.0
313.15	0.5955	828.8
313.15	0.7032	820.1
313.15	0.8009	812.3
313.15	0.8916	805.0
313.15	0.9641	799.4
313.15	0.9795	798.1

Mass density, kg/m3 [ref]

Operational conditions:

• Temperature, K = 303.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Mole fraction of 1-Butanol (1) - Liquid	Mass density, kg/m3 - Liquid
0.1411	875.69
0.3184	859.95
0.3797	854.67
0.4659	847.1
0.5634	838.65
0.6782	828.8
0.7595	821.86
0.8312	815.82
0.9291	807.64

Mass density, kg/m3 [ref]

Operational conditions:

• Pressure, kPa = 101 (Liquid)
• Temperature, K = 298.15 (Liquid)

Mole fraction of Ethyl Acetate (2) - Liquid	Mass density, kg/m3 - Liquid
0.0000	805.9
0.0589	810.8
0.0898	813.4
0.1537	818.8
0.1810	821.2
0.2553	827.6
0.2999	831.5
0.3496	835.8
0.3987	840.1
0.4498	844.6
0.5037	849.4
0.5476	853.3
0.6025	858.2
0.6560	863.0
0.6928	866.3
0.7384	870.4
0.7995	876.0
0.8486	880.4
0.8901	884.2
0.9522	890.0
1.0000	894.6

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of 1-Butanol (1) - Liquid	Mass density, kg/m3 - Liquid
298.15	0.0904	886.5
298.15	0.1337	882.3
298.15	0.2525	871.5
298.15	0.3723	860.7
298.15	0.4807	851.0
298.15	0.5955	840.9
298.15	0.7032	831.5
298.15	0.8009	823.0
298.15	0.8916	815.1
298.15	0.9641	808.6
298.15	0.9795	807.3
303.15	0.0904	880.4
303.15	0.1337	876.8
303.15	0.2525	866.7
303.15	0.3723	856.6
303.15	0.4807	847.5
303.15	0.5955	838.0
303.15	0.7032	828.8
303.15	0.8009	820.6
303.15	0.8916	813.0
303.15	0.9641	806.7
303.15	0.9795	805.3
313.15	0.0904	869.6
313.15	0.1337	866.0
313.15	0.2525	856.6
313.15	0.3723	846.8
313.15	0.4807	838.0
313.15	0.5955	828.8
313.15	0.7032	820.1
313.15	0.8009	812.3
313.15	0.8916	805.0
313.15	0.9641	799.4
313.15	0.9795	798.1

Mass density, kg/m3 [ref]

Operational conditions:

• Temperature, K = 303.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Mole fraction of 1-Butanol (1) - Liquid	Mass density, kg/m3 - Liquid
0.1411	875.69
0.3184	859.95
0.3797	854.67
0.4659	847.1
0.5634	838.65
0.6782	828.8
0.7595	821.86
0.8312	815.82
0.9291	807.64

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 300 (Liquid)

Mole fraction of Ethyl Acetate (2) - Liquid	Boiling temperature at pressure P, K - Liquid
0.0000	425.39
0.0390	421.19
0.1040	416.53
0.1490	414.22
0.2100	410.89
0.2350	409.30
0.3410	404.23
0.3720	402.96
0.4520	399.72
0.4770	398.78
0.5560	396.66
0.6180	394.79
0.7350	392.47
0.7780	392.11
0.8260	391.26
0.8580	390.67
0.8960	389.86
0.9440	388.81
0.9660	388.22
0.9830	388.06
0.9890	388.02
1.0000	387.95

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 300 (Liquid)

Mole fraction of Ethyl Acetate (2) - Liquid	Boiling temperature at pressure P, K - Liquid
0.0000	425.39
0.0390	421.19
0.1040	416.53
0.1490	414.22
0.2100	410.89
0.2350	409.30
0.3410	404.23
0.3720	402.96
0.4520	399.72
0.4770	398.78
0.5560	396.66
0.6180	394.79
0.7350	392.47
0.7780	392.11
0.8260	391.26
0.8580	390.67
0.8960	389.86
0.9440	388.81
0.9660	388.22
0.9830	388.06
0.9890	388.02
1.0000	387.95

Vapor Liquid Equilibrium at Constant Pressure [ref]

Operational condition: Pressure, kPa = 97.33 (VLE)

Fixed	Measured
T [K] - VLE	x1[mol/mol] of Ethyl Acetate (2) - Liquid	y1[mol/mol] of Ethyl Acetate (2) - Vapour
384.15	0.0460	0.2221
380.75	0.0815	0.3428
378.65	0.1050	0.4074
373.75	0.1695	0.5400
369.7	0.2310	0.6292
368.7	0.2405	0.6410
366.6	0.2840	0.6877
365.15	0.3145	0.7147
362.0	0.3965	0.7762
360.75	0.4310	0.7943
359.15	0.4990	0.8279
357.75	0.5485	0.8487
356.35	0.6020	0.8710
355.15	0.6515	0.8867
353.85	0.7170	0.9076
352.75	0.7735	0.9249
351.7	0.8250	0.9410
350.45	0.8910	0.9603

Vapor Liquid Equilibrium at Constant Pressure [ref]

Operational condition: Pressure, kPa = 101.33 (VLE)

T [K] - VLE	x1[mol/mol] of Ethyl Acetate (2) - Liquid
390.85	0.0000
383.15	0.0855
377.05	0.1738
371.65	0.2650
367.75	0.3593
363.55	0.4569
360.05	0.5579
357.05	0.6625
354.55	0.7709
352.35	0.8833

Vapor Liquid Equilibrium at Constant Pressure [ref]

Operational condition: Pressure, kPa = 101.33 (VLE)

Fixed	Measured
T [K] - VLE	x1[mol/mol] of Ethyl Acetate (2) - Liquid	y1[mol/mol] of Ethyl Acetate (2) - Vapour
384.65	0.0493	0.2750
381.15	0.0827	0.3200
378.15	0.1240	0.4170
376.45	0.1310	0.4540
371.05	0.2380	0.6080
366.45	0.3250	0.6950
362.65	0.3940	0.7520
361.15	0.4570	0.7930
359.85	0.5470	0.8350
358.35	0.6130	0.8520
356.65	0.6800	0.8830
355.35	0.7540	0.9060
354.55	0.7790	0.9160
353.25	0.8430	0.9430
352.45	0.8820	0.9580
351.75	0.9060	0.9670
350.25	1.0000	1.0000

Sources

• Dortmund Data Bank Vapor-Liquid Equilibrium Data
• Experimental Determination of Densities and Isobaric Vapor Liquid Equilibria of Methyl Acetate and Ethyl Acetate with Alcohols (C3 and C4) at 0.3 MPa
• Volumetric properties of ternary (IL + 2-propanol or 1-butanol or 2-butanol + ethyl acetate) systems and binary (IL + 2-propanol or 1-butanol or 2-butanol) and (1-butanol or 2-butanol + ethyl acetate) systems
• Volumetric and transport properties of ternary mixtures containing 1-alkanol + ethyl ethanoate + cyclohexane at 303.15 K: Experimental data, correlation and prediction by ERAS model