Chemical Properties of Carbonic acid, dimethyl ester (CAS 616-38-6)

Carbonic acid, dimethyl ester

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InChI
InChI=1S/C3H6O3/c1-5-3(4)6-2/h1-2H3
InChI Key
IEJIGPNLZYLLBP-UHFFFAOYSA-N
Formula
C3H6O3
SMILES
COC(=O)OC
Molecular Weight1
90.08
CAS
616-38-6
Other Names
  • CH3OCOOCH3
  • Dimethyl carbonate
  • Dimethyl ester of carbonic acid
  • Methyl carbonate
  • Methyl carbonate ((MeO)2CO)
  • UN 1161
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Contents

  1. Physical Properties
  2. Temperature Dependent Properties
  3. Datasets
  4. Similar Compounds
  5. Mixtures
  6. Sources

Physical Properties

Property Value Unit Source
PAff 830.20 kJ/mol NIST
BasG 799.20 kJ/mol NIST
Δf -364.54 kJ/mol Joback Calculated Property
Δfgas -482.27 kJ/mol Joback Calculated Property
Δfus 7.50 kJ/mol Joback Calculated Property
Δvap [37.70; 38.00] kJ/mol Show Hide
Δvap 38.00 ± 0.20 kJ/mol NIST
Δvap 37.70 ± 0.20 kJ/mol NIST
IE [11.00; 11.20] eV Show Hide
IE 11.00 eV NIST
IE 11.20 eV NIST
IE 11.00 eV NIST
log10WS -5.89e-03 Crippen Calculated Property
logPoct/wat 0.399 Crippen Calculated Property
McVol 66.440 ml/mol McGowan Calculated Property
Pc [4800.00; 4800.00] kPa Show Hide
Pc 4800.00 ± 150.00 kPa NIST
Pc 4800.00 ± 300.00 kPa NIST
ρc [342.30; 357.61] kg/m3 Show Hide
ρc 357.61 ± 9.91 kg/m3 NIST
ρc 342.30 ± 15.31 kg/m3 NIST
Inp 620.00 NIST
Tboil [337.84; 363.70] K Show Hide
Tboil 363.46 K VLE of ...
Tboil Outlier 337.84 K Measure...
Tboil 363.35 K Vapour-...
Tboil 363.36 K Measure...
Tboil 363.46 K Densiti...
Tboil 363.46 K Measure...
Tboil 363.25 K Isobari...
Tboil 363.41 K Organic...
Tboil 363.60 ± 0.10 K NIST
Tboil 363.70 K NIST
Tboil 363.00 K NIST
Tboil 363.60 ± 0.40 K NIST
Tboil 363.60 ± 0.30 K NIST
Tboil 363.40 ± 0.40 K NIST
Tboil 363.50 ± 0.50 K NIST
Tboil 363.50 ± 0.50 K NIST
Tboil 363.50 ± 0.50 K NIST
Tc [557.00; 557.00] K Show Hide
Tc 557.00 ± 2.00 K NIST
Tc 557.00 ± 2.00 K NIST
Tfus [267.55; 278.20] K Show Hide
Tfus 278.16 K Solid-l...
Tfus 278.20 K The sol...
Tfus 277.06 K Efficie...
Tfus 277.57 K Vapor P...
Tfus 278.16 K Solid-L...
Tfus Outlier 267.55 ± 0.50 K NIST
Vc 0.245 m3/kmol Joback Calculated Property

Temperature Dependent Properties

Property Value Unit Temperature (K) Source
Cp,gas [116.81; 146.98] J/mol×K [366.75; 547.10] Show Hide
Cp,gas 116.81 J/mol×K 366.75 Joback Calculated Property
Cp,gas 121.94 J/mol×K 396.81 Joback Calculated Property
Cp,gas 127.04 J/mol×K 426.87 Joback Calculated Property
Cp,gas 132.12 J/mol×K 456.93 Joback Calculated Property
Cp,gas 137.14 J/mol×K 486.99 Joback Calculated Property
Cp,gas 142.10 J/mol×K 517.05 Joback Calculated Property
Cp,gas 146.98 J/mol×K 547.10 Joback Calculated Property
Cp,liquid [153.20; 173.68] J/mol×K [288.15; 333.15] Show Hide
Cp,liquid 153.20 J/mol×K 288.15 Excess ...
Cp,liquid 165.51 J/mol×K 288.15 Densiti...
Cp,liquid 164.03 J/mol×K 288.15 Thermod...
Cp,liquid 163.61 J/mol×K 288.15 Isobari...
Cp,liquid 156.10 J/mol×K 293.15 Excess ...
Cp,liquid 166.07 J/mol×K 293.15 Densiti...
Cp,liquid 165.02 J/mol×K 298.15 Thermod...
Cp,liquid 164.65 J/mol×K 298.15 Isobari...
Cp,liquid 157.90 J/mol×K 298.15 Excess ...
Cp,liquid 167.10 J/mol×K 298.15 Densiti...
Cp,liquid 159.80 J/mol×K 303.15 Excess ...
Cp,liquid 168.48 J/mol×K 303.15 Densiti...
Cp,liquid 161.70 J/mol×K 308.15 Excess ...
Cp,liquid 166.30 J/mol×K 308.15 Thermod...
Cp,liquid 169.72 J/mol×K 308.15 Densiti...
Cp,liquid 165.92 J/mol×K 308.15 Isobari...
Cp,liquid 170.83 J/mol×K 313.15 Densiti...
Cp,liquid 162.90 J/mol×K 313.15 Excess ...
Cp,liquid 163.00 J/mol×K 318.15 Excess ...
Cp,liquid 172.18 J/mol×K 318.15 Densiti...
Cp,liquid 163.60 J/mol×K 323.15 Excess ...
Cp,liquid 173.68 J/mol×K 323.15 Densiti...
Cp,liquid 163.80 J/mol×K 328.15 Excess ...
Cp,liquid 164.80 J/mol×K 333.15 Excess ...
η [0.0003527; 0.0006230] Pa×s [293.15; 343.15] Show Hide
η 0.0006230 Pa×s 293.15 Dynamic...
η 0.0006230 Pa×s 293.15 Density...
η 0.0006163 Pa×s 293.15 Excess ...
η 0.0006173 Pa×s 293.15 Excess ...
η 0.0005771 Pa×s 298.15 Excess ...
η 0.0005840 Pa×s 298.15 Dynamic...
η 0.0005734 Pa×s 298.15 Excess ...
η 0.0005840 Pa×s 298.15 Density...
η 0.0005490 Pa×s 303.15 Density...
η 0.0005403 Pa×s 303.15 Excess ...
η 0.0005490 Pa×s 303.15 Dynamic...
η 0.0005433 Pa×s 303.15 Excess ...
η 0.0005170 Pa×s 308.15 Density...
η 0.0004807 Pa×s 313.15 Excess ...
η 0.0004880 Pa×s 313.15 Dynamic...
η 0.0004820 Pa×s 313.15 Excess ...
η 0.0004880 Pa×s 313.15 Density...
η 0.0004270 Pa×s 323.15 Excess ...
η 0.0004319 Pa×s 323.15 Excess ...
η 0.0003893 Pa×s 333.15 Excess ...
η 0.0003527 Pa×s 343.15 Excess ...
ΔfusH 11.58 kJ/mol 278.20 NIST
ΔvapH 36.40 kJ/mol 368.50 NIST
Pvap [1.92; 566.47] kPa [274.20; 428.15] Show Hide
Pvap 1.92 kPa 274.20 Vapour ...
Pvap 1.98 kPa 275.00 Vapour ...
Pvap 2.14 kPa 276.00 Vapour ...
Pvap 2.28 kPa 276.90 Vapour ...
Pvap 2.43 kPa 277.90 Vapour ...
Pvap 2.30 kPa 277.96 Low pre...
Pvap 2.84 kPa 280.70 Vapour ...
Pvap 3.12 kPa 282.06 Low pre...
Pvap 3.27 kPa 283.20 Vapour ...
Pvap 3.85 kPa 285.80 Vapour ...
Pvap 4.02 kPa 286.15 Low pre...
Pvap 4.42 kPa 288.20 Vapour ...
Pvap 4.86 kPa 290.25 Low pre...
Pvap 4.98 kPa 290.80 Vapour ...
Pvap 10.00 kPa 293.00 Vapor-L...
Pvap 5.71 kPa 293.10 Vapour ...
Pvap 6.31 kPa 294.35 Low pre...
Pvap 6.72 kPa 295.70 Vapour ...
Pvap 6.98 kPa 298.15 Low pre...
Pvap 7.57 kPa 298.30 Vapour ...
Pvap 8.55 kPa 300.70 Vapour ...
Pvap 9.72 kPa 302.54 Low pre...
Pvap 9.68 kPa 303.20 Vapour ...
Pvap 9.98 kPa 304.10 Vapour ...
Pvap 11.70 kPa 306.64 Low pre...
Pvap 14.02 kPa 310.74 Low pre...
Pvap 20.00 kPa 313.00 Vapor-L...
Pvap 19.82 kPa 318.15 Low pre...
Pvap 23.07 kPa 323.15 Low pre...
Pvap 41.02 kPa 337.35 Measure...
Pvap 70.00 kPa 353.00 Vapor-L...
Pvap 101.32 kPa 363.25 Isobari...
Pvap 101.30 kPa 363.35 Vapour-...
Pvap 101.30 kPa 363.36 Measure...
Pvap 101.32 kPa 363.41 Organic...
Pvap 140.00 kPa 373.00 Vapor-L...
Pvap 154.63 kPa 377.15 Measure...
Pvap 229.39 kPa 391.15 Measure...
Pvap 382.50 kPa 411.15 Measure...
Pvap 566.47 kPa 428.15 Measure...
n0 [1.35370; 1.36720]   [298.15; 298.15] Show Hide
n0 1.36720 298.15 Liquid ...
n0 1.36654 298.15 Isother...
n0 1.36654 298.15 Isother...
n0 1.36640 298.15 Propert...
n0 1.36640 298.15 Vapor-L...
n0 1.36640 298.15 Isobari...
n0 1.35370 298.15 Bubble ...
n0 1.36600 298.15 Viscosi...
n0 1.36647 298.15 Isother...
ρl [1016.32; 1076.43] kg/m3 [288.15; 333.15] Show Hide
ρl 1076.43 kg/m3 288.15 Permitt...
ρl 1076.39 kg/m3 288.15 Excess ...
ρl 1069.86 kg/m3 293.15 Excess ...
ρl 1069.83 kg/m3 293.15 Volumet...
ρl 1069.80 kg/m3 293.15 Densiti...
ρl 1069.92 kg/m3 293.15 Density...
ρl 1069.60 kg/m3 293.15 Densiti...
ρl 1069.70 kg/m3 293.15 Density...
ρl 1069.95 kg/m3 293.15 Permitt...
ρl 1069.79 kg/m3 293.15 Density...
ρl 1063.10 kg/m3 298.15 Excess ...
ρl 1063.40 kg/m3 298.15 Vapor p...
ρl 1063.26 kg/m3 298.15 Liquid ...
ρl 1063.38 kg/m3 298.15 Ebullio...
ρl 1063.26 kg/m3 298.15 Permitt...
ρl 1062.80 kg/m3 298.15 Densiti...
ρl 1063.34 kg/m3 298.15 Density...
ρl 1070.00 kg/m3 298.15 Low pre...
ρl 1063.24 kg/m3 298.15 Isother...
ρl 1063.26 kg/m3 298.15 Solid-l...
ρl 1060.87 kg/m3 298.15 Solid-l...
ρl 1063.20 kg/m3 298.15 Densiti...
ρl 1063.30 kg/m3 298.15 Isobari...
ρl 1063.26 kg/m3 298.15 Ternary...
ρl 1063.25 kg/m3 298.15 Volumet...
ρl 1063.10 kg/m3 298.15 Excess ...
ρl 1063.19 kg/m3 298.15 Measure...
ρl 1062.97 kg/m3 298.15 Densiti...
ρl 1063.50 kg/m3 298.15 Viscosi...
ρl 1063.35 kg/m3 298.15 Excess ...
ρl 1063.26 kg/m3 298.15 Isobari...
ρl 1063.10 kg/m3 298.15 Density...
ρl 1063.29 kg/m3 298.15 Separat...
ρl 1063.27 kg/m3 298.15 Excess ...
ρl 1061.90 kg/m3 298.20 Liquid ...
ρl 1061.90 kg/m3 298.20 Liquid ...
ρl 1056.40 kg/m3 303.15 Density...
ρl 1056.50 kg/m3 303.15 Densiti...
ρl 1056.80 kg/m3 303.15 Investi...
ρl 1056.75 kg/m3 303.15 Density...
ρl 1056.72 kg/m3 303.15 Density...
ρl 1056.63 kg/m3 303.15 Volumet...
ρl 1056.65 kg/m3 303.15 Excess ...
ρl 1056.20 kg/m3 303.15 Densiti...
ρl 1056.61 kg/m3 303.15 Permitt...
ρl 1050.01 kg/m3 308.15 Permitt...
ρl 1050.08 kg/m3 308.15 Volumet...
ρl 1049.80 kg/m3 308.15 Densiti...
ρl 1049.70 kg/m3 308.15 Density...
ρl 1050.07 kg/m3 308.15 Density...
ρl 1050.00 kg/m3 308.15 Excess ...
ρl 1049.80 kg/m3 308.15 Densiti...
ρl 1050.20 kg/m3 308.15 Investi...
ρl 1043.37 kg/m3 313.15 Density...
ρl 1043.00 kg/m3 313.15 Densiti...
ρl 1043.29 kg/m3 313.15 Excess ...
ρl 1043.10 kg/m3 313.15 Density...
ρl 1043.39 kg/m3 313.15 Density...
ρl 1043.19 kg/m3 313.15 Densiti...
ρl 1043.50 kg/m3 313.15 Investi...
ρl 1042.50 kg/m3 313.15 Densiti...
ρl 1043.44 kg/m3 313.15 Volumet...
ρl 1044.63 kg/m3 313.15 Densiti...
ρl 1036.69 kg/m3 318.15 Density...
ρl 1036.57 kg/m3 318.15 Excess ...
ρl 1036.80 kg/m3 318.15 Investi...
ρl 1036.62 kg/m3 318.15 Volumet...
ρl 1036.40 kg/m3 318.15 Density...
ρl 1035.60 kg/m3 318.15 Densiti...
ρl 1036.65 kg/m3 318.15 Permitt...
ρl 1029.83 kg/m3 323.15 Excess ...
ρl 1030.00 kg/m3 323.15 Investi...
ρl 1029.88 kg/m3 323.15 Volumet...
ρl 1029.94 kg/m3 323.15 Density...
ρl 1029.60 kg/m3 323.15 Density...
ρl 1028.40 kg/m3 323.15 Densiti...
ρl 1022.80 kg/m3 328.15 Density...
ρl 1023.25 kg/m3 328.15 Density...
ρl 1022.92 kg/m3 328.15 Permitt...
ρl 1023.03 kg/m3 328.15 Excess ...
ρl 1016.32 kg/m3 333.15 Density...
γ [0.03; 0.03] N/m [298.15; 308.15] Show Hide
γ 0.03 N/m 298.15 Analysi...
γ 0.03 N/m 308.15 Surface...

Datasets

  1. Refractive index (Na D-line) (1)
  2. Mass density, kg/m3 (3)

Refractive index (Na D-line)

Fixed Measured
Pressure, kPa - Liquid Temperature, K - Liquid Refractive index (Na D-line) - Liquid
93.00 298.15 1.3664
Reference

Mass density, kg/m3

Fixed Measured
Temperature, K - Liquid Pressure, kPa - Liquid Mass density, kg/m3 - Liquid
288.15 100.00 1076.5
288.15 5000.00 1080.6
288.15 10000.00 1084.8
288.15 20000.00 1092.8
288.15 30000.00 1100.3
288.15 40000.00 1107.5
298.15 100.00 1062.9
298.15 5000.00 1068.0
298.15 10000.00 1072.1
298.15 20000.00 1080.5
298.15 30000.00 1088.5
298.15 40000.00 1095.9
308.15 100.00 1049.4
308.15 5000.00 1054.6
308.15 10000.00 1059.4
308.15 20000.00 1068.3
308.15 30000.00 1076.7
308.15 40000.00 1084.5
Reference
Fixed Measured
Temperature, K - Liquid Pressure, kPa - Liquid Mass density, kg/m3 - Liquid
288.15 100.00 1076.83
288.15 5000.00 1081.15
288.15 10000.00 1085.32
288.15 15000.00 1089.52
288.15 20000.00 1093.35
288.15 25000.00 1096.99
288.15 30000.00 1100.63
288.15 35000.00 1104.08
288.15 40000.00 1107.4
293.15 100.00 1070.06
293.15 5000.00 1074.62
293.15 10000.00 1078.93
293.15 15000.00 1083.01
293.15 20000.00 1087.08
293.15 25000.00 1091.03
293.15 30000.00 1094.75
293.15 35000.00 1098.34
293.15 40000.00 1101.84
298.15 100.00 1063.45
298.15 5000.00 1068.0
298.15 10000.00 1072.51
298.15 15000.00 1076.72
298.15 20000.00 1080.9
298.15 25000.00 1084.89
298.15 30000.00 1088.82
298.15 35000.00 1092.44
298.15 40000.00 1096.04
303.15 100.00 1056.61
303.15 5000.00 1061.47
303.15 10000.00 1066.02
303.15 15000.00 1070.49
303.15 20000.00 1074.79
303.15 25000.00 1078.99
303.15 30000.00 1082.9
303.15 35000.00 1086.6
303.15 40000.00 1090.4
308.15 100.00 1049.91
308.15 5000.00 1054.84
308.15 10000.00 1059.69
308.15 15000.00 1064.3
308.15 20000.00 1068.73
308.15 25000.00 1073.0
308.15 30000.00 1077.1
308.15 35000.00 1080.78
308.15 40000.00 1084.38
Reference
Fixed Measured
Pressure, kPa - Liquid Temperature, K - Liquid Mass density, kg/m3 - Liquid
100.00 283.15 1083.17
100.00 288.15 1076.43
100.00 293.15 1069.76
100.00 298.15 1063.1
100.00 303.15 1056.41
100.00 308.15 1049.66
100.00 313.15 1042.86
100.00 318.15 1036.04
100.00 323.15 1029.21
100.00 328.15 1022.24
5000.00 283.15 1087.33
5000.00 288.15 1080.8
5000.00 293.15 1074.22
5000.00 298.15 1067.7
5000.00 303.15 1061.17
5000.00 308.15 1054.59
5000.00 313.15 1047.94
5000.00 318.15 1041.3
5000.00 323.15 1034.63
5000.00 328.15 1027.92
10000.00 283.15 1091.39
10000.00 288.15 1085.02
10000.00 293.15 1078.58
10000.00 298.15 1072.21
10000.00 303.15 1065.82
10000.00 308.15 1059.39
10000.00 313.15 1052.91
10000.00 318.15 1046.44
10000.00 323.15 1039.95
10000.00 328.15 1033.45
15000.00 283.15 1095.34
15000.00 288.15 1089.07
15000.00 293.15 1082.76
15000.00 298.15 1076.52
15000.00 303.15 1070.29
15000.00 308.15 1064.0
15000.00 313.15 1057.67
15000.00 318.15 1051.36
15000.00 323.15 1045.04
15000.00 328.15 1038.69
20000.00 283.15 1099.13
20000.00 288.15 1093.0
20000.00 293.15 1086.83
20000.00 298.15 1080.7
20000.00 303.15 1074.59
20000.00 308.15 1068.43
20000.00 313.15 1062.22
20000.00 318.15 1056.08
20000.00 323.15 1049.91
20000.00 328.15 1043.71
25000.00 283.15 1102.79
25000.00 288.15 1096.79
25000.00 293.15 1090.73
25000.00 298.15 1084.74
25000.00 303.15 1078.74
25000.00 308.15 1072.65
25000.00 313.15 1066.6
25000.00 318.15 1060.6
25000.00 323.15 1054.58
25000.00 328.15 1048.53
30000.00 283.15 1106.39
30000.00 288.15 1100.48
30000.00 293.15 1094.5
30000.00 298.15 1088.62
30000.00 303.15 1082.75
30000.00 308.15 1076.8
30000.00 313.15 1070.82
30000.00 318.15 1064.95
30000.00 323.15 1059.07
30000.00 328.15 1053.14
35000.00 283.15 1109.85
35000.00 288.15 1104.03
35000.00 293.15 1098.19
35000.00 298.15 1092.39
35000.00 303.15 1086.6
35000.00 308.15 1080.78
35000.00 313.15 1074.93
35000.00 318.15 1069.15
35000.00 323.15 1063.39
35000.00 328.15 1057.57
40000.00 283.15 1113.17
40000.00 288.15 1107.5
40000.00 293.15 1101.74
40000.00 298.15 1096.04
40000.00 303.15 1090.35
40000.00 308.15 1084.63
40000.00 313.15 1078.87
40000.00 318.15 1073.21
40000.00 323.15 1067.56
40000.00 328.15 1061.87
Reference

Similar Compounds

(CH3O)2CS. Tetramethyl orthocarbonate. Methylal. Methyl chloroformate. Methyl formate. Carbonic acid, ethyl-, methyl ester. Methane, trimethoxy-. Methoxycarbonylsulfenyl chloride. Diethyl carbonate. 1,3-Dioxolan-2-one. Carbonic acid, di(but-2-yn-1-yl) ester. Clorethate. (CD3)2O. Methyl radical, methoxy-. Dimethyl ether.

Find more compounds similar to Carbonic acid, dimethyl ester.

Mixtures

Find more mixtures with Carbonic acid, dimethyl ester.

Sources

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Outlier This icon means that the value is more than 2 standard deviations away from the property mean.